Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “HCl”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Antarctic stratospheric chemistry of chlorine nitrate, hydrogen chloride, and ice - Release of active chlorine

The reaction rate between atmospheric hydrogen chloride (HCl) and chlorine nitrate (ClONO2) is greatly enhanced in the presence of ice particles; HCl dissolves readily into ice, and the collisional reaction probability for ClONO2 on the surface of ice with HCl in the mole fraction range from about 0.003 to 0.010 is in the range from about 0.05 to 0.1 for temperatures near 200 K. Chlorine is released into the gas phase on a time scale of at most a few milliseconds, whereas nitric acid (HNO3), the other product, remains in the condensed phase. This reaction could play an important role in explaining the observed depletion of ozone over Antarctica; it releases photolytically active chlorine from its most abundant reservoir species, and it promotes the formation of HNO3 and thus removes nitrogen dioxide from the gas phase. Hence it establishes the necessary conditions for the efficient catalytic destruction of ozone by halogenated free radicals.

Molina, Mario J.↗
NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere

Laboratory studies of sticking coefficients of H2O, HCl, Cl2, and HNO3 on ice and heterogeneous reactions of ClONO2 with ice or HCl/ice have been performed in a fast flow reactor. A quadrupole mass spectrometer with electron impact ionization was used as a detector. Measured sticking coefficients are: 0.3 (+0.7, -0.1) for H2O, 0.4 (+0.6, -0.2) for HCL, less than 0.0001 for Cl2, and 0.3 (+0.7, -0.1) for HNO3 at 200 K. The reaction probability of ClONO2 on ice was found to be 0.06 (+ or - 0.03) while HOCl was observed as a sole product in the gas phase. With HCl present in ice, the reaction probability of ClONO2 is greatly enhanced, approaching 0.27 (+0.73, -0.13) while molecular chlorine was found to be the major product in the gas phase. Another reaction product was nitric acid which remained in the solid phase. Since the polar stratospheric clouds contain ice particles or possibly HCl/ice particles on the surface, the present results should be a major factor in producing the observed springtime ozone depletion in the Antarctic stratosphere.

Leu, Ming-Taun↗
NASA NTRS1988

Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures

The heterogeneous interactions of ClONO2, HCl, and HNO3 with sulfuric acid surfaces were studied using a Knudsen cell flow reactor. The surfaces studied, chosen to simulate global stratospheric particulate, were composed of 65-75 percent H2SO4 solutions at temperatures in the range -63 to -43 C. Heterogeneous loss, but not reaction, of HNO3 and HCl occurred on these surfaces; the measured sticking coefficients are reported. Chlorine nitrate reacted on the cold sulfuric acid surfaces, producing gas-phase HOCl and condensed HNO3. CLONO2 also reacted with HCl dissolved in the 65-percent H2SO4 solution at -63 C, forming gaseous Cl2. In all cases studied, the sticking and/or reaction coefficients were much larger for the 65-percent H2SO4 solution at -63 C than for the 75-percent solution at -43 C.

Tolbert, Margaret A.↗
NASA NTRS1989

Chemistry and transport in a three-dimensional stratospheric model - Chlorine species during a simulated stratospheric warming

The distributions in the stratosphere of a variety of chemical species were calculated for a 6-day period during the February 1979 stratospheric major warming, using winds derived from a spectral forecast model which included O(x), NO(x), HO(x), and ClO(x) chemistries as well as longitudinally varying reaction rate coefficients and photolysis rates for these molecules. The results obtained indicate a particular importance of chemistry and transport for the Cl-containing species ClO, ClONO2, HCl, and HOCl. Dynamical effects dominate the variability of HCl, while diurnal effects dominate that of ClONO2 and ClO. The effects of strong planetary wave activity may be seen in terms of large longitudinal variability of the total HCl and ClONO columns in the stratosphere; in the middle and high northern latitudes, it is sufficiently large to exceed the diurnal variability of the column.

Kaye, Jack A.↗
NASA NTRS1988

Quantification of several atmospheric gases from high resolution infrared solar spectra obtained at the South Pole in 1980 and 1986

High-resolution solar absorption spectra recorded at the Amundsen-Scott South Pole Station were analyzed to obtain total column amounts of O3, N2O, HNO3, CO2, CH4, and CF2Cl2, and to investigate the differences in the values obtained in December 1980 with those obtained in December 1986. In addition, vertical column amounts for HCl, NO, NO2, and C2H6 were derived for December 1986. One interesting feature of these results is that the total column amounts of HCl measured for several days at the South Pole (/6.4 + or - 0.8/ x 10 to the 15th molecules/sq cm) were high compared with the HCl column amounts reported for lower latitudes.

Goldman, Aaron↗
NASA NTRS1989

Infrared aircraft measurements of stratospheric composition over Antarctica during September 1987

The Jet Propulsion Laboratory Mark IV interferometer recorded high-resolution, infrared solar spectra from the NASA DC-8 aircraft during flights over Antarctica in September 1987. The atmospheric absorption features in these spectra have been analyzed to determine the burdens of O3, NO, NO2, HNO3, ClNO3, HCl, HF, CO2, CH4, N2O, HCN, CO, H2O, CFCl3, and CF2Cl2. The results show a 'collar' of high HNO3 and ClNO3 surrounding a 'core' in which the burdens of these and of HCl and NO2 are very low. Clear increases in the burdens of HF and HNO3 were observed during the course of September in the vortex core. HCl and NO2 exhibited smaller, less significant increases. The burdens of the tropospheric source gases, N2O, CH4, HCN, CFCl3, CF2Cl2, CO, and H2O, were observed to be much smaller over Antarctica than at midlatitudes. This, together with the fact that HF over Antarctica was more than double its midlatidue value, suggests that downwelling had occurred.

Toon, G. C.↗
NASA NTRS1989

Airborne measurements of stratospheric constituents over Antarctica in the austral spring, 1987. II - Halogen and nitrogen trace gases

The IR absorption spectra of the polar stratosphere, recorded by a Fourier transform spectrometer aboard the NASA DC-8 aircraft during the Airborne Antarctic Ozone Experiment, were used to derive vertical column amounts above flight altitude of HCl, HF, NO, NO2, ClONO2, and HNO3 in the region of disturbed ozone chemistry during September 1987. Significant reductions in the amounts of HCl, NO, NO2, and HNO3 were observed within the confines of the polar vortex, compared with amounts outside the vortex. When compared with the springtime observations by the same instrument in the Northern Hemisphere, the HCl and NO2 species displayed the most dramatic depletions. The results obtained are generally in agreement with the earlier ground measurements conducted at the McMurdo Station.

Coffey, M. T.↗
NASA NTRS1989

Laboratory chemistry and stratospheric clouds

Results are presented from laboratory experiments on the chemistry of ice particles to study the role of HCl and ClONO2 from CFCs in stratospheric ozone depletion over Antarctica. It is found that gaseous HCl is scavenged with high efficiency by the ice and the gas phase chlorine nitrate may react with the HCL-containing ice to produce Cl2. Also, consideration is given ot the behavior of solid nitric acid trihydrate and sulfuric acid aerosols.

Molina, Mario J.↗
NASA NTRS1989

El Chichon volcanic aerosols - Impact of radiative, thermal, and chemical perturbations

The impact of the March-April, 1982 eruption of El Chichon volcano on the earth's stratospheric chemistry is examined. Calculations, performed using a one-dimensional radiative transfer model, predict that total radiation increased by 8 percent within the aerosol layer longward of 3000 A. Consequently, changes in the photolysis rates were obtained with a photochemical model, which can in part explain the observed ozone changes; the results agree qualitatively with observations on other species, but fail to quantitatively account for the observed significant decreases in NO and NO2 and increases in HCl. A heterogeneous reaction, catalyzed by aerosol surfaces, which transforms ClNO3 into HCl is proposed, which would provide a pathway for sequestering NO(x) and at the same time reducing ClNO3 in favor of HCl.

Michelangeli, Diane V.↗
NASA NTRS1990

Effects of atmospheric transport on column abundances of nitrogen and chlorine compounds in the arctic stratosphere

In the absence of heterogeneous processes, distributions of NO(y), HNO3, Cl(x) and HCl in the polar winter stratosphere should be determined by transport. A model simulating distributions of these species in the arctic for January and February 1989 is developed using observed fields of potential vorticity and potential temperature. Comparison of model results with column measurements from the DC-8 indicates conversion of NO(x) to HNO3, condensation of HNO3, conversion of HCl to CINO3, and conversion of HCl plus CINO3 to an unmeasured species. Heterogeneous processes strongly affect abundances of NO(y) and Cl(x) species in the winter arctic stratosphere.

Yatteau, John H.↗
NASA NTRS1990

Heterogeneous chemistry on liquid sulfate aerosols - A comparison of in situ measurements with zero-dimensional model calculations

The possibility that stratospheric chlorine is converted from reservoir to reactive forms by heterogeneous reactions on background sulfate aerosols is examined. Tightly constrained photochemical models have been used to calculate ClO abundances for the morning and the afternoon conditions observed on January 24, 1989 outside the Arctic polar vortex by instruments on the NASA ER-2 aircraft. Calculations involving gas-phase chemistry only and calculations with heterogeneous chemistry including HCl evaporation from the aerosol both produce ClO abundances that agree with observations; calculations in which HCl removal from the aerosol is controlled by heterogeneous reactions produce ClO abundances that are 3 to 3.5 times larger than observations. These results suggest that HCl evaporation must be included in a model of the chemistry of background aerosols.

Mather, J. H.↗
NASA NTRS1991

The influence of polar heterogeneous processes on reactive chlorine at middle latitudes - Three dimensional model implications

Three-dimensional model calculations with the NASA/GSFC chemistry and transport model have been designed to consider the impact of heterogeneous processes occurring on polar stratospheric clouds (PSCs) in the Arctic vortex on the HCl distribution. By examining the HCl concentration for a calculation with PSCs relative to a calculation with gas phase chemistry only, the impact of polar processing on reactive chlorine species at middle latitudes is inferred. Results from the chemistry and transport model reproduce basic features of the ClO measurements (Toohey et al., 1991), which were made on the ferry flights of the ER-2 from Stavanger, Norway to Moffett Field, California via Wallops Island, Virginia on February 20 and 21, 1989. The model indicates that perturbed air which is contained within the polar vortex during winter is not homogeneously mixed, and that the ferry flights were made through air with the largest conversion of HCl to reactive chlorine that is seen at middle latitudes.

Douglass, Anne R.↗
NASA NTRS1991

Spatial and temporal variability of the extent of chemically processed stratospheric air

Simulations of the spatial and temporal variability of the extent of chemically processed air in the Arctic stratosphere have been carried out using a three-dimensional chemistry-transport model for the winters of 1979 and 1989. Chemically processed air is identified in the model as that in which the amounts of hydrogen chloride (HCl) calculated with parameterized loss for conditions appropriate to polar stratospheric cloud (PSC) formation are substantially smaller than those calculated in a model with gas phase chemistry only. It is seen that chemically processed air may be identified over much of the Arctic lower stratosphere from early January to late February, with HCl depletions being larger in 1989 than in 1979. Near the latitude of the Arctic circle, there is important spatial and temporal variability in the extent of chemically processed air. There is some evidence for transport to midlatitudes of processed air during these winters, but the HCl reductions are much smaller and more sporadic than those near the pole. At 62 and 42N, processed air is calculated to occur preferentially over the longitude regions from 60-120E and 270-330E.

Kaye, Jack A.↗
NASA NTRS1993

HALOE Antarctic observations in the spring of 1991

HALOE observations of O3, CH4, HF, H2O, NO, NO2, and HCl collected during the October 1991 Antarctic spring period are reported. The data show a constant CH4 mixing ratio of about 0.25 ppmv for the altitude range from 65 km down to about 25 km at the position of minimum wind speed in the vortex: i.e., the vortex center, and depressions in pressure versus longitude contours of NO, NO2, HF, and HCl in this same region. Water vapor, HF, and HCl enhancement are also observed in the vortex center region above about 25 km. Between 10 and 20 km, the expected mixing ratio signatures exist within the vortex, i.e., low ozone and dehydration. The water vapor increased by 50 percent, and the ozone level doubled inside the vortex between October 11 and 24 in the 15-20 km layer. These changes imply a time constant for recovery from ozone hole conditions of 19 and 30 days for O3 and H2O, respectively. The data further show the presence of air inside the vortex between 3 and 30 mb which has mixing ratios characteristic of midlatitudes.

Russell, James M., III↗
NASA NTRS1993

Heterogeneous chemistry on Antarctic polar stratospheric clouds - A microphysical estimate of the extent of chemical processing

A detailed model of polar stratospheric clouds (PSCs), which includes nucleation, condensational growth. and sedimentation processes, has been applied to the study of heterogeneous chemical reactions. For the first time, the extent of chemical processing during a polar winter has been estimated for an idealized air parcel in the Antarctic vortex by calculating in detail the rates of heterogeneous reactions on PSC particles. The resulting active chlorine and NO(x) concentrations at first sunrise are analyzed with respect to their influence upon the Antarctic ozone hole using a photochemical model. It is found that the species present at sunrise are primarily influenced by the relative values of the heterogeneous reaction rate constants and the initial gas concentrations. However, the extent of chlorine activation is also influenced by whether N2O5 is removed by reaction with HCl or H2O. The reaction of N2O5 with HCl, which occurs rapidly on type 1 PSCs, activates the chlorine contained in the reservoir species HCl. Hence the presence and surface area of type 1 PSCs early in the winter are crucial in determining ozone depletion.

Drdla, K.↗
NASA NTRS1993

Low temperature synthesis of monolithic transparent Ta2O5 gels from hydrolysis of metal alkoxide

Tantalum oxide gels in the form of transparent monoliths and powder were prepared from hydrolysis of tantalum pentaethoxide under controlled conditions using different mole ratios of Ta(OC2H5)5:C2H50H:H20:HCl. Alcohol acts as the mutual solvent and HCl as the deflocculating agent. For a fixed alkoxide:water:HCl ratio, time of gel formation increased with the alcohol to alkoxide mole ratio. Thermal evolution of the physical and structural changes in the gel was monitored by differential thermal analysis, thermogravimetric analysis, x-ray diffraction, and infrared spectroscopy. On heating to approximately 400 C, the amorphous gel crystallized into the low temperature orthorhombic phase Beta-Ta2O5, which transformed into the high temperature tetragonal phase Alpha-Ta2O5 when further heated to approximately 1450 C. The volume fraction of the crystalline phase increased with the firing temperature. The Alpha-Ta205 converted back into the low temperature phase, Beta-Ta2O5, on slow cooling through the transformation temperature of 1360 C indicating a slow but reversible transformation.

Bansal, Narottam P.↗
NASA NTRS1993

Synthesis and thermal evolution of structure in alkoxide-derived niobium pentoxide gels

Niobium pentoxide gels in the form of transparent monoliths and powder have been synthesized from the controlled hydrolysis and polycondensation of niobium pentaethoxide under different experimental conditions using various mole ratios of Nb(OC2H5)5:H2O:C2H5OH:HCl. Alcohol acted as the mutual solvent and HCl as the deflocculating agent. In the absence of HCl, precipitation of colloidal particles was encountered on the addition of any water to the alkoxide. The gels were subjected to various thermal treatments and characterized by differential thermal analysis, thermogravimetric analysis, x-ray diffraction, and infrared spectroscopy. After drying at 400 C, the gels were amorphous to x-rays. The amorphous powder crystallized into the low-temperature orthorhombic form of Nb2O5 at approximately 500 C, which transformed irreversibly into the high-temperature monoclinic alpha-Nb2O5 between 900 to 1000 C. The kinetics of crystallization of the amorphous niobium pentoxide have been investigated by non-isothermal differential scanning calorimetry. The crystallization activation energy was determined to be 399 kJ/mol.

Bansal, Narottam P.↗
NASA NTRS1993

Heterogeneous reaction probabilities, solubilities, and the physical state of cold volcanic aerosols

On 19 January 1992, heterogeneous loss of HNO3, ClNO3, and HCl was observed in part of the Mount Pinatubo volcanic cloud that had cooled as a result of forced ascent. Portions of the volcanic cloud froze near 191 kelvin. The reaction probability of ClNO3 and the solubility of HNO3 were close to laboratory measurements on liquid sulfuric acid. The magnitude of the observed loss of HCl suggests that it underwent a heterogeneous reaction. Such reactions could lead to substantial loss of HCl on background sulfuric acid particles and so be important for polar ozone loss.

Toon, O.↗