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At least 271 records · Page 15
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NASA NTRS1977

Computational tests of angular momentum decoupling approximations for pressure broadening cross sections

The utility of several approximate scattering methods for predicting collision induced spectral pressure broadening has been tested by comparison with accurate close coupling results. In particular, broadening of the pure rotational spectra of HD, HCl, CO, and HCN - all perturbed by low energy collisions with He atoms - has been computed using the effective potential formalism of Rabitz, the decoupled l-dominant approximation of DePristo and Alexander, and the j(2)-conserving coupled states method of McGuire and Kouri. For this last method, pressure broadening cross sections have been obtained with the new, correct expression recently derived by Goldflam and Kouri as well as with an earlier formalism based on an incorrect labeling of the scattering matrices. These methods were found to be generally diasppointing for predicting pressure broadening with the exception of the new, correctly formulated j(2)-conserving coupled states method which was found to agree quantitatively (better than 5%) with close coupling values for all cases studied.

Green, S.↗
NASA NTRS1977

Isothermal degradation of poly-2,2'-/m-phenylene/-5,5'-bibenzimidazole

The isothermal degradation of poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole in vacuo has been studied. Measurement of the increase in pressure with time, coupled with infrared analysis, was used to determine the distribution of the degradation products. Processes A and B with different second-order rate laws were determined to be significant in the temperature range of 550-700 C. Process A leads to the formation of equimolar quantities of hydrogen and ammonia and has an activation energy of 68 kcal/mole. Process B leads to the production of HCN, NH3, and H2 in the ratio of 1:1:2.5 and has an activation energy of 77 kcal/mole. The activation energies and the rate laws are consistent with a mechanism in which the initial degradation step is the bimolecular reaction of two aromatic rings.

Lerner, N. R.↗
NASA NTRS1977

Observation of J = 1-0 emission from H/N-15/C

Emission from the J = 1-0 transition of H(N-15)C has been detected in the direction of DR21(OH). The transition frequency of 88,865.69 MHz was measured in the laboratory by microwave absorption spectroscopy. The computed N-15/C-13 isotopic abundance ratio of 1.01 for DR21(OH) is larger than those calculated from isotopes of HCN in other interstellar clouds, perhaps implying a localized enrichment in N-15 in DR21(OH).

Brown, R. D.↗
NASA NTRS1978

The energetics of molecular clouds. II - The S140 molecular cloud

Techniques of analysis which allow estimates of kinetic temperature, gas density, gas cooling rate, and dust cooling rate are applied to the S140 molecular cloud. Maps of this cloud in various molecular lines are examined which reveal the existence of a strong temperature and density peak near the H-alpha rim and the presence of a strong near-IR source very near that peak. This source is found to have an energy distribution which is very similar to that of the Becklin-Neugebauer object, including the silicate feature at 9.5 microns. The heating and cooling rates for the gas and dust in S140 are estimated, and the predicted cooling rate for dust is shown to be much greater than that for gas. The molecular-line observations are compared with a spherical large-velocity-gradient trapping calculation. An optimum cloud model is developed which indicates that: (1) (C-13)O, HCO(+), and H2CO are about 10 times less abundant in S140 than in dark clouds; (2) the HCN abundance is approximately 4 times the H2CO abundance in S140, compared with roughly equal values in dark clouds; and (3) the (C-13)O/C(O-18) ratio is consistent with terrestrial isotope ratios.

Blair, G. N.↗
NASA NTRS1978

A new channel for the formation of hydrogen cyanide in CH2-N2 systems

The reaction between N2 and either the singlet or the triplet electronic state of CH2 is investigated in order to shed light on the formation of NO in fuel-rich hydrocarbon flames. For the reaction of N2 and the triplet CH2, a rate constant less than or equal to 10 to the minus 16th power cu cm/molecule-sec is obtained. The time history of hydrogen cyanide production from the CH2-N2 systems is discussed as a basis for understanding the possible reaction routes from HCN to NO.

Laufer, A. H.↗
NASA NTRS1978

Upper limits to trace constituents in Jupiter's atmosphere from an analysis of its 5 micrometer spectrum

A high-resolution spectrum of Jupiter at 5 micrometers recorded at the Kuiper Airborne Observatory is used to determine upper limits to the column density of 19 molecules. The upper limits to the mixing ratios of SiH4, H2S, HCN, and simple hydrocarbons are discussed with respect to current models of Jupiter's atmosphere. These upper limits are compared to expectations based upon the solar abundance of the elements. This analysis permits upper limit measurements (SiH4), or actual detections (GeH4) of molecules with mixing ratios with hydrogen as low as 10 to the minus 9th power. In future observations at 5 micrometers the sensitivity of remote spectroscopic analyses should permit the study of constituents with mixing ratios as low as 10 to the minus 10th power, which would include the hydrides of such elements as Sn and As as well as numerous organic molecules.

Treffers, R. R.↗
NASA NTRS1978

Nonequilibrium chemistry in shocked molecular clouds

The gas-phase chemistry is studied behind a 10-km/s shock propagating into a dense molecular cloud. The principal conclusions are that: the concentrations of certain molecules (CO, NH3, HCN, N2) are unperturbed by the shock; other molecules (H2CO, CN, HCO(+)) are greatly decreased in abundance; and substantial amounts of H2O, HCO, and CH4 are produced. Approximately 1 million yr (independent of the density) must elapse after shock passage before chemical equilibrium is attained.

Iglesias, E. R.↗
NASA NTRS1978

Computational test of the infinite order sudden approximation for excitation of linear rigid rotors by collisions with atoms

The infinite order sudden approximation for excitation of linear rigid rotors by collisions with atom is tested by comparing integral state-to-state cross sections with accurate close coupling and coupled states results. The systems studied are HCl-Ar, HCl-He, CO-He, HCN-He, CS-H2 and OCS-H2. With the exception of diatomic hydrides (e.g., HCl) which have atypically large rotational constants the method is found to be very accurate to remarkably low collision energies. This approximation should generally be extremely useful for thermal energy collisions.

Green, S.↗
NASA NTRS1979

Abundance of organic compounds photochemically produced in the atmospheres of the Outer Planets

Organic photochemical syntheses in the Jovian atmosphere was simulated by irradiating, at 147 nm, gaseous mixtures of methane and ammonia with varying amounts of hydrogen. Some results relevant to the photochemistry of the Jupiter atmosphere at several tens of kilometers above the clouds were obtained: (1) a favorable effect of the pressure of high amounts of H2 on the yield of hydrocarbon synthesis when NH3 is mixed with CH4; (2) a very low yield of synthesis of unsaturated hydrocarbons in such conditions; and (3) the possibility of formation of detectable amounts of HCN and CH3CN.

Raulin, F.↗
NASA NTRS1980

Neutral cometary atmospheres. II - The production of CN in comets

Brightness profiles of the CN (0-0) band at 3883 A have been constructed from spectrograms of comets Bennett (1979 II) and West (1976 VI). The subsequent analysis of these profiles shows that the parent molecule of CN had a radial scale length of (2.19 plus or minus 0.07) x 10 to the 4th r (H-squared), in kilometers. This, combined with current theories as well as photochemistry, is consistent with production by simple photodissociation of HCN. The rather random variation of the radial scale length for the apparent decay of CN is indicative not of a true decay scale length, but of the fact that no steady state in the CN parent production rate is achieved for the time scale necessary to build up the observed profile. A revision of the average CN production law with heliocentric distance from published photometry indicates an r(H to the -2nd) law for comet West out to at least 2.555 AU. This implies that the vaporization of this comet was controlled by some species more volatile than water. Based on this and other evidence, CO2 is suggested, but even more volatile molecules like CO cannot be ruled out.

Combi, M. R.↗
NASA NTRS1979

Iron and the formation of astrophysical dust grains

Condensation of metallic iron or the iron carbide cohenite Fe3C is proposed as the source of the approximately 1000 K dust condensate in nova shells, Wolf-Rayet stars, and other objects. Iron grains may serve as nucleation sites for carbon in carbon-star ejecta; however, nucleation of graphite at its equilibrium saturation temperature is almost certainly kinetically inhibited. A gas phase rich in CO, C2H2, and HCN is produced instead.

Lewis, J. S.↗
NASA NTRS1980

Infrared laser photolysis - A new tool for the study of prebiotic chemistry

Infrared laser induced dielectric breakdown and multiphoton absorption experiments on CH4/NH3 'atmospheres' are described. It is found that HCN, a central intermediate in prebiotic chemistry, is a principal product. This, combined with the fact that dielectric breakdown appears to have much in common with ordinary electric sparks, suggests that the laser could be a useful tool in studies of prebiotic chemistry. Several possible experiments in this vein are suggested.

Davis, D. D.↗
NASA NTRS1980

Cabin fire simulator lavatory tests

All tests were conducted in the Douglas Cabin Fire Simulator under in-flight ventilation conditions. All tests were allowed to continue for a period of one hour. Data obtained during these tests included: heat flux and temperatures of the lavatory; cabin temperature variations; gas analyses for O2, CO2, CO, HF, HC1, and HCN; respiration and electrocardiogram data on instrumented animal subjects (rats) exposed in the cabin; and color motion pictures. All tests resulted in a survivable cabin condition; however, occupants of the cabin would have been subjected to noxious fumes.

Schutter, K. J.↗
NASA NTRS1980

The middle-infrared spectrum of Saturn - Evidence for phosphine and upper limits to other trace atmospheric constituents

Observations of Saturn at high spectral resolution in the middle-IR spectral region (2.5-5.6 microns) were obtained using a Fourier spectrometer at ground-based and airborne observatories. These spectra establish that PH3 exists on Saturn with an abundance at least equal to the solar P/H value, and probably enhanced by about a factor of 2. No evidence is found for gaseous or solid NH3 on Saturn throughout this spectral region, and upper limits to several other molecules (H2O, HCN, SiH4, and GeH4) are determined. Frequent comparisons of the spectral data for Saturn with observations and interpretations of IR studies of Jupiter show that these two planetary atmospheres are chemically similar, with major observational differences accounted for by reduced H2O and NH3 abundances in Saturn's colder atmosphere.

Larson, H. P.↗
NASA NTRS1980

Neutral cometary atmospheres. III - Acceleration of cometary CN by solar radiation pressure

The acceleration of cometary CN radicals due to solar radiation pressure has been determined by fitting Monte Carlo models to nine observed sunward-tailward pairs of brightness profiles of the (0-0) band of CN at 3883 A. The profiles were determined from spectrograms of comets Bennett 1970 II and West 1976 VI. The values of the observed acceleration agree with those computed from resonance fluorescence calculations to within the expected uncertainties. This provides an independent confirmation of the identification of the observed scale lengths with the photochemical lifetimes and velocities associated with the production of observed cometary CN by the photodissociation of HCN. The ratio of the intensity of the (0-1) band of CN at 4216 A to the (0-0) band at 3883 A has been determined from spectrograms of comet West, and is compared with theoretical values.

Combi, M. R.↗
NASA NTRS1981

Transport properties associated with entry into the atmosphere of Titan

In this paper the transport properties in the atmosphere of Titan and at the shock front and the probe surface for non-ablative entry into Titan's atmosphere are calculated, using the kinetic theory of gases. The species N2, H2, CH4, HCN, N, and H contribute to the transport properties under these conditions. The transport properties were calculated by using accurate potential energy curves for each of the thirteen two-body interactions which occur between these species. Results are given for the binary diffusion coefficients, the non-reactive and reactive thermal conductivity, and the viscosity from 1000 K to 8000 K. This information is needed for calculating flowfield properties and surface heating rates. The most important conclusions are that the non-reactive thermal conductivity is much larger behind the shock layer than it is in the ambient atmosphere and that the nonreactive thermal conductivity appears to be nearly constant in the shock layer.

Flori, B.↗
NASA NTRS1981

Negative ions in comets

Negative ion sources in comets are identified and cometary plasma effects caused by negative ions are examined. The primary negative ion sources are shown to be: (1) for the inner coma - photodissociation of HCN, electron attachment of OH, and collision with alkalis; (2) in the vicinity of the nucleus - interplanetary dust collisions with the nucleus; and (3) for both the contaminated solar wind region and sporadic discharges in the nonhomogeneous inner coma plasma - dissociative electron attachment and charge inversion during keV positive ion scattering by cometary dust. Negative ion abundance for Halley's Comet has been estimated to be 10 to the -6th - 10 to the -10th of electron densities.

Wekhof, A.↗
NASA NTRS1981

Some new results on shock chemistry in IC 443

New observations have been made of CO, CO-13, SiO, SO, H2CO, HCO(+), N2H(+), CS, OCS, HCN, and OH in the shocked clouds of IC 443. It is found that at position IC 443 B, (1) the shocked CO is optically thin; (2) the HCO(+)/CO abundance ratio is 4-9 x 10 to the -4 th, representing a tenfold enhancement over that of normal interstellar clouds; (3) there is no enhancement of SO or SIO, as occurs in Orion KL; and (4) there is optically thin preshock OH, confirming a hundredfold enhancement of the OH/CO ratio in the shock.

Denoyer, L. K.↗