SEARCH · Engineering Papers

Results for “Diffusion rate”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15

All sources NASA NTRS DOE OSTI

NASA NTRS1974

Skylab experiments on metals

The Skylab Materials Processing Facility is described. Eight experiments on metal processing under near-zero-gravity conditions were performed in this facility. Three of these involved metals and procedures of potential application to fabrication in space. A Multipurpose electric furnace within the Materials Processing Facility was employed to heat three ampoules of samples for each of the other five experiments. These five investigations cover diffusion versus convection rates in molten zinc, several immiscible alloy compositions, a whisker-reinforced silver-based composite, heat treating of porous silver samples, and a copper-aluminum eutectic.

Lundquist, C. A.↗

NASA NTRS1977

Prediction of in-depth oxidation distribution of reinforced carbon-carbon materials for Space Shuttle leading edges

A method was developed for predicting oxidation distribution through the thickness of reinforced carbon-carbon material in an earth atmospheric entry environment. A mathematical model was developed which describes oxygen diffusion and reaction rates within material pores. Pertinent rate constants were derived, and material mass loss was computed for a range of temperatures and pressures. Results indicate that both temperature and pressure have an important effect on mass loss distribution. Analytical results were quite consistent with results of ground oxidation tests.

Medford, J. E.↗

NASA NTRS1982

Electron microprobe study of lunar and planetary zoned plagioclase feldspars: An analytical and experimental study of zoning in plagioclase

Natural and experimentally grown zoned plagioclase feldspars were examined by electron microprobe. The analyses revealed discontinuous, sector, and oscillary chemical zoning superimposed on continuous normal or reverse zoning trends. Postulated mechanisms for the origin of zoning are based on either physical changes external to the magma (P, T, H2O saturation) or kinetic changes internal to the magma (diffusion, supersaturation, growth rate). Comparison of microprobe data on natural zoned plagioclase with zoned plagioclase grown in controlled experiments show that it may be possible to distinguish zonal development resulting from physio-chemical changes to the bulk magma from local kinetic control on the growth of individual crystals.

Smith, R. K.↗

NASA NTRS1982

Viscosity dependence of the rates of diffusional processes

It is shown that the rates of diffusion-controlled processes may have a solvent vicosity independent part as well as a viscosity dependent part. Some relevant experiments involving intramolecular polypeptide movements are discussed, and implications for some experiments on diffusion in membranes are outlined.

Weaver, D. L.↗

NASA NTRS1982

Non-isothermal effects on SO2 absorption by water droplets. I - Model development. II - Results and discussion

An analytic model of SO2 absorption in a falling water droplet is developed and a simulation of SO2 washout is performed. Nonisothermic effects on drop growth, droplet physical parameters, reaction rates, and multicomponent diffusion are treated in the model. The gas-liquid interface is assumed to be at equilibrium, and interfacial resistance is negligible. Raindrops are simulated as falling from a 2 km height through an atmospheric region containing SO2. The droplets decrease in size from evaporation and cooling, and their slightly basic pH aids SO2 absorption. The simulation indicates higher SO2 absorption at higher altitudes, and desorption may occur at ground level. Isothermal effects are concluded to be significant, and quantification of effects will depend on further modelling.

Reda, M.↗

NASA NTRS1985

Experimental study of a three-dimensional, shear-driven, turbulent boundary layer using a three-dimensional laser Doppler velocimeter

Experimental data have been obtained in a three-dimensional, shear-driven, turbulent boundary layer subjected to sudden transverse strain. Measurements made with a newly developed, three-dimensional laser Doppler velocimeter include all components of mean flow, turbulent Reynolds stresses, and triple-product correlations. Eddy viscosities, production, convection, turbulent diffusion, and dissipation (balance of kinetic energy equation) are extracted from the data. It was shown experimentally that eddy viscosity is strongly direction-dependent (not a scalar), indicating a need for full Reynolds stress modeling. Turbulence models for eddy viscosity, stress diffusion, pressure rate-of-strain, and anisotropy of Reynolds stresses are tested using the data. Calculations using a Reynolds stress equation model are compared with the data.

Driver, D. M.↗

NASA NTRS1985

Turbulence in the Altitude Region 80-120 Km

Measurements of turbulent energy dissipation rates and eddy diffusion coefficients have been collated, and mean height profiles of fundamental turbulence parameters in the region 80 to 120 km are presented. Curves of Epsilon, and K vs. height are presented. A clear global and seasonal picture of turbulence variations is not yet apparent.

Hocking, W. K.↗

NASA NTRS1986

Comparisons between thermodynamic and one-dimensional combustion models of spark-ignition engines

Results from a one-dimensional combustion model employing a constant eddy diffusivity and a one-step chemical reaction are compared with those of one-zone and two-zone thermodynamic models to study the flame propagation in a spark-ignition engine. One-dimensional model predictions are found to be very sensitive to the eddy diffusivity and reaction rate data. The average mixing temperature found using the one-zone thermodynamic model is higher than those of the two-zone and one-dimensional models during the compression stroke, and that of the one-dimensional model is higher than those predicted by both thermodynamic models during the expansion stroke. The one-dimensional model is shown to predict an accelerating flame even when the front approaches the cold cylinder wall.

Ramos, J. I.↗

NASA NTRS1990

Stress versus temperature dependent activation energies in creep

The activation energy for creep at low stresses and elevated temperatures is lattice diffusion, where the rate controlling mechanism for deformation is dislocation climb. At higher stresses and intermediate temperatures, the rate controlling mechanism changes from that of dislocation climb to one of obstacle-controlled dislocation glide. Along with this change, there occurs a change in the activation energy. It is shown that a temperature-dependent Gibbs free energy does a good job of correlating steady-state creep data, while a stress-dependent Gibbs free energy does a less desirable job of correlating the same data. Applications are made to copper and a LiF-22 mol. percent CaF2 hypereutectic salt.

Freed, A. D.↗

NASA NTRS1990

The latitudinal gradient of the NO peak density

Results are presented from SME observations of the latitudinal gradients of peak NO densities at about 110-km altitude during the solstice and equinox periods from 1982 through 1985. It is shown that the response of the peak NO densities to the declining level of solar activity varies with latitude, with the polar regions exhibiting low sensitivity and the low-latitude regions responding strongly. The SME data also revealed marked asymmetries in the latitudinal structure of the two hemispheres for each season and considerable day-to-day variations in the NO densities. The solar cycle minimum data for June were simulated using a two-dimensional model; results of sensitivity studies performed with varied quenching rate and eddy diffusion coefficient are presented.

Fesen, C. G.↗

NASA NTRS1992

Stress versus temperature dependence of activation energies for creep

The activation energy for creep at low stresses and elevated temperatures is associated with lattice diffusion, where the rate controlling mechanism for deformation is dislocation climb. At higher stresses and intermediate temperatures, the rate controlling mechanism changes from dislocation climb to obstacle-controlled dislocation glide. Along with this change in deformation mechanism occurs a change in the activation energy. When the rate controlling mechanism for deformation is obstacle-controlled dislocation glide, it is shown that a temperature-dependent Gibbs free energy does better than a stress-dependent Gibbs free energy in correlating steady-state creep data for both copper and LiF-22mol percent CaF2 hypereutectic salt.

Freed, A. D.↗

NASA NTRS1993

A model for heterogeneous chemical processes on the surfaces of ice and nitric acid trihydrate particles

The study presents a model that incorporates the physics and physical chemistry of ice surfaces relevant to polar stratospheric clouds. Surface concentrations of H2O, HCl, HOCl, ClONO2, and N2O5 on ice and nitric acid trihydrate (NAT) crystals are computed, and surface reaction rates and reaction probabilities (sticking coefficients) are determined. For gas pressures of about 10 exp -7 torr and temperatures in the range of 180-200 K, HCl completely coats ice and water-rich NAT surfaces, while HOCl, ClOHO2, and N2O5 may cover 0.01-1 percent of these surfaces. The energy parameters are used to calculate surface temperatures such as adsorption and desorption constants, surface coverages, reaction rate coefficients, surface diffusion coefficients, and reaction probabilities for various species and chemical interactions on ice and NAT surfaces. Implications for chemical processing on polar stratospheric clouds are discussed.

Tabazadeh, Azadeh↗

NASA NTRS1957

Investigation of shock-boundary-layer interaction on the spike of a conical-spike nose inlet

Measurements were made of the height of the shock-induced boundary-layer thickening and separation over a Mach number range of 1.6 to 2.0. The behavior of the interaction depended on longitudinal spike position as well as on cone surface Mach number. The cone position affected the interaction by changing the rate of subsonic diffusion and thereby changing the pressure aft of the terminal shock. When the pressure rise due to the interaction exceeded about 1.9, the boundary layer was separated.

Wise, George A↗

NASA NTRS1937

Effects of Air-Fuel Spray and Flame Formation in a Compression-Ignition Engine

High-speed motion pictures were taken at the rate of 2,500 frames per second of the fuel spray and flame formation in the combustion chamber of the NACA combustion apparatus. The compression ratio was 13.2 and the speed 1,500 revolutions per minute. An optical indicator was used to record the time-pressure relationship in the combustion chamber. The air-fuel ratio was varied from 10.4 to 365. The results showed that as the air-fuel ratio was increased definite stratification of the charge occurred in the combustion chamber even though moderate air flow existed. The results also showed the rate of vapor diffusion to be relatively slow.

Rothrock, A M↗

NASA NTRS1993

Absence of magnetic trapping on closed field lines at Neptune

The large offset of Neptune's magnetic field in an offset tilted dipole (OTD) approximation allows some fraction of magnetospheric field lines to have monotonically increasing field magnitude over their entire length in the magnetosphere. The usual magnetic trapping is impossible on such field lines, meaning that all charged particles on these field lines will precipitate after mirroring at most once. These field lines can be thought of as the part of the global magnetic anomaly where no particles on the corresponding drift shells remain trapped for an entire rotation of the planet. In this paper we examine both the morphology and size of the affected surface area in the OTD2 and O8 magnetic field models. For regions where there are indications that part of the aurora could be due to monotonic field line precipitation we analyze whether these field lines could be sufficiently populated to produce auroral signatures by considering photoelectron production rates and radial diffusion. We conclude that monotonic field line precipitation may contribute to the observed Neptune aurora but does not explain the global phenomenon.

Paranicas, C.↗

NASA NTRS1997

Rotor Vortex Filaments: Living on the Slipstream's Edge

The purpose of this paper is to gain a better understanding of rotor wake evolution in hover and axial flow by deriving an analytical solution for the time dependent behavior of vortex filament circulation and core size. This solution is applicable only for vortex filaments in the rotor far-wake. A primarily inviscid vortex/shear layer interaction (where the slipstream boundary is modeled as a shear layer) has been identified in this analytical treatment. This vortex/shear layer interaction results in decreasing, vortex filament circulation and core size with time. The inviscid vortex/shear layer interaction is shown, in a first-order treatment, to be of greater magnitude than viscous diffusion effects. The rate of contraction, and ultimate collapse, of the vortex filament core is found to be directly proportional to the rotor inflow velocity. This new insight into vortex filament decay promises to help reconcile several disparate observations made in the literature and will, hopefully, promote new advances in theoretical modeling of rotor wakes.

Young, Larry A.↗

NASA NTRS1998

Soot Formation in Laminar Premixed Methane/Oxygen Flames at Atmospheric Pressure

Flame structure and soot formation were studied within soot-containing laminar premixed mc1hane/oxygen flames at atmospheric pressure. The following measurements were made: soot volume fractions by laser extinction, soot temperatures by multiline emission, gas temperatures (where soot was absent) by corrected fine-wire thermocouples, soot structure by thermophoretic sampling and transmission electron microscope (TEM), major gas species concentrations by sampling and gas chromatography, and gas velocities by laser velocimetry. Present measurements of gas species concentrations were in reasonably good agreement with earlier measurements due to Ramer et al. as well as predictions based on the detailed mechanisms of Frenklach and co-workers and Leung and Lindstedt: the predictions also suggest that H atom concentrations are in local thermodynamic equilibrium throughout the soot formation region. Using this information, it was found that measured soot surface growth rates could be correlated successfully by predictions based on the hydrogen-abstraction/carbon-addition (HACA) mechanisms of both Frenklach and co-workers and Colket and Hall, extending an earlier assessment of these mechanisms for premixed ethylene/air flames to conditions having larger H/C ratios and acetylene concentrations. Measured primary soot particle nucleation rates were somewhat lower than the earlier observations for laminar premixed ethylene/air flames and were significantly lower than corresponding rates in laminar diffusion flames. for reasons that still must be explained.

Xu, F.↗

NASA NTRS2000

Descending Layer Variability Over Arecibo

Descending layers of ionization over Arecibo exhibit very diverse behavior from night to night that does not appear to be strongly correlated to geomagnetic activity, solar forcing, or average semidiurnal tidal winds. On some nights, three or more distinct layers are observed to form near 170 km over timescales of approx. 2 hours. Rather than descending smoothly over periods of several hours, these layers stall, abruptly disappear, or even reverse direction in the midst of their descent. The time scales for their disappearance are examined and compared to loss rates arising from diffusion and recombination. Diffusion alone is found to be too slow to account for the observations, but recombination is fast enough provided that the convergent wind shear that forms the layer is relatively weak coincident with their disappearance. The continuity equation is solved in conjunction with a time sequence of radar profiles to estimate the vertical drift and horizontal neutral wind consistent with the observed behavior. The resultant wind field is northward, has an average speed of approx. 80 m/ s, and varies significantly near the altitude where the layers are observed. These inferred winds are consistent with the presence of the observed layers, and their magnitudes as obtained from the classical continuity and momentum equations are reasonable for this altitude range.

Earle, G. D.↗