Extinction and Laser-Induced Incandescence Imaging of Carbon Soot in Post-Detonation Fireballs.
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Beryllium (Be) isotope measurements provide insight into weapon design, yield, etc. Sample preparation nor measurement capability currently existed at LANL. Potential capability directly benefits nuclear forensics venture. PI Goehring has nearly 20 years of Be chemistry experience, including method implementation with difficult samples.
This report documents the generation of a skeletal chemical reaction mechanism for use with hemispherical pentaerythritol tetranitrate charges. Skeletal mechanisms can substantially reduce computation time while maintaining accuracy. The methodology within uses faster running sample simulations to build a representative thermodynamic state space. These thermodynamic states are used with a constant-volume reactor analysis and a reaction flow analysis to remove unimportant species and reactions from a full chemical reaction mechanism. For the given test case, this results in a 6x speedup in computation time for directly comparable simulations in 2D axisymmetric simulations. We see a 30x speedup in simulations in 3D Cartesian coordainates when compared to a prior full kinetics simulation. There is strong agreement between temperature and species mass fraction profiles between the full and skeletal chemical reaction mechanisms. These methodologies can be applied to any explosive, given the availability of sample simulations.
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Documents a study to examine model behavior as compared to open literature data on overdriven states in explosives
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Presentation at APS DFD 2024, SLC, Utah.
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