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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Heat Rejection from a Variable Conductance Heat Pipe Radiator Panel

A titanium-water heat pipe radiator having an innovative proprietary evaporator configuration was evaluated in a large vacuum chamber equipped with liquid nitrogen cooled cold walls. The radiator was manufactured by Advanced Cooling Technologies, Inc. (ACT), Lancaster, PA, and delivered as part of a Small Business Innovative Research effort. The radiator panel consisted of five titanium-water heat pipes operating as thermosyphons, sandwiched between two polymer matrix composite face sheets. The five variable conductance heat pipes were purposely charged with a small amount of non-condensable gas to control heat flow through the condenser. Heat rejection was evaluated over a wide range of inlet water temperature and flow conditions, and heat rejection was calculated in real-time utilizing a data acquisition system programmed with the Stefan-Boltzmann equation. Thermography through an infra-red transparent window identified heat flow across the panel. Under nominal operation, a maximum heat rejection value of over 2200 Watts was identified. The thermal vacuum evaluation of heat rejection provided critical information on understanding the radiator s performance, and in steady state and transient scenarios provided useful information for validating current thermal models in support of the Fission Power Systems Project.

Jaworske, D. A.↗

Results from the Space Shuttle STS-95 Electronic Nose Experiment

A miniature electronic nose in which the sensing media are insulating polymers loaded with carbon black as a conductive medium has been designed and built at the Jet Propulsion Laboratory. The ENose has a volume of 1700 cc, weighs 1.4 kg including the operating computer, and uses 1.5 W average power (3 W peak power). This ENose was used in a demonstration experiment aboard STS-95 (October, 1998), in which the ENose was operated continuously for six days and recorded the sensors' response to the air in the middeck. The ENose was designed to detect ten common contaminants in space shuttle crew quarters air. The experiment was controlled by collecting air samples daily and analyzing them using standard analytical techniques after the flight. Changes in humidity were detected and quantified, neither the ENose nor the air samples detected any of the contaminants on the target list. The device is microgravity insensitive.

Ryan, M. A.↗

Mechanical and Electrical Properties of a Polyimide Film Significantly Enhanced by the Addition of Single-Wall Carbon Nanotubes

Single-wall carbon nanotubes have been shown to possess a combination of outstanding mechanical, electrical, and thermal properties. The use of carbon nanotubes as an additive to improve the mechanical properties of polymers and/or enhance their thermal and electrical conductivity has been a topic of intense interest. Nanotube-modified polymeric materials could find a variety of applications in NASA missions including large-area antennas, solar arrays, and solar sails; radiation shielding materials for vehicles, habitats, and extravehicular activity suits; and multifunctional materials for vehicle structures and habitats. Use of these revolutionary materials could reduce vehicle weight significantly and improve vehicle performance and capabilities.

Meador, Michael A.↗

Microwave Photoelasticity: A Resonant Wavelength Approach Applied to PEEK Polymer

Every nondestructive testing (NDT) technique has its unique set of advantages and limitations. Currently, the only existing noncontact NDT method capable of measuring sub-surface stresses, in optically opaque materials, at near-real-time speeds and over large areas is Microwave Photoelasticity (MP). This paper presents a new MP approach, which correlates changes in resonant wavelengths to changes in stress. In addition to a theoretical outline of the approach, the design and operation of an instrument capable of conducting these measurements is described. Finally, the technique is demonstrated by conducting measurements on polyetheretherketone, commonly known as PEEK, polymer. Between the W-Band frequencies of 105 to 115 GHz, PEEK’s stress-optic-coefficient was determined to be of 𝐶𝐶 = −0.20 ± 0.02 1/GPa.

Schemmel, Peter J.↗

Composite Solid Electrolyte For Lithium Cells

Composite solid electrolyte material consists of very small particles, each coated with thin layer of Lil, bonded together with polymer electrolyte or other organic binder. Material offers significant advantages over other solid electrolytes in lithium cells and batteries. Features include high ionic conductivity and strength. Composite solid electrolyte expected to exhibit flexibility of polymeric electrolytes. Polymer in composite solid electrolyte serves two purposes: used as binder alone, conduction taking place only in AI2O3 particles coated with solid Lil; or used as both binder and polymeric electrolyte, providing ionic conductivity between solid particles that it binds together.

Peled, Emmanuel↗

Temperature effects on polymer-carbon composite sensors

At JPL we have investigated the effects of temperature on polymer-carbon black composite sensors. While the electrical properties of polymer composites have been studied, with mechanisms of conductivity described by connectivity and tunneling, it is not fully understood how these properties affect sensor characteristics and responses.

JPL Enose polymer-carbon composite sensor temperat↗

Breakdown in Tantalum Capacitors

Failures in tantalum capacitors can be considered as a time-dependent-breakdown and reliability of all types of capacitors, including wet, MnO2 and polymer cathode parts, depends on the efficiency of self-healing that can mend parts after breakdown. A mechanism of self-healing in MnO2 capacitors is associated with oxygen reduction in the cathode layer and isolation of the breakdown site with high-resistive Mn2O3/Mn3O4 compositions. Although this mechanism is commonly accepted, details of self-healing have not been analyzed sufficiently yet, and the effects of scintillations on behavior of the parts has not been fully understood. There is a lack of data on the self-healing efficiency in different lots of capacitors. Even less is known about self-healing in polymer tantalum capacitors. In this work, different types of polymer and MnO2 capacitors have been tested for scintillation breakdown using a constant current stress (CCS) technique modified to allow detection of the amplitudes and durations of current spikes during breakdown. Characteristics of the parts and in particular leakage currents were measured to assess the efficiency of self-healing and improve screening processes for tantalum capacitors. Damaged sites were localized using infrared camera and their appearance analyzed after deprocessing and crosssectioning. Thermal effects during scintillations have been modeled, self-healing processes in polymer and MnO2 cathode capacitors discussed, and mechanisms of breakdown based on the growth of conductive filaments in the dielectric suggested.

tantalum polymer capacitors↗

New Polymer Electrolyte Cell Systems

PAPERS PUBLISHED: 1. Pappenfus, Ted M.; Henderson, Wesley A.; Owens, Boone B.; Mann, Kent R.; Smyrl, William H. Complexes of Lithium Imide Salts with Tetraglyme and Their Polyelectrolyte Composite Materials. Journal of the Electrochemical Society (2004), 15 1 (2), A209-A2 15. 2. Pappenfus, Ted M.; Henderson, Wesley A.; Owens, Boone B.; Mann, Kent R.; Smyrl, William H. Ionic-liquidlpolymer electrolyte composite materials for electrochemical device applications. Polymeric Materials Science and Engineering (2003), 88 302. 3. Pappenfus, Ted R.; Henderson, Wesley A.; Owens, Boone B.; Mann, Kent R.; and Smyrl, William H. Ionic Conductivity of a poly(vinylpyridinium)/Silver Iodide Solid Polymer Electrolyte System. Solid State Ionics (in press 2004). 4. Pappenfus Ted M.; Mann, Kent R; Smyrl, William H. Polyelectrolyte Composite Materials with LiPFs and Tetraglyme. Electrochemical and Solid State Letters, (2004), 7(8), A254.

Smyrl, William H.↗

Multifunctional Polymers and Composites for Aerospace Applications

System needs and challenges for commercial aviation and space exploration are constantly changing. Multifunctional materials are ideal for aerospace applications because their integration into structural components has the potential to not only improve efficiency, but it can increase payload and mission capabilities without the burden of significant additions to mass and volume. Multiconstituent materials will play an important role in enabling structures with the potential to demonstrate true multifunctionality; however, modifications to traditional polymer processing methods may be necessary. This presentation will cover multifunctional materials development efforts underway at the NASA Glenn Research Center pertaining to fabricating novel electrical insulation to advance electric aircraft propulsion, impact resistant and electrically conductive textiles for space, and hybrid reinforcement for toughened polymer matrix composites.

Textiles↗

Deformation-Induced Anisotropy of Polymers

New theory calculates anisotropies induced by large deformations in polymers. Theory was developed primarily for calculating anistropy of thermal expansivity, but is also applicable to thermal conductivity, elastic moduli and other properties. Theory assumes that in isotropic state, long polymer chains are randomly coiled and not oriented in particular direction. They acquire an orientation when material is deformed. As average molecular orientation increases with deformation, properties of bulk material exhibit averaging of the microscopic anistropies of the oriented molecular segments.

Peng, S. T. J.↗

NASA's 'Mission to Planet Earth' begins with launch of UARS

The deployment of NASA's Upper Atmospher Research Satellite (UARS) is described in terms of the Shuttle flight and the expected contributions of the UARS to the 'Mission to Planet Earth'. The launch and daily activities of the Shuttle flight are described including microgravity-related materials experiments and the assembling of model space structures. The release of the UARS occurred without difficulty on the third day of the spaceflight, and experiments conducted included protein-crystal growth, middeck zero-gravity dynamics, rodent-physiology tests, cosmic radiation monitoring, and polymer-membrane processing. Millions of bytes of data resulted from the experiments conducted in space, and the UARS is expected to yield important data for the study of the global climate. The spaceflight culminated with the first nighttime landing at the Kennedy Space Center.

Schuiling, Roelof L.↗

Flame resistant elastomeric polymer development

Elastomeric products were developed for use in the space shuttle program, and investigations were conducted to improve the properties of elastomers developed in previous programs, and to evaluate the possibility of using lower-cost general purpose polymers. Products were fabricated and processed on conventional processing equipment; these products include: foams based on fluorinated rubber flame-retarded compounds with a density of 20-30 pounds/cubic foot for use as padding and in helmets; foams based on urethane for use in instrument packaging in the space shuttle; flexible and semi-rigid films of fluorinated rubber and neoprene compounds that would not burn in a 70% nitrogen, 30% oxygen atmosphere, and in a 30% nitrogen, 70% oxygen atmosphere, respectively for use in packaging or in laminates; coated fabrics which used both nylon and Kelvar fabric substrates, coated with either fluorinated or neoprene polymer compositions to meet specific levels of flame retardancy; and other flame-resistant materials.

Howarth, J. T.↗

Multiscale Experiments and Models for Polymer Nanocomposites

This report summarizes our research activities at the University of Virginia conducted under the support of this NASA research grant from March 2004 to October 2004 and provides a summary of the research to be conducted in the remaining period of the project at the University of Illinois at Urbana-Champaign (UIUC). The original research objectives will remain the same after our transition to UIUC. In the beginning of this program we completed the analysis on the graphite polymer micro and nanocomposites that were studied at NASA Langley and UVa in the summer of 2003. A publication summarizing this work was submitted in the fall of 2004 to the journal of Experimental Mechanics and the reviewer comments are currently addressed. The research program aims at understanding the local interactions between the polymer matrix and hard reinforcement in polymer nanocomposites (PNCs). The materials selected for this study were PNCs with different fillers (14nm silica nanospheres or nanoclays) and volume fractions (0.5%, 1%, 2% and 5%).

Chasiotis, Ioannis↗

Composite Materials for Low-Temperature Applications

Composite materials with improved thermal conductivity and good mechanical strength properties should allow for the design and construction of more thermally efficient components (such as pipes and valves) for use in fluid-processing systems. These materials should have wide application in any number of systems, including ground support equipment (GSE), lunar systems, and flight hardware that need reduced heat transfer. Researchers from the Polymer Science and Technology Laboratory and the Cryogenics Laboratory at Kennedy Space Center were able to develop a new series of composite materials that can meet NASA's needs for lightweight materials/composites for use in fluid systems and also expand the plastic-additive markets. With respect to thermal conductivity and physical properties, these materials are excellent alternatives to prior composite materials and can be used in the aerospace, automotive, military, electronics, food-packaging, and textile markets. One specific application of the polymeric composition is for use in tanks, pipes, valves, structural supports, and components for hot or cold fluid-processing systems where heat flow through materials is a problem to be avoided. These materials can also substitute for metals in cryogenic and other low-temperature applications. These organic/inorganic polymeric composite materials were invented with significant reduction in heat transfer properties. Decreases of 20 to 50 percent in thermal conductivity versus that of the unmodified polymer matrix were measured. These novel composite materials also maintain mechanical properties of the unmodified polymer matrix. These composite materials consist of an inorganic additive combined with a thermoplastic polymer material. The intrinsic, low thermal conductivity of the additive is imparted into the thermoplastic, resulting in a significant reduction in heat transfer over that of the base polymer itself, yet maintaining most of the polymer's original properties. Normal polymer processing techniques can turn these composite materials into unique, custom parts for ground support, Shuttle, and Constellation needs. We fabricated test specimens of the composite and base materials for thermal and mechanical characterization and found that the strength of the composite material at nominal-percentage loading remained relatively unchanged from the base material.

Source record↗

Polyimide/carbon Nanocomposites

The goal of this product is to design and characterize well-defined conductive nanocomposite materials. The materials will be composed of a polymer matrix composed of rigid-backbone polyimides, and will be filled with modified or unmodified multi-walled carbon nanotubes (MWNTs). The ultimate design of this project is to create composite materials with optical clarity and a high conductivity.

Harris, Frank W.↗

Mechanically Strong Lightweight Materials for Aerospace Applications (x-aerogels)

The X-Aerogel is a new NASA-developed strong lightweight material made by reacting the mesoporous surfaces of 3-D networks of inorganic nanoparticles with polymeric crosslinkers. Since the relative amount of the crosslinker and the backbone are comparable, X-Aerogels can be viewed either as aerogels modified by templated accumulation of polymer on the skeletal nanoparticles, or as nanoporous polymers made by templated casting of polymeric precursors on a nanostructured framework. The most striking feature of X-Aerogels is that for a nominal 3-fold increase in density (still a ultralightweight material), the mechanical strength can be up to 300 times higher than the strength of the underlying native aerogel. Thus, X-Aerogels combine a multiple of the specific compressive strength of steel, with the thermal conductivity of styrofoam. XAerogels have been demonstrated with several polymers such as polyurethanes/polyureas, epoxies and polyolefins, while crosslinking of approximately 35 different oxide aerogels yields a wide variety of dimensionally stable, porous lightweight materials with interesting structural, magnetic and optical properties. X-Aerogels are evaluated for cryogenic rocket fuel storage tanks and for Advanced EVA suits, where they will play the dual role of the thermal insulator/structural material. Along the same lines, major impact is also expected by the use of X-Aerogels in structural components/thermal protection for small satellites, spacecrafts, planetary vehicles and habitats.

Leventis, Nicholas↗

Module degradation catalyzed by metal-encapsulation reactions

Four major properties are considered to be relevant in determining service life of a photovoltaic module: (1) Mechanical: creep resistance, modulus, tensile strength; (2) Optical: integrated transmission at 0.4 to 1.1 m wavelength; (3) Chemical: inertness with respect to metals and other components, retention of stabilizers, etc. and (4) Electrical; maintaining effective isolation of conductive components. These properties were measured after exposing polymer specimens to three types of accelerated stress: thermal, ultraviolet radiation and metal catalysts. These conditions give rise to a large number of complex interrelated free-radical reactions that result in the deterioration of polymeric materials.

Gallagher, B. D.↗