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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

The Pathfinder Chemical Transfer Propulsion Program

Pathfinder is a research and technology initiative by the National Aeronautics and Space Administration (NASA) intended to strengthen the technology base of the United States civil space program in preparation for future space exploration missions. Pathfinder begins in FY-89. One of the four major thrusts is the Chemical Transfer Propulsion program which will provide the propulsion technology for high performance, liquid oxygen/liquid hydrogen expander cycle engines which are expected to be operated and maintained in space. These advanced engines will enhance or enable a variety of future space exploration missions. The goals and objectives, management, technical plan, and technology transfer for the Chemical Transfer Propulsion element of Pathfinder are described.

Hannum, Ned P.↗
NASA NTRS1991

Technical prospects for utilizing extraterrestrial propellants for space exploration

NASA's LeRC has supported several efforts to understand how lunar and Martian produced propellants can be used to their best advantage for space exploration propulsion. A discussion of these efforts and their results is presented. A Manned Mars Mission Analysis Study identified that a more thorough technology base for propellant production is required before the the net economic benefits of in situ propellants can be determined. Evaluation of the materials available on the moon indicated metal/oxygen combinations are the most promising lunar propellants. A hazard analysis determined that several lunar metal/LOX monopropellants could be safely worked with in small quantities, and a characterization study was initiated to determine the physical and chemical properties of potential lunar monopropellant formulations. A bipropellant metal/oxygen subscale test engine which utilizes pneumatic injection of powdered metal is being pursued as an alternative to the monopropellant systems. The technology for utilizing carbon monoxide/oxygen, a potential Martian propellant, was studied in subscale ignition and rocket performance experiments.

Linne, Diane L.↗
NASA NTRS1991

Time evolution of interstellar dust and far-infrared luminosity of disk galaxies

The evolution of interstellar dust in disk galaxies is modeled, assuming that dust forms predominantly in molecular clouds associated with star formation. Analytical solutions for the dust abundance in disk galaxies as a function of galaxy age are obtained for the prompt initial enrichment and accretion models of chemical evolution, consistent with observations of the heavy element abundance in the Galaxy. Star formation rates in the disks of galaxies are taken as either constant or decreasing exponentially with time. It is found that the total amount of dust in the early history of galaxies can be up to 4 times the value observed today. The total emission from dust in galaxies is calculated, using an average dust temperature derived from IRAS observations. In the strongly evolving models, the far-infrared luminosity from galaxies can be roughly two orders of magnitude larger than the current value.

Wang, Boqi↗
NASA NTRS1991

Technical prospects for utilizing extraterrestrial propellants for space exploration

NASA's LeRC has supported several efforts to understand how lunar and Martian produced propellants can be used to their best advantage for space exploration propulsion. A discussion of these efforts and their results is presented. A Manned Mars Mission Analysis Study identified that a more thorough technology base for propellant production is required before the net economic benefits of in situ propellants can be determined. Evaluation of the materials available on the moon indicated metal/oxygen combinations are the most promising lunar propellants. A hazard analysis determined that several lunar metal/LOX monopropellants could be safely worked with in small quantities, and a characterization study was initiated to determine the physical and chemical properties of potential lunar monopropellant formulations. A bipropellant metal/oxygen subscale test engine which utilizes pneumatic injection of powdered metal is being pursued as an alternative to the monopropellant systems. The technology for utilizing carbon monoxide/oxygen, a potential Martian propellant, was studied in subscale ignition and rocket performance experiments.

Linne, Diane L.↗
NASA NTRS1997

Spectrophotometry of Dust in Comet Hale-Bopp

Comets, such as Hale-Bopp (C/1995 O1), are frozen reservoirs of primitive solar nebula dust grains and ices. Analysis of the composition of cometary dust grains from infrared spectroscopic techniques permits an estimation of the types of organic and inorganic materials that constituted the early primitive solar nebula. In addition, the cometary bombardment of the Earth (approximately 3.5 Gy ago) supplied the water for the oceans and brought organic materials to Earth which may have been biogenic. Spectroscopic observations of comet Hale-Bopp suggest the possible presence of organic hydrocarbon species, silicate and olivine dust grains, and water ice. Spectroscopy near 3 microns obtained in Nov 1996 r=2.393 AU, delta=3.034 AU) shows a feature which we attribute to PAH emission. The spatial morphology of the 3.28 microns PAH feature is also presented. Optical and infrared spectrophotometric observations of comets convey valuable information about the spatial distribution and properties of dust and gas within the inner coma. In the optical and NIR shortward of 2 microns, the observed light is primarily scattered sunlight from the dust grains. At longer wavelengths, particularly in the 10 gm window, thermal emission from these grains dominates the radiation allowing an accurate estimate of grain sizes and chemical composition. Here we present an initial analysis of spectra taken with the NASA HIFOGS at 7-14 microns as part of a multiwavelength temporal study of the "comet of the century".

Witteborn, Fred C.↗
NASA NTRS1993

Metallicity Gradients in Elliptical Galaxies

The study of metalicity gradients is an examination of the relics of the first epoch of star formation and, thus, another issue that metallicity gradients can address is the relationship between chemical and dynamical evolution during the initial phase of star formation.

elliptical galaxies photometry evolution formation↗
NASA NTRS2017

Oxidative Alteration of Ferrous Smectites: A Formation Pathway for Martian Nontronite?

Ferric (Fe3+-bearing) smectites, including nontronite, constitute the majority of hydrous mineral exposures observed on Mars. These smectite exposures are commonly interpreted as weathering products of Martian basaltic crust. However, ferrous (Fe2+-dominated) smectites, not ferric, are the thermo-dynamically predicted products of weathering in anoxic conditions, as predicted for early Mars. Earth was anoxic until the Proterozoic Great Oxidation Event; Mars likely experienced an analogous oxidative evolution to its present oxidized state, but the timing of this evolution is unresolved. We hypothesize that Fe3+-smectites observed by orbital spectroscopy are not the initial products of Noachian-era chemical weathering, but are instead the oxidative products of primary Fe2+-smectites. To test this hypothesis experimentally, we synthesized ferrous smectites and exposed them to Mars-relevant oxidants.

Chemtob, S. M.↗
NASA NTRS2018

Efficacy of FTIR Analysis in Determining CO2 Loading on Diglycolamine

In support of advanced air revitalization technologies to enable human spaceflight beyond low earth orbit, performance studies have been conducted using a liquid amine, Diglycolamine (DGA) between teams at NASA?s Johnson Spaceflight Center (JSC) and Ames Research Center (ARC). Liquid amines have been used in regenerable earth-based systems to remove CO2 from industrial systems as well as for closed-environment air revitalization because they can be regenerated at lower temperatures than solid sorbent systems. As an additional advantage to solid sorbent based systems, liquid sorbents can be cycled between an adsorbing contactor and degassing chamber, thereby reducing system complexity by operation in a continuous loop. In an effort to inform a regeneration system design for micro-gravity applications, ARC has performed a number of tests to characterize the degas mechanics of DGA. In order to accurately measure the amount of CO2 captured or released by the amine, methods such as gravimetric weighing and chemical decomposition are reasonable, however the initial design for a scaled down degas system required analysis on small sample sizes. In order to accomplish CO2 loading measurements with a sample size of approximately 500µL, Fourier-transform infrared spectroscopy (FTIR) was used. Calibration against acid decomposition showed relatively good correlation and test data showed reasonable adherence to expected trends, however more extensive testing should be conducted to fully validate the usage of FTIR to determine CO2 loading on DGA.

Diglycolamine↗
NASA NTRS1992

Radio emission from chemically peculiar stars

In five VLA observing runs the initial survey of radio emission from magnetic Bp-Ap stars by Drake et al. is extended to include a total of 16 sources detected at 6 cm out of 61 observed, giving a detection rate of 26 percent. Of these stars, three are also detected at 2 cm, four at 3.6 cm, and five at 20 cm. The 11 new stars detected as radio sources have spectral types B5-A0 and are He-weak and Si-strong. No classical (SrCrEu-type) Ap stars have yet been detected. The 16 detected sources show a wide range of radio luminosities with the early-B He-S stars on average 20 times more radio luminous than the late-B He-W stars and 1000 times more luminous than Theta Aurigae. Multifrequency observations indicate flat spectra in all cases. Four stars have a detectable degree of circular polarization at one or more frequencies. It is argued that the radio-emitting CP (chemically peculiar) stars form a distinct class of radio stars that differs from both the hot star wind sources and the active late-type stars. The observed properties of radio emission from these stars may be understood in terms of optically thick gyrosynchrotron emission from a nonthermal distribution of electrons produced in a current sheet far from the star. In this model the electrons travel along magnetic fields to smaller radii and higher magnetic latitudes where they mirror and radiate microwave radiation.

Linsky, Jeffrey L.↗
DOE OSTI2020

Chemical Safety and Security Education in ACS-Approved Chemistry Programs

To date, chemical security education practices in postsecondary institutions are poorly understood. The purpose of this study is to provide an initial understanding of the practices, attitudes, and barriers toward chemical security education for undergraduate and graduate programs in the United States (US) by surveying representatives of American Chemical Society (ACS)-approved programs. All programs with ACS-approved undergraduate chemistry programs (n = 691) were contacted for participation: 21% (n = 148) fully completed and 6% (n = 41) partially completed the survey for a combined total of 27% complete and/or partially complete surveys (n = 189). We observed that most programs currently teach chemical safety (undergraduate >99%, graduate 73%); however, only about one-third of programs teach chemical security at any education level (undergraduate 32%, graduate 34%). We also observed that safety education is provided more frequently than security education. Further, ACS-approved programs reported that their chemical safety culture was stronger than chemical security culture and felt that safety should be taught differently than security. The overwhelming majority of respondents (96%) indicated that chemical safety should be mandatory at some level, while only about half of respondents (57%) indicated that chemical security should be mandatory at some level. More efforts are needed by the chemistry community to raise awareness of the importance of chemical security education so that more institutions commit to training their faculty and students on the topic. The authors suggest that adoption of chemical security education could be increased if ACS were to advocate for chemical security by including it in its guidelines for educational program approval.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2006

The Ozone Budget in the Upper Troposphere from Global Modeling Initiative (GMI)Simulations

Ozone concentrations in the upper troposphere are influenced by in-situ production, long-range tropospheric transport, and influx of stratospheric ozone, as well as by photochemical removal. Since ozone is an important greenhouse gas in this region, it is particularly important to understand how it will respond to changes in anthropogenic emissions and changes in stratospheric ozone fluxes.. This response will be determined by the relative balance of the different production, loss and transport processes. Ozone concentrations calculated by models will differ depending on the adopted meteorological fields, their chemical scheme, anthropogenic emissions, and treatment of the stratospheric influx. We performed simulations using the chemical-transport model from the Global Modeling Initiative (GMI) with meteorological fields from (It)h e NASA Goddard Institute for Space Studies (GISS) general circulation model (GCM), (2) the atmospheric GCM from NASA's Global Modeling and Assimilation Office(GMAO), and (3) assimilated winds from GMAO . These simulations adopt the same chemical mechanism and emissions, and adopt the Synthetic Ozone (SYNOZ) approach for treating the influx of stratospheric ozone -. In addition, we also performed simulations for a coupled troposphere-stratosphere model with a subset of the same winds. Simulations were done for both 4degx5deg and 2degx2.5deg resolution. Model results are being tested through comparison with a suite of atmospheric observations. In this presentation, we diagnose the ozone budget in the upper troposphere utilizing the suite of GMI simulations, to address the sensitivity of this budget to: a) the different meteorological fields used; b) the adoption of the SYNOZ boundary condition versus inclusion of a full stratosphere; c) model horizontal resolution. Model results are compared to observations to determine biases in particular simulations; by examining these comparisons in conjunction with the derived budgets, we may pinpoint deficiencies in the representation of chemical/dynamical processes.

Rodriquez, J.↗
NASA NTRS2004

New Reduced Two-Time Step Method for Calculating Combustion and Emission Rates of Jet-A and Methane Fuel With and Without Water Injection

A simplified kinetic scheme for Jet-A, and methane fuels with water injection was developed to be used in numerical combustion codes, such as the National Combustor Code (NCC) or even simple FORTRAN codes that are being developed at Glenn. The two time step method is either an initial time averaged value (step one) or an instantaneous value (step two). The switch is based on the water concentration in moles/cc of 1x10(exp -20). The results presented here results in a correlation that gives the chemical kinetic time as two separate functions. This two step method is used as opposed to a one step time averaged method previously developed to determine the chemical kinetic time with increased accuracy. The first time averaged step is used at the initial times for smaller water concentrations. This gives the average chemical kinetic time as a function of initial overall fuel air ratio, initial water to fuel mass ratio, temperature, and pressure. The second instantaneous step, to be used with higher water concentrations, gives the chemical kinetic time as a function of instantaneous fuel and water mole concentration, pressure and temperature (T4). The simple correlations would then be compared to the turbulent mixing times to determine the limiting properties of the reaction. The NASA Glenn GLSENS kinetics code calculates the reaction rates and rate constants for each species in a kinetic scheme for finite kinetic rates. These reaction rates were then used to calculate the necessary chemical kinetic times. Chemical kinetic time equations for fuel, carbon monoxide and NOx were obtained for Jet-A fuel and methane with and without water injection to water mass loadings of 2/1 water to fuel. A similar correlation was also developed using data from NASA's Chemical Equilibrium Applications (CEA) code to determine the equilibrium concentrations of carbon monoxide and nitrogen oxide as functions of overall equivalence ratio, water to fuel mass ratio, pressure and temperature (T3). The temperature of the gas entering the turbine (T4) was also correlated as a function of the initial combustor temperature (T3), equivalence ratio, water to fuel mass ratio, and pressure.

Molnar, Melissa↗
NASA NTRS2005

Simplified Two-Time Step Method for Calculating Combustion and Emission Rates of Jet-A and Methane Fuel With and Without Water Injection

A simplified kinetic scheme for Jet-A, and methane fuels with water injection was developed to be used in numerical combustion codes, such as the National Combustor Code (NCC) or even simple FORTRAN codes. The two time step method is either an initial time averaged value (step one) or an instantaneous value (step two). The switch is based on the water concentration in moles/cc of 1x10(exp -20). The results presented here results in a correlation that gives the chemical kinetic time as two separate functions. This two time step method is used as opposed to a one step time averaged method previously developed to determine the chemical kinetic time with increased accuracy. The first time averaged step is used at the initial times for smaller water concentrations. This gives the average chemical kinetic time as a function of initial overall fuel air ratio, initial water to fuel mass ratio, temperature, and pressure. The second instantaneous step, to be used with higher water concentrations, gives the chemical kinetic time as a function of instantaneous fuel and water mole concentration, pressure and temperature (T4). The simple correlations would then be compared to the turbulent mixing times to determine the limiting rates of the reaction. The NASA Glenn GLSENS kinetics code calculates the reaction rates and rate constants for each species in a kinetic scheme for finite kinetic rates. These reaction rates are used to calculate the necessary chemical kinetic times. Chemical kinetic time equations for fuel, carbon monoxide and NOx are obtained for Jet-A fuel and methane with and without water injection to water mass loadings of 2/1 water to fuel. A similar correlation was also developed using data from NASA's Chemical Equilibrium Applications (CEA) code to determine the equilibrium concentrations of carbon monoxide and nitrogen oxide as functions of overall equivalence ratio, water to fuel mass ratio, pressure and temperature (T3). The temperature of the gas entering the turbine (T4) was also correlated as a function of the initial combustor temperature (T3), equivalence ratio, water to fuel mass ratio, and pressure.

Molnar, Melissa↗
NASA NTRS1989

The Pathfinder Chemical Transfer Propulsion program

Pathfinder is a research and technology initiative by the National Aeronautics and Space Administration (NASA) intended to strengthen the technology base of the United States civil space program in preparation for future space exploration missions. Pathfinder begins in FY-89. One of the four major thrusts of Pathfinder is Space Transfer technology. A key element of this thrust is the Chemical Transfer Propulsion program which will provide the propulsion technology for high performance, liquid oxygen/liquid hydrogen expander cycle engines which are expected to be operated and maintained in space. These advanced engines will enhance or enable a variety of future space exploration missions. This paper describes the goals and objectives, management, technical plan, and technology transfer for the Chemical Transfer Propulsion element of Pathfinder.

Hannum, Ned P.↗
DOE OSTI2026

Quark flavor equilibration of the quark-gluon plasma

The early stage of a heavy-ion collision is marked by rapid entropy production and the transition from a gluon saturated initial condition to a plasma of quarks and gluons that evolves hydrodynamically. However, during the early times of the hydrodynamic evolution, the chemical composition of the QCD medium is still largely unknown. We present a study of quark chemical equilibration in the (Q)GP using a novel model of viscous hydrodynamic evolution in partial chemical equilibrium. Motivated by the success of gluon saturated initial condition models, we initialize the QCD medium as a completely gluon dominated state. Local quark production during the hydrodynamic phase is then simulated through the evolution of time-dependent fugacities for each independent quark flavor, with the timescales set as free parameters to compare different rates of equilibration. We present the results of complete heavy-ion collision simulations using this partial chemical equilibrium model, and show the effects on hadronic and electromagnetic observables. In particular, we show that the development of flow is sensitive to the equilibration timescale, providing an empirical way to probe the chemical equilibration of the QCD medium.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1992

Comet impacts and chemical evolution on the bombarded earth

Amino acids yields for previously published shock tube experiments are used with minimum Cretaceous-Tertiary (K/T) impactor mass and comet composition to predict AIB amino acid K/T boundary sediment column density. The inferred initial concentration of all amino acids in the K/T sea and in similar primordial seas just after 10 km comet impacts would have been at least 10 exp -7 M. However, sinks for amino acids must also be considered in calculating amino acid concentrations after comet impacts and in assessing the contribution of comets to the origin of life. The changing concentration of cometary amino acids due to ultraviolet light is compared with the equilibrium concentration of amino acids produced in the sea from corona discharge in the atmosphere, deposition in water, and degradation by ultraviolet light. Comets could have been more important than endogenous agents for initial evolution of amino acids. Sites favorable for chemical evolution of amino acids are examined, and it is concluded that chemical evolution could have occurred at or above the surface even during periods of intense bombardment of earth before 3.8 billion years ago.

Oberbeck, Verne R.↗