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At least 271 records · Page 15

All sources NASA NTRS DOE OSTI

DOE OSTI2018

Evaluation of Immobilizing Secondary Waste from a Proposed Treatment Process for Hanford WTP LAW Melter Condensate

The off-gas system in the Low Activity Waste (LAW) vitrification facility at the Hanford Waste Treatment and Immobilization Plant (WTP) will generate an aqueous condensate recycle stream. Two unit operations generate this condensate, a Submerged Bed Scrubber and a Wet Electrostatic Precipitator (LAW SBSWESP condensate). The expected disposition of this stream during baseline operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. The primary reason to recycle this stream is to immobilize the semivolatile 99 Tc isotope into the glass. During the Direct Feed Low Activity Waste (DFLAW) portion of the mission, the condensate is sent to the Effluent Management Facility (EMF) where it is evaporated then recycled to the LAW facility where the evaporated condensate is combined with the LAW feed from the pretreatment system.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Alkaline Modified Solid Oxide Catalysts for Condensation Reactions between Biomolecules

The coupling of oxygenates derived from biomass is critical to the production of sustainable commodity chemicals. However, most current industrial oxygenate condensation processes rely on highly corrosive homogenous basic catalysts. To find greener alternatives, several condensation reactions were screened using a variety of alkaline-doped MgO and MgO-Al2O3 heterogenous catalysts. These include i) the self-condensation of hexanedione to methylcyclopentenone, ii) the self-condensation of methyl ethyl ketone to form C8 or C12 ketones, and iii) the coupling of dimethyl succinate and benzaldehyde. We demonstrate substantial yields for several condensation reactions that typically require homogenous base catalysts

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Impact of synchronous condensers on fault location and black start in multi-inverter isolated microgrids

Synchronous condensers have been used in power systems for decades, but they are now attracting interest as a potential means for solving certain issues associated with inverter-based resources in islanded power systems. They have been extensively studied in applications to large wind farms and weak grids, but there has been very little study of synchronous condensers in intentionally-islanded systems, and especially self-healing ones. This report documents the results of an LDRD project intended to create modeling tools for use in the study of synchronous condensers in these smaller off-grid systems, and to explore synchronous condensers in this application. The results indicate that synchronous condensers have the potential to provide many benefits, but there are also several unanswered questions and technical challenges requiring further study.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2020

Condensed Phase Guerbet Reactions of Ethanol/Isoamyl Alcohol Mixtures

The self-condensation and cross-condensation reactions of ethanol and isoamyl alcohol are examined to better understand the potential routes to value-added byproducts from fuel ethanol production. Reactions have been carried out in both batch autoclave and continuous condensed-phase reactors using a lanthanum-promoted, alumina-supported nickel catalyst at near-critical condensed phase conditions. Analysis of multiple candidate kinetic models led to a Langmuir–Hinshelwood rate expression that is first-order in alcohol with water as the strongly adsorbed species. This model provides the best fit of data from both batch and continuous reactor experiments. Activation energies for primary condensation reactions increase as carbon chain lengths increase. Selectivities to higher alcohols of 94% and 87% for ethanol and isoamyl alcohol, respectively, were observed at different operating conditions.

Nezam, Iman (ORCID:0000000277598069)↗

NASA NTRS1974

Geothermal steam condensate reinjection

Geothermal electric generating plants which use condensing turbines and generate and excess of condensed steam which must be disposed of are discussed. At the Geysers, California, the largest geothermal development in the world, this steam condensate has been reinjected into the steam reservoir since 1968. A total of 3,150,000,000 gallons of steam condensate has been reinjected since that time with no noticeable effect on the adjacent producing wells. Currently, 3,700,000 gallons/day from 412 MW of installed capacity are being injected into 5 wells. Reinjection has also proven to be a satisfactory method of disposing of geothermal condensate a Imperial Valley, California, and at the Valles Caldera, New Mexico.

Chasteen, A. J.↗

NASA NTRS1978

Condensation processes and the formation of cosmic grains

The case of condensation from a gas in the absence of any preexisting grains or nuclei upon which condensation can occur is considered. Some of the analysis is expected to apply to condensation on grains already present. An attempt is made to examine the basic assumptions of the various procedures used to describe condensation and to examine their applicability to astronomical systems. Attention is given to thermodynamic equilibration calculations, nucleation theory, kinetic mechanisms, the theoretical mechanisms, and condensation experiments.

Donn, B.↗

NASA NTRS1979

Concentrations of condensation nuclei in the vicinity of jetstream maxima

Ozone and condensation nuclei were measured on March 29, 1977 (and March 30, GMT) from a Sabreliner in a frontal zone south of Denver, Colo. The ozone served as a tracer for stratospheric air and the condensation nuclei as a tracer for tropospheric air. Both the Langer condensation nucleus counter and the Rich-100 counter can be used to measure condensation nucleus concentrations in the vicinity of the tropopause. However, the former counter is more sensitive to low concentrations. The nuclei measured were found to be almost entirely larger than 0.005 micron in radius, consisting of thousands of molecules. The mesostructure of the ozone and condensation nucleus concentrations agreed well with a double structure of the frontal zone that became apparent from a detailed analysis of radiosonde data.

Cadle, R. D.↗

NASA NTRS1982

The growth of filaments by the condensation of coronal arches

A model of filament formation based on the condensation of coronal arches is described. The condensation results from initiating the radiative instability within an arch by superimposing a transient energy supply upon the steady state heating mechanism. The transient energy supply increases the density within the arch so that when it is removed the radiative losses are sufficient to lead to cooling below the minimum in the power loss curve. Times from the initial formation of the condensation to its temperature stabilization as a cool filament have been calculated for various initial conditions. They lie in the range 10,000-100,000 s with the majority of the time spent above a temperature of 1 x 10 to the 6th K. Under the assumption that the condensation of a single arch forms an element of the filament, a complete filament requires the condensation of an arcade of loops. Using experimentally derived parameters, filament densities of 10 to the 11th to 10 to the 12th per cu cm can be obtained.

Davis, J. M.↗

NASA NTRS1985

Structure-to-glass transition temperature relationships in high temperature stable condensation polyimides

The presence of a hexafluoroisopropylidene (6F) connecting group in aryl dianhydrides used to prepare aromatic condensation polyimides provides high glass transition temperature (T sub g) polyimides with excellent thermo-oxidative stability. The purpose of this study was to determine if a trifluorophenyl-ethylidene (3F) connecting group would have a similar effect on the T sub g of aromatic condensation polyimides. A new dianhydride containing the 3F connecting group was synthesized. This dianhydride and an aromatic diamine also containing the 3F connecting group were used together and in various combinations with known diamines or known dianhydrides, respectively, to prepare new 3F containing condensation polyimides. Known polyimides, including some with the 6F connecting linkage, were also prepared for comparison purposes. The new 3F containing polymers and the comparison polymers were prepared by condensation polymerization via the traditional amic-acid polymerization method in N,N-dimethylacetamide solvent. The solutions were characterized by determining their inherent viscosities and then were thermally converted into polyimide films under nitrogen atmosphere at 300 to 500 C, usually 350 C. The T sub g's of the films and resin discs were then determined by thermomechanical analysis and were correlated as a function of the final processing temperatures of the films and resin discs. The results showed that similarities existed in the T sub g's depending on the nature of the connecting linkage in the monomers used to prepare the condensation polyimides.

Alston, W. B.↗

NASA NTRS1986

Condensation modes in magnetized plasmas

Condensation modes in magnetized cylindrical plasmas, with concentration on how magnetic field affects the stability were studied. It is found that the effects of magnetic field (shear, twist, and strength) on the condensation modes are different depending on the wave vector. For modes whose wave vector is not perpendicular to magnetic field lines the plasma motion is mainly along the field lines; the effects of magnetic field on the modes are negligible except on the heat flow parallel to the field line. For a mode which is localized near a surface where the wave vector is perpendicular to the field line, the plasma moves perpendicular to the line carrying the field line into the condensed region; magnetic field affects the mode by building up magnetic pressure in the condensed region. The stability of condensation modes strongly depends on how density and temperature vary with field twist. The stable nature of global quiescent prominence magnetic configurations implies that prominences form for low field twist for which ideal MHD modes are stable; plasma temperature should increase with field twist for stable prominence formation.

An, Chang-Hyuk↗

NASA NTRS1989

Condensation polyimides

Polyimides belong to a class of polymers known as polyheterocyclics. Unlike most other high temperature polymers, polyimides can be prepared from a variety of inexpensive monomers by several synthetic routes. The glass transition and crystalline melt temperature, thermooxidative stability, toughness, dielectric constant, coefficient of thermal expansion, chemical stability, mechanical performance, etc. of polyimides can be controlled within certain boundaries. This versatility has permitted the development of various forms of polyimides. These include adhesives, composite matrices, coatings, films, moldings, fibers, foams and membranes. Polyimides are synthesized through both condensation (step-polymerization) and addition (chain growth polymerization) routes. The precursor materials used in addition polyimides or imide oligomers are prepared by condensation method. High molecular weight polyimide made via polycondensation or step-growth polymerization is studied. The various synthetic routes to condensation polyimides, structure/property relationships of condensation polyimides and composite properties of condensation polyimides are all studied. The focus is on the synthesis and chemical structure/property relationships of polyimides with particular emphasis on materials for composite application.

Hergenrother, P. M.↗

NASA NTRS1990

Steady evaporation and condensation of isolated clouds in hot plasma

The evaporation and condensation of an isolated cloud embedded in a thermally stable hot gas is studied under the assumption that the ambient hot gas is in thermal equilibrium at constant temperature and that the cloud is large enough that classical conduction is valid. It is found that the cloud will evaporate provided that it is smaller than the Field length, which gives the maximum range of thermal conduction. A large cloud can condense only if the pressure exceeds the saturated vapor pressure p(sat). The pressure required for condensation increases as the cloud radius decreases, until condensation becomes impossible. Since p(sat) is close to the maximum pressure at which the hot gas can exist in equilibrium, condensation is likely to occur under unsteady conditions. The Compton-bremsstrahlung case is treated as an example.

Mckee, Christopher F.↗

NASA NTRS1990

Self-irradiated cooling condensations - The source of the optical line emission from cooling flows

The optical filaments seen at the centers of clusters of galaxies, which cannot be explained by standard photoionization or shock models, can be straightforwardly interpreted as self-irradiated cooling condensations. Fully developed (about 10,000 K) condensations embedded in thermally unstable 10 million K gas will be bathed in a powerful EUV/soft X-ray flux emanating from the surrounding condensing regions. The present models of the condensation/irradiation process give line ratios and luminosities similar to those observed. Because it is assumed that the condensations arise from linear perturbations, which grow significantly only when the local cooling time is less than the free-fall time, condensing regions of the type modeled here should arise only in cooling flows of central pressure less than about 1 billion ergs/cu cm and should extend only over the inner regions of the cluster.

Voit, G. Mark↗

NASA NTRS1990

Influence of iodine on the treatment of spacecraft humidity condensate to produce potable water

Several compounds in the ersatz humidity condensate do react with iodine to form iodine-substituted organic compounds (TOI), most notably phenol, acetaldehyde, ethanol, and sodium formate. Iodination of the ersatz humidity condensate produced 3.0 to 3.5 mg/L of TOI within 24 hours. The TOI that was produced by the passage of the ersatz humidity condensate through the first iodinated resin (IR) in the adsorption system was removed by the granular activated carbon that followed. TOI detected in the final effluent was formed by the reaction of the non-adsorbable condensate compounds with the final IR in the treatment series. The activated carbon bed series in the adsorption system performed poorly in its removal of TOC. The rapid breakthrough of TOC was not surprising, as the ersatz humidity condensate contained several highly soluble organic compounds, alcohols and organic acids.

Symons, James M.↗

NASA NTRS1991

A numerical study of the direct contact condensation on a horizontal surface

The results of a numerical study of the direct contact condensation on a slowly moving horizontal liquid surface are presented. The geometrical configuration and the input conditions used to obtain numerical solutions are representative to those of experiments of Celata et al. The effects of Prandtl number (Pr), inflow Reynolds number, and Richardson number on the condensation rate are investigated. Numerical predictions of condensation rate for laminar flow are in good agreement with experimental data. The effect of buoyancy on the condensation rate is characterized by Richardson number. A correlation based on the numerical solutions is developed to predict the average condensation Nusselt number in terms of Richardson number, Peclet number, and inflow Reynolds number.

Hasan, M. M.↗

NASA NTRS1991

A numerical study of the direct contact condensation on a horizontal surface

Hasan, M. M.↗

NASA NTRS1992

Possible prebiotic significance of polyamines in the condensation, protection, encapsulation, and biological properties of DNA

While DNA which has undergone ionic condensation with Co(3+)(NH3)6 is resistant to the action of the endonuclase DNAse I, in much the same way as DNA condensed with spermidine, it was significantly less active in transcription with the E. coli RNA polymerase than DNA-spermidine condensed forms. Although both compacted forms of DNA were more efficiently encapsulated into neutral liposomes, negatively charged liposomes were seldom formed in the presence of the present, positive ion-condensed DNA; spermidine is accordingly proposed as a plausible prebiotic DNA-condensing agent. Attention is given to the relevance of the polyimide-nucleic acids complexes in the evolution of life.

Baeza, Isabel↗

NASA NTRS1993

Film condensation in a horizontal rectangular duct

Condensation heat transfer in a horizontal rectangular duct was experimentally and analytically investigated. To prevent the dripping of condensate on the film, the experiment was conducted inside a horizontal rectangular duct with vapor condensing only on the bottom cooled plate of the duct. R-113 and FC-72 (Fluorinert Electronic Fluid developed by the 3M Company) were used as the condensing fluids. The experimental program included measurements of film thickness, local and average heat transfer coefficients, wave length, wave speed, and a study of wave initiation. The measured film thickness was used to obtain the local heat transfer coefficient. The wave initiation was studied both with condensation and with an adiabatic air-liquid flow. The test sections used in both experiments were identical.

Lu, Qing↗