Transition of Blast Furnace Slag from Silicate Based to Aluminate Based: Electrical Conductivity
The electrical conductivity of the CaO-SiO{sub 2}-Al{sub 2}O{sub 3}-MgO-TiO{sub 2} slag was determined using the four-electrode method. The effect of the Al{sub 2}O{sub 3} and Al{sub 2}O{sub 3}/SiO{sub 2} mass ratio on the electrical conductivity was studied. At a fixed CaO/SiO{sub 2} ratio of 1.20, the electrical conductivity decreases with increasing Al{sub 2}O{sub 3} from 16 mass pct to 24 mass pct because of the increased polymerization of aluminosilicate structures and the reduced amount of conductive ions. However, it increases with Al{sub 2}O{sub 3} of more than 24 mass pct because of the difference in the stable energy between [AlO{sub 4}]{sup 5−} and [SiO{sub 4}]{sup 4−}. Increasing the Al{sub 2}O{sub 3}/SiO{sub 2} ratio from 0.47 to 0.79 causes the electrical conductivity to increase and has an opposite effect when the ratio is greater than 0.79. Furthermore, Raman spectroscopy of the quenched slags was analyzed to understand the structural role of Al{sub 2}O{sub 3} and Al{sub 2}O{sub 3}/SiO{sub 2} mass ratio in the network. The Raman spectroscopy results indirectly supported the variations of electrical conductivity with the composition of the slags.