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At least 271 records · Page 15

Effect of temperature and geometric parameters on elastic properties of tungsten nanowire: A molecular dynamics study

Tungsten is a promising material and has potential use as battery anode. Tungsten nanowires are gaining attention from researchers all over the world for this wide field of application. In this paper, we investigated effect of temperature and geometric parameters (diameter and aspect ratio) on elastic properties of Tungsten nanowire. Aspect ratios (length to diameter ratio) considered are 8:1, 10:1, and 12:1 while diameter of the nanowire is varied from 1-4 nm. For 2 nm diameter sample (aspect ratio 10:1), temperature is varied (10 K ~ 1500 K) to observe elastic behavior of Tungsten nanowire under uniaxial tensile loading. EAM potential is used for molecular dynamic simulation. We applied constant strain rate of 10{sup 9} s{sup −1} to deform the nanowire. Elastic behavior is expressed through stress vs. strain plot. We also investigated the fracture mechanism of tungsten nanowire and radial distribution function. Investigation suggests peculiar behavior of Tungsten nanowire in nano-scale with double peaks in stress vs. strain diagram. Necking before final fracture suggests that actual elastic behavior of the material is successfully captured through atomistic modeling.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Tuning the plasmon band number of aluminum nanorod within the ultraviolet-visible region by gold coating

The localized surface plasmon (LSP) properties of Al nanorod with Au coating have been investigated by using the quasi-static calculation. Because of the anisotropic plasmon splitting and the plasmon coupling between the Al and Au surfaces, the band number of LSP in the Al-Au core-shell nanorod could be tuned from 2 to 4 continuously in the ultraviolet-visible region. Due to the non-spherical symmetry and the dielectric polarization-induced plasmon energy fading, the Au coating-dependent plasmon shift and split are further affected by the aspect ratio and the dielectric surrounding. When the aspect ratio or the surrounding dielectric constant has a small value, the band number of LSP could only be tuned from 2 to 3. However, the band number of LSP could only be tuned from 3 to 4 when the aspect ratio or the surrounding dielectric constant has a large value. This tunable band number of LSP in the Au-coated Al nanorod provides potential application for multichannel plasmonic nanosensors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Thermal confinement and transport in spherical tokamaks: a review

Here, we review the thermal plasma confinement and transport properties observed and predicted in low aspect ratio tokamaks, or spherical tokamaks (STs), which can depart significantly from those observed at higher aspect ratio. In particular, thermal energy confinement scalings show a strong, near linear dependence of energy confinement time on toroidal magnetic field, while the dependence on plasma current is more modest, the opposite of what is seen at higher aspect ratio. STs have revealed a very strong improvement in normalized confinement with decreasing collisionality, much stronger than at higher aspect ratio, which bodes well for an ST-based fusion pilot plant should this trend continue at an even lower collisionality than has already been accessed. These differences arise because of fundamental differences in transport in STs due to the more extreme toroidicity (i.e. reduced region of bad curvature), and to the relatively larger $E_r \times B$ shearing rates, both of which can suppress electrostatic drift wave instabilities at both ion and electron gyroradius scales. In addition, electromagnetic effects are much stronger in STs because they operate at high β T . Gyrokinetic (GK) studies, coupled with low- and high-k turbulence measurements, have shed light on the underlying physics controlling transport. At lower β T , both ion- and electron-scale electrostatic drift turbulence may be responsible for transport. At higher β T , microtearing, kinetic ballooning, and hybrid trapped electron/kinetic ballooning modes increasingly play a role, and they have a much stronger impact in the core of ST plasmas than at higher aspect ratio. Flow shear affects the balance between ion- and electron-scale modes. Non-linear GK simulations find regimes where the electron heat flux decreases with decreasing collisionality, consistent with the experimental global normalized confinement scaling. The ST is unique in that the relatively low toroidal magnetic field allows for localized measurements of electron-scale turbulence, and this coupled with turbulence measurements at ion-scales has facilitated detailed comparisons with GK simulations. These data have provided compelling evidence for the presence of ion temperature gradient and electron temperature gradient turbulence in some plasmas, and direct experimental support for the impact of experimental actuators like rotation shear, density gradient and magnetic shear on turbulence and transport.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

New insights into the drainage of inundated ice-wedge polygons using fundamental hydrologic principles

Abstract. The pathways and timing of drainage from the inundated centers of ice-wedge polygons in a warming climate have important implications for carbon flushing, advective heat transport, and transitions from methane to carbon dioxide dominated emissions. Here, we expand on previous research using a recently developed analytical model of drainage from a low-centered polygon. Specifically, we perform (1) a calibration to field data identifying necessary model refinements and (2) a rigorous model sensitivity analysis that expands on previously published indications of polygon drainage characteristics. This research provides intuition on inundated polygon drainage by presenting the first in-depth analysis of drainage within a polygon based on hydrogeological first principles. We verify a recently developed analytical solution of polygon drainage through a calibration to a season of field measurements. Due to the parsimony of the model, providing the potential that it could fail, we identify the minimum necessary refinements that allow the model to match water levels measured in a low-centered polygon. We find that (1) the measured precipitation must be increased by a factor of around 2.2, and (2) the vertical soil hydraulic conductivity must decrease with increasing thaw depth. Model refinement (1) accounts for runoff from rims into the ice-wedge polygon pond during precipitation events and possible rain gauge undercatch, while refinement (2) accounts for the decreasing permeability of deeper soil layers. The calibration to field measurements supports the validity of the model, indicating that it is able to represent ice-wedge polygon drainage dynamics. We then use the analytical solution in non-dimensional form to provide a baseline for the effects of polygon aspect ratios (radius to thaw depth) and coefficient of hydraulic conductivity anisotropy (horizontal to vertical hydraulic conductivity) on drainage pathways and temporal depletion of ponded water from inundated ice-wedge polygon centers. By varying the polygon aspect ratio, we evaluate the relative effect of polygon size (width), inter-annual increases in active-layer thickness, and seasonal increases in thaw depth on drainage. The results of our sensitivity analysis rigorously confirm a previous analysis indicating that most drainage through the active layer occurs along an annular region of the polygon center near the rims. This has important implications for transport of nutrients (such as dissolved organic carbon) and advection of heat towards ice-wedge tops. We also provide a comprehensive investigation of the effect of polygon aspect ratio and anisotropy on drainage timing and patterns, expanding on previously published research. Our results indicate that polygons with large aspect ratios and high anisotropy will have the most distributed drainage, while polygons with large aspect ratios and low anisotropy will have their drainage most focused near their periphery and will drain most slowly. Polygons with small aspect ratios and high anisotropy will drain most quickly. These results, based on parametric investigation of idealized scenarios, provide a baseline for further research considering the geometric and hydraulic complexities of ice-wedge polygons.

Harp, Dylan R. (ORCID:0000000197778000)↗

Using solar availability factors to adjust cool-wall energy savings for shading and reflection by neighboring buildings

The extent to which a solar-reflective “cool” wall can reduce a building's cooling load in summer or increase its heating load in winter scales with the wall's incident solar radiation, or solar availability. We assess how the solar availability at the wall of a central (modeled) building is affected by a neighboring wall across an urban canyon by calculating the central wall's solar availability factor (SAF), defined as the ratio of sunlight incident on the central wall in the presence of the neighboring wall to that incident in the absence of the neighboring wall. Cool-wall heating, ventilation, and air conditioning (HVAC) energy savings simulated for an isolated central building (no neighbors) can be multiplied by SAFs to account for interactions with neighboring walls. Monthly values of SAF were evaluated in 17 climates across the United States, including three in California, for north, east, south, and west central walls, over a wide range of canyon aspect ratio (height/width). Results for four representative aspect ratios—0.2, 1, 2, and 10—are presented. In Fresno, CA, monthly SAF ranges from 0.90 to 0.96 for central walls facing north, east, south, or west when the aspect ratio is 0.2 (two-story single-family homes across a street) and both the central and neighboring walls are conventional (albedo 0.25). Monthly SAFs decrease as aspect ratio rises, falling to 0.06–0.24 at an aspect ratio of 10 (adjacent 10-story buildings on the same side of the street). An example worked for a two-story single-family home in Fresno on the west side of a residential street yields SAFs of 0.47 (north), 0.92 (east), 0.50 (south), and 0.63 (west) to apply to the cool-wall annual HVAC energy savings computed for an isolated central building. Shading and reflection reduce the home's annual HVAC energy cost savings by 31%.

14 SOLAR ENERGY↗

Fast Magnetic Reconnection: “Ideal” Tearing and the Hall Effect

One of the main questions in magnetic reconnection is the origin of triggering behavior with on/off properties that, once it is activated, accounts for the fast magnetic energy conversion to kinetic and thermal energies at the heart of explosive events in astrophysical and laboratory plasmas. Over the past decade, progress has been made on the initiation of fast reconnection via the plasmoid instability and what has been called “ideal” tearing, which sets in once current sheets thin to a critical inverse aspect ratio (a/L){sub c}. As shown by Pucci and Velli, at (a/L){sub c}∼S{sup −1/3}, the timescale for the instability to develop becomes of the order of the Alfvén time and independent of the Lundquist number (here defined in terms of current sheet length L). However, given the large values of S in natural plasmas, this transition might occur for thicknesses of the inner resistive singular layer that are comparable to the ion inertial length d {sub i}. When this occurs, Hall currents produce a three-dimensional quadrupole structure of the magnetic field, and the dispersive waves introduced by the Hall effect accelerate the instability. Here we present a linear study showing how the “ideal” tearing mode critical aspect ratio is modified when Hall effects are taken into account, including more general scaling laws of the growth rates in terms of sheet inverse aspect ratio: the critical inverse aspect ratio is amended to a/L≃(di/L){sup 0.29}(1/S){sup 0.19}, at which point the instability growth rate becomes Alfvénic and does not depend on either of the (small) parameters d{sub i}/L,1/S. We discuss the implications of this generalized triggering aspect ratio for recently developed phase diagrams of magnetic reconnection.

79 ASTRONOMY AND ASTROPHYSICS↗

Mass flow rate and pressure distribution of gas through three-dimensional micro-channels

An effective method to predict the mass flow rate and pressure distribution of gas through three dimensional micro-channels with different cross-section shapes has been proposed. For rectangular cross sections often employed in experiment, the present solutions versus measured data of Zohar et al. (2002) show that the side walls significantly affect the mass flow rates as the aspect ratio is smaller than 10, whereas the non-dimensional pressure distributions, mainly determined by the inlet-to-outlet pressure ratio, are insensitive to the aspect ratio.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Ice Particle and Aggregate Simulator (IPAS). Part I: Extracting Dimensional Properties of Ice–Ice Aggregates for Microphysical Parameterization

Aggregation, the process by which two or more ice particles attach to each other, is typically observed in clouds that span a range of temperatures and is influenced by the crystal shape (habit). In this study, the resulting characteristics of ice–ice two-monomer aggregation is investigated, which is expected to improve microphysical parameterizations through more precise aggregate characteristics and in turn better predict the rate of aggregation and snow development. A systematic way to determine the aspect ratio of the aggregate was developed, which takes into account the expected falling orientations, overlap of each monomer, and any contact angle that may form through so-called constrained randomization. Distributions were used to obtain the most frequent aspect ratio, major axis, and minor axis of aggregated particles with respect to the monomer aspect ratio. Simulations were completed using the Ice Particle and Aggregate Simulator (IPAS), a model that uses predefined three-dimensional geometries, (e.g., hexagonal prisms) to simulate ice crystal aggregation and allows for variation in crystal size, shape, number, and falling orientation. In this study, after collection in a theoretical grid space, detailed information is extracted from the particles to determine the properties of aggregates. It was found that almost all monomer aspect ratios aggregate to less extreme aggregate aspect ratios at nearly the same rate. Newly formed aggregate properties are amenable to implementation into more sophisticated bulk microphysical models designed to predict and evolve particle properties, which is crucial in realistically evolving cloud ice mass distribution and for representing the collection process.

54 ENVIRONMENTAL SCIENCES↗

Collisionless microtearing modes in hot tokamaks: Effect of trapped electrons

Collisionless microtearing modes have recently been found linearly unstable in sharp temperature gradient regions of large aspect ratio tokamaks. The magnetic drift resonance of passing electrons has been found to be sufficient to destabilise these modes above a threshold plasma β. A global gyrokinetic study, including both passing electrons as well as trapped electrons, shows that the non-adiabatic contribution of the trapped electrons provides a resonant destabilization, especially at large toroidal mode numbers, for a given aspect ratio. The global 2D mode structures show important changes to the destabilising electrostatic potential. The β threshold for the onset of the instability is found to be generally downshifted by the inclusion of trapped electrons. A scan in the aspect ratio of the tokamak configuration, from medium to large but finite values, clearly indicates a significant destabilizing contribution from trapped electrons at small aspect ratio, with a diminishing role at larger aspect ratios.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Controllable synthesis of ZnO nanograss with different morphologies and enhanced performance in dye-sensitized solar cells

A series of ZnO nanograss films grown on fluorine-doped tin oxide coated glass substrates were synthesized via hydrothermal method by using polyethyleneimine (PEI) as adjusting agent. The films were characterized by field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD). It was found that the PEI not only affected the aspect ratios of ZnO nanograss but also changed the geometrical shape of ZnO nanograss. A possible mechanism based on PEI adsorbed on the non-polar facets of ZnO that governed the growth rate of different directions were proposed to elucidate the effect of PEI on morphology of ZnO. The ZnO nanograss films were applied to dye-sensitized solar cells (DSSCs). The results showed that the photocurrent density significantly enhanced, and the power conversion efficiency increased by 55% based on ZnO nanograss synthesized in a growth solution containing 7 mmol/L PEI, resulting from the dye loading properties related to the different morphologies. - Graphical abstract: Effect of PEI on ZnO nanograss: controlling the aspect ratio and morphology of ZnO and enhancing their photovoltaic performance. Highlights: Black-Right-Pointing-Pointer ZnO nanograss with different aspect ratios were synthesized by adjusting PEI content. Black-Right-Pointing-Pointer PEI affects both on the aspect ratios and geometrical shapes of ZnO nanograss. Black-Right-Pointing-Pointer ZnO nanograss with high aspect ratio and needle-like tip was advantageous for improved photovoltaic conversion performance.

36 MATERIALS SCIENCE↗

Atomic layer deposition frequency-multiplied Fresnel zone plates for hard x-rays focusing

The design and fabrication of Fresnel zone plates for hard x-ray focusing up to 25 keV photon energies with better than 50 nm imaging half-pitch resolution is reported as performed by forming an ultrananocrystalline diamond (UNCD) scaffold, subsequently coating it with atomic layer deposition (ALD) with an absorber/phase shifting material, followed by back side etching of Si to form a diamond membrane device. The scaffold is formed by chemical vapor-deposited UNCD, electron beam lithography, and deep-reactive ion etching of diamond to desired specifications. The benefits of using diamond are as follows: improved mechanical robustness to prevent collapse of high-aspect-ratio ring structures, a known high-aspect-ratio etch method, excellent radiation hardness, extremely low x-ray absorption, and significantly improved thermal/dimensional stability as compared to alternative materials. Central to the technology is the high-resolution patterning of diamond membranes at wafer scale, which was pushed to 60 nm lines and spaces etched 2.2-mu m-deep, to an aspect ratio of 36:1. The absorber growth was achieved by ALD of Ir, Pt, or W, while wafer-level processing allowed to obtain up to 121 device chips per 4 in. wafer with yields better than 60%. X-ray tests with such zone plates allowed resolving 50 nm lines and spaces, at the limit of the available resolution test structures.

36 MATERIALS SCIENCE↗

Rheology of bi-disperse dense fiber suspensions

While significant progress has been made in the modeling and simulation of uniform fiber suspensions, no existing model has been validated for industrially-relevant concentrated suspensions containing fibers of multiple aspect ratios. In the present work, we investigate bi-disperse suspensions with two fiber populations in varying aspect ratios in a steady shear flow using direct numerical simulations. Moreover, we measure the suspension viscosity by creating a controlled length bidispersity for nylon fibers suspended in a Newtonian fluid. Here the results showed good agreement between the experimentally measured and numerically predicted viscosity for bi-disperse suspensions. The ratio between the aspect ratio of large to small fibers (size ratio) and the volume fraction of large fibers (composition) in bi-disperse systems strongly affected the rheological behavior of the suspension. The increment of relative viscosity associated with size ratio and composition can be explained by the decrease in the maximum flowable limit or jamming volume fraction. Moreover, the relative viscosity of bi-disperse suspensions collapses, when plotted against the reduced volume fraction, demonstrating the controlling influence of the jamming fraction in bi-disperse fiber suspensions.

42 ENGINEERING↗

Recent progress on spherical torus research

The spherical torus or spherical tokamak (ST) is a member of the tokamak family with its aspect ratio (A = R{sub 0}/a) reduced to A ∼ 1.5, well below the normal tokamak operating range of A ≥ 2.5. As the aspect ratio is reduced, the ideal tokamak beta β (radio of plasma to magnetic pressure) stability limit increases rapidly, approximately as β ∼ 1/A. The plasma current it can sustain for a given edge safety factor q-95 also increases rapidly. Because of the above, as well as the natural elongation κ, which makes its plasma shape appear spherical, the ST configuration can yield exceptionally high tokamak performance in a compact geometry. Due to its compactness and high performance, the ST configuration has various near term applications, including a compact fusion neutron source with low tritium consumption, in addition to its longer term goal of an attractive fusion energy power source. Since the start of the two mega-ampere class ST facilities in 2000, the National Spherical Torus Experiment in the United States and Mega Ampere Spherical Tokamak in UK, active ST research has been conducted worldwide. More than 16 ST research facilities operating during this period have achieved remarkable advances in all fusion science areas, involving fundamental fusion energy science as well as innovation. These results suggest exciting future prospects for ST research both near term and longer term. The present paper reviews the scientific progress made by the worldwide ST research community during this new mega-ampere-ST era.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Particle shape inhomogeneity and plasmon-band broadening of solar-control LaB{sub 6} nanoparticles

An ensemble inhomogeneity of non-spherical LaB{sub 6} nanoparticles dispersion has been analyzed with Mie theory to account for the observed broad plasmon band. LaB{sub 6} particle shape has been characterized using small-angle X-ray scattering (SAXS) and electron tomography (ET). SAXS scattering intensity is found to vary exponentially with exponent −3.10, indicating the particle shape of disk toward sphere. ET analysis disclosed dually grouped distribution of nanoparticle dispersion; one is large-sized at small aspect ratio and the other is small-sized with scattered high aspect ratio, reflecting the dual fragmentation modes during the milling process. Mie extinction calculations have been integrated for 100 000 particles of varying aspect ratio, which were produced randomly by using the Box-Muller method. The Mie integration method has produced a broad and smooth absorption band expanded towards low energy, in remarkable agreement with experimental profiles by assuming a SAXS- and ET-derived shape distribution, i.e., a majority of disks with a little incorporation of rods and spheres for the ensemble. The analysis envisages a high potential of LaB{sub 6} with further-increased visible transparency and plasmon peak upon controlled particle-shape and its distribution.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of surface protrusion on plasma sheath properties in atmospheric microdischarges

The electric field enhancement due to the presence of cathode surface protrusion is investigated in atmospheric microdischarges with the goal of identifying the plasma sheath properties (such as cathode sheath thickness and electric field distortion). The electric field enhancement caused by surface protrusion is examined by adjusting the aspect ratio and the protrusion size. It is found that the cathode electric field enhancement depends strongly (weakly) on the aspect ratio (size) of the protrusion when it is much smaller than the discharge gap distance. In particular, the axial electric field in both vacuum and discharges becomes nonlinear with the protrusion on the cathode. The cathode sheath thicknesses obtained by two different methods are compared. With the same axial (or radial) protrusion dimension, increasing the aspect ratio will result in a significant decrease in the sheath thickness, whereas increasing the axial protrusion size with an unchanged aspect ratio will only lead to a slight decrease in the sheath thickness. The results contribute to predicting the relative plasma sheath properties from the geometrical parameter of the surface protrusion in atmospheric microdischarges.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Ice Particle and Aggregate Simulator (IPAS). Part II: Analysis of a Database of Theoretical Aggregates for Microphysical Parameterization

Abstract Bulk ice-microphysical models parameterize the dynamic evolution of ice particles from advection, collection, and sedimentation through a cloud layer to the surface. Frozen hydrometeors can grow to acquire a multitude of shapes and sizes, which influence the distribution of mass within cloud systems. Aggregates, defined herein as the collection of ice particles, have a variety of formations based on initial ice particle size, shape, falling orientation, and the number of particles that collect. This work focuses on using the Ice Particle and Aggregate Simulator (IPAS) as a statistical tool to repetitively collect ice crystals of identical properties to derive bulk aggregate characteristics. A database of 9 744 000 aggregates is generated with resulting properties analyzed. After 150 single ice crystals (monomers) collect, the most extreme aggregate aspect ratio calculations asymptote toward and ϕ ca ≈ 0.50 for aggregates composed of quasi-horizontally oriented and randomly oriented monomers, respectively. The results presented are largely consistent with both a previous theoretical study and estimates derived from ground-based observations from two different geographic locations. Particle falling orientation highly influences newly formed aggregate aspect ratios from the collection of particles with extreme aspect ratios; quasi-horizontally oriented particles can produce aggregate aspect ratios an order of magnitude more extreme than randomly oriented particles but can also produce near-spherical aggregates as the number of monomers comprising the aggregate reach approximately 100. Finally, a majority of collections result in aggregates that are closer to prolate than oblate spheroids.

54 ENVIRONMENTAL SCIENCES↗

Crystallinity effects on scaling properties of photoinduced modes in silver nanoprisms

The crystallinity effects on scaling properties of photoinduced modes in crystalline silver nanoprisms with C{sub 3v} symmetry are studied using a realistic atomistic model and group theory. Among all vibrational modes, photoinduced modes can be identified as those vibrational modes which possess larger in-phase radial atomic displacement and can be projected out by the projected density of states method. We found that the properties of vibrations in silver nanoprisms strongly depend on the particle’s aspect ratio (bisector length over thickness). By considering crystallinity of silver nanoprisms, the dominant modes with the in-plane oscillation become several closely spaced modes, and become obvious for nanoprisms with a smaller aspect ratio. The oscillation spectra show that the dominant planar modes are insensitive to thickness change. On the contrary, the atomic displacements show significantly different patterns for nanoprisms of different thicknesses. We also found that, for nanoprisms with same aspect ratio that is larger than 4, the vibrational properties of dominant modes exhibit scaling similarity. By using a simple linear transformation, the vibration frequencies for large-sized nanoprisms of aspect ratio 6 can be obtained by a corresponding scaling factor. The calculated results are in good agreement with experimental data.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Free-standing gold elliptical nanoantenna with tunable wavelength in near-infrared region for enhanced Raman spectroscopy

The purpose of this work is to present a surface-enhanced Raman scattering (SERS) amplifying antenna for the possible usage in the near-infrared region. Instead of the visible-light range amplifying antenna such as a bowtie, the finite-difference time-domain (FDTD) simulation results indicate that elliptical antenna could provide large electromagnetic field enhancement at near-infrared wavelength by combining the free-standing enhancement property with large aspect ratios of the ellipse geometry. The simulation results consist with the enhancement factors characterized by SERS measurements at the excited wavelength of 785 nm for different aspect ratios and periodicities. In addition to the redshift of the resonance wavelength as the aspect ratio of ellipse increases, the free-standing structure modifies the resonance behavior and the dielectric environment of antenna by elevating the elliptical disk from the substrate. To interpret the simulation results, the analytical solution of resonance wavelength for ellipsoid dimmer is derived based on Lorentz–Mie theory, and comparisons are made between the analytical solution and simulation results. The quasi-static analytical solution provides a way to characterize the resonance behavior of two ellipsoid particles as a function of the gap distance, aspect ratio, and dielectric environment. In conclusion, the electrodynamic analysis for the periodic structure was performed in our FDTD simulations.

47 OTHER INSTRUMENTATION↗