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At least 253 records · Page 14

Combing Visible and Infrared Spectral Tests for Dust Identification

The MODIS Dark Target aerosol algorithm over Ocean (DT-O) uses spectral reflectance in the visible, near-IR and SWIR wavelengths to determine aerosol optical depth (AOD) and Angstrom Exponent (AE). Even though DT-O does have "dust-like" models to choose from, dust is not identified a priori before inversion. The "dust-like" models are not true "dust models" as they are spherical and do not have enough absorption at short wavelengths, so retrieved AOD and AE for dusty regions tends to be biased. The inference of "dust" is based on postprocessing criteria for AOD and AE by users. Dust aerosol has known spectral signatures in the near-UV (Deep blue), visible, and thermal infrared (TIR) wavelength regions. Multiple dust detection algorithms have been developed over the years with varying detection capabilities. Here, we test a few of these dust detection algorithms, to determine whether they can be useful to help inform the choices made by the DT-O algorithm. We evaluate the following methods: The multichannel imager (MCI) algorithm uses spectral threshold tests in (0.47, 0.64, 0.86, 1.38, 2.26, 3.9, 11.0, 12.0 micrometer) channels and spatial uniformity test [Zhao et al., 2010]. The NOAA dust aerosol index (DAI) uses spectral contrast in the blue channels (412nm and 440nm) [Ciren and Kundragunta, 2014]. The MCI is already included as tests within the "Wisconsin" (MOD35) Cloud mask algorithm.

aerosol optical depth↗

Systems and Methods for Automated Water Detection Using Visible Sensors

Systems and methods are disclosed that include automated machine vision that can utilize images of scenes captured by a 3D imaging system configured to image light within the visible light spectrum to detect water. One embodiment includes autonomously detecting water bodies within a scene including capturing at least one 3D image of a scene using a sensor system configured to detect visible light and to measure distance from points within the scene to the sensor system, and detecting water within the scene using a processor configured to detect regions within each of the at least one 3D images that possess at least one characteristic indicative of the presence of water.

Rankin, Arturo L.↗

Deep HST/STIS Visible-Light Imaging of Debris Systems Around Solar Analog Hosts

We present new Hubble Space Telescope observations of three a priori known starlight-scattering circumstellar debris systems (CDSs) viewed at intermediate inclinations around nearby close-solar analog stars: HD 207129, HD202628, and HD 202917. Each of these CDSs possesses ring-like components that are more massive analogs of our solar systems Edgeworth Kuiper Belt. These systems were chosen for follow-up observations to provide imaging with higher fidelity and better sensitivity for the sparse sample of solar-analog CDSs that range over two decades in systemic ages, with HD 202628 and HD 207129 (both approx. 2.3 Gyr) currently the oldest CDSs imaged in visible or near-IR light. These deep (10-14 ks) observations, made with six-roll point-spread-function template visible-light coronagraphy using the Space Telescope Imaging Spectrograph, were designed to better reveal their angularly large debris rings of diffuse low surface brightness, and for all targets probe their exo-ring environments for starlight-scattering materials that present observational challenges for current ground-based facilities and instruments. Contemporaneously also observing with a narrower occulter position, these observations additionally probe the CDS endo-ring environments that are seen to be relatively devoid of scatterers. We discuss the morphological, geometrical, and photometric properties of these CDSs also in the context of other CDSs hosted by FGK stars that we have previously imaged as a homogeneously observed ensemble. From this combined sample we report a general decay in quiescent-disk F disk /F star optical brightness approx. t( exp.-0.8), similar to what is seen at thermal IR wavelengths, and CDSs with a significant diversity in scattering phase asymmetries, and spatial distributions of their starlight-scattering grains.

starlight-scattering circumstellar debris systems ↗

Using Citizen Science Reports to Define the Equatorial Extent of Auroral Visibility

An aurora may often be viewed hundreds of kilometers equatorward of the auroral oval owing to its altitude. As such, the NOAA Space Weather Prediction Center (SWPC) Aurora Forecast product provides a "view line" to demonstrate the equatorial extent of auroral visibility, assuming that it is sufficiently bright and high in altitude. The view line in the SWPC product is based upon the latitude of the brightest aurora, for each hemisphere, as specified by the real-time oval variation, assessment, tracking, intensity, and online nowcasting (OVATION) Prime (2010) aurora precipitation model. In this study, we utilize nearly 500 citizen science auroral reports to compare with the view line provided by an updated SWPC aurora forecast product using auroral precipitation data from OVATION Prime (2013). The citizen science observations were recorded during March and April 2015 using the Aurorasaurus platform and cover one large geomagnetic storm and several smaller events. We find that this updated SWPC view line is conservative in its estimate and that the aurora is often viewable further equatorward than Is indicated by the forecast. By using the citizen reports to modify the scaling parameters used to link the OVATION Prime (2013) model to the view line, we produce a new view line estimate that more accurately represents the equatorial extent of visible aurora. An OVATION Prime (2013) energy flux-based equatorial boundary view line is also developed and is found to provide the best overall agreement with the citizen science reports, with an accuracy of 91 percent.

Case, N. A.↗

In-Flight Calibration and Performance of the OSIRIS-REx Visible and IR Spectrometer (OVIRS)

Performance of the Origins, Spectral Interpretation, Resource Identification, Security-Regolith Explorer (OSIRIS-REx) Visible and InfraRed Spectrometer (OVIRS) instrument was validated, showing that it met all science requirements during extensive thermal vacuum ground testing. Preliminary instrument radiometric calibration coefficients and wavelength mapping were also determined before instrument delivery and launch using NIST-traceable sources. One year after launch, Earth flyby data were used to refine the wavelength map by comparing OVIRS spectra with atmospheric models. Near-simultaneous data from other Earth-orbiting satellites were used to cross-calibrate the OVIRS absolute radiometric response, particularly at visible wavelengths. Trending data from internal calibration sources and the Sun show that instrument radiometric performance has been stable to better than 1% in the 18 months since launch.

spectrometer↗

Geostationary Visible Imager Calibration for the CERES SYN1deg Edition 4 Product

The Clouds and the Earth’s Radiant Energy System (CERES) project relies on geostationary (GEO) imager derived TOA broadband fluxes and cloud properties to account for the regional diurnal fluctuations between the Terra and Aqua CERES and MODIS measurements. Anchoring the GEO visible calibration to the MODIS reference calibration and stability is critical for consistent fluxes and cloud retrievals across the 16 GEO imagers utilized in the CERES record. The CERES Edition 4A used GEO and MODIS ray-matched radiance pairs over all-sky tropical ocean (ATO-RM) to transfer the MODIS calibration to the GEO imagers. The primary GEO ATO-RM calibration was compared with the deep convective cloud (DCC) ray-matching and invariant desert/DCC target calibration methodologies, which are all tied to the same Aqua-MODIS calibration reference. Results indicate that most GEO record mean calibration method biases are within 1% with respect to ATO-RM. Most calibration method temporal trends were within 0.5% relative to ATO-RM. The monthly gain trend standard errors were mostly within 1% for all methods and GEOs. The close agreement amongst the independent calibration techniques validates all methodologies, and verifies that the coefficients are not artifacts of the methodology but rather adequately represent the true GEO visible imager degradation.

Doelling, David↗

Building Supply Chain Visibility for Risk Management: Illuminating the COVID-19 Pandemic Impact Upon NASA Suppliers

NASA mission projects rely upon global supply chains subject to an array of risks that threaten to disrupt or deny the timely, affordable provision of products and services as required for mission success. Visibility into these supply chains is key to the management of risks, such as those stemming from the coronavirus pandemic and its associated effects upon suppliers. Accordingly, the Supplier Research and Analysis (SRA) Program within Goddard Space Flight Center’s Safety and Mission Assurance (SMA) Directorate produced the COVID-19 pandemic/NASA suppliers dashboard as part of the NASA Meta Information System. The dashboard provides visibility and situational awareness to aid risk assessment, planning and decision-making over the course of the pandemic recovery phase. The approach of integrating data and information into visual dashboard displays has also been employed by the SRA Program to focus on specific risks pertaining to foreign-based suppliers. This webinar is presented by the NASA Office of SMA and its Supply Chain Risk Management Program, in collaboration with the NASA Safety Center and Goddard’s SMA Directorate.

supplier research and analysis, supply chain risk ↗

Weak Spectral Features on (101995) Bennu from the OSIRIS-REx Visible and InfraRed Spectrometer

Context. The NASA Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission has obtained thousands of spectra of asteroid (101955) Bennu with the OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS). Aims. We present a spectral search for minor absorption bands and determine compositional variations on the surface of Bennu. Methods. Reflectance spectra with low and high spatial resolutions were analyzed for evidence of weak absorption bands. Spectra were also divided by a global average spectrum to isolate unique spectral features, and variations in the strongest band depths were mapped on a surface shape model. The global visible to near-IR spectrum of Bennu shows evidence of several weak absorption bands with depths of a few percent. Results. Several observed bands are consistent with phyllosilicates, and their distribution correlates with the stronger 2.74-μm hydration band. A 0.55-μm band is consistent with iron and is deepest in the spectrally reddest areas on Bennu. The presence of hydrated phyllosilicates and iron oxides indicates substantial aqueous alteration in Bennu’s past. Conclusions. Bennu’s spectra are not identical to a limited set of carbonaceous chondrite spectra, possibly due to compositional properties and spatial scale differences; however, returned samples should contain a mixture of common chondrite materials.

OSIRIS-REx↗

Spectral Properties of Dust on Asteroid (101955) Bennu with the OSIRIS-REx Visible and Infrared Spectrometer (OVIRS)

The Origins, Spectral Interpretation, Resource Identification, Security-Regolith Explorer (OSIRIS-REx) spacecraft successfully collected a sample of regolith from asteroid (101955) Bennu on October 20, 2020[1]. The Touch-and-Go (TAG) spacecraft maneuver used to collect the sample mobilized material, including very fine particles (dust),from up to ~1m in depth and ~10m in diameter from the point of contact with the asteroid [1,2].TAG created a dust plume that intercepted the spacecraft and accumulated on the instruments. As a result, all instruments show degradation in optical throughput, with the degree of degradation depending on their aperture size, orientation, and position on the spacecraft [1]. In this study, we analyzed OSIRIS-REx Visible and Infrared Spectrometer (OVIRS) from before and after TAG to assess the dust on the instrument with implications for Bennu’s dust composition and scattering properties, and future visible–near-infrared (VNIR)spectral observations with the OSIRIS-REx spacecraft. OVIRS is a point spectrometer that measures reflected light at VNIR wavelengths from 0.4 to 4.3 μm with a 4 mrad circular field of view(FOV) [3]. Previous observations with OVIRS revealed widespread hydrated minerals and carbon-bearing materials on Bennu [4,5]. A ~3 μm absorption feature is observed globally in OVIRS spectra, with a band position and depth that is consistent with Mg/Fe phyllosilicates and suggests a similar degree of aqueous alteration to that experienced by some carbonaceous chondrite meteorites[4,6]. A series of weak (<5%) VNIR spectral features, potentially associated with hydrated phyllosilicates and iron oxides, are also found in OVIRS spectra (Fig. 1), though not typically observed in meteorite spectra [7]. OSIRIS-REx Thermal Emission Spectrometer (OTES) spectra are consistent with a very thin accumulation (a few to ~ten microns) of fine particles (<~65–100 microns in size)across the surface of Bennu, and particularly on the roughest boulders, an interpretation that is supported by the dust plume seen during TAG [1,8]. An analysis of TAG contamination on the OTES optics revealed a 15% decrease in throughput, and OTES observations of space with and without that contamination allow a recreation of the thermal infrared spectrum [1]. The spectrum of the contamination lacks volume scattering features and exhibits a stronger Mg-OH absorption (~16.5 μm) than average Bennu, suggesting a Mg-rich phyllosilicate composition [1,6]. Here we present the first compositional analysis of Bennu dust at VNIR wavelengths by analyzing the contaminant on OVIRS.

H H Kaplan↗

QWIP: A Quantitative Metric for Quality Control of Aquatic Reflectance Spectral Shape using the Apparent Visible Wavelength

The colors of the ocean and inland waters span clear blue to turbid brown, and the corresponding spectral shapes of the waterleaving signal are diverse depending on the various types and concentrations of phytoplankton, sediment, detritus and colored dissolved organic matter. Here we present a simple metric developed from a global dataset spanning blue, green and brown water types to assess the quality of a measured or derived aquatic spectrum. The Quality Water Index Polynomial (QWIP) is founded on the Apparent Visible Wavelength (AVW), a one-dimensional geophysical metric of color that is inherently correlated to spectral shape calculated as a weighted harmonic mean across visible wavelengths. The QWIP represents a polynomial relationship between the hyperspectral AVW and a Normalized Difference Index (NDI) using red and green wavelengths. The QWIP score represents the difference between a spectrum’s AVW and NDI and the QWIP polynomial. The approach is tested extensively with both raw and quality controlled field data to identify spectra that fall outside the general trends observed in aquatic optics. For example, QWIP scores less than or greater than 0.2 would fail an initial screening and be subject to additional quality control. Common outliers tend to have spectral features related to: 1) incorrect removal of surface reflected skylight or 2) optically shallow water. The approach was applied to hyperspectral imagery from the Hyperspectral Imager for the Coastal Ocean (HICO), as well as to multispectral imagery from the Visual Infrared Imaging Radiometer Suite (VIIRS) using sensor-specific extrapolations to approximate AVW. This simple approach can be rapidly implemented in ocean color processing chains to provide a level of uncertainty about a measured or retrieved spectrum and flag questionable or unusual spectra for further analysis.

remote sensing reflectance↗

Development of Radioluminescent Tritium Polymeric Material for High Visibility Applications

The Development of Radioluminescent Tritium Polymeric Material for High Visibility Applications effort investigates the nature and properties of materials consisting of tritium lights combined with various silicone adhesives. Physical, mechanical, and optical properties will be observed/measured, including their durability in the low earth orbit environment. Tritium or hydrogen-three is a radioactive isotope of hydrogen that emits beta particles as it undergoes a process called beta decay. A beta particle is a high-energy, high-speed electron (or positron) emitted from radioactive decay of an atomic nucleus. Because it is a gas, tritium must be bound to a material or encapsulated in a sealed glass container. The gaseous tritium can then be combined with a phosphor source which when struck with beta particles, fluoresces and emits light. Such a light source is referred to as a gaseous tritium light source (GTLS). A self-powered, radioluminescent tritium material capable of surviving multiple space environments has the potential to fulfill visibility requirements levied on space flight hardware and facilitate additional long term internal and external lighting needs such as for imaging, docking, tracking, and xEMU suits for lunar exploration on the moon.

Lauren Fisher↗

The Spectral Characteristics of Lunar Agglutinates: Visible-Near-Infrared Spectroscopy of Apollo Soil Separates

The lunar surface evolves over time due to space weathering, and the visible–near-infrared spectra of more mature (i.e., heavily weathered) soils are lower in reflectance and steeper in spectral slope (i.e., darker and redder) than their immature counterparts. These spectral changes have traditionally been attributed to the space-weathered rims of soil grains (and particularly nanophase iron therein). However, understudied thus far is the spectral role of agglutinates—the agglomerates of mineral and lithic fragments, nanophase iron, and glass that are formed by micrometeoroid impacts and are ubiquitous in mature lunar soils. We separated agglutinates and non-agglutinates from six lunar soils of varying maturity and composition, primarily from the 125–250 μm size fraction, and measured their visible–near-infrared reflectance spectra. For each soil, the agglutinate spectra are darker, redder, and have weaker absorption bands than the corresponding non-agglutinate and unsorted soil spectra. Moreover, greater soil maturity corresponds to darker agglutinate spectra with weaker absorption bands. These findings suggest that agglutinates (rather than solely the space-weathered rims) play an important role in both the darkening and reddening of mature soils—at least for the size fractions examined here. Comparisons with analog soils suggest that high nanophase iron abundance in agglutinates is likely responsible for their low reflectance and spectrally red slope. Additional studies of agglutinates are needed both to more comprehensively characterize their spectral properties (across size fractions and in mixing with non-agglutinates) and to assess the relative roles of agglutinates and rims in weathering-associated spectral changes. Plain Language Summary - In scientific study of the Moon, one key focus is surface processes: how do physical and chemical properties of the Moon’s surface change over time due to weathering (e.g., bombardment by micrometeoroids and by particles from the Sun)? Such investigations provide valuable insights into the Moon’s history (such as the ages of impact craters) that are often deduced from measurements of reflected light; as a soil is weathered it reflects light differently, which manifests visually as a progressive darkening of the soil. This phenomenon had primarily been attributed to weathering-associated development of rims on individual soil grains, but in this work we explored an alternative cause: soil particles known as agglutinates (misshapen, vesicular agglomerates of mineral fragments, iron, and glass that form due to weathering processes). We isolated agglutinates of six soil samples from the Moon and measured how they reflect light. We find that they reflect light in patterns reminiscent of how the Moon’s surface does when weathered. These findings suggest that agglutinates play a more important role than previously thought in determining the light-reflecting properties of the Moon’s surface, thus warranting greater and more nuanced consideration in future studies of how the Moon’s surface changes over time.

spectroscopy↗

Simultaneous measurement of visible energy and momentum transfer in anti-electron neutrino interactions on hydrocarbon

Precise knowledge of neutrino interaction cross sections is required for current and future accelerator-based neutrino oscillation experiments. Precision neutrino oscillation measurements require inference of the neutrino energy and flavor from the visible particles in the neutrino interaction in the detector. This inference is different for the true neutrino flavors measured, electron and muon neutrinos, and can be studied by observation of neutrino interactions in an experiment’s near detector. However, anti-electron neutrinos make up only a few percent of an anti-muon neutrino beam and pose a challenge in making cross section measurements and predictions. The reported measurements were made using data from MINERvA, a neutrino-nucleus scattering experiment, with an anti-neutrino beam configuration of mean energy ~ 6 GeV. This thesis provides two double-differential cross sections of anti-electron neutrino inclusive charged-current reactions using the kinematics of visible energy, three-momentum transfer, and transverse momentum. The analysis is carried out at low three-momentum transfer, making it sensitive to regions with multi-nucleon effects.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Hydrazone-Linked Heptazine Polymeric Carbon Nitrides for Synergistic Visible-Light-Driven Catalysis

Heptazine-based conjugated polymeric carbon nitrides (PCNs) are promising metal-free photocatalysts, yet their synthesis is challenging due to the electron-deficiency and insolubility of heptazine units. Indeed, heptazine-containing polymers have only been prepared through nucleophilic substitution with amines by using toxic cyameluric chloride as the starting material. Herein, we report the novel and environmentally friendly method for preparing heptazine-based mesoporous PCNs with hydrazone links formed through a simple Schiff base condensation of melem-NH 2 and aldehydes. Unlike cyameluric chloride, melem-NH 2 is non-toxic, stable, and can be readily obtained from melem and hydrazine in solution. We demonstrate that the hydrazone linkages and the heptazine units synergistically enhance the photocatalytic activity of PCNs in visible-light-driven aerobic oxidation of benzyl alcohol to benzaldehyde. In particular, the polymer constructed from melem-NH2 and p-phthalaldehyde shows 17 times more activity than graphitic carbon nitride (g-C 3 N 4 ).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhanced visible-light-assisted peroxymonosulfate activation on cobalt-doped mesoporous iron oxide for orange II degradation

Sulfate radical-based advanced oxidation processes (SR-AOP) attracted a lot of attention due to their capability and adaptability in wastewater treatment. Although heterogeneous cobalt-based catalysts have been extensively studied and have emerged superior for peroxymonosulfate (PMS) activation, leaching of cobalt is still a major concern. Herein, we report a photo-assisted PMS activation approach using cobalt doped mesoporous iron oxide with exceptional activity and stability up to 7 cycles with very low cobalt leaching (0.5 ppm). The highest activity was obtained by 1 mol % cobalt doped mesoporous iron oxide. Orange II dye was completely degraded by the reactive oxygen species (ROS) generated under visible light irradiation within 1 min. ROS were evaluated using two distinct techniques (Fluorescence probes and Electron Paramagnetic Resonance (EPR). ROS quenching experiments were also used to highlight the dominant pathway. This study correlates the structural and electronic changes induced with cobalt doping to the exceptional activity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Visibility-enhanced model-free deep reinforcement learning algorithm for voltage control in realistic distribution systems using smart inverters

Increasing integration of distributed solar photovoltaic (PV) into distribution networks could result in adverse effects on grid operation. Traditional model-based control algorithms require accurate model information that is difficult to acquire and thus are challenging to implement in practice. Here, this paper proposes a surrogate model-enabled grid visibility scheme to empower deep reinforcement learning (DRL) approach for distribution network voltage regulation using PV inverters with minimal system knowledge. In contrast to existing DRL methods, this paper presents and corroborates the adverse impact of missing load information on DRL performance and, based on this finding, proposes a surrogate model methodology to impute load information utilizing observable data. Additionally, a multi-fidelity neural network is utilized to construct the DRL training environment, chosen for its efficient data utilization and enhanced robustness to data uncertainty. The feasibility and effectiveness of the proposed algorithm are assessed by considering DRL testing across varying degrees of observable load information and diverse training environments on a realistic power system.

14 SOLAR ENERGY↗

Zero-biased and visible-blind UV photodetectors based on nitrogen-doped ultrananocrystalline diamond nanowires

Taking advantage of the superflat surface of ultrananocrystalline diamond (UNCD), highly precise UNCD nanowire (NW) arrays were fabricated to develop high-performance UV photodetectors. The large surface-to-volume ratio of a nanowire significantly increases the number of surface trap states, and the reduced dimensionality effectively confines the active area of the charge carrier and shortens the transit time, which results in an enhanced photoconductivity and response speed. Here, in this paper, the zero-biased UV photodetectors based on nitrogen-incorporated ultrananocrystalline diamond nanowire arrays have been demonstrated and characterized. The estimated responsivity was 2.0 A/W for 350 nm incident light when the device operated at room temperature. The UVA and UVB photocurrent signals from this visible blind photodetector were well defined with a rise and decay time of less than 1 s.

36 MATERIALS SCIENCE↗

Visible Out-of-plane Polarized Luminescence and Electronic Resonance in Black Phosphorus

Black phosphorus (BP) is unique among layered materials because of its homonuclear lattice and strong structural anisotropy. While recent investigations on few-layer BP have extensively explored the in-plane (a, c) anisotropy, much less attention has been given to the out-of-plane direction (b). Here, the optical response from bulk BP is probed using polarization-resolved photoluminescence (PL), photoluminescence excitation (PLE), and resonant Raman scattering along the zigzag, out-of-plane, and armchair directions. An unexpected b-polarized luminescence emission is detected in the visible, far above the fundamental gap. PLE indicates that this emission is generated through b-polarized excitation at 2.3 eV. The same electronic resonance is observed in resonant Raman with the enhancement of the A g phonon modes scattering efficiency. These experimental results are fully consistent with DFT calculations of the permittivity tensor elements and demonstrate the remarkable extent to which the anisotropy influences the optical properties and carrier dynamics in black phosphorus.

36 MATERIALS SCIENCE↗