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At least 253 records · Page 14

Increasing Main Cooler Thermal Performance for sCO2 Power Cycles

Increasing sCO2 power cycle cooler performance will increase the efficiency and lower the cost of electricity for sCO2 power cycles. This work considered the heat transfer performance of two counter-flow, shell-and-tube heat exchangers using local measurements. The heat exchangers were constructed using commercial tubing. One heat exchanger was constructed with a conventional, smooth inner tube (7 mm nominal inner diameter). The other was constructed with an additively manufactured tube with a square cross section and angled rib turbulators. For the present study, the measured Nusselt number was 30% less than the Dittus-Boelter correlation. The decrease was attributed to heat transfer degradation. The cooler performance was also reported as heat exchanger effectiveness. A factor of two improvement in Nusselt number (94%) relative to smooth conventional tubes was observed, indicating that heat transfer enhancement features (such as the ribs) are a suitable technology to overcome heat transfer degradation in sCO2 coolers. Trends in heat exchanger effectiveness indicated that the ribs were most beneficial when the water flow rates were at the low end of the range considered: 0.016 – 0.126 kg/s. Using results from prior system modeling, it is anticipated that adding heat transfer enhancement features in a cycle cooler will increase the sCO2 cycle efficiency by 0.34 percentage points.

Searle, Matthew↗

Preliminary Assessment of Additively Manufactured Cooling Channel Performance for Helium-Cooled Blanket Concepts

Sufficient cooling of the blanket first wall remains a critical challenge for the design and deployment of fusion power plants. Helium has been targeted as a potential blanket coolant due to its inertness and low neutron interactivity, among other advantages. However, the low thermal mass of helium creates a need for heat transfer enhancements in coolant channels to provide adequate cooling to the blanket’s first wall. Toward this end, a series of ribbed flow channels of various rib cross sections and configurations has been produced via additive manufacturing (AM) to study the efficacy of AM for first wall heat transfer enhancement and the optimization of heat transfer geometries. Helium cooling performance is studied in AM test articles at 4 MPa operating pressure, Reynolds numbers up to 197 000, and outer surface heat fluxes up to 42 kW/m 2 in the recently commissioned helium flow loop experiment (HFLE). Preliminary results of this study are presented herein. Heat transfer performance of nominally smooth (i.e., featureless) AM channels is quantified via measured Nusselt numbers and friction factors and compared to off-the-shelf smooth pipe experiments. Results are compared to existing correlations and used to discuss the effects of the AM processes on thermal-hydraulic performance. It is seen that the inherent roughness of the AM channels leads to an increase in both heat transfer coefficient and pressure drop when compared to the conventional pipe. In conclusion, recommendations are made for future studies based on these findings and additional considerations for the deployment of AM blanket cooling components.

36 MATERIALS SCIENCE↗

Numerical simulation of falling film sensible heat transfer over round horizontal tubes

Numerical simulations are performed to explore the heat transfer characteristics of falling films over horizontal round tubes with uniform heat flux imposed for a range of Reynolds numbers spanning the droplet, jet, and sheet regimes. Simulations results agree well with available experimental measurements. The study analyzes the local as well as average heat transfer behavior under the different flow modes. The numerical results show that the local Nusselt number (Nu) distribution depends on the flow features in each mode and varies substantially in all directions for the respective mode. In the droplet mode, the Nu value varies significantly as the droplet impinges and the remnant liquid-bridge retracts (peak instantaneous Nu near 6), followed by wave propagation over the tube surface with peak Nu around 0.25. For the jet modes, the local maximum in the heat transfer occurs off-center to the impingement location with magnitudes of peak Nu = 3.1 for the inline jet mode and Nu = 2.7 for the staggered jet mode, while on the rest of the tube surface, it has an inverse relation with the liquid film thickness. Substantial variations in the heat transfer value are also recorded in the middle of the two impinging jets with Nu = 0.95 in the inline jet mode where the neighboring jets do not interact, and Nu = 0.60 in the crest region of the staggered jet mode where the neighboring jets interact with each other. In the sheet mode, the Nu was seen to depend on the thickness of the liquid waves traversing over the tube surface. Lower Nu values were recorded beneath the crest location of the liquid waves, which increases (1.4–11.6% depending on circumferential location) abruptly in magnitude at the advancing fronts of the waves. The temperature distribution in the liquid film in each of the modes was examined to evaluate the mechanism of heat transfer process. This study also compares the local heat transfer coefficient distribution with the analytical heat transfer models derived to predict heat transfer performance over horizontal tube surfaces.

42 ENGINEERING↗

Validation of SOLPS-ITER simulations with kinetic, fluid, and hybrid neutral models for JET-ILW low-confinement mode plasmas

For JET L-mode plasmas in low-recycling conditions (electron temperature at the outer strike point, T e,ot ≳ 30 eV ), SOLPS-ITER simulations agree within the error bars for the experimental profiles at the low-field side (LFS) divertor target. The peak Balmer-α (Dα ) emission in the LFS divertor agrees within the error bars of the KS3 filterscope diagnostic, but is approximately 30% lower than the peak value of the KT1 spectrometer. Simulations have been performed with fluid, kinetic, and hybrid models for the neutrals. The large fluid-kinetic discrepancies of more than a factor 2 are successfully corrected by using a hybrid fluid-kinetic approach, for which kinetic atoms are transferred to the fluid population when the local Knudsen number of the atom becomes smaller than a user-defined transition Knudsen number Kn t . The hybrid-kinetic discrepancies are limited to a few % for Kn t ≤ 100 . When increasing the upstream density to high-recycling conditions, at the onset of detachment ( T e,ot ≈ 5 eV ), the simulations predict more than a factor 2 lower peak ion saturation current to the LFS divertor than the experiments. Also the Dα emission is underpredicted with approximately a factor 2. For these high-recycling conditions, the fluid-kinetic discrepancies are limited to maximum 50%, which are again corrected by using the hybrid approach.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates

For this work, two neptunium(III) mellitates, 237 Np 2 (mell)(H 2 O) 9 ·1.5H 2 O (Np-1α) and 237 Np 2 (mell)(H 2 O) 8 ·2H 2 O (Np-1β), have been synthesized from 237 NpCl 4 (dme) 2 by reduction with KC 8 and subsequent reaction with an aqueous solution of mellitic acid (H 6 mell). Characterization by single-crystal X-ray crystallography and UV–vis–NIR spectroscopy confirms that the neptunium is in its +3 oxidation state and both polymorphs are isostructural to the previously reported plutonium mellitates. Of the two morphologies, Np-1α is indefinitely stable in air, while Np-1β slowly oxidizes over several months. This is due to the change in the energy of the metal-ligand charge-transfer absorption exhibited by these compounds attributed to differing numbers of carboxylate bonds to Np(III), where in Np-1β the energy is low enough to result in spontaneous oxidation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Development of a 300 MWe Utility Scale Oxy-Fuel sCO2 Turbine

A 300 MWe direct-fired supercritical carbon dioxide (sCO2) oxy-fuel turbine is being developed that will burn natural gas-fired, coal syngas and even hydrogen mixtures capable of 1,150ºC turbine inlet temperature at 300 bar. This design will significantly improve the state-of-the-art for thermal efficiency and results in a high-pressure stream of CO2 with 98%+ carbon capture, making the power plant near emission-free and more efficient than Natural Gas Combined Cycle (NGCC) plants with carbon capture. This power plant will be capable of burning coal through gasification and cleanup of the synthesis gas (syngas). sCO2 power cycles are a transformational technology for the energy industry, providing higher efficiency heat source energy conversion for conventional and alternative energy sources. This novel cycle significantly reduces capital costs because of smaller equipment footprints, design modularity, and allows for rapid cyclic load and source following to balance solar and wind energy power swings. Oxy-fuel sCO2 cycles take these advantages even further, utilizing higher firing temperatures, improved efficiency, and simpler carbon capture strategies. This turbine will require cooled turbine nozzles and blades as well as advanced thermal management systems to accommodate these high temperatures. The cooled blade heat transfer correlations required new test programs at higher Reynolds number than air-breathing gas turbines for impingement, serpentine, and pin-fin regions. Novel blade optimization was performed to maximize aerodynamic efficiency, while minimizing cooling flows. A turbine layout was generated utilizing individual combustor cans with cooled liners feeding into a 6-stage axial flow turbine with cooled stator nozzles and turbine blades. The case design and thermal management preliminary design will be described.

Moore, Jeffrey↗

Data-Driven Reduced-Order Modeling of Convective Heat Transfer in Porous Media

This work presents a data-driven Reduced-Order Model (ROM) for parametric convective heat transfer problems in porous media. The intrusive Proper Orthogonal Decomposition aided Reduced-Basis (POD-RB) technique is employed to reduce the porous medium formulation of the incompressible Reynolds-Averaged Navier–Stokes (RANS) equations coupled with heat transfer. Instead of resolving the exact flow configuration with high fidelity, the porous medium formulation solves a homogenized flow in which the fluid-structure interactions are captured via volumetric flow resistances with nonlinear, semi-empirical friction correlations. A supremizer approach is implemented for the stabilization of the reduced fluid dynamics equations. The reduced nonlinear flow resistances are treated using the Discrete Empirical Interpolation Method (DEIM), while the turbulent eddy viscosity and diffusivity are approximated by adopting a Radial Basis Function (RBF) interpolation-based approach. The proposed method is tested using a 2D numerical model of the Molten Salt Fast Reactor (MSFR), which involves the simulation of both clean and porous medium regions in the same domain. For the steady-state example, five model parameters are considered to be uncertain: the magnitude of the pumping force, the external coolant temperature, the heat transfer coefficient, the thermal expansion coefficient, and the Prandtl number. For transient scenarios, on the other hand, the coastdown-time of the pump is the only uncertain parameter. The results indicate that the POD-RB-ROMs are suitable for the reduction of similar problems. The relative L2 errors are below 3.34% for every field of interest for all cases analyzed, while the speedup factors vary between 54 (transient) and 40,000 (steady-state).

German, Péter (ORCID:0000000307285283)↗

Equations of Motion for the Vertical Rigid-Body Rotor: Linear and Nonlinear Cases

Centuries ago, the prolific mathematician Leonhard Euler (1707–1783) wrote down the equations of motion (EOM) for the heavy symmetrical top with one point fixed. The resulting set of equations turned out to be nonlinear and had a limited number of closed-form solutions.Today, tools such as transfer matrix and finite elements enable the calculation of the rotordynamic properties for rotor-bearing systems. Some of these tools rely on the “linearized” version of the EOM to calculate the eigenvalues, unbalance response, or transients in these systems.In fact, industry standards mandate that rotors be precisely balanced to have safe operational characteristics. However, in some cases, the nonlinear aspect of the EOM should be considered.The purpose of this chapter is to show examples of how the linear vs. nonlinear formulations differ. This chapter also shows how excessive unbalance is capable of dramatically altering the behavior of the system and can produce chaotic motions associated with the “jump” phenomenon.

Laos, Hector↗

Reactor Containment Passive Safety Analysis: Steam Condensation in Presence of Non-condensable Gas Scaled Experiment and Modeling

This study presents steam condensation scaled experiments and semi-empirical models in presence of nitrogen (N)—a noncondensable gas (NCG), simulating air in the reactor containment—to support water-cooled small modular reactors (SMRs) passive containment cooling system (PCCS) design and analysis. Previous experimental studies on PCCS are focused on fixed and smaller tube (mostly 2-in.) geometries and specific test condition variations, bringing challenges with geometric scaling and mismatching with SMR prototypic design. To address these challenges, this study presents steam condensation test dataset obtained from three scaled test sections of 1-, 2-, and 4-in.-diameter steam condensers with an annular/jacket cooling of 2-, 3-, and 6 in.-diameter tubes, respectively. Test data were collected for steam ranges from 58 to 63 kg/hr., and NCG flow of 4.4 to 13.3 kg/hr. Annular cooling water flow was varied to obtain required testing conditions of saturated steam inlet and fully condensed outlet. Axial temperature test data of bulk cooling water, steam and condensate were collected by thermocouples for three test sections and various steam-NCG mixing/testing conditions. A standard data reduction method was adopted—utilizing iterative and nodalized mass and heat transfer calculation—to estimate axial local heat fluxes, heat transfer coefficients (HTCs), condensation rates, film thickness, and Nusselt number. Based on the obtained dataset semi-empirical model results—a ratio of experimental and Nusselt’s theoretical HTC are presented. Such results and findings are supportive of developing scaled-up testing facility, to enable model validations and accelerate next generation of reactors development and deployment

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Presentation: Reactor Containment Passive Safety Analysis: Steam Condensation in Presence of Non-condensable Gas Scaled Experiment and Modeling

This study presents steam condensation scaled experiments and semi-empirical models in presence of nitrogen--a noncondensable gas (NCG), simulating air in the reactor containment--to support water-cooled small modular reactors (SMRs) passive containment cooling system (PCCS) design and analysis. Previous experimental studies on PCCS are focused on fixed and smaller tube (mostly 2-in.) geometries and specific test condition variations, bringing challenges with geometric scaling and mismatching with SMR prototypic design. To address these challenges, this study presents steam condensation test dataset obtained from three scaled test sections of 1-, 2-, and 4-in.-diameter steam condensers with an annular/jacket cooling of 2-, 3-, and 6 in.-diameter tubes, respectively. Test data were collected for steam ranges from 58 to 63 kg/hr., and NCG flow of 4.4 to 13.3 kg/hr. Annular cooling water flow was varied to obtain required testing conditions of saturated steam inlet and fully condensed outlet. Axial temperature test data of bulk cooling water, steam and condensate were collected by thermocouples for three test sections and various steam-NCG mixing/testing conditions. A standard data reduction method was adopted--utilizing iterative and nodalized mass and heat transfer calculation to estimate axial local heat fluxes, heat transfer coefficients (HTCs), condensation rates, film thickness, and Nusselt number. Based on the obtained dataset semi-empirical model results--a ratio of experimental and Nusselt's theoretical HTC are presented. Such results and findings are supportive of developing scaled-up testing facility, to enable model validations and accelerate next generation of reactors development and deployment.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Measurement of the Natural Convection Heat Transfer in a Magnesium Oxide Electrolytic Cell Concept

The rate of heat transfer by natural convection between the wall and electrolyte of an electrolytic cell that produces magnesium (Mg) from magnesium oxide (MgO) at temperatures near 1000 °C in a molten fluoride salt electrolyte is presented. An experimental model of the cell was developed that enabled measurements of the heat transfer in the absence of electrolysis and at temperatures less than 100 °C over ranges of Rayleigh numbers from 1 × 10 -7 to 7 × 10 -8 and Prandtl numbers from 2 to 6200, ranges that include those anticipated in the operation of the MgO electrolytic cell. The model avoids the substantial experimental challenges associated with the high-temperature, corrosive molten salt to enable a conservative estimate of the heat transfer at a lower cost and greater accuracy than would otherwise be possible. The results are correlated by the expression Nu = 0.412Ra 0.23 Pr 0.15 with Nusselt numbers spanning 30–80. The application of the correlation shows that the heat transfer between the cell wall and the molten fluoride electrolyte at ≈1000 °C is characterized by convection coefficients between 100 and 600 W/m 2 -K and is fast enough to enable heat fluxes up to 10 W/cm 2 without compromising the structural integrity of the steel cell wall.

Engineering↗

Robust foil regenerator flow loss and heat transfer tests under oscillating flow condition

A regenerator works as an energy storage component in a Stirling engine. Thus, it is one of the most critical components that makes the Stirling engine highly efficient. Traditionally, the regenerators are made of wire media such as woven screens and random fibers. These wire regenerators experience considerably high flow losses through the regenerator due to the flow separation and the resulting vortices. The high flow losses associated with the flow separation and vortices result in a lower engine efficiency. This research is to test a new robust foil regenerator to investigate its feasibility for free-piston Stirling engine applications. The robust foil regenerator is configured with parallel flow channels and stiffening ribs. Comparing to complex flows patterns in woven screen and random fiber regenerators, the flows in the parallel plates are simple and the flow losses are considerably small, and the heat transfer coefficient is also relatively small. To test the regenerator experimentally, a regenerator test rig was manufactured. To verify the accuracy of the test rig, a woven screen regenerator was made and tested prior to the robust foil regenerator test. The friction factor correlation of the woven screen regenerator shows a good agreement with the published regenerator correlations. The robust foil regenerator tests were conducted under the oscillating flow condition with different Reynolds numbers. The flow losses were measured with dynamic pressure transducers and the friction coefficient was derived from measured pressure drop. The measured temperature difference over the regenerator was used to calculate the heat transfer coefficient and Nusselt number. The figure of merit with two methods of NPH/NTU ratio and j/f ratio was calculated to evaluate the suitability of the robust foil regenerator. The results show that the robust foil regenerator has considerably higher figure of merit and therefore, better performance than other types of regenerator.

42 ENGINEERING↗

Limiting the number of quantisation levels of a harmonic lens as a method for improving the quality of the generated image

The characteristics (modulation transfer functions) of harmonic lenses made by direct laser patterning of resist are experimentally studied. The influence of technological errors in the manufacture of lenses on the formation of the point spread function is modelled for harmonic lenses with 32 and 256 quantisation levels. Direct laser writing is used to produce lenses with these numbers of levels. It is experimentally shown that the modulation transfer function of the harmonic lens with 32 quantisation levels is significantly greater at high spatial frequencies (50 mm{sup −1}). (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Active- and transfer-learning applied to microscale-macroscale coupling to simulate viscoelastic flows

Active- and transfer-learning are applied to microscale dynamics of polymer flows for the multiscale discovery of effective constitutive approximations required in viscoelastic flow simulation. The result is macroscopic rheology directly connected to a microstructural model. Micro and macroscale simulations are adaptively coupled by means of Gaussian process regression (GPR) to run the expensive microscale computations only as necessary. This multiscale method is demonstrated with flows of a polymer solution as a model system. At the microscale level dissipative particle dynamics (DPD) is employed to model the fluid as a suspension of bead-spring micro-structures subjected to steady shear flow. The results yield the non-Newtonian viscosity and the first normal stress difference at strain rates as training data used in a GPR model. DPD parameters are calibrated with respect to experimental data for a real polymer solution. Compliance with these data requires adjustment of the DPD model's cutoff radius, which then becomes a function of the second invariant of the strain rate tensor. The FENE-P model is chosen for the macroscale description using the spectral element method (SEM) to simulate channel flow and flow past a circular cylinder. The DPD results at the lowest possible shear strain rate yield an estimate of the zero-shear rate viscosity, which allows the initiation of the macroscale flow by SEM as a Newtonian fluid. The resulting strain-rate field is surveyed to determine additional shear strain rate sampling points for the DPD system. This new information allows an initial fitting of parameters of the constitutive equation followed by new SEM simulations at the macroscale. Additionally, guided by active-learning GPR to select new sampling points, this process continues until convergence is achieved. The effectiveness of this new simulation paradigm for viscoelastic flows is tested with different macroscale operating conditions. The effective closure learned in the channel simulation is then transferred directly to the flow past a circular cylinder at low Reynolds number, where the results show that only two additional DPD simulations are required to achieve a satisfactory constitutive model. With an increase of the Reynolds number, the active-learning scheme automatically detects the inaccuracy of the learned constitutive model, and initiates additional DPD simulations for the extra data needed to once again close the microscale-macroscale coupled system. This new paradigm of active- and transfer-learning for multiscale modeling is readily applicable to other microscale-macroscale coupled simulations of complex fluids and other materials. Furthermore, the coupling between microscale and macroscale solvers can be seamlessly implemented with our open source multiscale universal interface (MUI) library.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Correlated solvent coordinates accelerate multi-donor proton-coupled electron transfer

The rate of charge transfer within a discrete donor–acceptor (D/A) pair is well-described by semi-classical electron transfer theory, but the effects of multiple equivalent redox sites remain less understood. We report a series of ground-state intramolecular proton-coupled electron transfer (PCET) complexes designed to isolate the effects of donor number, N, while holding geometry, coupling, and driving forces constant. The [Ru(L) 3−N (OH) N ] 2+ complexes incorporate one, two, or three identical phenolic electron donors linked to Ru through rigid phenanthroline bridges (OH = 2,4-di-tert-butyl-6-(1-methyl-1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol). Upon flash photolysis and oxidative quenching with methyl viologen (MV 2+ ), the transient Ru(III) oxidizes an appended phenol by PCET with the hydrogen-bonded imidazole nitrogen atom functioning as the base. The rate increased by 3.4-fold and 5.7-fold (1.7-fold and 1.9-fold after statistical correction) for two- and three-donor complexes compared to the single-donor system. The supra-statistical acceleration is attributed to a reduced effective outer sphere reorganization energy (λ m ) modeled by a partially shared solvent reaction coordinate, in which a subset of solvent dipoles is already oriented to stabilize charge from any donor. The final phenoxyl radical state is localized due to the transfer of a proton, and the recombination reaction with the viologen radical is not accelerated. These results demonstrate the effects of solvent dynamics on intramolecular PCET rates, offering a new strategy for the design of synthetic charge transfer systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lossy checkpoint compression in full waveform inversion: a case study with ZFPv0.5.5 and the overthrust model

This paper proposes a new method that combines checkpointing methods with error-controlled lossy compression for large-scale high-performance full-waveform inversion (FWI), an inverse problem commonly used in geophysical exploration. This combination can significantly reduce data movement, allowing a reduction in run time as well as peak memory. In the exascale computing era, frequent data transfer (e.g., memory bandwidth, PCIe bandwidth for GPUs, or network) is the performance bottleneck rather than the peak FLOPS of the processing unit. Like many other adjoint-based optimization problems, FWI is costly in terms of the number of floating-point operations, large memory footprint during backpropagation, and data transfer overheads. Past work for adjoint methods has developed checkpointing methods that reduce the peak memory requirements during backpropagation at the cost of additional floating-point computations. Combining this traditional checkpointing with error-controlled lossy compression, we explore the three-way tradeoff between memory, precision, and time to solution. We investigate how approximation errors introduced by lossy compression of the forward solution impact the objective function gradient and final inverted solution. Empirical results from these numerical experiments indicate that high lossy-compression rates (compression factors ranging up to 100) have a relatively minor impact on convergence rates and the quality of the final solution.

58 GEOSCIENCES↗

Pauli transfer matrix direct reconstruction: channel characterization without full process tomography

Abstract We present a tomographic protocol for the characterization of multiqubit quantum channels. We discuss a specific class of input states, for which the set of Pauli measurements at the output of the channel directly relates to its Pauli transfer matrix components. We compare our results to those of standard quantum process tomography, showing an exponential reduction in the number of different experimental configurations required by a single matrix element extraction, while keeping the same number of shots. This paves the way for more efficient experimental implementations, whenever a selective knowledge of the Pauli transfer matrix is needed. We provide several examples and simulations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Two-Phase Cooling for High Packaging Density Planar Inverter: Cooperative Research and Development Final Report, CRADA Number CRD-15-00592

The project objective was to utilize two-phase heat transfer to enable compact and power-dense inverters. The high heat transfer capacity and near isothermal characteristics of two-phase cooling can enable higher power densities, reducing the size and cost of the power electronics system. This project focused on developing efficient, passive (no pump or compressor) two-phase cooling strategies that consist of an air-cooled condenser and evaporator. This report describes the modeling work conducted to design the evaporator and air-cooled condenser for a prototype inverter development work underway in the John Deere. Prototypes of the final evaporator and condenser designs were then fabricated via 3D printing for testing. Experiments on the evaporator confirmed that this component can meet the heat load and junction temperatures requirements for Si IGBT (insulated-gate bipolar transistor) inverter. Experiments with the air-cooled condenser were not possible due to leaks through the condenser walls.

33 ADVANCED PROPULSION SYSTEMS↗