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DOE OSTI2025

Stabilization of magnetic bubbles in [Ni/Co]n multilayers on an oxygen-reconstructed Nb(110) surface via an ultra-thin Cu interlayer

Magnetic thin films hosting topological spin textures, such as magnetic skyrmions, hold high potential for breakthroughs in the field of spintronics, due to good scalability and energy efficiency. Novel computational architectures such as memory-in-logic devices rely on material platforms able to host those topological spin textures. Furthermore, recently proposed designs of novel quantum information technologies are based on heterostructures where topological spin textures are in direct proximity to a superconducting layer. Here, we demonstrate the stabilization of out-of-plane magnetic bubbles in highly ordered [Ni/Co]n multilayers on a Nb(110) single crystal. This is achieved without the need for the removal of the well-known Nb(110)-oxide surface reconstruction, due to the introduction of an ultra-thin Cu interlayer in between the Nb substrate and the magnetic multilayer. The Cu interlayer generates a well-ordered hexagonal surface, which is key for the epitaxial growth of the [Ni/Co]n multilayers hosting the desired out-of-plane anisotropy. The magnetic ground state of the prepared material stacks is directly imaged via spin-polarized low-energy electron microscopy, revealing the presence of magnetic bubble domains with lateral sizes as small as 450 nm.

Dibajeh, Ahmad↗

NASA NTRS1973

Studies of hydrodynamic events in stellar evolution. 3: Ejection of planetary nebulae

The dynamic behavior of the H-rich envelope (0.101 solar mass) of an evolved star (1.1 solar mass) as the luminosity rises to 19000 solar luminosity during the second ascent of the red giant branch. For luminosities in the range 3100 L 19000 solar luminosity the H-rich envelope pulsates like a long-period variable (LPV) with periods of the order of a year. As L reaches 19000 solar luminosity, the entire H-rich envelope is ejected as a shell with speeds of a few 10 km/s. The ejection occurs on a timescale of a few LPV pulsation periods. This ejection is associated with the formation of a planetary nebula. The computations are based on an implicit hydrodynamic computer code. T- and RHO-dependent opacities and excitation and ionization energies are included. As the H-rich envelope is accelerated off the stellar core, the gap between envelope and core is approximated by a vacuum, filled with radiation. Across the vacuum, the luminosity is conserved and the anisotropy of the radiation is considered as well as the solid angle subtended by the remnant star at the inner surface of the H-rich envelope. Spherical symmetry and the diffusion approximation are assumed.

Sparks, W. M.↗

NASA NTRS1984

Reflectance Modeling

A classical description of the one dimensional radiative transfer treatment of vegetation canopies was completed and the results were tested against measured prairie (blue grama) and agricultural canopies (soybean). Phase functions are calculated in terms of directly measurable biophysical characteristics of the canopy medium. While the phase functions tend to exhibit backscattering anisotropy, their exact behavior is somewhat more complex and wavelength dependent. A Monte Carlo model was developed that treats soil surfaces with large periodic variations in three dimensions. A photon-ray tracing technology is used. Currently, the rough soil surface is described by analytic functions and appropriate geometric calculations performed. A bidirectional reflectance distribution function is calculated and, hence, available for other atmospheric or canopy reflectance models as a lower boundary condition. This technique is used together with an adding model to calculate several cases where Lambertian leaves possessing anisotropic leaf angle distributions yield non-Lambertian reflectance; similar behavior is exhibited for simulated soil surfaces.

Smith, J. A.↗

DOE OSTI2023

Rear-Side Irradiance Simulation of Field PV Modules: Preprint

Assessing the durability of photovoltaic (PV) module backsheet is critical to increasing module lifetime. Historically, laboratory-based accelerated testing has insufficient in predicting large-scale failures of commercial polymeric materials. Additionally, there is growing concern that standard condition tests do not reflect non-uniformities in field exposure, and that certain modules experience more severe degradation due to their location. Anisotropy in field exposures is installation dependent and reflects different levels of exposure to irradiance due to mounting geometry, ground surface albedo, and climatic zone. "Bificial Radiance" [1], simulates the amount of reflected irradiance on the Polyethylene Naphthalate (PEN) backsheet of a PV array located in Maryland. In our work, site specific weather data are gathered for the entire length of exposure for the modules. The total full-spectrum dose for the incident irradiance on the backsheet was then determined. The simulation results are integrated with historical field survey data to better understand realworld outdoor degradation.

backsheet↗

DOE OSTI2021

Partial charge transfer and absence of induced magnetization in EuS(111)/Bi 2 Se 3 heterostructures

We report that heterostructures made from topological and magnetic insulators promise to form excellent platforms for new electronic and spintronic functionalities mediated by interfacial effects. We report the results of a first-principles density functional theory study of the geometric, electronic structure, and magnetic properties of the EuS( 111 )/Bi 2 Se 3 interface, including van der Waals and relativistic spin-orbit effects. In contrast to previous theoretical studies, we find no appreciable magnetic anisotropy in such a heterostructure. We also do not see additional induced magnetization at the interface or the magnetic proximity effect on the topological states. This is due to the localized nature of Eu moments and because of a partial charge transfer of ~ 0.5 electron from Eu to Se. The formation of the surface dipole shifts the Dirac cone about 0.4 eV below the chemical potential, and the associated electrostatic screening moves the topological state from the first to the second quintuple layer of Bi 2 Se 3 .

36 MATERIALS SCIENCE↗

DOE OSTI2024

Tuning Surface, Phase, and Magnetization of Superparamagnetic Magnetite by Ionic Liquids: Single-Step Microwave-Assisted Synthesis

Achieving colloidal and chemical stability in ferrofluids by surface modification requires multiple steps, including purification, ex situ modification steps, and operation at high temperatures. In this study, a single-step microwave-assisted methodology is developed for iron oxide nanoparticle (IONP) synthesis utilizing a series of imidazolium-based ionic liquids (ILs) with chloride, bis(trifluoromethylsulfonyl)imide, and pyrrolide anions as the reaction media, thus eliminating the use of volatile organics while enabling rapid synthesis at 80 °C as well as in situ surface functionalization. The characterized surface functionality, hydrodynamic particle size, magnetization, and colloidal stability of the IONPs demonstrate a strong dependence on the IL structure, ion coordination strength, reactivity, and hydrophilicity. The IONPs present primarily a magnetite (Fe 3 O 4 ) phase with superparamagnetism with the highest saturation magnetization at 81 and 73 emu/g at 10 and 300 K, respectively. Depending on the IL coating, magnetization and exchange anisotropy decrease by 20 and 2–3 emu/g (at 35 wt % IL), respectively, but still represent the highest magnetization achieved for coated IONPs by a coprecipitation method. Further, the surface-functionalized superparamagnetic magnetite nanoparticles show good dispersibility and colloidal stability in water and dimethyl sulfoxide at 0.1 mg/mL concentration over the examined 3 month period. This study reports on the intermolecular and chemical interactions between the particle surface and the ILs under synthetic conditions as they relate to the magnetic and thermal properties of the resulting IONPs that are well suited for a variety of applications, including separation and catalysis.

36 MATERIALS SCIENCE↗

NASA NTRS2019

Myco-Architecture off Planet: Growing Surface Structures at Destination

Our work focused on filling major select key technical knowledge gaps, and technical aspects to be addressed in a Phase II proposal were identified such as the secretion of glues or plastics by the fungi or bacteria to form biocomposites. Specifically, we raised the technical TRL by assessing the growth of in-house mycelial-producing strains on potential food substrates and analyzed the advantages and disadvantages to their use off planet. Growth of the mycelia on sawdust and powdered nutrients including dried, powdered algae, was used as a baseline. We measured growth as a function of temperature, tested the relevant material properties of the mycelia products produced, and measured the mass of input and output volume for production per volume of material. Mycotecture was produced in a bag simulating the proposed mission implementation. Post-production such as heat treatment (as is done with terrestrial mycotecture)was assessed.The material properties of the dried, frozen and baked mycelial outputs included density, strength,thermal insulation and flame retardation. Tensile/compression testing on biocomposite material specimens was performed to obtain three-dimensional elastic constants, as well as to examine deformation and fracture behavior. These mechanical tests were performed on both dormant and activated samples to understand the evolution of the structural material. In addition, experimental data obtained from the mechanical testing was used to build a failure prediction model that accounts for material anisotropy. This aided in future structural design through a quantitative understanding of the mechanical limits of the material. To examine the texture, defects, fracture surfaces of the material, high-resolution microstructural imaging was utilized before and after the mechanical tests. This microstructural analysis informed us about the macro-structural behavior and influenced structural design. Thermal decomposition analysis was also performed tounderstand the thermal limits.

Biocomposites↗

DOE OSTI2022

Strong Induced Circular Dichroism in a Hybrid Lead‐Halide Semiconductor Using Chiral Amino Acids for Crystallite Surface Functionalization

Abstract Chirality is a desired property in functional semiconductors for optoelectronic, catalytic, and spintronic applications. Here, introducing enantiomerically‐pure 3‐aminobutyric acid (3‐ABA) into thin films of the 1D semiconductor dimethylammonium lead iodide (DMAPbI 3 ) is found to result in strong circular dichroism (CD) in the optical absorption. X‐ray diffraction and grazing incidence small angle X‐ray scattering (GISAXS) are applied to gain molecular‐scale insights into the chirality transfer mechanism, which is attributed to a chiral surface modification of DMAPbI 3 crystallites. This study demonstrates that the CD signal strength can be controlled by the amino‐acid content relative to the crystallite surface area. The CD intensity is tuned by the composition of the precursor solution and the spin‐coating time, thereby achieving anisotropy factors ( g abs ) as high as 1.75 × 10 –2 . Grazing incidence wide angle scattering reveals strong preferential ordering that can be suppressed via tailored synthesis conditions. Different contributions to the chiroptical properties are resolved by a detailed analysis of the CD signal utilizing an approach based on the Mueller matrix model. This report of a novel class of chiral hybrid semiconductors with precise control over their optical activity presents a promising approach for the design of circularly polarized light detectors and emitters.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Rear-Side Irradiance Simulation of Field PV Modules

Assessing the durability of photovoltaic (PV) module backsheet is critical to increasing module lifetime. Historically, laboratory-based accelerated testing has insufficient in predicting large-scale failures of commercial polymeric materials. Additionally, there is growing concern that standard condition tests do not reflect non-uniformities in field exposure, and that certain modules experience more severe degradation due to their location. Anisotropy in field exposures is installation-dependent and reflects different levels of exposure to irradiance due to mounting geometry, ground surface albedo, and climatic zone. "Bificial_Radiance" [1], simulates the amount of reflected irradiance on the Polyethylene Naphthalate (PEN) backsheet of a PV array located in Maryland. In our work, site specific weather data are gathered for the entire length of exposure for the modules. The total full-spectrum dose for the incident irradiance on the backsheet was then determined. The simulation results are integrated with historical field survey data to better understand real orld outdoor degradation.

backsheet↗

NASA NTRS1988

CSDUST3 - A radiation transport code for a dusty medium with 1-D planar, spherical or cylindrical geometry

The program solves the radiation transport problem in a dusty medium with one-dimensional planar, spherical or cylindrical geometry. It determines self-consistently the effects of multiple scattering, absorption, and re-emission of photons on the temperature of dust grains and the characteristics of the internal radiation field. The program can treat radiation field anisotropy, linear anisotropic scattering, and multi-grain components. The program output consists of the dust-temperature distribution, flux spectrum, surface brightness at each frequency and the observed intensities (involving a convolution with a telescope beam pattern).

Egan, Michael P.↗

NASA NTRS1989

Large-scale cosmic microwave background anisotropies in isocurvature baryon open universe models

The large-angular-scale cosmic microwave background anisotropy is calculated in a low-density baryon-dominated universe with isocurvature primordial inhomogeneities. In models in which the initial power spectra of perturbations are steeper than white noise, predictions for the quadrupole moment of the anisotropy are found to be in conflict with existing observational limits, if the universe remained fully ionized and Compton drag inhibited growth of inhomogeneities until z = about 100. In order to lower the amplitude of the anisotropy, it is necessary to substantially prolong the duration of the growth phase of density perturbations, while smearing out fine-scale anisotropies, thereby requiring reionization to occur at a redshift smaller than 100, but larger than the redshift of the last scattering surface (in a reionized model).

Gorski, Krzysztof M.↗

NASA NTRS1992

Energetic Particles Investigation (EPI)

The EPI instrument operates during the pre-entry phase of the Galileo Probe. The main objective is the study of the energetic particle population in the inner Jovian magnetosphere and in the upper atmosphere. This will be achieved through omnidirectional measurements of electrons, protons, alpha-particles and heavy ions (Z greater than 2) and recording intensity profiles with a spatial resolution of about 0.02 Jupiter radii. Sectored data will also be obtained for electrons, protons, and alpha-particles to determine directional anisotropies and particle pitch angle distributions. The detector assembly is a two-element telescope using totally depleted circular silicon surface-barrier detectors surrounded by cylindrical tungsten shielding. The lower energy threshold of the particle species investigated during the Probe's pre-entry phase is determined by the material thickness of the Probe's rear heat shield which is required for heat protection of the scientific payload during entry into the Jovian atmosphere. The EPI instrument is combined with the Lightning and Radio Emission Detector and both instruments share one interface of the Probe's power, command, and data unit.

Fischer, H. M.↗

DOE OSTI2026

Self-Assembly Interactions in Magnetite-Coated Cellulose Nanocrystals: Implications for Magnetic Hyperthermia Applications

Magnetic cellulose nanocrystal (MCNC) nanocomposites are promising sustainable and biocompatible platforms for magnetic hyperthermia; however, the molecular mechanisms governing Fe 3 O 4 adsorption and deposition onto CNCs remain poorly understood. Here, sulfated (S-CNC) and TEMPO-oxidized CNCs (T-CNC) were used to prepare nanocomposites at 1:2 and 1:4 CNC:Fe 3 O 4 mass ratios, enabling a systematic evaluation of how surface chemistry and nanoparticle loading dictate interfacial interactions and magneto-colloidal behavior. Bare magnetite nanoparticles were 21 ± 5 nm by TEM but grew to 144 ± 18 in the DLS measurement at pH 7. The S-CNC nanocomposites had hydrodynamic sizes between 144 and 210 nm, not much larger than the 140 nm long CNC rods, suggesting an enhanced dispersion stability compared to Fe3O4 alone. X-ray photoelectron spectroscopy combined with density functional theory revealed that −OH and −COOH groups drive electrostatic adsorption with charge transfer from Fe 3 O 4 to the CNC surface, while T-CNCs showed more favorable adsorption energies and evidence of covalent Fe−O bonding. Vibrating sample magnetometry demonstrated superparamagnetic behavior for all samples, with S-CNC/Fe 3 O 4 1:4 and 1:2 displaying saturation magnetizations of 78 and 77 emu/g-Fe 3 O 4 , close to the 83 emu/g of bare magnetite. The T-CNC composites showed lower (60 and 66 emu/g-Fe3O4) saturation magnetizations. Zero-field-cooled/field-cooled measurements resulted in a blocking temperature of 112 K for all samples, except T-CNC/Fe 3 O 4 1:2 (100 K). Magnetic hyperthermia studies revealed that specific absorption rate (SAR) increased with field strength and Fe 3 O 4 content; however, S-CNC/Fe 3 O 4 (1:2) achieved the highest intrinsic SAR per gram of Fe 3 O 4 (649 W/g-Fe 3 O 4 ) likely due to its anisotropy and fast magnetic relaxation. Cytotoxicity assays confirmed that all nanocomposites were nontoxic toward mammalian cells. These results establish quantitative structure−property relationships between CNC surface chemistry, interfacial bonding mechanisms, and magnetic heating performance, providing a foundation for rational design of biocompatible magnetic nanocomposites for hyperthermia and related applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRSDate not supplied

CERES Top-of-atmosphere and Surface fluxes in the Arctic: A comparison with ARISE and MOSAiC measurements

Uncertainty in the NASA Clouds and the Earth’s Radiant Energy System (CERES)-derived irradiances is larger over sea ice than any other surface type and comes from several sources. This presentation summarizes results from comparisons of CERES data with the year-long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition in the central Arctic and the Arctic Radiation and Icebridge Sea ice Experiment (ARISE). The CERES Synoptic 1degree (SYN1deg) product overestimates the downwelling shortwave flux by 11.40 Wm–2 and underestimates the upwelling shortwave flux by –15.70 Wm–2 and downwelling longwave fluxes by –12.58 Wm–2 at the surface during summer. In addition, large differences are found in the upwelling longwave flux when the surface approaches the melting point (approximately 0C). The large negative bias in upwelling shortwave flux can be attributed in large part to lower surface albedo (–0.15) in satellite footprint relative to surface sensors. The CERES-MOSAiC broadband albedo differences (approximately 20 Wm–2) explain a larger portion of the upwelling shortwave flux difference than the spectral albedo shape differences (approximately 3 Wm–2). The ARISE results indicate the some of these differences in the SW are due to the scene identification and representation of anisotropy in partly cloud scenes. Switching from imager-based to passive microwave-based sea ice data in the CERES inversion process reduces the differences in the grid box average fluxes and in the sea ice partly cloudy scene anisotropy in the instantaneously-matched footprints. Our analysis indicates that calibration and sampling uncertainty limit the ability to place strong constraints (<7%) on CERES TOA fluxes with aircraft measurements. The results indicate that improvements in the surface albedo and cloud data would substantially reduce the uncertainty in the Arctic surface radiation budget derived from CERES data products.

Patrick C Taylor↗

DOE OSTI2022

Investigating a novel magnetic MAX phase nitride and its (001)-surfaces

We report magnetic MAX phases including their surfaces exhibit promising functional properties for magneto-electronic devices and self-monitoring smart coatings. By employing an integrated ab-initio approach, here we investigate a new member of the MAX phase, Mn 2 AuN. This compound satisfies the chemical, mechanical and dynamical stability criteria, leading to a possibility of its synthesis, and exhibits electronic and elastic anisotropy. The identified ferromagnetic configuration (with high Curie temperature) is the most energetically favorable among the five different spin configurations i.e., non-magnetic, ferromagnetic, and three anti-ferromagnetic. From the coatings perspective, the surface properties of Mn 2 AuN(001) terminations are investigated considering the four possible surface termination models. Remarkably, the magnetism does not get vanished even after cleaving the bulk unit cell into the (001)-surfaces. While evaluating the surface energetics in different chemical potentials, the N-001 terminated surface comes out to be the most stable termination contrasting with carbide MAX phases and is the only termination that exhibits the magnetic characteristics.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Electron correlations in the ${H_{c2}}$ of FeySe$_{1-x}$Sx (0.10 $\leqslant x\leqslant$ 0.24, $y\geqslant$ 0.9)

In this work, we report on the evolution of the electronic correlation strength across the nematic critical point in FeySe$_{1-x}$Sx ($0.10\leqslant x \leqslant0.24; y \geqslant0.9$), inferred from the measurements of the slope of the upper critical field $H_{c2}$. Superconducting transition T c and quasiparticle mass $m^*$ exhibit similar reduction with sulfur content x. Our results indicate that electronic correlations from all Fermi surface pockets show strong interconnection with pairing strength and are not governed by the change of nematic fluctuations. The upper critical field anisotropy γH = $H_{c2}^{ab}$/$H_{c2}^c$ exhibits a minimum in the critical region and stronger temperature dependence away from it.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1987

The bowshock and magnetopause

Results achieved in magnetopause and the bow-shock research during the years 1983-1986 are discussed. The review on bow-shock phenomenona includes work done on the terrestrial bow shock, interplanetary shocks, and bow shocks of other planets, describing research on macroscopic aspects of shocks as well as on the microphysics of quasi-perpendicular and quasi-parallel shocks. In the area of magnetopause research, global aspects of the boundary are first examined. Next, the issues of reconnection and energy transfer through the magnetopause, including viscous and surface-wave phenomena, are considered. Finally, flux-transfer events are discussed in terms of their characteristic magnetic signatures, energetic-particle anisotropies, and distribution with IMF orientations.

Elphic, R. C.↗

NASA NTRS2015

Next-Generation Angular Distribution Models for Top-of-Atmosphere Radiative Flux Calculation from the CERES Instruments: Methodology

The top-of-atmosphere (TOA) radiative fluxes are critical components to advancing our understanding of the Earth's radiative energy balance, radiative effects of clouds and aerosols, and climate feedback. The Clouds and the Earth's Radiant Energy System (CERES) instruments provide broadband shortwave and longwave radiance measurements. These radiances are converted to fluxes by using scene-type-dependent angular distribution models (ADMs). This paper describes the next-generation ADMs that are developed for Terra and Aqua using all available CERES rotating azimuth plane radiance measurements. Coincident cloud and aerosol retrievals, and radiance measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS), and meteorological parameters from Goddard Earth Observing System (GEOS) data assimilation version 5.4.1 are used to define scene type. CERES radiance measurements are stratified by scene type and by other parameters that are important for determining the anisotropy of the given scene type. Anisotropic factors are then defined either for discrete intervals of relevant parameters or as a continuous functions of combined parameters, depending on the scene type. Significant differences between the ADMs described in this paper and the existing ADMs are over clear-sky scene types and polar scene types. Over clear ocean, we developed a set of shortwave (SW) ADMs that explicitly account for aerosols. Over clear land, the SW ADMs are developed for every 1 latitude1 longitude region for every calendar month using a kernel-based bidirectional reflectance model. Over clear Antarctic scenes, SW ADMs are developed by accounting the effects of sastrugi on anisotropy. Over sea ice, a sea-ice brightness index is used to classify the scene type. Under cloudy conditions over all surface types, the longwave (LW) and window (WN) ADMs are developed by combining surface and cloud-top temperature, surface and cloud emissivity, cloud fraction, and precipitable water. Compared to the existing ADMs, the new ADMs change the monthly mean instantaneous fluxes by up to 5Wm(exp -2) on a regional scale of 1 deg. latitude x 1 deg. longitude, but the flux changes are less than 0.5Wm(exp -2) on a global scale.

Su, W.↗