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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

SRAM-Based Digital Arbiter PUF

The increased use of Field Programmable Gate Arrays (FPGAs) in critical systems brings new challenges in securing the diversely programmable fabric from cyber-attacks. FPGAs are an inexpensive, efficient, and flexible alternative to Application Specific Integrated Circuits (ASICs), which are becoming increasingly expensive and impractical for low volume manufacturing as technology nodes continue to shrink. Unfortunately, FPGAs are not designed for high security applications, and their high-flexibility lends itself to low security and vulnerability to malicious attacks. Similar to securing an ASIC’s functionality, FPGA programmers can exploit the inherent randomness introduced into hardware structures during fabrication for security applications. Physically Unclonable Functions (PUFs) are one such solution that uses the die specific variability in hardware fabrication for both secret key generation and verification. PUFs strive to be random, unique, and reliable. Throughout recent years many PUF structures have been presented to try and maximize these three design constraints, reliability being the most difficult of the three to achieve. This thesis presents a new PUF structure that combines two elementary PUF concepts (a bi-stable SRAM PUF and a delay-based arbiter PUF) to create a PUF with increased reliability, while maintaining both random and unique qualities. Properties of the new PUF will be discussed as well as the various design modifications that can be made to tweak the desired performance and overhead.

97 MATHEMATICS AND COMPUTING↗

Conditional Generative Adversarial Networks for Solving Heat Transfer Problems

Generative Adversarial Networks (GANs) have been used as a deep learning approach to solving physics and engineering problems. Using deep learning for these problems is attractive in that reasonably accurate models can be inferred from only raw data, eliminating the need to define the exact physical equations governing a problem. We expand on previous work using GANs to generate steady-state solutions to the two-dimensional heat equation. Using a basic conditional GAN (cGAN), we generate accurate solutions for rectangular domains conditioned on four edge boundary conditions (MAE < 0.5%). For finding steady-state solutions over arbitrary two-dimensional domains (not constrained to rectangles), we use a cGAN designed for image-to-image translation. We train this GAN on various types of geometric domains (circles, squares, triangles, shapes with one circular or rectangular hole), achieving accurate results on test data made up of geometries similar to those in training (MAE < 1%). For both of these GANs, we experiment with different loss function terms, showing that a term using the gradients of solution images significantly improves the basic cGAN but not the image-to-image GAN. Lastly, we show that the image-to-image GAN performs poorly when applied to two-dimensional geometries that vary in structure from training data (MAE < 8% for shapes with multiple holes or different shaped holes). This demonstrates the cGAN's lack of generalizability. While the cGAN is an accurate and computationally efficient method when trained and tested on similarly structured data, it is a much less reliable method when applied to data that is slightly different in structure from the training data.

97 MATHEMATICS AND COMPUTING↗

Nanosecond rf-Power Switch for Gyrotron-Driven Millimeter-Wave Accelerators

The development of alternative mm-wave high-gradient, >200 MV/m, accelerating structures offers a promising path to reduce the cost and footprint of future TeV-scale linear colliders, as well as linacs for industrial, medical, and security applications. The major factor limiting accelerating gradient is vacuum rf breakdown. The probability of such breakdowns increases with pulse length. For reliable operation, millimeter-wave structures require nanoseconds-long pulses at the megawatt level. This power is available from gyrotrons, which have a minimum pulse length on the order of microseconds. To create shorter pulses and to reliably detect rf breakdowns, we developed the following devices: a laser-based rf switch capable of selecting 10 ns long pulses out of the microseconds long gyrotron pulses, thus enabling the use of the gyrotrons as power sources for mm-wave high-gradient linacs, and a shot-to-shot sub-THz spectrometer with high-frequency resolution, capable of detecting pulse shortening due to rf breakdowns. We will describe the principle of operation of these devices and their achieved parameters. Here, we also report on the experimental demonstration of these devices with the high-power gyrotron at the Massachusetts Institute of Technology. In the experiments, we demonstrate nanosecond rf power modulation, shot-to-shot measurements of the pulse spectra, and detection of rf breakdowns.

43 PARTICLE ACCELERATORS↗

Probabilistic Modeling of Landfill Subsidence Introduced by Buried Structure Collapse - 13229

The long-term reliability of land disposal facility final cover systems - and therefore the overall waste containment - depends on the distortions imposed on these systems by differential settlement/subsidence. The evaluation of differential settlement is challenging because of the heterogeneity of the waste mass and buried structure placement. Deterministic approaches to long-term final cover settlement prediction are not able to capture the spatial variability in the waste mass and sub-grade properties, especially discontinuous inclusions, which control differential settlement. An alternative is to use a probabilistic model to capture the non-uniform collapse of cover soils and buried structures and the subsequent effect of that collapse on the final cover system. Both techniques are applied to the problem of two side-by-side waste trenches with collapsible voids. The results show how this analytical technique can be used to connect a metric of final cover performance (inundation area) to the susceptibility of the sub-grade to collapse and the effective thickness of the cover soils. This approach allows designers to specify cover thickness, reinforcement, and slope to meet the demands imposed by the settlement of the underlying waste trenches. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Assessing the reliability of the NIST library during routine GC-MS analyses: Structure and spectral data corroboration for 5,5-diphenyl-1,3-dioxolan-4-one during a recent OPCW proficiency test

In the field of analytical chemistry, it is the nature of the available instrumentation that makes a specific technique uniquely suited for answering a specific challenge. Often times, instruments equipped with ultrasensitive array of detectors and state-of-the-art separation components have served to highlight their invaluable role in the field. Nonetheless, it is their ultimate ability to predict the structure of an unknown material on the basis of mass spectral data that exponentially magnifies their value. Their efficacy in achieving this prediction is largely based on the size of their internal mass spectral library that conveniently can be accessed by using the software. The library can thus exhaustively correlate an unknown compound's mass spectrum to known compounds in a database and provide the analytical chemist with a probable structure for the unknown analyte. During routine analysis, it is customary that after the appropriate collection of the compound's mass spectrum, the next step involves its comparison with a compound in the instrument's National Institute of Standards and Technology (NIST) library.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The one-loop matter bispectrum in the Effective Field Theory of Large Scale Structures

With this study, given the importance of future large scale structure surveys for delivering new cosmological information, it is crucial to reliably predict their observables. The Effective Field Theory of Large Scale Structures (EFTofLSS) provides a manifestly convergent perturbative scheme to compute the clustering of dark matter in the weakly nonlinear regime in an expansion in k/k NL , where k is the wavenumber of interest and k NL is the wavenumber associated to the nonlinear scale. It has been recently shown that the EFTofLSS matches to 1% level the dark matter power spectrum at redshift zero up to k ≃ 0.3 h Mpc –1 and k ≃ 0.6 h Mpc –1 at one and two loops respectively, using only one counterterm that is fit to data. Similar results have been obtained for the momentum power spectrum at one loop. This is a remarkable improvement with respect to former analytical techniques. Here we study the prediction for the equal-time dark matter bispectrum at one loop. We find that at this order it is sufficient to consider the same counterterm that was measured in the power spectrum. Without any remaining free parameter, and in a cosmology for which kNL is smaller than in the previously considered cases (σ 8 =0.9), we find that the prediction from the EFTofLSS agrees very well with N-body simulations up to k ≃ 0.25 h Mpc –1 , given the accuracy of the measurements, which is of order a few percent at the highest k's of interest. While the fit is very good on average up to k ≃ 0.25 h Mpc –1 , the fit performs slightly worse on equilateral configurations, in agreement with expectations that for a given maximum k, equilateral triangles are the most nonlinear.

79 ASTRONOMY AND ASTROPHYSICS↗

Thermomechanical characterization and modeling for TSV structures

Continual scaling of devices and on-chip wiring has brought significant challenges for materials and processes beyond the 32-nm technology node in microelectronics. Recently, three-dimensional (3-D) integration with through-silicon vias (TSVs) has emerged as an effective solution to meet the future technology requirements. Among others, thermo-mechanical reliability is a key concern for the development of TSV structures used in die stacking as 3-D interconnects. This paper presents experimental measurements of the thermal stresses in TSV structures and analyses of interfacial reliability. The micro-Raman measurements were made to characterize the local distribution of the near-surface stresses in Si around TSVs. On the other hand, the precision wafer curvature technique was employed to measure the average stress and deformation in the TSV structures subject to thermal cycling. To understand the elastic and plastic behavior of TSVs, the microstructural evolution of the Cu vias was analyzed using focused ion beam (FIB) and electron backscattering diffraction (EBSD) techniques. Furthermore, the impact of thermal stresses on interfacial reliability of TSV structures was investigated by a shear-lag cohesive zone model that predicts the critical temperatures and critical via diameters.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A causal perspective on reliability assessment

Causality in an engineered system pertains to how a system output changes due to a controlled change or intervention on the system or system environment. Engineered systems designs reflect a causal theory regarding how a system will work, and predicting the reliability of such systems typically requires knowledge of this underlying causal structure. The aim of this work is to introduce causal modeling tools that inform reliability predictions based on biased data sources. We present a novel application of the popular structural causal modeling (SCM) framework to reliability estimation in an engineering application, illustrating how this framework can inform whether reliability is estimable and how to estimate reliability given a set of data and assumptions about the subject matter and data generating mechanism. When data are insufficient for estimation, sensitivity studies based on problem-specific knowledge can inform how much reliability estimates can change due to biases in the data and what information should be collected next to provide the most additional information. We apply the approach to a pedagogical example related to a real, but proprietary, engineering application, considering how two types of biases in data can influence a reliability calculation.

42 ENGINEERING↗

Zero-Strain Metal-Insulator Transition by the Local Fluctuation of Cation Dimerization

The coupled electronic and structural transitions in metal-insulator transition (MIT) hinder ultrafast switching and ultimate endurance. Decoupling these transitions and achieving a zero-strain electronic MIT can overcome the fundamental limitations of MIT in solid materials. Here, this study demonstrates that iso-valent Ti dopants in supercooled VO 2 epitaxial films cause MIT with minimal hysteresis without changing unit-cell volume and crystal symmetry. The Ti dopants in the VO 2 lattice locally alter the configuration of V-V pairs, where the long-range ordering in V-V pairs is disrupted, and the nano-domains of V-V dimers are formed. Strikingly, these local V-V dimers persist even above the electronic transition temperature (T MI ), facilitating the zero-strain electronic MIT with nanoscale structural heterogeneity. The geometrically compatible interface between insulating and metallic phases drastically enhances switching speed and endurance during electrically and optically driven zero-strain MIT. In conclusion, this discovery offers a fresh perspective on the scientific understanding of MIT and the improved functionality in terms of device speed and reliability by decoupling electronic and structural transitions.

36 MATERIALS SCIENCE↗

Resilience Design Patterns: A Structured Approach to Resilience at Extreme Scale (V.2.0)

Reliability is a serious concern for future extreme-scale high-performance computing (HPC) systems. Projections based on the current generation of HPC systems and technology roadmaps suggest the prevalence of very high fault rates in future systems. The errors resulting from these faults will propagate and generate various kinds of failures, which may result in outcomes ranging from result corruptions to catastrophic application crashes. Therefore, the resilience challenge for extreme-scale HPC systems requires coordination between various hardware and software technologies that are capable of handling a broad set of fault models at accelerated fault rates. Also, due to practical limits on power consumption in future HPC systems, they are likely to embrace innovative architectures, increasing the levels of hardware and software complexities. Therefore, the techniques that seek to improve resilience must navigate the complex trade-off space between resilience and the overheads to power consumption and performance. While the HPC community has developed various resilience solutions, application-level techniques as well as system-based solutions, the solution space of HPC resilience techniques remains fragmented. There are no formal methods to integrate the various HPC resilience techniques into composite solutions, nor are there methods to holistically evaluate the adequacy and efficacy of such solutions in terms of their protection coverage, and their performance & power efficiency characteristics. Additionally, few implementations of current resilience solutions are portable to newer architectures and software environments that will be deployed on future systems. We developed a new structured approach to the management of HPC resilience using the concept of resilience-based design patterns. In general, a design pattern is a repeatable solution to a commonly occurring problem. We identified the well-known solutions that are commonly used to deal with faults, errors and failures in HPC systems. In the initial design patterns specification (version 1.0), we described the various solutions, which address specific problems in the design of resilient HPC environments, in the form of patterns. Each pattern describes a problem caused by a fault, error or failure event in an HPC environment, and then describes the core of the solution of the problem in such a way that this solution may be adapted to different systems and implemented at different layers of the system stack. The catalog of these resilience design patterns provides designers with a collection of design elements. To construct complete resilience solutions using combinations of various patterns, we defined a framework that enhances HPC designers' understanding of the important constraints and the opportunities for the design patterns to be implemented and deployed at various layers of the system stack. The design framework is also useful for establishing interfaces and mechanisms to coordinate flexible fault management across hardware and software components, as well as to consider the trade-off between performance, resilience, and power consumption when constructing a solution. The resilience design patterns specification version 1.1 included more detailed explanations of the pattern solutions, the context in which the patterns are applicable, and the implications for hardware or software design. It also provided several additional examples and detailed case studies to demonstrate the use of patterns to build realistic solutions. In version 1.2 of the specification document, we have improved the pattern descriptions, including graphical representations of the pattern components. These improvements are largely based on critical comments, feedback and suggestions received from pattern experts and readers of the previous versions of the specification. The pattern classification has been modified to further clarify the relationships between pattern categories. This version of the specification also introduces a pattern language for resilience design patterns. The pattern language presents the patterns in the catalog as a network, revealing the relations among the resilience patterns. The language provides designers with the means to explore alternative techniques for handling a specific fault model that may have different efficiency and complexity characteristics. Using the pattern language also enables the design and implementation of comprehensive resilience solutions as a set of interconnected resilience patterns that can be instantiated across layers of the system stack. The overall goal of this work is to provide hardware and software designers, as well as the users and operators of HPC systems, a systematic methodology for the design and evaluation of resilience technologies in HPC systems that keep scientific applications running to a correct solution in a timely and cost-efficient manner despite frequent faults, errors, and failures of various types. Version 2.0 expands the resilience design pattern classification and catalog to include self-stabilization patterns and reliability, availability and performance models for each structural pattern.

97 MATHEMATICS AND COMPUTING↗

Monitoring of dielectric permittivity in accelerated alkali-silica reaction concrete with microwave backscattering

Deterioration of concrete due to the alkali–silica reaction (ASR) involves a reaction between alkaline ions in the cement pore solution and non-crystalline silica found in many aggregates. The product of reaction is a porous hydrophilic ASR gel, which causes expansion and cracking of concrete structure. Currently, there is no reliable method for non-destructive evaluation of ASR. We have investigated the feasibility of using relative dielectric permittivity obtained from X-band microwave backscattering of concrete. Advantages of this method of concrete evaluation are that measurements are non-contact and one-sided, and the approach is scalable to arbitrary-size concrete structures. The exploratory study was performed using an unrestrained set of accelerated ASR concrete prism specimens developed according to the ASTM1293 standard. One set of specimens contained no entrained air, while another set was contained entrained air. The specimens were removed from the environmental chamber at different times during a year-long study to create a set of different ASR maturity specimens. Strain measurements were performed on all specimens. Strain data both air entrained and non-air entrained sets were shown to be in close agreement with Larive model of isothermal unrestrained ASR expansion with similar fitting parameters. Furthermore, relative dielectric permittivity of concrete specimens was correlated with strain data. Both sets show correlation between dielectric permittivity and strain, with stronger linear correlation observed for the air-entrained specimens. Development of such correlation would enable estimating expansion of actual concrete structures from microwave backscattering measurements, which could be used for risk stratification to guide and minimize coring.

36 MATERIALS SCIENCE↗

STAR COUNT DENSITY PROFILES AND STRUCTURAL PARAMETERS OF 26 GALACTIC GLOBULAR CLUSTERS

We used an appropriate combination of high-resolution Hubble Space Telescope observations and wide-field, ground-based data to derive the radial stellar density profiles of 26 Galactic globular clusters from resolved star counts (which can be all freely downloaded on-line). With respect to surface brightness (SB) profiles (which can be biased by the presence of sparse, bright stars), star counts are considered to be the most robust and reliable tool to derive cluster structural parameters. For each system, a detailed comparison with both King and Wilson models has been performed and the most relevant best-fit parameters have been obtained. This collection of data represents the largest homogeneous catalog collected so far of star count profiles and structural parameters derived therefrom. The analysis of the data of our catalog has shown that (1) the presence of the central cusps previously detected in the SB profiles of NGC 1851, M13, and M62 is not confirmed; (2) the majority of clusters in our sample are fit equally well by the King and the Wilson models; (3) we confirm the known relationship between cluster size (as measured by the effective radius) and galactocentric distance; (4) the ratio between the core and the effective radii shows a bimodal distribution, with a peak at {approx}0.3 for about 80% of the clusters and a secondary peak at {approx}0.6 for the remaining 20%. Interestingly, the main peak turns out to be in agreement with that expected from simulations of cluster dynamical evolution and the ratio between these two radii correlates well with an empirical dynamical-age indicator recently defined from the observed shape of blue straggler star radial distribution, thus suggesting that no exotic mechanisms of energy generation are needed in the cores of the analyzed clusters.

79 ASTRONOMY AND ASTROPHYSICS↗

Development of a Systematic and Extensible Force Field for Peptoids (STEPs)

Peptoids (N-substituted glycines) are a class of biomimetic polymers that have attracted significant attention due to their accessible synthesis and enzymatic and thermal stability relative to their naturally occurring counterparts (polypeptides). While these polymers provide the promise of more robust functional materials via hierarchical approaches, they present a new challenge for computational structure prediction for material design. The reliability of calculations hinges on the accuracy of interactions represented in the force field used to model peptoids. For proteins, structure prediction based on sequence and de novo design has made dramatic progress in recent years; however, these models are not readily transferable for peptoids. Current efforts to develop and implement peptoid-specific force fields are spread out, leading to replicated efforts and a fragmented collection of parameterized sidechains. Here, we developed a peptoid-specific force field containing 70 different side chains, using GAFF2 as starting point. The new model is validated based on the generation of Ramachandran-like plots from DFT optimization compared against force field reproduced potential energy and free energy surfaces as well as the reproduction of equilibrium cis/trans values for some residues experimentally known to form helical structures. In conclusion, equilibrium cis/trans distributions (Kct) are estimated for all parameterized residues to identify which residues have an intrinsic propensity for cis or trans states in the monomeric state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pressure dependence of band-gap and phase transitions in bulk CuX (X = Cl, Br, I)

Usually a phase transition, in theoretical studies, is explored or verified by studying the total energy as a function of the volume considering various plausible phases. The intersection point, if any, of the free energy vs. volume curves for the different phases is then the indicator of the phase transition(s). The question is, can the theoretical study of a single phase alone indicate a phase transition? i.e. can we look beyond the phase under consideration through such a study? Using density-functional theory, we report a novel approach to suggest phase transition(s) through theoretical study of a single phase. Copper halides have been engaged for this study. These are direct band-gap semiconductors, with zinc blende structure at ambient conditions, and are reported to exhibit many phase transitions. We show that the study of volume dependence of energy band-gap in a single phase facilitates looking beyond the phase under consideration. This, when translated to pressures, reflects the phase transition pressures for CuX (X = Cl, Br, I) with an encouraging accuracy. This work thus offers a simple, yet reliable, approach based on electronic structure calculations to investigate new semiconducting materials for phase changes under pressure.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Scientific substantiation of safe operation of the Earthen Dams at the Votkinsk HPP

Over a period of 15 years, coworkers of the B. E. Vedeneev Scientific-Research Institute of Hydraulic Engineering have conducted scientific accompaniment of the operation of the earthen dams at the Votkinsk HPP. During that time, basic performance characteristics associated with complex hydrogeologic and hydrochemical conditions, and the forms of their unfavorable manifestations influencing the reliability and safety of the structures were revealed, and, recommendations and measures were developed for their elimination.

13 HYDRO ENERGY↗

The Clustering of Luminous Red Galaxies at z ∼ 0.7 from EBOSS and BOSS Data

We present the first scientific results from the luminous red galaxy (LRG) sample of the extended Baryon Oscillation Spectroscopic Survey (eBOSS) combined with the high-redshift galaxies of the previous BOSS sample. We measure the small- and intermediate-scale clustering from a sample of more than 97,000 galaxies in the redshift range 0.6<z<0.9. We interpret these measurements in the framework of the Halo Occupation Distribution. The bias of this sample of LRGs is 2.30 ± 0.03, with a satellite fraction of 13% ± 3% and a mean halo mass of 2.5×10{sup 13} h{sup −1} M{sub ⊙}. These results are consistent with expectations, demonstrating that these LRGs will be reliable tracers of large-scale structure at z∼0.7. The galaxy bias implies a scatter of luminosity at fixed halo mass, σ{sub logL}, of 0.19 dex. Using the clustering of massive galaxies from BOSS CMASS, BOSS LOWZ, and SDSS, we find that σ{sub logL}=0.19 is consistent with observations over the full redshift range that these samples cover. The addition of eBOSS to previous surveys allows the investigation of the evolution of massive galaxies over the past ∼7 Gyr.

79 ASTRONOMY AND ASTROPHYSICS↗

Robustness and Versatility of Thin Films on Low Temperature Cofired Ceramic (LTCC)

Thin film multilayers have previously been introduced on multilayer low temperature cofired ceramic (LTCC). The ruggedness of a multipurpose Ti-Cu-Pt-Au stack has continued to benefit fabrication and reliability in state-of-theart modules. Space optimization is described, preserving miniaturization of critical spaces and component pads. Additional soldering details are also presented, including trends with solder-stop materials. Feature compensation becomes a simple step in the normal manufacturing flow which enables exact targeting of desired feature sizes. In addition, fine details of the manufacturing process, including ion milling, will be discussed. We will discuss full long-term aging results and structural details that reinforce the reliability and function. Different thin film materials for specific applications can be exploited for additional capabilities such as filters and other integral components. Cross sections verify the results shown. This successful integration of thin films on LTCC points to higher frequencies which require finer lines and spaces. Advancements of these applications become possible due to the associated progression of smaller skin depth and thinner metallic material.

36 MATERIALS SCIENCE↗