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At least 253 records · Page 14

Kinetics Measurements in Resistive Electrolytes Using Ring-Disk Electrode: Ring as Current “Shield” Enables Uniform Disk Current Distribution

Rotating disk electrodes are commonly used for electrochemical kinetics measurements. A major disadvantage of these types of electrodes is their nonuniform secondary current distribution, especially when performing electroanalytical measurements in resistive electrolytes. Such nonuniform current distribution can render the values of kinetics constants extracted from the disk electrode to be highly inaccurate. Furthermore, one emerging class of electrolytes that suffer from low ionic conductivities is deep eutectic solvents (DES). DES are a promising class of electrolytes for various emerging applications; however, due to their resistive nature, the secondary current distribution when using them is typically highly nonuniform. For example, the Wagner number when measuring Cu²⁺/Cu⁺ kinetics in choline chloride–ethylene glycol DES (1:4 molar ratio of ChCl:EG) is very low (<0.1), indicating highly nonuniform current distribution over the disk electrode. We show here that the Cu²⁺/Cu⁺ exchange current density measured using disk electrodes is very inaccurate due to the aforementioned nonuniform current distribution. To obtain uniform disk current distribution, we employ here a coplanar concentric rotating ring-disk electrode (RRDE), where the ring serves the function of a current “shield.” Specifically, we show using modeling that the ring minimizes the current distribution nonuniformity at the disk by effectively shielding the disk against current spikes near the disk edge. This enables improved precision in electrode kinetics measurements for the Cu²⁺/Cu⁺ couple in resistive DES. To enable broad applicability of this technique, an analytical expression based on the Wagner number is integrated into an iterative algorithm to help users identify ring conditions to achieve uniform current distribution and thus improved electroanalytics at the disk.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Practical galaxy morphology tools from deep supervised representation learning

Astronomers have typically set out to solve supervised machine learning problems by creating their own representations from scratch. We show that deep learning models trained to answer every Galaxy Zoo DECaLS question learn meaningful semantic representations of galaxies that are useful for new tasks on which the models were never trained. We exploit these representations to outperform several recent approaches at practical tasks crucial for investigating large galaxy samples. The first task is identifying galaxies of similar morphology to a query galaxy. Given a single galaxy assigned a free text tag by humans (e.g. ‘#diffuse’), we can find galaxies matching that tag for most tags. The second task is identifying the most interesting anomalies to a particular researcher. Our approach is 100 per cent accurate at identifying the most interesting 100 anomalies (as judged by Galaxy Zoo 2 volunteers). The third task is adapting a model to solve a new task using only a small number of newly labelled galaxies. Models fine-tuned from our representation are better able to identify ring galaxies than models fine-tuned from terrestrial images (ImageNet) or trained from scratch. We solve each task with very few new labels; either one (for the similarity search) or several hundred (for anomaly detection or fine-tuning). This challenges the longstanding view that deep supervised methods require new large labelled data sets for practical use in astronomy. To help the community benefit from our pretrained models, we release our fine-tuning code zoobot. Zoobot is accessible to researchers with no prior experience in deep learning.

79 ASTRONOMY AND ASTROPHYSICS↗

Validating pyORBIT for Modeling Beam Dynamics in the IOTA Ring

The Integrable Optics Test Accelerator (IOTA) ring is a new Fermilab facility dedicated to beam physics experiments, currently operating with 150 MeV electrons. Space charge effects are expected to be significant when it operates with 2.5 MeV protons. In this contribution, we present results of a suite of validation tests of PyORBIT, a PICstyle space charge code. Single particle dynamics of quasiintegrable optics using an octupole string in IOTA is compared with MADX, and shown to be in good agreement. Requirements for the convergence of space charge computations are systematically established and when possible, tests involving space charge are compared with theoretical predictions.

Li, Runze↗

Structure of Saturn's rings: Optical and dynamical considerations

The photometric phase curves of Saturn's rings are considered, as well as a conflict between dynamical and photometric models of the rings. The dependence of ring brightness on angular separation of the earth and sun as viewed from Saturn is discussed. The nonlinear brightness surge is interpreted. Some quantitative calculations were carried out for bodies in and near the asteroidal belt. Predicted density profiles of the ring obtained with Mimas in an eccentric orbit and in a circular orbit are also included.

Franklin, F. A.↗

Collision mechanics and the structure of planetary ring edges

The present numerical simulation of collisional evolution, in the case of a hypothetical ring whose parameters are modeled after those of Saturn's rings, gives attention to changes in radial structure near the ring edges and notes that when random motion is in equilibrium, the rings tend to spread in order to conserve angular momentum while energy is dissipated in collisions. As long as random motion is damped, ring edges may contract rather than spread, producing a concentration of material at the ring edges. For isotropic scattering, damping dominates for a coefficient of restitution of velocity value of up to 0.83.

Spaute, Dominique↗

Radiative transfer modeling of Saturn's outer B ring

The present investigation of Voyager images of the Saturn outer B ring's light-scattering behavior gives attention to the four radial regions formed by brighter and darker areas within and outside the 'spokes'. The B-ring particles are found to have a strongly backscattering phase function and a large-particle scattering albedo of 0.54 in the dark regions and 0.58 in the bright ones; these albedos are interpretable as due to multiple scattering among very pure ice grains covering the ring particle surfaces. It is shown that dark micrometeoroid impacts into the B ring would have darkened the particles to their current spherical albedo in as little as 100 to 200 million years.

Doyle, Laurance R.↗

Small orbital debris measurement: Recent advances and future problems

New measurements of the small orbital debris environment during the past three years have greatly expanded our knowledge of the population of orbital debris at sizes from 10 cm down to 100 microns. The Long Duration Exposure Facility (LDEF) has provided new data for micro-debris at sizes below 1 mm. Telescope and radar measurements have provided new data for sizes in the range from about 2 mm to 10 cm., and have verified the predictions of Kessler's debris environment model. 'Clumps' or 'rings' of small debris, that are not accounted for in any environment models, have been detected both by LDEF and by the radars. Significant measurement problems remain. The relation between optical and radar measurements of debris is not understood. We have almost no information about the debris population in geosynchronous, Molniya and low-inclination orbits, and we lack evidence for the prediction of debris environments. Models of collisions in space between debris objects are beginning to be developed.

Potter, Andrew E.↗

Ring Current Ion Coupling with Electromagnetic Ion Cyclotron Waves

A new ring current global model has been developed that couples the system of two kinetic equations: one equation describes the ring current (RC) ion dynamic, and another equation describes wave evolution of electromagnetic ion cyclotron waves (EMIC). The coupled model is able to simulate, for the first time self-consistently calculated RC ion kinetic and evolution of EMIC waves that propagate along geomagnetic field lines and reflect from the ionosphere. Ionospheric properties affect the reflection index through the integral Pedersen and Hall conductivities. The structure and dynamics of the ring current proton precipitating flux regions, intensities of EMIC global RC energy balance, and some other parameters will be studied in detail for the selected geomagnetic storms.

Khazanov. G. V.↗

On the radial structure of planetary rings

Viscous shear stress of a ring of particles in orbit about a planet due to the radial gradient of orbital velocity is discussed. This stress tends to spread the ring with time. At low optical depth (t) and at high t, the shear stress is an increasing function of t. In the intermediate range stress may decrease with increasing t, leading to a diffusive instability which tends to break an initially uniform ring into ringlets of high and low optical depths. According to the shepherd satellite model of narrow ring confinement, the viscous shear stress is opposed by tidal torques from neighboring shepherds, so that radial spreading does not occur. By requiring that the gradient of the viscous shear stress (i.e., angular momentum deposited) be equal to the shepherd satellite torque density at all radii in the rings, equilibrium radial density profiles of a confined ring were constructed. The most noteworthy feature of these profiles is a narrow, high density ringlet surrounded by a low optical density halo of greater width.

Harris, A. W.↗

AGR-3/4 Modeling and Transport Parameters

Outline AGR-3/4 experiment and objectives Description of AGR-3/4 modeling approach and inputs Source term (release from particles) Temperature profiles Diffusion through concentric rings Adsorption across gaps between rings Simplified Source Model and updated model results Reconstruction of fission product distributions from gamma tomography data

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Ring Current Ion Coupling with Electromagnetic Ion Cyclotron Waves

A new ring current global model has been developed for the first time that couples the system of two kinetic equations: one equation describes the ring current (RC) ion dynamic, and another equation describes wave evolution of electromagnetic ion cyclotron waves (EMIC). The coupled model is able to simulate, for the first time self-consistently calculated RC ion kinetic and evolution of EMIC waves that propagate along geomagnetic field lines and reflect from the ionosphere. Ionospheric properties affect the reflection index through the integral Pedersen and Hall coductivities. The structure and dynamics of the ring current proton precipitating flux regions, intensities of EMIC, global RC energy balance, and some other parameters will be studied in detail for the selected geomagnetic storms. The space whether aspects of RC modelling and comparison with the data will also be discussed.

Khazanov, George V.↗

A global analytical representation of the magnetic field produced by the region 2 Birkeland currents and the partial ring current

A quantitative model is developed of the magnetic field produced by the electric current system of region 2 Birkeland currents, closed via the partial ring current. The distribution of j-perpendicular is computed from a given axially asymmetric spatial distribution of hot isotropic magnetospheric plasma over an infinitely thin L shell in an axisymmetric purely dipolar geomagnetic field, while the field-aligned current density is found from the continuity of the net electric current. The magnetic field distribution is derived by a Biot-Savart integral over the electric current system. An assumed cosine dependence of the plasma pressure on local time makes it possible to reduce the problem of analytical representation of the B field to two dimensions. The obtained numerical fits for the partial ring current/region 2 Birkeland current magnetic field are relatively simple, continuous, and valid throughout the whole extraterrestrial space from ionospheric heights up to tens of earth radii.

Tsyganenko, N. A.↗

Uranian ring orbits from earth-based and Voyager occultation observations

A novel kinematical model of the Uranian rings has been derived from Voyager occultation timings and earth-based observations of the occultations of U23, U25, and U28, to yield an improved orbit solution that is accurate to about 1 km in the ring plane; this allows a critical comparison to be conducted between ring locations and suspected resonances. The gamma ring is noted to have a peculiar orbit that combines a precessing elliptical ring with a radially-oscillating normal mode. The kinematical model confirms the suspected association of resonances between the 1986U7 and 1986U8 satellites with some of the rings.

French, Richard G.↗

First Voyager view of the rings of Saturn

Voyager 1 imaging data of the Saturn rings, taken at a resolution of 1000 km/line pair between September 3 and October 13, 1980 are discussed. It is pointed out that as the spacecraft approached Saturn, finer radial structure in the rings between and within the major divisions became apparent, together with extensive azimuthal structure in the B ring. It is shown that the fine structure observed in the rings cannot, for the most part, be attributed to classical resonances with the known inner satellites. Preliminary model calculations of ring brightness based on photometry data indicate that the particles of the A and B rings are characterized by a greater degree of diffuse backscattering ability than previously suspected, behaving like Lambert spheres, while those of the C ring are either darker or more highly forward scattering than the A or B ring particles.

Collins, S.A.↗

A Model For the Limiting Time in Vortex Ring Formation

In another presentation, Gharib et at provide experimental results to show that when a vortex ring is created from a pipe by a piston, there is a limiting time or piston stroke length beyond which multiple rings appear. This time appeared to be insensitive to piston velocity history and Reynolds number. Nature might exploit such a. limit in different contexts to coherently deliver mass or momentum flux with the least number of strokes. Here, a simple hypothesis is considered: the limiting time occurs when the apparatus is no longer able to deliver energy at a rate compatible with the requirement, due to Kelvin, that a steady vortex ring have maximum energy given circulation and impulse. More specifically, the limit is expected to occur when the quantity alpha = E/square root of Gamma(sup 3)I delivered by the piston drops below the value, alpha(sub lim) for a limiting steady vortex ring solution. The resulting predictions agree very well with the experiments (after using alpha(sub lim) measured using the experimental flow fields). The insensitivity to piston history also emerges from the model. Finally, piston histories are designed that may extend the limiting time somewhat.

Shariff, Karim↗

Fully Inkjet‐Printed, 2D Materials‐Based Field‐Effect Transistor for Water Sensing

Abstract Despite significant progress in solution‐processing of 2D materials, it remains challenging to reliably print high‐performance semiconducting channels that can be efficiently modulated in a field‐effect transistor (FET). Herein, electrochemically exfoliated MoS 2 nanosheets are inkjet‐printed into ultrathin semiconducting channels, resulting in high on/off current ratios up to 10 3 . The reported printing strategy is reliable and general for thin film channel fabrication even in the presence of the ubiquitous coffee‐ring effect. Statistical modeling analysis on the printed pattern profiles suggests that a spaced parallel printing approach can overcome the coffee‐ring effect during inkjet printing, resulting in uniform 2D flake percolation networks. The uniformity of the printed features allows the MoS 2 channel to be hundreds of micrometers long, which easily accommodates the typical inkjet printing resolution of tens of micrometers, thereby enabling fully printed FETs. As a proof of concept, FET water sensors are demonstrated using printed MoS 2 as the FET channel, and printed graphene as the electrodes and the sensing area. After functionalization of the sensing area, the printed water sensor shows a selective response to Pb 2+ in water down to 2 ppb. This work paves the way for additive nanomanufacturing of FET‐based sensors and related devices using 2D nanomaterials.

36 MATERIALS SCIENCE↗