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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Development of a coarse-grained molecular dynamics model for poly(dimethyl- co -diphenyl)siloxane

Polydimethylsiloxane is an important polymeric material with a wide range of applications. However, environmental effects like low temperature can induce crystallization in this material with resulting changes in its structural and dynamic properties. The incorporation of phenyl-siloxane components, e.g., as in a poly(dimethyl-co-diphenyl)siloxane random copolymer, is known to suppress such crystallization. Molecular dynamics (MD) simulations can be a powerful tool to understand such effects in atomistic detail. Unfortunately, all-atomistic molecular dynamics (AAMD) is limited in both spatial dimensions and simulation times it can probe. Here, to overcome such constraints and to extend to more useful length- and time-scales, we systematically develop a coarse-grained molecular dynamics (CGMD) model for the poly(dimethyl-co-diphenyl)siloxane system with bonded and non-bonded interactions determined from all-atomistic simulations by the iterative Boltzmann inversion (IBI) method. Additionally, we propose a lever rule that can be useful to generate non-bonded potentials for such systems without reference to the all-atomistic ground truth. Our model captures the structural and dynamic properties of the copolymer material with quantitative accuracy and is useful to study long-time dynamics of highly-entangled systems, sequence-dependent properties, phase behaviour, etc.

36 MATERIALS SCIENCE↗

SU-E-T-354: Efficient and Enhanced QA Testing of Linear Accelerators Using a Real-Time Beam Monitor

Purpose: To investigate the feasibility of performing routine QA tests of linear accelerators (Linac) using the Integral Quality Monitoring (IQM) system. The system, consisting of a 1-D sensitivity gradient large area ion-chamber mounted at the collimator, allows automatic collection and analysis of beam data. Methods: The IQM was investigated to perform several QA constancy tests, similar to those recommended by AAPM TG142, of a Linac including: beam output, MLC calibration, beam symmetry, relative dose factor (RDF), dose linearity, output as a function of gantry angle and dose rate. All measurements by the IQM system accompanied a reference measurement using a conventional dosimetry system and were performed on an Elekta Infinity Linac with Agility MLC. The MLC calibration check is done using a Picket-Fence type 2×10cm{sup 2} field positioned at different off-axis locations along the chamber gradient. Beam symmetry constancy values are established by signals from an 4×4cm{sup 2} aperture located at various off-axis positions; the sensitivity of the test was determined by the changes in the signals in response to a tilt in the beam. The data for various square field sizes were used to develop a functional relationship with RDF. Results: The IQM tracked the beam output well within 1% of the reference ion-chamber readings. The Picket-Fence type field test detected a 1mm shift error of one MLC bank. The system was able to detect 2.5% or greater beam asymmetry. The IQM results for all other QA tests were found to agree with the reference values to within 0.5%. Conclusion: It was demonstrated that the IQM system can effectively monitor the Linac performance parameters for the purpose of routine QA constancy tests. With minimum user interactions a comprehensive set of tests can be performed efficiently, allowing frequent monitoring of the Linac. The presenting author’s salary is funded by the manufacturer of the QA device. All the other authors have financial interests with the commercialization of this QA device.

07 ISOTOPE AND RADIATION SOURCES↗

Mach-zehnder based optical marker/comb generator for streak camera calibration

This disclosure is directed to a method and apparatus for generating marker and comb indicia in an optical environment using a Mach-Zehnder (M-Z) modulator. High speed recording devices are configured to record image or other data defining a high speed event. To calibrate and establish time reference, the markers or combs are indicia which serve as timing pulses (markers) or a constant-frequency train of optical pulses (comb) to be imaged on a streak camera for accurate time based calibration and time reference. The system includes a camera, an optic signal generator which provides an optic signal to an M-Z modulator and biasing and modulation signal generators configured to provide input to the M-Z modulator. An optical reference signal is provided to the M-Z modulator. The M-Z modulator modulates the reference signal to a higher frequency optical signal which is output through a fiber coupled link to the streak camera.

42 ENGINEERING↗

Reference Materials for Laser and Xenon Flash Thermal Diffusivity Systems

This report presents the status of current standard reference materials for thermal diffusivity testing. In most thermal properties testing systems, it is common to use standard reference materials to show the reproducibility of the tests and certify the instrument is producing results within expected uncertainty range. The definition of reference materials or standards vary depending on the quality control protocols of the project. For thermal diffusivity, although there were standards available by the National Bureau of Standards (NBS) 40 years ago, there has been no recent NIST standard reference material (SRM). There are only a few sources that produce and provide traceable reference standards for thermal diffusivity. The certificate typically expires in 5 years and only applies to the specific lot of materials. Other reference materials are provided by the testing systems manufacturers. They are mostly well-known reference materials or materials used by the equipment manufacturers with historic data. However, most these reference materials no longer carry valid certificates. Various reference materials will be discussed along with the industry practice when only secondary standards are available.

36 MATERIALS SCIENCE↗

Theoretical and numerical investigations of inverse patchy colloids in the fluid phase

We investigate the structural and thermodynamic properties of a new class of patchy colloids, referred to as inverse patchy colloids (IPCs) in their fluid phase via both theoretical methods and simulations. IPCs are nano- or micro- meter sized particles with differently charged surface regions. We extend conventional integral equation schemes to this particular class of systems: our approach is based on the so-called multi-density Ornstein-Zernike equation, supplemented with the associative Percus-Yevick approximation (APY). To validate the accuracy of our framework, we compare the obtained results with data extracted from NpT and NVT Monte Carlo simulations. In addition, other theoretical approaches are used to calculate the properties of the system: the reference hypernetted-chain (RHNC) method and the Barker-Henderson thermodynamic perturbation theory. Both APY and RHNC frameworks provide accurate predictions for the pair distribution functions: APY results are in slightly better agreement with MC data, in particular at lower temperatures where the RHNC solution does not converge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Wide Temperature, Radiation Tolerant, CMOS-compatible Precision Voltage Reference for Extreme Environment Instrumentation Systems

Many design techniques have been incorporated into modern CMOS design practices to improve radiation tolerance of integrated circuits. Annular-gate NMOS structures have been proven to be significantly more radiation tolerant than the standard straight-gate variety. Many circuits can be designed using the annular-gate NMOS and the inherently radiation tolerant PMOS. Band-gap reference circuits, however, typically require p-n junction diodes. These p-n junction diodes are the dominating factor in radiation degradation in band-gap reference circuits. This paper proposes a different approach to band-gap reference design to alleviate the radiation susceptibility presented by the p-n junction diodes.

radiation hardened by design↗

Pulse-shaping assisted multidimensional coherent electronic spectroscopy

Understanding nuclear and electronic dynamics of molecular systems has advanced considerably by probing their nonlinear responses with a suitable sequence of pulses. Moreover, the ability to control crucial parameters of the excitation pulses, such as duration, sequence, frequency, polarization, slowly varying envelope, or carrier phase, has led to a variety of advanced time-resolved spectroscopic methodologies. Recently, two-dimensional electronic spectroscopy with ultrashort pulses has become a more and more popular tool since it allows to obtain information on energy and coherence transfer phenomena, line broadening mechanisms, or the presence of quantum coherences in molecular complexes. Here, we present a high fidelity two-dimensional electronic spectroscopy setup designed for molecular systems in solution. It incorporates the versatility of pulse-shaping methods to achieve full control on the amplitude and phase of the individual exciting and probing pulses. Selective and precise amplitude- and phase-modulation is shown and applied to investigate electronic dynamics in several reference molecular systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Photovoltaic (PV) Quick Reference Guide

This Photovoltaic (PV) and Energy Storage System (EES) Quick Reference Guide is for inspectors inspecting projects permitted with SolarAPP+.

ENERGY PLANNING, POLICY, AND ECONOMY,SOLAR ENERGY↗

Mass optimization of a supercritical CO 2 Brayton cycle with a direct cooled nuclear reactor for space surface power

A long life, reliable, and compact surface power system will be necessary to achieve future goals in space exploration. This application uniquely requires the system to be optimized with respect to mass because system mass directly drives the space launch cost associated with transporting the system to its desired location. In this study, a supercritical CO 2 Brayton cycle coupled to a direct-cooled nuclear reactor was designed and optimized for mass. Robust models were developed for each Brayton cycle component in order to model the cycle performance. The three most massive components of this cycle are the radiator-based heat rejection system (subsequently referred to as the “radiator”), recuperator, and reactor. Mass correlations for the recuperator and radiator were established through interactions with component experts from industry and national labs. A reactor model was developed to predict the minimum mass reactor that satisfies neutronic and thermal limitations for given cycle conditions. The system optimization explores tradeoffs between the reactor, recuperator, and radiator sizes in order to identify the least massive system that will satisfy the power (40 kWe) and life (10 yr) requirements. To explore the effects of turbine inlet temperature on system mass, three types of microtube and shell recuperator technologies were considered: baseline stainless steel (which is consistent with the industry partner’s current designs), stainless steel with non-heritage tube sizes (which requires further development of manufacturing techniques), and Inconel (which is not a current/legacy design). Both stainless steel designs have a temperature limit of 823 K, which limits the turbine inlet temperature to 900 K. The baseline stainless steel design results in a combined mass of 738 kg. The stainless steel design allowing for non-heritage tube sizes reduces the combined mass to 674 kg (a 9% improvement). The Inconel design leads to an optimal turbine inlet temperature of 1120 K and reduces the combined mass to 391 kg (a 47% improvement). Furthermore, the interesting conclusion from this study include: (1) radiator mass dominates the total mass, and this drives the cycle to relatively high heat rejection temperatures resulting in a compressor inlet state point that is not close to the vapor dome; thus, the typical advantages of an sCO 2 system are not realized, and a working fluid with a higher critical temperature may be more suitable, and (2) neutronic limitations cause the reactor size to be relatively unaffected by the power level.

42 ENGINEERING↗

SU-E-T-265: Development of Dose-To-Water Conversion Models for Pre-Treatment Verification with the New AS1200 Imager

Purpose: To develop and evaluate models for dose verification of flattened (FF) and flattening filter free (FFF) beams for the new Varian aS1200 backscatter-shielded electronic portal imaging device (EPID). Methods: The model converts EPID images to incident energy fluence using deconvolution of EPID scatter kernels and fluence to dose in water using convolution with dose-to-water kernels. Model parameters were optimized using non-transmission EPID images of varying jaw defined field sizes for energies of 6 and 10 MV FF and FFF beams. Energy fluence was obtained from the Acuros planning system and reference dose profiles and output factors were measured at depths of 5, 10, 15 and 20 cm in a water phantom. Images for 34 IMRT fields acquired at 6 and 10 MV FF energy were converted to dose at 10 cm depth in water and compared to treatment planning system dose plane calculations using gamma criteria. Results: Gamma evaluations for the IMRT fields had mean (1 standard deviation) pass rates of 99.4% (0.8%) and mean gamma scores of 0.32 (0.06) with 2%, 2 mm criteria and 10% of maximum dose threshold. Conclusion: The developed model has been shown to be highly accurate for pre-treatment verification with the new aS1200 imager which does not display support-arm backscatter artefact and has improved dosimetric properties. Further investigation of FFF modes is in progress. The model is currently being evaluated at sites for potential clinical release.

60 APPLIED LIFE SCIENCES↗

Liquid fuel molten salt reactors for thorium utilization

Molten salt reactors (MSRs) represent a class of reactors that use liquid salt, usually fluoride- or chloride-based, as either a coolant with a solid fuel (such as fluoride salt-cooled high temperature reactors) or as a combined coolant and fuel with fuel dissolved in a carrier salt. For liquid-fuelled MSRs, the salt can be processed online or in a batch mode to allow for removal of fission products as well as introduction of fissile fuel and fertile materials during reactor operation. The MSR is most commonly associated with the 233 U/thorium fuel cycle, as the nuclear properties of 233 U combined with the online removal of parasitic absorbers allow for the ability to design a thermal-spectrum breeder reactor; however, MSR concepts have been developed using all neutron energy spectra (thermal, intermediate, fast, and mixed-spectrum zoned concepts) and with a variety of fuels including uranium, thorium, plutonium, and minor actinides. Early MSR work was supported by a significant research and development (R&D) program that resulted in two experimental systems operating at ORNL in the 1960s, the Aircraft Reactor Experiment and the Molten Salt Reactor Experiment. Subsequent design studies in the 1970s focusing on thermal-spectrum thorium-fueled systems established reference concepts for two major design variants: (1) a molten salt breeder reactor (MSBR), with multiple configurations that could breed additional fissile material or maintain self-sustaining operation; and (2) a denatured molten salt reactor (DMSR) with enhanced proliferation-resistance. T MSRs has been selected as one of six most promising Generation IV systems and development activities have been seen in fast-spectrum MSRs, waste-burning MSRs, MSRs fueled with low-enriched uranium (LEU), as well as more traditional thorium fuel cycle-based MSRs. This study provides an historical background of MSR R&D efforts, surveys and summarizes many of the recent development, and provides analysis comparing thorium-based MSRs.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

A Cost-Effective Wave Energy Harvesting System with Maximum Power Point Tracking Capability

In this paper, we propose a low-cost bidirectional four-switch inverter that transfers three-phase energy between a permanent magnet synchronous generator (PMSG) driven by a wave energy collector and the power grid or a local ac load. To achieve high control performance, the machine-side inverter uses a high-gain observer for rotor position estimation and a Lyapunov-based approach for torque control. For the gridside inverter control, we estimate the filter capacitor voltage with a model reference adaptive system and control the dc-link voltage with a Lyapunov-based energy function. We also track the maximum power point from the sea waves with an integral control law that actively matches the generator impedance with that of the wave collection device. The proposed system supports both grid-following/forming modes. We validate our control design with simulation results on a 3-kW hardware setup.

wave energy, power systems integration, control de↗

Advanced Energy Harvesting Control Schemes for Marine Renewable Energy Devices

The Advanced Energy Harvesting Control Schemes for Marine Renewable Energy Devices (Project) investigated, analyzed and modeled advanced turbine control schemes with the objective of increasing the energy harvested by hydrokinetic turbines in turbulent flow. Ocean Renewable Power Company (ORPC) implemented and validated a feedforward controller to increase power capture; and applied and tested the controls on ORPC’s RivGen® Power Systems in Igiugig, Alaska. Assessments of performance improvements were made for the RivGen® in the Igiugig environment and for ORPC’s TidGen® Power System in a reference tidal environment. Annualized Energy Production (AEP) and Levelized Cost of Energy (LCOE) improvements associated with implementation of the recommended control methodology were made for the TidGen® Power System in the DOE reference tidal environment. System Performance Advancement (SPA) goals were selected for the project. SPA targets were to improve Power to Weight Ratio (PWR) and system Availability, with the intention of reducing Levelized Cost of Electricity (LCOE). This project focused primarily reducing in PWR. Reductions in PWR of 25.5% were achieved. Reductions of 20.3% in LCOE were achieved. This project evaluated four types of controllers which were tested in simulation, emulation, a laboratory flume, and the field. The adaptive Kω2 controller performs similarly to the non-adaptive version of the same controller and may be useful in tidal channels where the mean velocity is continually evolving. Trends in simulation were largely verified through experiments, which also provided the opportunity to test assumptions about turbine responsiveness and control resilience to varying scales of turbulence. Laboratory experiments provided an essential stepping stone between simulation and implementation on a field-scale turbine. Experiments also demonstrated that using “energy loss” as a metric to differentiate between well-designed controllers operating at an optimal tip-speed ratio set-point is difficult, which anticipated the outcome from field experiments. The clear message is that the feedforward Kω2 controller out-performs the feedback controllers in almost all aspects and modes of evaluation. The controllers proved a substantial improvement over the baseline performance of the TidGen® turbine, in terms of energy capture. The effects of noise-contaminated angular velocity signals were investigated and validated by simulation as an explanation for the performance limitations observed for TidGen® turbine operations in Eastport, Maine. Measurements of loads performed as part of the laboratory testing indicate that there are limited differences in average axial thrust force between control architectures. This suggests that none of the control strategies are likely to substantially affect loads on the turbine support structure. Velocity measurements during the ORPC RivGen® turbine deployment at Igiugig, Alaska, in 2014 were used to assess the variability of the river flow. Results suggest that the river flow is approximately steady, in the mean sense, at any particular location in the river, with random turbulent fluctuations that are around 10% of the mean flow. The mean flow in the center channel of the river is 2.5 m/s, with reductions near the riverbanks and in the shallows. Spectral analysis and lagged correlation results indicate that temporal fluctuations at a given point are dominated by large scale fluctuations, such that measurements at the turbine location are just as useful for inflow control implementation as upstream measurements. At this site, and likely at many other river sites, flow is generally steady at a given location, but flow varies dramatically between locations, particularly laterally across the river. The primary result is that a lateral change in position of a few meters results in changes to flow speed that far exceed the turbulence fluctuations at any given location. The turbulence is dominated by long time scales. Following final system tests, the RivGen® device was submerged and each evaluated controller was tested across a range of gain/set point values and filter configurations for a minimum of 5 minutes, with longer runs attempted for well-performing cases. In addition to testing controllers during the 2015 deployment season, LGL Alaska Research Associates Inc. (LGL) performed a fish monitoring study in compliance with Alaska Department of Fish and Game fisheries habitat permit for the project. During the season, LGL reviewed 10% of 179 one-hour blocks of footage (6 minutes on the hour) and documented a total of over 1200 fish in the vicinity of the RivGen® device, including over 800 salmon smolt and over 350 adult salmon. No evidence of adverse effects including passage delay by upstream migrating salmon was noted. This is an important result for future deployments and has a direct impact on commercial system designs.

16 TIDAL AND WAVE POWER↗

Best Practices for Plug Load Management Using a Building Energy Management System

The University of California San Diego (UCSD) successfully integrated PLCs with their BEMS, which resulted in 66% energy savings over one week across 25 plug loads (K. Chia et al. 2023). UCSD documented each step of this effort, highlighting best practices along the way, in their 10-page brief, "Best Practices for Plug Load Management Using a Building Energy Management System" (also referred to as "brief" in this document). This fact sheet provides highlights and key takeaways from UCSD's brief. The reader is encouraged to read UCSD's full brief if they wish to move forward with implementing PLC integration with their BEMS.

Building Energy Management System Integration↗

Development of a Reference Governor-based Control Scheme for Integrated Energy Systems

The concept of an Integrated Energy System (IES) is meant to combine different energy technologies in synergistic ways to achieve a more secure and economical energy supply. The RAVEN-based HYBRID framework is used to find the optimal installed capacity and the optimal economical dispatch of each component of the IES. In practice what is achievable is limited by not only the inherent physical response characteristics of individual plant units but also by equipment operating limits. The inherent response characteristics are presently accounted for in the RAVEN-based HYBRID framework by dynamic models for plant units. The equipment operating limits, which are not yet addressed in HYBRID, are the subject of this report. These limits are set to achieve a design service life for a plant unit and are based on material degradation in the presence of mechanical fatigue induced by thermal cycling and by structure creep resulting from elevated temperature conditions. In general, the plant unit designer determines and specifies the allowable operating range of key process variables. It is then up to the integrated system design engineer to ensure those conditions are met. This can be accomplished through a combination of limiting the demand rates made on the plant unit and designing a control system that limits variations of key process variables. The typical control system design procedure, however, is not well suited for achieving this for complex dynamic systems such as encountered in integrated energy systems where multiple plant units must be simultaneously coordinated. This report describes how equipment operating limitations in an IES can be formally met through a control system design procedure know as the Reference Governor. The approach augments the existing controllers in a plant unit with an advance controller that modifies the issued setpoints so that selected process variables remain within limits. The design procedure is applied to the reference multi-unit system that has been the focus of Modeling and Simulation task in the Integrated Energy System program. Results describing application to the problem of limiting key process variables during operational transients for two of the plant units, the balance of plant and the gas turbine, are then presented. It is demonstrated that the Reference Governor method is an effective means for ensuring equipment operating constraints can be met in an IES. The software that implements the method has been made accessible to others on the Modeling and Simulation upload site.

42 ENGINEERING↗

Model predictive control for active insulation in building envelopes

Active insulation systems (AISs) refer to building envelopes with insulation materials that can change their thermal conductivity and are coupled with thermal mass to reduce building energy consumption and peak power. In this research, a novel optimal control approach is proposed to evaluate the maximum theoretical energy and cost-saving potential of AISs. A time-varying model predictive control (TV-MPC) controller was used to optimally select the AIS mode and simultaneously determine the operation of the heating, ventilation and air conditioning (HVAC) system so that the maximum saving potential of the entire system can be realized. To comprehensively evaluate the power shifting flexibility of AISs, two optimization objectives—minimizing weekly electric energy consumption and minimizing weekly electricity cost—were considered. The summer season simulation results show that under the first objective, more than 50% electric and thermal energy was saved when the upper boundary of the indoor air temperature was set to 25 °C. Furthermore under the second optimization objective, 38% of the cost was saved. It can be expected that the developed approach can be easily applied to multiple types of AISs with different mechanisms.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Emergent biaxiality in chiral hybrid liquid crystals

Biaxial nematic liquid crystals are fascinating systems sometimes referred to as the Higgs boson of soft matter because of experimental observation challenges. Here we describe unexpected states of matter that feature biaxial orientational order of colloidal supercritical fluids and gases formed by sparse rodlike particles. Colloidal rods with perpendicular surface boundary conditions exhibit a strong biaxial symmetry breaking when doped into conventional chiral nematic fluids. Minimization of free energy prompts these particles to orient perpendicular to the local molecular director and the helical axis, thereby imparting biaxiality on the hybrid molecular-colloidal system. The ensuing phase diagram features colloidal gas and liquid and supercritical colloidal fluid states with long-range biaxial orientational symmetry, as supported by analytical and numerical modeling at all hierarchical levels of ordering. Unlike for nonchiral hybrid systems, dispersions in chiral nematic hosts display biaxial orientational order at vanishing colloid volume fractions, promising both technological and fundamental research utility.

Colloids↗

Upgrade Your Work Plans for Better Performance - 16103

Most work plans involve at least two basic pieces: a list of things to do and a timeline for doing them. These 'tasks-and-times' plans can be used for managing a project, an organizational change, or the implementation of a strategic objective. But given the high rate of plan failures - often cited as ranging from 35% to over 80% - something must be missing. Three ideas for upgrading work plans have demonstrated higher success rates than the time-and-task method alone. First, maintain a 'GPS Scorecard' of the Goals, Performance metrics, and Schedules for accomplishment. Second, maintain a Performance Circle Register of all key players, and the key deliverables to and from each of them, that will ensure success. Third, implement all three parts of an accountability management system, collectively referred to as 'T3': Tracking, Team assignments, and Talk-times to update status and progress against the plan. Why bother to take the extra steps to strengthen work plans? There are three reasons: (a) Because traveling without a map is risky in times of high change in infrastructure, staffing, and technology; (b) Because 'expectations' do not guarantee delivery as reliably as well-defined agreements; and (c) Because 'accountability' is a management practice, not a personality trait. Together, implementing these three ideas can provide for clarity of purpose, guidance in establishing the productive relationships necessary for success, and a system of supporting accountability for all participants, both on the team and with others inside and outside of the organization. (authors)

99 GENERAL AND MISCELLANEOUS↗