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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Electronic Structure, Chemical Bonding and Electrocatalytic Activity of Novel Ba(Fe0.7Ta0.3)O3-d Compounds

Ba(Fe0.7Ta0.3)O3-d (BFTO) compounds were synthesized using conventional, high-temperature solid-state ceramic reaction method by varying the sintering temperature (Ts=1200-1350 °C). The crystal structure, electronic structure and electrocatalytic activity of BFTO compounds were evaluated. Processing temperature induced phase transformations and structural quality influences the electronic structure and electrocatalytic activity of BFTO compounds. At Ts=1200 oC, Ba(Fe0.7Ta0.3)O3-d stabilizes in mixed phase of orthorhombic + rhombohedral phase (Amm2 + R3m). With increasing Ts (=1250 oC), Ba(Fe0.7Ta0.3)O3-d ceramics stabilize in tetragonal + rhombohedral [P4mm + R3m] mixed phase with a variation in the quantity of respective phases. High-resolution X-ray photoelectron spectroscopy of constituent elements, namely, Ba 3d, Fe2p, Ta 4f and O 1s reveal the electronic structure changes due to changes in chemical environment resulted from structural transformation. The electrocatalytic activity of BFTO was evaluated towards hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR). Though all the samples demonstrated appreciable electrocatalytic properties, the best electrochemical catalytic activity was shown by BFTO samples sintered at 1350 °C. BFTO-1350 oC showed an onset potential of -0.690 V vs. RHE for HER and an onset potential of 0.73 V vs. RHE for ORR indicating its significant electrocatalytic performance. A general increase in activity with sintering temperature is potentially due to the improved structural quality of the BFTO ceramics. In addition to offering the fundamental insights into solid state materials based on doped BaTiO3 for electrocatalysis, the present work may contribute to the design and development of materials for high-temperature electrocatalytic converters.

Ba(Fe0.7Ta0.3)O3-d, Phase Transformation↗
DOE OSTI2021

Causality, intermittence, and crossphase evolution during confinement transitions in the TJ-II stellarator

In this work, we study spontaneous electron to ion root transitions in TJ-II using Langmuir probes. By scanning the probe position on a shot to shot basis, we reconstruct a spatiotemporal map of the evolution of important turbulent quantities in the plasma edge region. We pay particular attention to the evolution of the cross phase between transport-relevant variables, showing the spatiotemporal evolution of this quantity for the first time, revealing the outward propagation of the changes associated with the transition. Additionally, we also compute the intermittence parameter, which allows us to conclude that the turbulence, although its amplitude increases, condenses in a reduced number of dominant modes and becomes less bursty. The causal relationship between variables is studied using the transfer entropy, clarifying the interactions between the main variables and offering a rather complete picture of the complex evolution of the plasma across the confinement transition.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Validation of MARS-F modeling of plasma response to RMPs using internal measurements on DIII-D

The linear resistive plasma response model is validated against the plasma internal measurement data from DIII-D edge-localized mode (ELM) control experiments with applied resonant magnetic perturbation (RMP). Considered are DIII-D discharges where the n = 1, 2, and 3 (n is the toroidal mode number) RMP field was applied. Experimental data for the plasma boundary displacement, as well as the three-dimensional (3D) pressure perturbation in the edge pedestal region, are deduced from the vertical Thomson scattering (TS) system and the horizontal charge exchange recombination (CER) system on DIII-D. The linear response model produces results that are in reasonable quantitative agreement with the DIII-D internal measurements. The plasma boundary displacement of up to 15 mm is modeled, with the pedestal pressure perturbation reaching 3 kPa. As an important insight, the larger plasma displacement measured by the vertical TS system, as compared to that measured by the horizontal CER system, is due to the contribution from the tangential component of the plasma displacement to the former. This mixing of displacement components is also found to influence the sensitivity of the CER measurement comparisons. The results of this study provide further confidence in the linear resistive plasma response model for analyzing ELM control experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

A Thermosensitive, Phase-Variable Epigenetic Switch: pap Revisited

It has been more than a decade since the last comprehensive review of the phase-variable uropathogen-associated pyelonephritis-associated pilus (pap) genetic switch. Since then, important data have come to light, including additional factors that regulate pap expression, better characterization of H-NS regulation, the structure of the Lrp octamer in complex with pap regulatory DNA, the temperature-insensitive phenotype of a mutant lacking the acetyltransferase RimJ, evidence that key components of the regulatory machinery are acetylated, and new insights into the role of DNA binding by key regulators in shaping both the physical structure and regulatory state of the papI and papBA promoters. This review revisits pap, integrating these newer observations with older ones to produce a new model for the concerted behavior of this virulence-regulatory region.

gene silencing↗
DOE OSTI2023

Real-Time Krylov Theory for Quantum Computing Algorithms

Quantum computers provide new avenues to access ground and excited state properties of systems otherwise difficult to simulate on classical hardware. New approaches using subspaces generated by real-time evolution have shown efficiency in extracting eigenstate information, but the full capabilities of such approaches are still not understood. In recent work, we developed the variational quantum phase estimation (VQPE) method, a compact and efficient real-time algorithm to extract eigenvalues on quantum hardware. Here we build on that work by theoretically and numerically exploring a generalized Krylov scheme where the Krylov subspace is constructed through a parametrized real-time evolution, which applies to the VQPE algorithm as well as others. We establish an error bound that justifies the fast convergence of our spectral approximation. We also derive how the overlap with high energy eigenstates becomes suppressed from real-time subspace diagonalization and we visualize the process that shows the signature phase cancellations at specific eigenenergies. We investigate various algorithm implementations and consider performance when stochasticity is added to the target Hamiltonian in the form of spectral statistics. To demonstrate the practicality of such real-time evolution, we discuss its application to fundamental problems in quantum computation such as electronic structure predictions for strongly correlated systems.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Texture Memory in Hexagonal Metals and Its Mechanism

Texture memory is a phenomenon in which retention of initial textures occurs after a complete cycle of forward and backward transformations, and it occurs in various phase-transforming materials including cubic and hexagonal metals such as steels and Ti and Zr alloys. Texture memory is known to be caused by the phenomena called variant selection, in which some of the allowed child orientations in an orientation relationship between the parent and child phases are preferentially selected. Without such variant selection, the phase transformations would randomize preferred orientations. In this article, the methods of prediction of texture memory and mechanisms of variant selections in hexagonal metals are explored. The prediction method using harmonic expansion of orientation distribution functions with the variant selection in which the Burgers orientation relationship, {110}β//{0001} α-hex <1$\bar{1}$1>β//$\langle2\bar{11}0\rangle$ α-hex , is held with two or more adjacent parent grains at the same time, called “double Burgers orientation relation (DBOR)”, is introduced. This method is shown to be a powerful tool by which to analyze texture memory and ultimately provide predictive capabilities for texture changes during phase transformations. Variation in nucleation and growth rates on special boundaries and an extensive growth of selected variants are also described. Analysis of textures of commercially pure Ti observed in situ by pulsed neutron diffraction reveals that the texture memory in CP-Ti is indeed quite well predicted by consideration of the mechanism of DBOR. The analysis also suggests that the nucleation and growth rates on the special boundary of 90° rotation about $\langle2\bar{11}0\rangle$ α-hex should be about three times larger than those of the other special boundaries, and the selected variants should grow extensively into not only one parent grain but also other grains in α-hex(hexagonal)→β(bcc) transformation. The model calculations of texture development during two consecutive cycles of α-hex→β→α-hex transformation in CP-Ti and Zr are also shown.

36 MATERIALS SCIENCE↗
NASA NTRS1970

Propagation of long waves in curved ducts

Mathematical model for two-dimensional, long-wave propagation in curved acoustic ducts determining vibrational velocity distribution and variation and phase of motion at any point in system

Rostafinski, W.↗
NASA NTRS1972

Spectrophotometry of beta Lyrae

Two hundred and fourteen scans over the wavelength region 1100 A to 1800 A with 10 A resolution were obtained by OAO spacecraft for the eclipsing binary Beta Lyrae between JD 2440889.5 and JD 2440904.5. Preliminary results indicate that: (1) The intensity at primary minimum is almost exactly one-half that at maximum and that the primary eclipse is less deep than that in the visual or longer ultraviolet wavelengths; (2) except for the 1100 to 1200 A region, the depth of the primary eclipse appears independent of wavelength; (3) the energy distribution at secondary minimum is similar to that at primary; (4) the two most prominent emission lines match well both with Si IV and C IV emission observed in gamma Vel and imply an exciting source of high temperature; (5) the emission lines do not show variation with phase.

Houck, T. E.↗
NASA NTRS1974

Spatial distribution of polarization over the disks of Venus, Jupiter, Saturn, and the moon

The method of photographic subtraction, which superposes positive and negative photographs taken with the analyzer rotated through 90 deg, is used to analyze polarization photographs of Venus, Jupiter, Saturn, and the moon. For Venus, near 90 deg phase angle, variation in polarization in ultraviolet light appears to correspond generally with the position of the cloud markings. The northern hemisphere of Saturn shows higher polarization in blue light than does the rest of the planet. The polarization of the moon is shown to deviate significantly from Umov's law for reciprocity of polarization and reflectivity in certain regions.

Fountain, J. W.↗
NASA NTRS1974

Six-color photometry of Iapetus, Titan, Rhea, Dione and Tethys

Six-color photometric observations made during Saturn's 1972/73 opposition enable us to separate the solar phase and orbital phase contributions to the observed light variations of Iapetus, Titan, Rhea, Dione and Tethys. Titan shows no orbital variations, but has phase coefficients which range from negligible values in the infrared to 0.014 mag/deg in the ultraviolet. Rhea has a bright leading side, a light curve amplitude of about 0.2 mag, and surprisingly large phase coefficients. Combined with other available information, the observations suggest a very porous, texturally complex surface layer. Dione has a leading side which is a few tenths of a magnitude brighter than the trailing side, but the light curve amplitude has little wavelength dependence and the phase coefficients are significantly smaller than those of Rhea, suggesting a less intricate surface texture. The leading side of Tethys is probably a few tenths of a magnitude brighter than the trailing side. Our Iapetus observations generally supplement the earlier work by Millis.

Noland, M.↗
NASA NTRS1977

The X-ray emitting galaxy Cen-A

OSO-8 X-ray observations of Cen-A in 1975 and 1976 are reported. The source spectrum is well fit in both years by a power law of number index 1.62 and absorption due to 1.3 x 10 to the 23rd power at/sq cm. The total flux varied by a factor 2 between 1975 and 1976. In 1976 there were approximately 40% flux variations on a time scale of days. The 6.4 keV Fe fluorescent line and the 7.1 keV absorption edge were measured implying Fe/H approximately equals .000016. Simultaneous radio measurements show variation in phase with X-ray variability. Models considering radio, milimeter, IR and X-ray data show that all the data can be accounted for by a model in which the X-rays are due to a synchrotron self-Compton source embedded in a cold H(2) cloud.

Mushotzky, R. F.↗
NASA NTRS1977

Io's sodium emission profiles - Variations due to Io's phase and magnetic latitude

We present recent measurements of high-resolution sodium D2 emission line profiles of Io's atmosphere and cloud. The high-velocity skirts of these profiles are strongest when Io is on the magnetic equator where protons and heavy ions, which sputter atoms from Io's surface, are concentrated. The skirts are most prominent on the long-wavelength side of the line when Io is west of Jupiter, and they are most prominent on the short-wavelength side of the line when Io is east of Jupiter. Our observations also indicate that there is a shift in the emission peak with respect to Io which is correlated with Io's orbital phase angle.

Trafton, L.↗
NASA NTRS1978

The X-ray emitting galaxy Centaurus A

OSO-8 X-ray observations of Cen A in 1975 and 1976 are reported. The source spectrum can be well fitted in both years by a power law of number index 1.66 and absorption due to 1.3 by 10 to the 23rd power atoms/sq cm. The total flux varied by a factor of 2 between 1975 and 1976. In 1976 there were flux variations of approximately 40% on a time scale of days. Measurements of the 6.4-keV Fe fluorescent line and the 7.1-keV absorption edge imply Fe/H of approximately 0.000016. Simultaneous radio measurements show variation in phase with X-ray variability. Consideration of radio, millimeter, infrared, and X-ray data shows that all the data can be accounted for by a model in which the X-rays are due to a synchrotron self-Compton source embedded in a cold H2 cloud.

Mushotzky, R. F.↗
NASA NTRS1979

HEAO-1 observations of AM Herculis between 0.1 and 3 keV

Results are reported for HEAO A2 scanning observations of AM Her in the energy range from 0.1 to 3 keV. A light curve of AM Her is plotted, a typical flux of 8 x 10 to the -10th erg/sq cm-sec in the 0.15-0.5-keV range at X-ray maximum is estimated, and no pronounced spectral variation with phase is detected. It is found that both a 0.025-keV blackbody spectrum and an exponential spectrum with an energy-dependent Gaunt factor provide an acceptable fit to the data. It is concluded that the spectrum of the radiation from the plasma at the surface of the strongly magnetic and relatively massive white dwarf in AM Her consists of three components: (1) a high-temperature (about 100 million to 1 billion K) component produced by electron-ion bremsstrahlung in the hot postshock plasma; (2) a blackbody component of about 100,000 to 1 million K produced by the heated surface of the white dwarf; and (3) a still softer component produced by optically thick electron cyclotron emission in the postshock region.

Tuohy, I. R.↗
NASA NTRS1980

On the relationship between secular brightness changes of Titan and solar variability

Titan's geometric albedo varied noticeably from 1972 to 1978, in phase with variations in solar activity (Lockwood and Thompson, 1979). A series of radiative transfer and aerosol formation calculations were made to demonstrate the feasibility of the following scenario for these secular brightness changes. Solar activity changes, especially in the UV output of the sun, result in alterations to the mass production rate of aerosols in Titan's atmosphere, which lead to modifications of their microphysical properties. The latter, in turn, cause the albedo to vary. Current estimates of the change in the solar UV radiation below the dissociation limit of methane imply alterations to the mean radius of the aerosols over an 11-yr solar cycle that are consistent in sign and magnitude with those required to explain the observed secular brightness changes.

Pollack, J. B.↗