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At least 253 records · Page 14

Anomalous thermodynamic properties of quantum critical superconductors

Recent high-precision measurements employing different experimental techniques have unveiled an anomalous peak in the doping dependence of the London penetration depth which is accompanied by anomalies in the heat capacity in iron-pnictide superconductors at the optimal composition associated with the hidden antiferromagnetic quantum critical point. Here, we argue that finite temperature effects can be a cause of observed features. Specifically we show that quantum critical magnetic fluctuations under superconducting dome can give rise to a nodal-like temperature dependence of both specific heat and magnetic penetration depth in a fully gapped superconductor. In the presence of line nodes in the superconducting gap fluctuations can lead to the significant renormalization of the relative slope of T-linear penetration depth which is steepest at the quantum critical point. The results we obtain are general and can be applied beyond the model we use.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

High Density Thermal Energy Storage by Highly Stable Glauber’s Salt Composites with Low Supercooling for Building-Scale Application

Phase change materials (PCM) are a promising candidate for thermal energy storage in building infrastructure, enabling grid-integrated peak load shaving by utilizing energy production in off-peak hours. Glauber’s salt (Na2SO4.10H2O, Sodium sulfate hydrate) are highly attractive due to their high energy storage capacity and low cost but Glauber’s salt suffers from long-standing challenges including high supercooling ( > 15oC) and low thermal cyclic stability, which is a major setback for practical building-scale energy storage applications. Here, we developed a unique ionic molecular nucleating agent for Glauber’s salt which reduced the supercooling temperature to less than 5oC. By combining this nucleated SSD with a polymer, phase segregation of salt hydrate for over 100 thermal cycles without degradation was achieved. Key was that the polymer confined the SSD crystals, preventing phase separation. In addition, we applied our stable Glauber’s salt composite in a miniatured building model and demonstrate that our PCM composite can be utilized for real-world building infrastructure.

additives↗

The Viking seismometer

The Viking seismometer, operating on the Martian surface in the region of Utopia Planitia, includes three inertial velocity transducers, amplifiers, filters, automatic event detectors, data compactors, and temporary data storage capability within a unit weighing 2.2 kg. The seismometer functions at a peak magnification of 218,000 with a ground resolution of 2 nanosec and 3 Hz. Since the telemetry capacities associated with the system are limited, the seismometer instrument package employs three data processing modes: a high sampling rate mode; a heavily filtered background monitoring mode; and a frequently-used data compacting mode.

Miller, W. F.↗

Performance of charge-injection-device infrared detector arrays at low and moderate backgrounds

Three 2 x 64 element charge injection device infrared detector arrays were tested at low and moderate background to evaluate their usefulness for space based astronomical observations. Testing was conducted both in the laboratory and in ground based telescope observations. The devices showed an average readout noise level below 200 equivalent electrons, a peak responsivity of 4 A/W, and a noise equivalent power of 3x10 sq root of W/Hz. Array well capacity was measured to be significantly smaller than predicted. The measured sensitivity, which compares well with that of nonintegrating discrete extrinsic silicon photoconductors, shows these arrays to be useful for certain astronomical observations. However, the measured readout efficiency and frequency response represent serious limitations in low background applications.

Mckelvey, M. E.↗

Storing Affordability: Battery Storage as an Asset to Reduce Data Center Cost Shifts

This report examines how battery energy storage systems (BESS) can help utilities accommodate large load growth while protecting affordability for existing ratepayers. Rapid growth in electricity demand from artificial intelligence (AI) data centers is straining the U.S. grid. Furthermore, many new data centers are entering rural markets, which could offer economic benefits but may also pose implementation challenges for smaller utilities. At the same time, retail electricity prices are increasing faster than inflation, elevating customer affordability as a key challenge. While data centers have not been the primary driver of increases in residential prices to date, they have pushed wholesale energy and capacity prices higher in several markets. Fundamental utility cost-allocation principles show that data center growth can be rate-positive for existing customers only if new peak demand grows faster than the costs a utility must incur to serve it. Several factors, including a utility’s degree of wholesale market exposure, forecast uncertainty and stranded-asset risk, and tariff design can determine the outcome of load growth on retail rates. Energy storage can make several affordability contributions in the face of this landscape of uncertainty and market volatility, including deferral of higher-cost grid investments through improved utilization of existing assets and flexibility of new large loads, insulation from volatile wholesale prices through peak shaving, and reliability support to address grid risks stemming from the behavior of AI data center loads. Different potential BESS deployment pathways—utility-scale front-of-the-meter systems, aggregated small-scale storage installations, and data center-sited behind-the-meter storage—are compared against each other and against conventional capacity alternatives. This framework is intended as a conceptual resource to utilities, particularly smaller public utilities with rural service territories, who may be considering the role that energy storage can play in insulating existing ratepayers from data center cost shifts.

25 ENERGY STORAGE↗

Enhanced Airport Capacity Through Safe, Dynamic Reductions in Aircraft Separation: NASA's Aircraft VOrtex Spacing System (AVOSS)

An aspect of airport terminal operations that holds potential for efficiency improvements is the separation criteria applied to aircraft for wake vortex avoidance. These criteria evolved to represent safe spacing under weather conditions conducive to the longest wake hazards, and are consequently overly conservative during a significant portion of operations. Under many ambient conditions, such as moderate crosswinds or turbulence, wake hazard durations are substantially reduced. To realize this reduction NASA has developed a proof-of-concept Aircraft Vortex Spacing System (AVOSS). Successfully operated in a real-time field demonstration during July 2000 at the Dallas Ft. Worth International Airport, AVOSS is a novel integration of weather sensors, wake sensors, and analytical wake prediction algorithms. Gains in airport throughput using AVOSS spacing as compared to the current criteria averaged 6%, with peak values approaching the theoretical maximum of 16%. The average throughput gain translates to 15-40% reductions in delay when applied to realistic capacity ratios at major airports.

OConnor, Cornelius J.↗

Local Air Quality Impacts of a Peak-Shaving Diesel Generator Unit in Waynesville, North Carolina

The Waynesville Electric Department in Waynesville, North Carolina, operates a 2,000-kW diesel generator with a 4% capacity factor, emitting less than 1 ton annually of PM2.5, VOCs, carbon monoxide (CO), and sulfur dioxide (SO2), and approximately 1.8 tons of NO. The National Laboratory of the Rockies (NLR) conducted high-resolution, near-source air-quality modeling to evaluate the generator's impacts. Results indicate minimal effects on ambient pollutant concentrations: annual PM2.5 increases are below 0.0004 microgrm/m3 for local census tracts, while CO and SO2 levels increase by less than 0.00004 ppm and 0.0002 ppb, respectively. Estimated annual premature mortality attributable to PM2.5 exposure is less than 0.001 cases across Haywood County, with an associated economic impact of approximately $12,000. This report complements a separate technoeconomic analysis to inform Waynesville's investment strategies for demand reduction.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Optimization of Operating Profit for the FEED of the PZAS Process for CO 2 Capture on a 460 MW NGCC

A rating model of PZAS (Piperazine with the Advanced Stripper) for a 460 MW natural gas combined cycle was developed from vendor-provided equipment performance data. Surrogate rating models were built and used to optimize variable profit of the system subject to natural gas and electricity price at a fixed value for CO 2 of $\$80$/tonne. Several process constraints were considered between ambient temperatures of 4.4 and 40.5 °C. Lower lean loading resulted in lower reboiler heat duty of about 2.2 GJ/tonne. Lean loading at 0.2 mol/equiv N was sufficient at an ambient temperature of 4.4 °C to maximize variable profit. Solvent precipitation was avoided even at low lean loading (0.18 mol/mol) in the absence of a trim cooler for the lean solvent between the absorber and the cold cross exchanger. Optimal CO 2 removal was always higher than the design case removal of 90% and achieved a peak of 93.6% for 4.4 ºC ambient temperature. Lean solvent rate was a significant driver of profitability. The maximum capacity of the compressor was a significant constraint on profitability. Increasing compressor capacity by 20–30% could increase variable profit by about 21% in the case of 0.18 lean loading at 4.4 °C ambient temperature. Furthermore, this increase in profit was lower at higher ambient temperature and higher lean loading. The breakeven gas price was $\$4.6$/MMBtu at high lean loading of 0.22 mol/mol. Below this value, profit was maximized by increasing the boiler heat rate. Above this value, profit could not be increased by burning additional natural gas, requiring a reduction in boiler heat rate and consequently, specific heat duty. At lower lean loading (0.2, 0.18 mol/mol), this transition in heat duty was not observed due to the lower heat duty. As the ambient temperature increased, a similar trend in heat duty was observed at 0.22 lean loading, but the transition to lower heat duty occurred earlier at $\$4$/MMBtu. This was because of the lower CO 2 production at higher ambient temperature, making the process unprofitable at a gas price higher than $\$3$/MMBtu unless the heat duty of the stripper and natural gas boiler is steeply decreased.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved internal short circuit models for thermal runaway simulations in lithium-ion batteries

Thermal runaway (TR) modeling is one of the primary tools that can be used to overcome challenges associated with lithium-ion battery (LIB) safety. Among all LIB accidents that have occurred over the past decade, Internal Short Circuit (ISC) remains the most common trigger mechanism. Many available models in the literature either use a simplified approach to simulate ISC or completely ignore its contribution. The aim of this study is to understand the nature of the heat released for different types of ISC scenarios, including aluminum-anode, anode–cathode, and copper-cathode ISC. We study ISC behavior using a coupled electrochemical–thermal model with an integrated TR chemical kinetics solver built in the COMSOL Multiphysics framework. The time duration of heat release and the magnitude of the peak ISC current are studied as functions of parameters such as the size of the penetrating filament and the capacity of the cell. The numerical results are used to build an empirical model validated against the published experimental TR propagation data. Our model can be successfully used as a viable low-cost substitute in lower order (lumped) TR simulations to enable TR prevention and mitigation.

Singh, Bakhshish Preet (ORCID:0000000264751992)↗

Test results of a ten cell bipolar nickel-hydrogen battery

A ten cell bipolar nickel hydrogen 6.5 ampere-hour battery demonstrated over 2000 low Earth orbit cycles at an 80 percent depth-of-discharge. Charge/discharge cyclic ampere-hour and watt-hour efficiencies of 88 and 76 percent, respectively, observed. Peak power capability was determined at 1.1 kW. A 10C discharge rate yields 83 percent of the nominal stark capacity to the 1.0 volt cut off in just under 6 minutes.

Cataldo, R. L.↗

Test results of a ten cell bipolar nickel-hydrogen battery

A ten cell bipolar nickel hydrogen 6.5 ampere-hour battery demonstrated over 2000 low earth orbit cycles at an 80 percent depth-of-discharge. Charge/discharge cyclic ampere-hour and watt-hour efficiencies of 88 and 76 percent, respectively, observed. Peak power capability was determined at 1.1 kW. A 10C discharge rate yields 83 percent of the nominal stark capacity to the 1.0 volt cut off in just under 6 minutes. Previously announced in STAR as N83-26253

Cataldo, R. L.↗

Short-bearing approximation for full journal bearings

A short-bearing approximation of pressure distribution in the oil film is presented which is an extension of the pressure-distribution function of Michell and Cardullo and includes end-leakage effects. Equations giving applied load, attitude angle, location and magnitude of peak film pressure, friction, and required oil flow rate as functions of the eccentricity ratio are also given. The capacity number, a basic non dimensional quantity resulting from this analysis is the product of the Sommerfeld number and the square of the length-diameter ratio. Curves determined by this analysis are compared with previously published experimental data and theoretical curves of Sommerfeld and Cameron and Wood. Conclusions reached indicate that this approximation is of practical value for analysis of short bearings.

FRICTION AND LUBRICATION - HYDRODYNAMIC THEORY↗

Supine Treadmill Exercise in Lower Body Negative Pressure Combined with Resistive Exercise Counteracts Bone Loss, Reduced Aerobic Upright Exercise Capacity and Reduced Muscle Strength

Long-term exposure to weightlessness leads to cardiovascular and musculoskeletal deconditioning. In this report, the effectiveness of combined supine treadmill exercise in a lower body negative pressure chamber (LBNPex) and flywheel resistive exercise (Rex) countermeasures was determined to prevent bone loss, reduced aerobic upright exercise capacity and reduced muscle strength. We hypothesized that exercise subjects would show less decrease in bone mineral density (BMD), peak oxygen consumption (VO2pk) and knee extensor strength (KES) than control subjects. Sixteen healthy female subjects participated in a 60-d 6(sup 0) head-down tilt bed rest (BR) study after providing written informed consent. Subjects were assigned to one of two groups: a non-exercising control group CON or an exercise group EX performing LBNPex 2-4 d/wk and Rex every 3rd-d. VO2pk was measured with a maximal, graded, upright treadmill test performed pre-BR and on 3-d after BR. BMD was assessed before and 3-d after BR. Isokinetic KES was measured before and 5-d after BR. Two-way repeated measures ANOVA were performed. Statistical significance was set at p less than 0.05. CON experienced a significant decrease in BMD in the trochanter (PRE: 0.670 plus or minus 0.045; POST: 0.646 plus or minus 0.352 g (raised dot) per square centimeter) and in the whole hip (PRE=0.894 plus or minus 0.059; POST: 0.858 plus or minus 0.057 g (raised dot) per square centimeter). BMD also decreased significantly in EX in the trochanter (PRE: 0.753 plus or minus 0.0617; POST: 0.741 plus or minus 0.061 g (raised dot) per square centimeter) and whole hip (PRE: 0.954 plus or minus 0.067; POST: 0.935 plus or minus 0.069 g (raised dot) per square centimeter). BMD losses were significantly less in EX than in CON subjects. VO2pk was significantly decreased in the CON after BR (PRE: 38.0 plus or minus 4.8; POST: 29.9 plus or minus 4.2 ml (raised dot) per kilogram per minute), but not in the EX (PRE: 39.0 plus or minus 2.0; POST: 37.8 plus or minus 1.9 ml (raised dot) per kilogram per minute). KES was significantly reduced by 30% in Con (PRE: 113 plus or minus 12; POST: 78 plus or minus 8 N-m), but was not different in EX (PRE: 126 plus or minus 25; POST: 115 plus or minus 25 N-m). The combination LBNPex and Rex during 60-d BR protects against cardiovascular and musculoskeletal deconditioning and may be efficacious countermeasure for prolonged space flight.

Meuche, Sabine↗

Performance of Compressor of XJ-41-V Turbojet Engine VI - Analysis of Compressor Flow Choking: Analysis of Compressor Flow Choking - 6

An extended analysis was made of the previously reported performance investigation of the original compressor from the XJ-41-v turbojet engine and a similar compressor revised a to obtain a 33-percent increase in the geometric passage area at the vaned-collector entrance. This analysis was based on the concept of the vaned-collector entrance as the throat section of a nozzle. Because of nonuniform air distribution at the vaned-collector entrance, approximately 90 percent of the available flow area was utilized in the original compressor and 94percent in the revised com$ressor. The increase in maximum weight flow obtained with the revised compressor was disproportionate to the increased effective critical throat area because. the air density at the revised vaned-collector entrance for maximum flow was lower than that obtained in the original compressor. This reduction in density resulted from the large pressure losses near the impeller inlet of the revised compressor, which is indicative of impending flow choking in the impeller, The.calculated maximum corrected weight-flow capacity of a compressor consisting of the revised vaneless diffuser and vaned collector with a theoretical impeller that combined peak impeller pressure ratio and peak impeller efficiency at the . maximum flow point would be 112 pounds per second for an equivalent impeller speed of 11,500 rpm;

Creagh, John W. R.↗

Multi-site assessment of the potential of fine resolution red-edge vegetation indices for estimating gross primary production

Gross primary production (GPP) models driven by fine resolution remote sensing data characterize the spatial and temporal heterogeneities in plant photosynthesis, which is largely dependent on biome-specific maximum photosynthetic capacity. The red-edge reflectance, sensitive to leaf chlorophyll content, is a good proxy of maximum photosynthetic capacity. More importantly, studies show that the red-edge reflectance-related chlorophyll content index (CIr) multiplied by the incident photosynthetic active radiation (PAR in ) strongly correlates to GPP estimated at carbon flux towers (GPP flux ). Yet, to the best of our knowledge, there is no systematic study investigating the general relationship between fine spatial resolution CIr and GPP among biomes and the relationship between CIr and maximum photosynthetic capacity in GPP models. To provide an overview on incorporating space-borne CIr into a GPP model, we applied fine resolution Sentinel-2-derived CIr and GPP flux over 57 flux sites representative of 10 biomes. We investigated the relationship between CIr and GPP flux , and the spatio-temporal relationship between CIr and ecosystem maximum photosynthetic capacity indicated by the potential ecosystem light use efficiency (LUE pot ). We also evaluated the relationship between other five vegetation indices (VIs) and GPP flux . Results showed that the CIr multiplied by PARin has a higher agreement (R 2 > 0.5) with GPP than other VIs. A universal relationship exists between the CIr multiplied by PARin and GPP, except for forest biomes. The CIr also strongly (R 2 > 0.5) relates to the LUE pot during the peak of the growing season. The CIr has a low spatial variance (CV = 0.25) among biomes, highlighting that CIr can be a proxy of maximum photosynthetic capacity in GPP models that do not require biome-dependent coefficients. This study provides insight for incorporating CIr into GPP models and better quantifying global terrestrial photosynthesis.

59 BASIC BIOLOGICAL SCIENCES↗

Project Phase 1 Report: Reducing Data Center Peak Cooling Demand and Energy Costs With Cold Underground Thermal Energy Storage (Cold UTES)

Cold Underground Thermal Energy Storage (Cold UTES) is an ultra-long duration grid energy storage technology. With Cold-UTES, low-cost grid power is converted to cold thermal energy and stored in the native subsurface rock at the point of use. Cold UTES is one approach within the general category of engineered geothermal systems. Cold UTES for peak-hour cooling of data centers (DCs) was studied for deployment in Maricopa County, Arizona and Loudoun County, Virgina using thermal storage capacities from 4 GWh-th to over 1,000 GWh-th (>1 Terawatt-hour). The two sites have different power and transmission systems, available grid energy resources, daily and seasonal load profiles, weather conditions, and grid regulatory requirements. The study results indicate high value for both locations and because of this, likely indicates value across most of the US and the world. The basis of the study was a 1,000 MW-e hourly electric use of DC computing and auxiliary loads, which was modeled as 1 GW-th of thermal load to a dry cooled heat rejection system - i.e. a cooling system that does not consume water. The electric power required for cooling the DC varies as the air temperature changes. In cold weather only the dry-coolers are used, with an electrical load for cooling load as low as 10 MW-e. In hot summer hours, chillers and dry- coolers are required, which raises the electrical load for cooling load to as much as 300 MW-e. The continuous and peak cooling electrical loads result in a grid interconnection requirement of no less than 1,300 MW-e. From both a grid and thermal design modeling perspective the 1.3 GW-e could either be a single facility or result from the total load at multiple sites.

15 GEOTHERMAL ENERGY↗

Advanced Materials and Additive Manufacturing for Phase Change Thermal Energy Storage and Management: A Review

Abstract Phase change materials (PCMs) can enhance the performance of energy systems by time shifting or reducing peak thermal loads. The effectiveness of a PCM is defined by its energy and power density—the total available storage capacity (kWh m −3 ) and how fast it can be accessed (kW m −3 ). These are influenced by both material properties as well as geometry of the energy systems; however, prior efforts have primarily focused on improving material properties, namely, maximizing latent heat of fusion and increasing thermal conductivity. The latter is often at the expense of the former. Advanced manufacturing techniques hold tremendous potential to enable co‐optimization of material properties and device geometry, while potentially reducing material waste and manufacturing time. There is an emerging body of research focused on additive manufacturing of PCM composites and devices for thermal energy storage (TES) and thermal management. In this article, the fundamentals and applications of PCMs are reviewed and recent additive manufacturing advances in latent heat TES for both the PCM composite and associated heat exchanger are discussed. A forward‐looking perspective on the future and potential of PCM additive manufacturing for TES and thermal management is provided.

25 ENERGY STORAGE↗

MPC solution for optimal load shifting for buildings with ON/OFF staged packaged units: Experimental demonstration, and lessons learned

Small and medium-sized commercial buildings (SMCB) are significant demand response resources, and it is important to develop grid-responsive control algorithms that exploit those resources and create financial benefits for building owners and HVAC service providers. Furthermore, unlike large-sized commercial buildings, there is an opportunity to have universally applicable control solutions for many SMCBs since those buildings have a consistent HVAC system configuration: SMCBs are commonly served by multiple-staged air conditioning units controlled by their own thermostats. Despite the demand response potential and scalability, however, very few control solutions are available for SMCBs. Typical model predictive control (MPC) and heuristic control approaches for cooling load shifting that lower thermostat setpoints before an electric price jump are suitable mainly for large-sized commercial buildings where a continuous capacity modulation is possible, e.g., via dampers in variable air volume terminal units. However, those approaches can cause undesired, high peaks for SMCBs due to the nature of ON/OFF unit staging and narrow thermostat deadbands. This could discourage the use of advanced grid-responsive controls for SMCBs due to the concern of high demand charges, and has to be resolved. This paper presents a MPC solution that overcomes this challenge. It has a hierarchical MPC structure where an upper level MPC is responsible for electrical load shifting in response to an electric price signal while a lower level MPC is responsible for coordinating compressor stages to eliminate unnecessary peaks and follows the setpoints determined by the upper level MPC. In this work, two one-month, comprehensive laboratory tests have been carried out to demonstrate load shifting and cost savings for the algorithm. Interesting trade-offs between energy efficiency and load flexibility were observed and are discussed, and lessons learned for applying MPCs for SMCBs are also presented.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗