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At least 253 records · Page 14

Invertible Temper Modeling using Normalizing Flows and the Effects of Structure Preserving Loss

Advanced manufacturing research and development is typically small-scale, owing to costly experiments associated with these novel processes. Deep learning techniques could help accelerate this development cycle but frequently struggle in small-data regimes like the advanced manufacturing space. While prior work has applied deep learning to modeling visually plausible advanced manufacturing microstructures, little work has been done on data-driven modeling of how microstructures are affected by heat treatment, or assessing the degree to which synthetic microstructures are able to support existing workflows. We propose to address this gap by using invertible neural networks (normalizing flows) to model the effects of heat treatment, e.g., tempering. The model is developed using scanning electron microscope imagery from samples produced using shear-assisted processing and extrusion (ShAPE) manufacturing. This approach not only produces visually and topologically plausible samples, but also captures information related to a sample’s material properties or experimental process parameters. We also demonstrate that topological data analysis, used in prior work to characterize microstructures, can also be used to stabilize model training, preserve structure, and improve downstream results. We assess directions for future work and identify our approach as an important step towards end-to-end deep learning system for accelerating advanced manufacturing research and development.

Howland, Sylvia↗

Visualization of Two-phase Flow Maldistribution in Brazed Plate Heat Exchangers

Brazed plate heat exchangers (BPHEs) are widely used in refrigeration and HVAC applications, but are susceptible to two-phase flow maldistribution especially when operated as evaporators. Existing visualization approaches are either limited to idealized conditions or suffer from poor optical transparency. This paper presents a novel visualization method in which one edge of a BPHE, parallel to the refrigerant inlet or outlet port, is removed by wire electrical discharge machining and replaced with a flat, transparent plate. The planar geometry allows the use of optically and infrared (IR)-transparent materials, enabling both high-speed videography and IR thermography of the two-phase flow at the channel entrances and exits. Preliminary tests with R134a and R1234ze(Z) at saturation temperatures between 5 °C and 15 °C demonstrate that distinct two-phase flow patterns in the inlet header can be clearly identified and differentiated under realistic operating conditions. Potentials of optical flow analysis of high-speed videos are shown to provide objective, quantitative indicators for flow regime characterization and comparison. IR imaging of the outlet port reveals non-uniform temperature distributions at the channel exits, providing independent evidence of maldistribution across the channel stack. Limitations of IR temperature accuracy due to the spectral properties of the sapphire window are discussed, and directions for improvement are identified.

Hausherr, Carsten [Technical University of Berlin ↗

A hybrid machine-learning approach for analysis of methane hydrate formation dynamics in porous media with synchrotron CT imaging

Fast multi-phase processes in methane hydrate bearing samples pose a challenge for quantitative micro-computed tomography study and experiment steering due to complex tomographic data analysis involving time-consuming segmentation procedures. This is because of the sample's multi-scale structure, which changes over time, low contrast between solid and fluid materials, and the large amount of data acquired during dynamic processes. Here, a hybrid approach is proposed for the automatic segmentation of tomographic data from time-resolved imaging of methane gas-hydrate formation in sandy granular media, which includes a deep-learning 3D U-Net model. To prepare a training dataset for the 3D U-Net, a technique to automate data labeling based on sample-specific information about the mineral matrix immobility and occasional fluid movement in pores is proposed. Automatic segmentation allowed for studying properties of the hydrate growth in pores, as well as dynamic processes such as incremental flow and redistribution of pore brine. Results of the quantitative analysis showed that for typical gas-hydrate stability parameters (100 bar methane pressure, 7°C temperature) the rate of formation is slow (less than 1% per hour), after which the surface area of contact between brine and gas increases, resulting in faster formation (2.5% per hour). Hydrate growth reaches the saturation point after 11 h of the experiment. Finally, the efficacy of the proposed segmentation scheme in on-the-fly automatic data analysis and experiment steering with zooming to regions of interest is demonstrated.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Ultralow-temperature cryogenic transmission electron microscopy using a new helium flow cryostat stage

Advances in cryogenic electron microscopy have opened new avenues for probing quantum phenomena in correlated materials. This study reports the installation and performance of a new side-entry condenZero cryogenic cooling system for JEOL (Scanning) Transmission Electron Microscopes (S/TEM), utilizing compressed liquid helium (LHe) and designed for imaging and spectroscopy at ultra-low temperatures. The system includes an external dewar mounted on a vibration-damping stage and a pressurized, low-noise helium transfer line with a remotely controllable needle valve, ensuring stable and efficient LHe flow with minimal thermal and mechanical noise. Performance evaluation demonstrates a stable base temperature of 4.37 K measured using a Cernox bare chip sensor on the holder with temperature fluctuations within ±0.004 K. Complementary in-situ electron energy-loss spectroscopy (EELS) via aluminum bulk plasmon analysis was used to measure the local specimen temperature and validate cryogenic operation during experiments. The integration of cryogenic cooling with other microscopy techniques, including electron diffraction and Lorentz TEM, was demonstrated by resolving charge density wave (CDW) transitions in NbSe2 using electron diffraction, and imaging nanometric magnetic skyrmions in MnSi via Lorentz TEM. In conclusion, this platform provides reliable cryogenic operation below 7 K, establishing a low-drift route for direct visualization of electronic and magnetic phase transformations in quantum materials.

Charge density wave↗

Butanol-Based Organosolv Lignin and Reactive Modification of Poly(ethylene-glycidyl methacrylate)

Biomass processing industries and modern society are both interested in environmentally friendly plant-based polymers, such as lignin, to replace petrochemical derivatives. In this study, an n-butanol-based solvent system that can be produced through fermentation of cellulosic biomass, was used to fractionate hybrid poplar and isolate high purity lignin. The resulting unique glassy lignin fraction exhibited good melt-flow characteristics but poor mechanical behavior. Therefore, to produce a reusable and tough thermoplastic material, the lignin was reactively blended with glycidyl methacrylate modified polyethylene plastic using a high shear melt-mixing technique at 170 °C. Mechanical and rheological analyses revealed that the reactively processed blends with 30 wt % lignin have good compatibility between both polymers. Scanning electron microscopy, dynamic mechanical thermal analysis, and infrared spectroscopy data indicated improved interaction between lignin and the functional polyethylene matrix. The blends exhibited a thermal relaxation in the temperature range of 10 to 20 °C, because of the branched glycidyl methacrylate moiety. Finally, the optimal composition, consisting of 30% lignin, exhibited ~10 MPa tensile strength with 50% strain to failure; such a lignin-modified polymer may find use as packaging, as textile coatings, and in various horticultural applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Techno-Economic and life cycle assessment of standalone Single-Stream material recovery facilities in the United states

Material Recovery Facilities (MRFs) are crucial players in achieving a circular economy. MRFs receive complex waste streams and separate valuable recyclables from these mixtures. This study conducts techno-economic analysis (TEA) to estimate the net present value (NPV) and life cycle assessment (LCA) to estimate different environmental impacts of a commercial scale standalone, single-stream MRF to assess the economic feasibility and environmental impacts of recovering valuable recyclables from an MRF processing 120,000 tonnes per year (t/y). The TEA employs a discounted cash flow rate of return (DCFROR) analysis over a 20-year facility lifetime, along with a sensitivity analysis on the impact of different operating and economic parameters. Results show that the total fixed cost of building the MRF facility is $\$ $23 MM, and the operating cost is $\$ $45.48/tonne. Further the NPV of the MRF can vary from $\$ $3.57 MM to $\$ $60 MM, while 100-year global warming potential can range from 5.98 to 8.53 kg carbon dioxide equivalents (CO2-eq) per tonne of MSW. We have also found that MSW composition (arising from regional effects) significantly impacts costs, 100-year global warming potential, and other impact categories such as acidification potential, eutrophication potential, ecotoxicity, ozone depletion, photochemical oxidation, carcinogenic effects, and non-carcinogenic effects. Sensitivity and uncertainty analysis indicate that waste composition and market prices significantly impact the profitability of the MRF, and the waste composition mostly impacts global warming potential. Our analysis also indicates that facility capacity, fixed capital cost, and waste tipping fees are vital parameters that affect the economic viability of MRF operations.

36 MATERIALS SCIENCE↗

Selection of Vadose Zone Flow and Transport Properties with Gravel Fraction Corrections for the Hanford Site Composite Analysis and Cumulative Impact Evaluation

This environmental calculation file (ECF) is a compilation of hydrologic and radiological/chemical properties to be used for the updated Hanford Site Composite Analysis (CA) and Cumulative Impact Evaluation (CIE) vadose zone (VZ) modeling. The CA will provide an all-pathways dose projection to a hypothetical future member of the public from all planned low-level radioactive waste disposal facilities and potential contributions from all other projected end-state sources of radioactive material left at the Hanford Site following site closure. Its primary purpose is to support the decision-making process of the U.S. Department of Energy (DOE) under DOE O 435.1 Chg 1, Radioactive Waste Management, related to managing low-level waste disposal facilities at the Hanford Site. The CIE evaluates the effects of cleanup decisions regarding groundwater quality in the Hanford Site Central Plateau (DOE/RL-2018-69, Cumulative Impact Evaluation Technical Approach Document). Due to the complexity and large number of waste sites in source operable units (OUs), the computational tools used for the CIE must be capable of representing a range of site conditions and source terms in the VZ while also efficiently computing the impact that cleanup decisions have on the underlying aquifer. Waste-site proximity between and within source OUs has resulted in contaminants commingling in the vadose and saturated zones in complex ways. Plume commingling requires cleanup decisions to be evaluated considering the surrounding waste sites and existing groundwater contamination, therefore demonstrating the need to evaluate cumulative impacts from the VZ to groundwater.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hydropower Geotechnical Foundations: Current Practice and Innovation Opportunities for Low-Head Applications

Hydropower is a renewable energy resource that produces electricity from flowing water under pressure. Engineered hydropower structures, such as dams, are used to create a hydraulic head, enabling a turbinegenerator unit to convert pressurized flow into electricity. While hydropower has been a source of renewable energy since antiquity, new development in the United States has slowed in recent decades. Based on recent resource assessments, the largest opportunity to expand hydropower in the United States is from new stream-reach development (i.e., new hydropower development along stream-reaches that do not currently have hydroelectric facilities or other forms of infrastructure, such as dams). Roughly 75% of identified new stream-reach development potential is from low-head sites (less than 30 ft of head), which typically suffer from smaller power densities and higher normalized costs, given economies of scale. Hydropower developers and other stakeholders are thus interested in strategies to reduce initial capital costs while practicing sustainable development to maximize environmental compatibility with minimal disruption to natural aquatic life, sediment, and water flows. Historically, civil works have represented a significant cost driver for new hydropower development, with the foundation system representing a major cost component and source of uncertainty. The foundation system is the collection of engineered structural features (e.g. cutoff trenches, walls, grouting, anchors) constructed at or below the preconstruction ground surface that interfaces between the overlying structures (superstructures) and the bed material below (subsurface). Development of a hydropower foundation system must consider the various characteristics of the surrounding stream environment and subsurface while adhering to the engineering requirements of the superstructure that it supports. The care of water, excavation, and other construction activities are important features of foundation design and construction. The design and construction cost of the foundation system is largely dependent on the site geology and riverbed composition and is influenced by the level of geotechnical assessment required and conducted. Thus, a hydropower facility’s geotechnical foundation is often highly site-specific, with proper site selection and assessment being important to project success. The foundation system is designed to provide structural stability (of the foundation and dam), limit seepage, ensure public safety, and maintain functionality for the project life, during both construction and facility operations. Inadequate foundation or dam design can result in dam failure and the uncontrolled release of significant volumes of water, which could cause a high number of casualties and extensive property damage downstream of the failure. According to the Association of State Dam Safety Officials, approximately 30% of all historical dam failures in the United States are attributed to foundation or abutment defects, and another 20% are attributed to piping or seepage through the embankment, foundation, or abutment. To ameliorate these safety considerations, foundations often require massive amounts of construction material (e.g., grout, concrete, engineered dam fill) and long construction times. Foundation design also requires significant analysis prior to construction because the initial in-stream and abutment subsurface conditions are site-specific, and sufficient data for them often are lacking. Current practice requires on-site assessment, using expensive drilling and invasive and non-invasive investigation methods, to determine the expected cost of foundation material and treatment. Additionally, foundation construction often requires site dewatering (and other care of water activities), which involves constructing temporary diversion structures upstream and often downstream, called cofferdams, and water diversion systems that route water around the construction site. Cofferdams and water diversion systems can drastically increase construction costs and contribute to environmental disruption, including modification of flow patterns and benthic habitats. Given the technical, economic, and environmental challenges associated with hydropower foundations, opportunities exist to improve the current state of practice and to develop new and innovative solutions to Hydropower is a renewable energy resource that produces electricity from flowing water under pressure. Engineered hydropower structures, such as dams, are used to create a hydraulic head, enabling a turbinegenerator unit to convert pressurized flow into electricity. While hydropower has been a source of renewable energy since antiquity, new development in the United States has slowed in recent decades. Based on recent resource assessments, the largest opportunity to expand hydropower in the United States is from new stream-reach development (i.e., new hydropower development along stream-reaches that do not currently have hydroelectric facilities or other forms of infrastructure, such as dams). Roughly 75% of identified new stream-reach development potential is from low-head sites (less than 30 ft of head), which typically suffer from smaller power densities and higher normalized costs, given economies of scale. Hydropower developers and other stakeholders are thus interested in strategies to reduce initial capital costs while practicing sustainable development to maximize environmental compatibility with minimal disruption to natural aquatic life, sediment, and water flows. Historically, civil works have represented a significant cost driver for new hydropower development, with the foundation system representing a major cost component and source of uncertainty. The foundation system is the collection of engineered structural features (e.g. cutoff trenches, walls, grouting, anchors) constructed at or below the preconstruction ground surface that interfaces between the overlying structures (superstructures) and the bed material below (subsurface). Development of a hydropower foundation system must consider the various characteristics of the surrounding stream environment and subsurface while adhering to the engineering requirements of the superstructure that it supports. The care of water, excavation, and other construction activities are important features of foundation design and construction. The design and construction cost of the foundation system is largely dependent on the site geology and riverbed composition and is influenced by the level of geotechnical assessment required and conducted. Thus, a hydropower facility’s geotechnical foundation is often highly site-specific, with proper site selection and assessment being important to project success. The foundation system is designed to provide structural stability (of the foundation and dam), limit seepage, ensure public safety, and maintain functionality for the project life, during both construction and facility operations. Inadequate foundation or dam design can result in dam failure and the uncontrolled release of significant volumes of water, which could cause a high number of casualties and extensive property damage downstream of the failure. According to the Association of State Dam Safety Officials, approximately 30% of all historical dam failures in the United States are attributed to foundation or abutment defects, and another 20% are attributed to piping or seepage through the embankment, foundation, or abutment. To ameliorate these safety considerations, foundations often require massive amounts of construction material (e.g., grout, concrete, engineered dam fill) and long construction times. Foundation design also requires significant analysis prior to construction because the initial in-stream and abutment subsurface conditions are site-specific, and sufficient data for them often are lacking. Current practice requires on-site assessment, using expensive drilling and invasive and non-invasive investigation methods, to determine the expected cost of foundation material and treatment. Additionally, foundation construction often requires site dewatering (and other care of water activities), which involves constructing temporary diversion structures upstream and often downstream, called cofferdams, and water diversion systems that route water around the construction site. Cofferdams and water diversion systems can drastically increase construction costs and contribute to environmental disruption, including modification of flow patterns and benthic habitats. Given the technical, economic, and environmental challenges associated with hydropower foundations, opportunities exist to improve the current state of practice and to develop new and innovative solutions to challenges frequently encountered with traditional approaches. With this understanding, it is critically important to understand and document the current state of practice for hydropower geotechnical foundations, identify key challenges, and define opportunities for innovative solutions. To this end, this report documents the current state of practice across the three main phases of geotechnical foundation development: (1) geotechnical site assessment, (2) design, and (3) construction for hydropower systems. It also describes the major challenges with conventional approaches and identifies opportunities for innovation to reduce hydropower foundations costs, timelines, and risks. Key takeaways from this report include the following: Approximately 80% of available low-head sites are expected to have foundations on soil beds rather than rock beds, suggesting that rockfill and earthfill dams may be the most cost-effective conventional dam type for new projects.; Geotechnical and geologic investigation activities are time-consuming and expensive but are essential to define the parameters and criteria needed for foundation design.; Certain riverbed soil and bedrock types present significant technical challenges or require expensive foundation construction, which can prove financially prohibitive for low-head project development.; Modular hydropower design and prefabricated modular foundations represent a promising but unproven paradigm for new hydropower development. Design and construction approaches using optimized and highly repeatable, reliable components would benefit project cost, time, and risk but require additional research and development.; Temporary construction features for foundations, including cofferdams, water diversion, and water control systems, can prove costly and have inherent construction risk.; For economically viable development, hydropower geotechnical foundations should be limited to 4 to 15% of the project’s total initial capital costs. Many proposed projects have experienced cost overruns attributable to foundation difficulties or surprises during construction. These overruns may have been due to inadequate investigations, lack of adequate engineering effort to tailor the structures to site geology and topography, and/or contractual terms, among other considerations.; Challenges for hydropower foundations and opportunities for innovative technology solutions are identified in the following areas (consistent with the three main phases of foundation development): Geotechnical site assessment, Foundation design and materials, Construction methods and technology. Ultimately, this report aims to provide information about geotechnical foundations for low-head hydropower and to motivate transformative technologies to support hydropower growth.

13 HYDRO ENERGY↗

Strongly Anisotropic Thermomechanical Response to Shock Wave Loading in Oriented Samples of the Triclinic Molecular Crystal 1,3,5-Triamino-2,4,6-trinitrobenzene

All-atom molecular dynamics (MD) simulations were used to study shock wave loading in oriented single crystals of the highly anisotropic triclinic molecular crystal 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). The crystal structure consists of planar hydrogen-bonded sheets of individually planar TATB molecules that stack into graphitic-like layers. Shocks were studied for seven systematically prepared crystal orientations with limiting cases that correspond to shock propagation exactly perpendicular and exactly parallel to the graphitic-like layers. The simulations were performed for initially defect-free crystals using a reverse-ballistic configuration that generates explicit, supported shocks. Final longitudinal stress components are between ≈8.5 and ≈10.5 GPa for the 1.0 km s –1 impact speed studied. Orientation-dependent properties are reported including shock speeds, stresses, temperatures, compression ratios, and local material strain rates. Spatiotemporal maps of the temperature, stress tensor, material flow, and molecular orientations reveal complicated processes that arise for specific shock directions. Furthermore, the results indicate that TATB shock response is highly sensitive to crystal orientation, with significant qualitative differences for the time evolution of the stress tensor and temperature, elastic/inelastic compression response, defect formation and growth, critical von Mises stress, and strain rates during shock rise that span nearly an order of magnitude. A variety of inelastic deformation mechanisms are identified, ranging from crumpling of graphitic-like layers to dislocation-mediated plasticity to intense shear strain localization. To our knowledge, these are the first systematic MD simulations and analysis of explicit shock wave propagation along nontrivial crystal directions in a triclinic molecular crystal.

36 MATERIALS SCIENCE↗

Aerodynamic Analysis of Wind Loading on Parabolic Trough Collectors Using High-Fidelity CFD Modeling

Wind loading on parabolic solar collector support structures is the key driver for material costs. As identified by NREL's CSP Best Practices project [1], ability to predict wind-loading in deep-arrays and the impact of edge effects has potential to decrease levelized cost of electricity (LCoE) by 15%. In this study, we present a high-fidelity computational model that can model the flow around deep arrays of parabolic troughs under varying turbulent inflow conditions. Ability to accurately reproduce atmospheric boundary layer (ABL) profiles is first demonstrated through Large Eddy Simulation (LES) simulations and compared against wind tunnel measurements. Thereafter, unsteady turbulent flow past single row and six row configurations is computed using hybrid RANS/LES simulations. Investigations of wind loading, through parametric tilt angle variations of single row and on waked collectors in six-row configuration, are used to highlight design considerations for parabolic troughs only possible through high-fidelity unsteady calculations.

aerodynamics↗

Analysis of the NorthStar Inconel 718 Window

NorthStar Medical Radioisotopes, LLC, is planning to produce the important medical radioisotope molybdenum-99 (Mo-99) through photonuclear reactions in molybdenum-100 (Mo-100). In this approach, a target comprising multiple thin disks of enriched molybdenum metal will be bombarded with a 40-MeV electron beam. Because enriched Mo-100 is expensive, there is a desire to utilize as much beam power as possible to achieve maximum production yield and minimize the size of the target. This requirement leads to very high beam power density (heat deposition in the target), which sets challenging requirements for cooling of the target. In the latest concept developed by NorthStar, a stack of target (sintered molybdenum) disks is irradiated from two sides by a 40-MeV electron beam, with a total power of 240 kW (120 kW from each side). As shown in Figure 1, the target disks are cooled by pressurized helium gas flowing through channels between the disks. A housing encloses the target disks and helium coolant. Thinned regions on opposite sides of the housing act as windows, forming the pressure boundary between the helium within the housing and the evacuated beam tube. A pulsed (50-Hz) 40-MeV electron beam is used, with 120 kW total power and a 10% duty cycle. The pulsing beam creates a corresponding cyclic thermal load within the window material. To examine the effects of the cyclic thermal load on the window, a combination of analyses was performed, including computational fluid dynamics (CFD) and finite element analysis (FEA). The analyses presented in this report were primarily performed using the finite element method. However, because of the curved surface of the window, CFD analysis was used to calculate the convective cooling boundary included in the FEA model. Transient thermal and structural models were used to explore the window geometry, including thickness, radius of curvature, and diameter, while staying within the temperature and stress limits of the material as well as maintaining mechanical stability (i.e., avoiding buckling). Additionally, variations in the size and location of the electron beam were evaluated. Multiple parameters for the window and the electron beam were examined throughout the analysis. Upper and lower bounds were established for the window geometry parameters, and limitations were established for the size and position of the electron beam.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Nuclear Safety [Vol. 36, No. 1, January-June 1995]

Nuclear Safety is a journal that covers significant issues in the field of nuclear safety. Its primary scope is safety in the design, construction, operation, and decommissioning of nuclear power reactors worldwide and the research and analysis activities that promote this goal, but it also encompasses the safety aspects of the entire nuclear fuel cycle, including fuel fabrication, spent-fuel processing and handling, and nuclear waste disposal, the handling of fissionable materials and radioisotopes, and the environmental effects of all these activities. Table of Contents for this issue follows. THE CHORNOBYL ACCIDENT: 1 The Chornobyl Accident Revisited, Part II: The State of the Nuclear Fuel Located Within the Chornobyl Sarcophagus, A A. Borovoi and A. R. Sich; GENERAL SAFETY CONSIDERATIONS: 33 Nuclear Power Safety in Central and Eastern Europe, R. Wilson; 46 Safety of Nuclear Power Reactors in the Former Eastern European Countries, S. Chakraborty; 53 Technical Note: On the Definition of Common-Cause Failures, H. Paula; ACCIDENT ANALYSIS: 58 Modeling and Analysis of Core-Debris Recriticality During Hypothetical Severe Accidents in the Advanced Neutron Source Reactor, S.-H. Kim, V. Georgevich, D. B. Simpson, C. O. Slater, and R. P. Taleyarkhan; 68 Ignitability of Hydrogen/Oxygen/Diluent Mixtures in the Presence of Hot Surfaces, R. K. Kumar and G. W. Koroll; 94 Coupled RELAP5 and CONTAIN Accident Analysis Using PVM, K. A. Smith, A. J. Baratta, and G. E. Robinson; CONTROL AND INSTRUMENTATION: 109 Application of Fuzzy Logic in Nuclear Reactor Control Part I: An Assessment of State-of-the-Art, A. S. Heger, N. K. Alang-Rashid, and M. Jamshidi; DESIGN FEATURES: 122 Twenty-Third DOE/NRC Nuclear Air-Cleaning and Treatment Conference, R. R. Bellamy, J. J. Hayes, and M. W. First; ENVIRONMENTAL EFFECTS: 135 Atmospheric Dispersion and the Radiological Consequences of Normal Airborne Effluents from a Nuclear Power Plant, D. Fang, C. Z. Sun, and L. Yang; 142 Calculation of Distribution Coefficients for Radionuclides in Soils and Sediments, I. Puigdomenech and U. Bergstrom: OPERATING EXPERIENCES: 155 Reactor Shutdown Experience, Compiled by J. W. Cletcher; U.S. NUCLEAR REGULATORY COMMISSION INFORMATION AND ANALYSES: 158 Operating Experience Feedback Report—Reliability of Safety-Related Steam Turbine-Driven Standby Pumps Used in U.S. Commercial Nuclear Power Plants, J. R. Boardman; 166 Turbine Building Hazards, H. L Ornstein; RECENT DEVELOPMENTS: 169 Reports, Standards, and Safety Guides, D. S. Queener; 175 Proposed Rule Changes as of Dec. 31,1994; ANNOUNCEMENTS: 32 Harvard School of Public Health In-Place Filter Testing Workshop; 134 International Conference on Advances in the Operational Safety of Nuclear Power Plants; 193 30th Tennessee Industries Week; 193 DOE Technical Standards Program 1995 Workshop; 194 Multiphase Flow Experiments and Instrumentation; 180 The Authors; 185 Indexes to Nuclear Safety, Volumes 34 and 35.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Ambient Temperature Sodium Polysulfide Catholyte for Nonaqueous Redox Flow Batteries

This study reports a sodium polysulfide catholyte for nonaqueous redox flow batteries (RFBs). We demonstrate reversible capacities up to 200 mAh/gS with negligible fade over 250 cycles at room temperature for sodium polysulfide|biphenyl full cells containing Na + ß '' -Al 2 O 3 solid electrolyte (BASE) membranes. Interestingly, formation of insoluble S and Na 2 S 4 phases did not inhibit the catholyte's cycle life which is likely due to the low concentrations used in the lab-scale prototypes. 3-electrode galvanostatic AC impedance measurements demonstrate that voltage losses were dominated by charge transfer at the cathode, and relevant kinetic parameters (i.e., transfer coefficients and exchange current density) were calculated through a Tafel analysis. To the best of our knowledge, this is the first report applying such an impedance approach to nonaqueous RFBs. Overall, the use of low-cost active materials makes sodium polysulfide|biphenyl RFBs promising for long duration energy storage applications. Furthermore, if strategies are developed to increase the solubility of S and/or low order polysulfides (Na 2 S x , x ≤ 4), specific energies up to 100 Wh kg -1 (including combined mass of the anolyte and catholyte) can be achieved.

25 ENERGY STORAGE↗

Scaling CFB risers: Maintaining microstructure dynamics

Over the years there have been numerous approaches to develop a scaleup methodology for circulating fluidized beds. Many of these past approaches have relied on macroscopic definitions of similitude to define dimensionless groups such as Reynolds number, Froude number, density ratios, and dimensional ratios involving different length scales. These approaches have demonstrated various levels of success, but often fail when used outside the bounds of experimental datasets. The issue with these methods is that they rely on macroscopic similitude with the hopes that those conditions would provide microscopic similitude as it does in single phase systems where the Buckingham Pi techniques have given reasonable success. Two of the main reasons for failure are 1) changing fluidization regimes and 2) changing material properties that result in the material falling into a different Geldart group. Both are certain to change the microstructure (local instantaneous volume solids fraction) and changes to the microstructure affect the interphase transport properties of the reactor system, namely the mass transfer and heat transfer. Here, this work presents a new approach towards scaling based upon maintaining similitude at the microscale. It reviews a novel dimensionless flow regime map developed from analysis of the deterministic chaos parameters and higher order moments to ensure microstructure similitude. The work then examines four cases from the literature to assess the scaling approach used: (1) same particle-different scale risers for Geldart Group B particles, (2) Glicksman scaling of atmospheric circulating fluidized bed combustor, (3) same particle-different scale risers for Geldart Group A particles and (4) Glicksman scaling for pressurized gasification. General findings are that none of the scaling approaches produced directly applicable microstructure similar behavior based upon the chaotic and higher moment analysis. The positive take away is that the approach can define scale conditions that will provide similar microstructure that can be us to predict transport behavior.

42 ENGINEERING↗

Insights into the interaction of nitrobenzene and the Ag(111) surface: A DFT study

Here, this study explores the potential of nitrobenzene as an anolyte material for nonaqueous redox flow batteries (RFBs) by theoretically examining its low-coverage adsorption behavior on neutral and charged Ag(111) model electrode surfaces. At the low coverage limit, DFT calculations show a preference for nitrobenzene to adsorb parallel to the surface, with the benzene ring and nitro group centered over HCP sites. Interactions between nitrobenzene and the surface were analyzed using induced charge density analysis, Bader charge analysis, and projected density of states (PDOS). It was found that nitrobenzene adsorbs primarily through van der Waals interactions with the surface. As nitrobenzene accumulates negative charge, the strength of adsorption diminishes. Understanding the electrode-electrolyte interface is crucial for enhancing RFB electrochemical performance, and this study sheds light on nitrobenzene's interaction with a model Ag electrode.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NMDQi Thermal-hydraulic Optimization, Analysis, and Scoping Tool (TOAST)

The Thermal-hydraulic Optimization, Analysis, and Scoping Tool (TOAST) is developed to support the thermal-hydraulic aspects for the design of optimal irradiation vehicles for the Nuclear Materials Discovery and Qualification initiative (NMDQi). TOAST is currently a MATLAB-based tool that utilizes a simplified steady-state analytical model where a radial thermal resistance circuit is utilized to account for conduction through up to 2 capsules, a gas gap, a thermal bond, a sample cladding, and a sample, as well as the convection from a water coolant outside the capsules. The geometry is discretized axially along the user-defined height of a basket with a user-defined number of points/nodes, essentially turning TOAST into a semi-2D heat transfer analysis utility for cylindrical irradiation vehicles with practically any configuration, solving for temperatures radially at multiple axial locations. TOAST utilizes a Graphical User Interface (GUI) in-which a user can define the geometrical layout, the materials utilized for each component, the coolant characteristics, and the required solution. The user can define the geometry by inputting the diameters, thicknesses, and heights for each component, whereas the materials are defined via the user-provided constant or variable thermal conductivities. The user can select the coolant's inlet temperature, pressure, and the pressure drop across the height of the problem (which is used to calculate the velocity of the flow). Finally, the user can choose to solve for a sample heat generation rate limit by inputting temperature limits for the sample and capsules or can choose to purely solve for the axial temperature distributions of each component by inputting a pre-selected heat generation rate. Either way, TOAST provides the user with axial temperature distributions of all the components including the coolant, and the heat generation rate limit as well as the maximum outlet coolant temperature. The user can also choose to do one of 6 sensitivity analyses in TOAST. The sensitivity analyses yield plots of the sensitivity of the heat generation rate limit, the maximum coolant temperature, and the pressure limit for the annular components due to perturbations in 1-2 unknown variables based on the selected sensitivity analysis. Benchmarks between computations in TOAST and equivalent 2D axis symmetric ABAQUS models are presented, showing that TOAST results are within less than 3% of ABAQUS results in most cases, and a maximum of 8% difference in some cases. The benchmarks also revealed that this uncertainty is tied to the selection of an appropriate Nusselt number correlation and appropriate thermal conductivities, which the user can do from the GUI. Regardless, TOAST is demonstrated as a computationally efficient, highly accessible, and accurate utility for optimization and scoping s of studies different irradiation vehicles.

42 ENGINEERING↗

In‐Process Melt Separation of PE/PET Blends for Upcycling via Twin‐Screw Extrusion. Impact of Catalyst Reagents on PET Depolymerization

Part 1 of this work focused on depolymerizing polyethylene terephthalate (PET) in twin-screw extrusion, as part of a broader project to continuously separate PET from polyolefins in the melt. This study focused on linear low-density polyethylene (LLDPE) and PET films and the use of ethylene glycol (EG), diethylene glycol (DEG), triethylene glycol (TEG), and bis(2-hydroxyethyl) terephthalate (BHET) to depolymerize the PET in the extruder to levels above 90% Mw. In part 2, the focus will shift to achieving separation of the two polymers in the twin-screw extruder, which is made possible due to a 90% reduction in the Mw of the PET, which caused a decrease of its viscosity by several orders of magnitude. Owing to the viscosity difference and pressure buildup in the die, the low-viscosity PET preferentially exited a degassing vent instead of going through the die. This is because the flow of the PET would travel through a non-pressure vent rather than through a high-pressure die. However, owing to the higher viscosity of the LLDPE, the pressure was too high to pass through such a small diameter vent hole. Supercritical CO₂ (SCCO₂) was used to assist in this extraction, but SCCO₂ negatively impacted the overall degree of separation. Through analysis of the separated materials, it was concluded that a very high separation of the two materials was achieved. TGA and FTIR confirmed that the material separated from the vent was 100% PET. The material removed from the die was composed of 90% LLDPE and 10% PET.

36 MATERIALS SCIENCE↗

Localized mix-induced radiative cooling in a capsule implosion at the National Ignition Facility

In this work, w present direct measurements of electron temperature variations within an inertially confined deuterium-tritium plasma caused by localized mix of higher-Z materials into the central hot spot. The data are derived from newly developed differentially filtered penumbral imaging of the bremsstrahlung continuum emission. Our analysis reveals distinct localized emitting features in the stagnated hot-spot plasma, and we infer spatial variations in the electron temperature: the mixed region is 660±130eV colder than the surrounding hot-spot plasma at 3.26±0.11keV. Our analysis of the energy flow shows that we measure approximately steady-state conditions where the radiative losses in the mix region are balanced by heat conduction from the surrounding hot deuterium-tritium plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗