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At least 253 records · Page 14

Improving Quantitative Laboratory Analysis of Phycobiliproteins to Provide High Quality Validation Data for Ocean Color Remote Sensing Algorithm

Identification and characterization of phytoplankton communities and their physiology is a primary aim of NASA's PACE satellite mission. The concentration and composition of phytoplankton pigments modulate the spectral distribution of light emanating from the ocean, which is measured by ocean color satellites, and thus provide critical information on phytoplankton community composition and physiological parameters. One diagnostic class of pigments not routinely well-characterized is the phycobiliproteins (PBPs), and NASA has a requirement to collect and distribute high quality in situ data in support of data product validation activities for ocean color missions. Phycobiliproteins are light-harvesting proteins that are the predominant photosynthetic pigments in some classes of phytoplankton including cyanobacteria, such as Synechococcus, Trichodesmium, and Microcystis. With the advance of hyperspectral ocean color sensors such as on PACE (expected to launch in late 2022), it is essential that we implement routine analysis of PBPs that satisfies several considerations: reproducible, high extraction efficiency for a variety of environments, and Suitable for large scale analysis. Published techniques for PBP analysis vary in recommendations for: collection, extraction, disruption mode, and analysis; evidence suggests the variation in results may depend at least in part on the species and even strain(s) of interest. Experiments that tested variations in these parameters have drawn very different conclusions regarding extraction efficiency and reproducibility. Cyanobacteria are more difficult to extract than other PBP-containing algae such as cryptophytes, but can be important primary producers. We used a cryptophyte (Rhodomonas salina) and cyanobacterium (Synechococcus sp.) to compare extraction efficiencies of water samples concentrated via centrifugation to filtered samples using two different extraction buffers (phosphate and asolectin-CHAPS). Samples were analyzed on a fluorometer configured for PC and PE detection. The results have important implications for collection and storage of samples for routine analysis; some previous studies (although not all) have suggested that filtered samples have a much lower extraction efficiency than whole water samples.

Kenemer, Christopher↗

Ground-based studies of emission-line variability: Recent results for NGC 5548 and future plans

Ever since emission-line variability was first detected in AGNs, it has been clearly understood that light-travel time effects in the broadline region (BLR) afford a tool for studying the structure of these spatially unresolved regions. However, only within the last few years has the observational problem become well defined in terms of the sampling rates and quality of data necessary to address the problem correctly. The amount of data required to extract structural information about the BLR from the continuum and emission-line light curves is so considerable that the most promising approach seemed to be to combine the observational efforts. The goal was to work together to produce a large, high-quality database which would then be released to individual investigators for more complete analysis. The cornerstone of this effort, was a joint NASA/ESA/SERC program to monitor the spectrum of NGC 5548 every four days with IUE from December 1988 through August 1988. A concurrent ground-based program was organized in an effort to enhance the scientific return on the project by extending the wavelength coverage and providing higher spectral resolution and signal to noise ratios than would be possible with IUE. It also turned out that the temporal resolution of the ground-based program was somewhat better than the temporal resolution of the IUE program, and the temporal baseline is longer and continues to grow. The database and initial results are presented by Peterson et al., (1991). The important results of the ground-based program are summarized, some additional applications of the existing data are described, and a few comments are made on what can be done in the future to expand on this work.

Peterson, Bradley M.↗

Recent Development Work with Self-Aligned Focusing Schlieren

A novel compact focusing schlieren instrument has recently been developed that eliminates the need for a separate source and cutoff grid. The technique works by projecting an image of a grid onto a retroreflective surface and then reimaging the projection back onto the original grid. By manipulating the polarization state of the light passing through the instrument, a single Rochon polarizing prism can be used to adjust the schlieren sensitivity by translating it along the instrument’s optical axis, which changes the in-plane offset between the reimaged projection and the original grid. This arrangement makes the instrument inherently self-aligned. Relative to conventional focusing schlieren instruments, which require alignment of a separate source grid and cutoff grid to achieve sensitivity, the setup time required in order to obtain high quality focusing schlieren images is significantly reduced. Further, the self-aligned nature of this instrument makes it insensitive to vibrations and allows for on-the-fly adjustments to field-of-view. In this paper we discuss recent work that has been performed to expand the capabilities of this self-aligned focusing schlieren instrument including: schlieren visualization at extreme angles for optically-restricted test facilities, 3D schlieren visualization using a light field camera, acquisition of high quality focusing schlieren images from facilities with low quality windows, and obtaining focusing schlieren images in full-scale ground test facilities.

Brett Bathel↗

Data recording and processing for speckle image reconstruction

Image reconstruction from astronomical speckle data using the Knox-Thompson algorithm has now been extensively demonstrated as feasible through analysis and computer simulations. Experimental verification of the technique and its implementation for astronomy places stringent constraints on the recording system and requires complex processing algorithms to handle the many experimental details. In this paper we describe a video recording system specifically designed for the requirements of speckle imaging. This system has been built and tested, yielding high quality image reconstructions from a laboratory-atmospheric simulator for a wide range of input light levels and test objects.

Nisenson, P.↗

JPL tests of a LaJet concentrator facet

A LaJet Energy Company (LEC) concentrator facet, 60 in. in diameter, was tested for imaging quality. The following two methods were used: (1) autofocus tests with a point source of light at the facet's radius of curvature; and (2) tests with the Sun close to the horizon as a distant source. The tests of the LaJet facet indicate that all of the solar image reflected by an LEC 460 solar concentrator made of like facets should fall within a 9-in. aperture if the outer facets are carefully adjusted. Such a concentrator would have acceptable performance, but complete evaluation must be made with an assembled concentrator.

Dennison, E. W.↗

Silicon solar cell process development, fabrication and analysis

Measurements of minority carrier diffusion lengths were made on the small mesa diodes from HEM Si and SILSO Si. The results were consistent with previous Voc and Isc measurements. Only the medium grain SILSO had a distinct advantage for the non grain boundary diodes. Substantial variations were observed for the HEM ingot 4141C. Also a quantitatively scaled light spot scan was being developed for localized diffusion length measurements in polycrystalline silicon solar cells. A change to a more monochromatic input for the light spot scan results in greater sensitivity and in principle, quantitative measurement of local material qualities is now possible.

Leung, D. C.↗

Radiation issues for piloted Mars mission

Current radiation risk for a piloted Mars mission is estimated using the idea of absorbed dose and ICRP-26, LET-dependent quality factors. In a spacecraft with aluminum walls (2 g/sq cm) at solar minimum the calculated dose equivalent is 0.73 Sv for a 406-day mission. Based on the current thinking this leads to an excess cancer mortality in a 35-year male of about 1 percent. About 75 percent of the dose equivalent is contributed by HZE particles and target fragments with average quality factors of 10.3 and 20, respectively. The entire concept of absorbed dose, quality factor, and dose equivalent as applied to such missions needs to be reexamined, in light of the fact that less than 50 percent of the nuclei in the body of the astronaut would have been traversed by a single GCR nuclei in the 406-day mission.

Badhwar, Gautam D.↗

The Efficiency of Small Bearings in Instruments of the Type Used in Aircraft

This report deals with the construction and properties of bearings and pivots for use in instruments. The static and running friction for both thrust and radial loads was determined for a number of conical pivots and cylindrical and ball bearings. The static rocking friction was also measured for several conical and ball bearings under a heavy load, especially to determine their suitability for use in N. P. L. (National Physical Laboratory) type wind tunnel balance. In constructing conical pivots and sockets it was found that the pivots should be hardened and highly polished, preferably with a revolving lap, and that the sockets should be made by punching with a hardened and polished punch. It was found that for a light load the conical pivots give less friction than any other type, and their wearing qualities when hardened are excellent. Very small ball bearings are unsatisfactory because the proportional accuracy of the balls and races is not high enough to insure smooth running. For rocking pivots under heavy loads it was found that a ball-and-socket bearing, consisting of a hemispherical socket and a sphere of smaller diameter concentric with it, with a row of small balls resting between the two, was superior to a pivot resting in a socket. It was found that vibration such as occurs in an airplane will greatly reduce the static friction of a pivot or bearing, in some cases to as little as one-twentieth of its static value.

Norton, F H↗

Miniaturization in x ray and gamma ray spectroscopy

The paper presents advances in two new sensor technologies and a miniaturized associated electronics technology which, when combined, can allow for very significant miniaturization and for the reduction of weight and power consumption in x-ray and gamma-ray spectroscopy systems: (1) Mercuric iodide (HgI2) x-ray technology, which allows for the first time the construction of truly portable, high-energy resolution, non-cryogenic x-ray fluorescence (XRF) elemental analyzer systems, with parameters approaching those of laboratory quality cryogenic instruments; (2) the silicon avalanche photodiode (APD), which is a solid-state light sensitive device with internal amplification, capable of uniquely replacing the vacuum photomultiplier tube in scintillation gamma-ray spectrometer applications, and offering substantial improvements in size, ruggedness, low power operation and energy resolution; and (3) miniaturized (hybridized) low noise, low power amplification and processing electronics, which take full advantage of the favorable properties of these new sensors and allow for the design and fabrication of advanced, highly miniaturized x-ray and gamma-ray spectroscopy systems. The paper also presents experimental results and examples of spectrometric systems currently under construction. The directions for future developments are discussed.

Iwanczyk, Jan S.↗

Gravitational Effects on the Morphology and Kinetics of Photodeposition of Polydiacetylene Thin Films From Monomer Solutions

The goal of this proposed work is to study gravitational effects on the photodeposition of polydiacetylene thin films from monomer solutions onto transparent substrates. Polydiacetylenes have been an extensively studied class of organic polymers because they exhibit many unusual and interesting properties, including electrical conductivity and optical nonlinearity. Their long polymeric chains render polydiacetylenes readily conducive to thin film formation, which is necessary for many applications. These applications require thin polydiacetylene films possessing uniform thicknesses, high purity, minimal inhomogeneities and defects (such as scattering centers), etc. Also, understanding and controlling the microstructure and morphology of the films is important for optimizing their electronic and optical properties. The lack of techniques for processing polydiacetylenes into such films has been the primary limitation to their commercial use. We have recently discovered a novel method for the formation of polydiacetylene thin films using photo-deposition from monomer solutions onto transparent substrates with UV light. This technique is very simple to carry out, and can yield films with superior quality to those produced by conventional methods. Furthermore, these films exhibit good third-order properties and are capable of waveguiding. We have been actively studying the chemistry of diacetylene polymerization in solution and the photo-deposition of polydiacetylene thin films from solution. It is well-known that gravitational factors such as buoyancy-driven convection and sedimentation can affect chemical and mass transport processes in solution. One important aspect of polydiacetylene thin film photodeposition in solution, relevant to microgravity science, is that heat generated by absorption of UV radiation induces thermal density gradients that under the influence of gravity, can cause fluid flows (buoyancy-driven convection). Additionally, changes in the chemical composition of the solution during polymerization may cause solutal convection. These fluid flows affect transport of material to and from the film surface and thereby affect the kinetics of the growth process. This manifests itself in the morphology of the resulting films; films grown under the influence of convection tend to have less uniform thicknesses, and can possess greater inhomogeneities and defects. Specifically, polydiacetylene films photodeposited from solution, when viewed under a microscope, exhibit very small particles of solid polymer which get transported by convection from the bulk solution to the surface of the growing film and become embedded. Even when carried out under conditions designed to minimize unstable density gradients (i.e., irradiating the solution from the top), some fluid flow still takes place (particles remain present in the films). It is also possible that defect nucleation may be occurring within the films or on the surface of the substrate; this, too, can be affected by convection (as is the case with crystal growth). Hence films grown in 1-g will, at best, still possess some defects. The objective of this proposal is to investigate, both in 1-g and in low-g, the effects of gravitational factors (primarily convection) on the dynamics of these processes, and on the quality, morphology, and properties of the films obtained.

Paley, Mark S.↗

Improving the Visible and Infrared Contrast Ratio of Microshutter Arrays

Three device improvements have been developed that dramatically enhance the contrast ratio of microshutters. The goal of a microshutter is to allow as much light through as possible when the shutters are in the open configuration, and preventing any light from passing through when they are in the closed position. The ratio of the transmitted light that is blocked is defined here as the contrast ratio. Three major components contribute to the improved performance of these microshutters: 1. The precise implementation of light shields, which protect the gap around the shutters so no light can leak through. It has been ascertained that without the light shield there would be a gap on the order of 1 percent of the shutter area, limiting the contrast to a maximum of 100. 2. The precise coating of the interior wall of each microshutter was improved with an insulator and metal using an angle deposition technique. The coating prevents any infrared light that finds an entrance on the surface of the microshutter cell from being emitted from a sidewall. Since silicon is in effect transparent to any light with a wavelength longer than .1 micrometer, these coatings are essential to blocking any stray signals when the shutters are closed. 3. A thin film of molybdenum nitride (MoN) was integrated onto the surface of the microshutter blade. This film provides the majority of light blockage over the microshutter and also ensures that the shutter can be operated over a wide temperature range by maintaining its flatness. These improvements were motivated by the requirements dictated by the James Webb Space Telescope NIRSpec instrument. The science goals of the NIRSpec require observing some of the very faintest objects in a given field of view that also may contain some very bright objects. To observe the faint objects, the light from the bright objects - which could be thousands of times brighter - must be completely blocked. If a closed microshutter is even slightly transmissive, a very bright object will still transmit a small signal, which can be larger than a signal from a very faint object transmitted through an open shutter. Since this situation can completely corrupt the results, it was necessary that the closed shutters be able to attenuate light by at least a factor of 2,000. There currently exist four flight-quality microshutter arrays that have been fully or are currently undergoing testing and the results support that the three improvements described above have successfully led to contrast levels greater than 50,000 in over 99 percent of the microshutters at an operating temperature of 35 K. Applications for these high-contrast microshutters are in the photomask generation and stepper equipment used to make integrated circuits and microelectromechanical (MEMS) devices. Since microshutters are a reconfigurable optical element, their versatility in these industries provides an improvement over printed masks and fixed projection alignment systems.

Jhabvala, Murzy↗

Cryogenic Flow Sensor

An acousto-optic cryogenic flow sensor (CFS) determines mass flow of cryogens for spacecraft propellant management. The CFS operates unobtrusively in a high-pressure, high-flowrate cryogenic environment to provide measurements for fluid quality as well as mass flow rate. Experimental hardware uses an optical plane-of-light (POL) to detect the onset of two-phase flow, and the presence of particles in the flow of water. Acousto-optic devices are used in laser equipment for electronic control of the intensity and position of the laser beam. Acousto-optic interaction occurs in all optical media when an acoustic wave and a laser beam are present. When an acoustic wave is launched into the optical medium, it generates a refractive index wave that behaves like a sinusoidal grating. An incident laser beam passing through this grating will diffract the laser beam into several orders. Its angular position is linearly proportional to the acoustic frequency, so that the higher the frequency, the larger the diffracted angle. If the acoustic wave is traveling in a moving fluid, the fluid velocity will affect the frequency of the traveling wave, relative to a stationary sensor. This frequency shift changes the angle of diffraction, hence, fluid velocity can be determined from the diffraction angle. The CFS acoustic Bragg grating data test indicates that it is capable of accurately determining flow from 0 to 10 meters per second. The same sensor can be used in flow velocities exceeding 100 m/s. The POL module has successfully determined the onset of two-phase flow, and can distinguish vapor bubbles from debris.

Justak, John↗

Solutions Network Formulation Report. NASA's Potential Contributions for Using Solar Ultraviolet Radiation in Conjunction with Photocatalysis for Urban Air Pollution Mitigation and Increasing Air Quality

This Candidate Solution is based on using NASA Earth science research on atmospheric ozone and aerosols data as a means to predict and evaluate the effectiveness of photocatalytically created surfaces (building materials like glass, tile and cement) for air pollution mitigation purposes. When these surfaces are exposed to near UV light, organic molecules, like air pollutants and smog precursors, will degrade into environmentally friendly compounds. U.S. EPA (Environmental Protection Agency) is responsible for forecasting daily air quality by using the Air Quality Index (AQI) that is provided by AIRNow. EPA is partnered with AIRNow and is responsible for calculating the AQI for five major air pollutants that are regulated by the Clean Air Act. In this Solution, UV irradiance data acquired from the satellite mission Aura and the OMI Surface UV algorithm will be used to help understand both the efficacy and efficiency of the photocatalytic decomposition process these surfaces facilitate, and their ability to reduce air pollutants. Prediction models that estimate photocatalytic function do not exist. NASA UV irradiance data will enable this capability, so that air quality agencies that are run by state and local officials can develop and implement programs that utilize photocatalysis for urban air pollution control and, enable them to make effective decisions about air pollution protection programs.

Underwood, Lauren↗

Development of TEMPO Products and Tools to Support Air Quality Management Decisions

The TEMPO mission has been observing air pollutants every hour during the daytime across its Field of Regard (FoR) covering greater North America since First Light on August 2, 2023. The highly anticipated public release of TEMPO data occurred on May 20, 2024, consisting of level 2 and level 3 trace gas data products of nitrogen dioxide, formaldehyde, and ozone. Our project at the NASA SPoRT Center is developing value-added products and tools to support the TEMPO mission and Early Adopters program with special attention on the air quality management community. The initial focus of this project is evaluating the TEMPO products over stakeholder target areas using Pandora and surface monitor observations. Methods for oversampling TEMPO data to 1 km resolution are being applied over the target areas to resolve fine-scale emission sources and pollutant gradients. Machine learning techniques using TEMPO, surface monitor, and model data to estimate surface-level nitrogen dioxide concentrations are being developed over the target areas. Our SPoRT viewer has been updated to include visualizations of the TEMPO products and an ArcGIS dashboard is being designed for enabling air quality management stakeholders to efficiently analyze TEMPO data. Training materials including user guides are being developed to ensure the effective and sustained use of TEMPO data in air quality management applications. The major outcome of this project is to support the inclusion of TEMPO data in exceptional event demonstrations by active engagement with stakeholders and ultimately enable more informed air quality management decisions in the future. This talk will provide an update on our project activities and showcase use cases of TEMPO data for monitoring different emission sources including wildland fire smoke.

air quality↗

A simulation investigation of scout/attack helicopter directional control requirements for hover and low-speed tasks

A piloted simulator experiment was conducted to investigate directional axis handling qualities requirements for low speed and hover tasks performed by a Scout/Attack helicopter. Included were the directional characteristics of various candidate light helicopter family configurations. Also, the experiment focused on conventional single main/tail rotor configurations of the OH-58 series aircraft, where the first-order yaw-axis dynamic effects that contributed to the loss of tail rotor control were modeled. Five pilots flew 22 configurations under various wind conditions. Cooper-Harper handling quality ratings were used as the primary measure of merit of each configuration. The results of the experiment indicate that rotorcraft configurations with high directional gust sensitivity require greater minimum yaw damping to maintain satisfactory handling qualities during nap-of-the-Earth flying tasks. It was also determined that both yaw damping and control response are critical handling qualities parameters in performing the air-to-air target acquisition and tracking task. Finally, the lack of substantial yaw damping and larger values of gust sensitivity increased the possibility of loss of directional control at low airspeeds for the single main/tail rotor configurations.

Bivens, Courtland C.↗

Effects of Nighttime Light Radiance on the Sleep of the General Population

The objectives of this study is to verify if the exposure to greater nighttime radiance is associated with changes in the sleep/wake schedule and with greater sleep disturbances. Methods: The target population was the adults (18 years and older) living in California, USA. This represents 24 million of inhabitants. A total of 3,104 subjects participated in the survey (participation rate 85.6%). The participants were interviewed by telephone using the Sleep-EVAL system. The interviews covered several topics including sleeping habits, sleep quality, sleep disturbances, physical symptoms related to menopause. Chronic insomnia was defined as difficulty initiating or maintaining sleep for at least 3 months. Global nighttime light emissions have been collected by the Defense Meteorological Satellite Program's Operational Linescan System (DMSP/OLS) sensors. We extracted the radiance calibrated nighttime lights corresponding to the date of the interviews for a three by three window centered on each coordinate corresponding to an interview address. Results: Dissatisfaction with sleep quantity and/or quality was associated with an increased nighttime radiance (p=0.02). Similarly, excessive sleepiness accompanied with impaired functioning was significantly associated with an increased nighttime radiance (p (is) less than 0.0001). The association remained significant after controlling for age, gender and use of a night lamp in the bedroom. Confusional arousals were also significantly associated with an increased nighttime radiance (p (is) less than 0.0001). Bedtime hour was linearly increasing with the intensity of nighttime radiance: the later the bedtime, the greater the nighttime radiance (p (is) less than 0.0001). Similarly, wakeup time became progressively later as the nighttime radiance increased (p (is) less than 0.0001). Both associations remained significant after controlling for age, gender and use of a night lamp in the bedroom. Circadian Rhythm Disorders were the only sleep disorder significantly associated with increased nighttime radiance (p (is) less than 0.0001). Exposure to increased nighttime light radiance appeared to cause a shift in the sleep/wake schedule, excessive sleepiness and Circadian Rhythm Disorders.

Excessive Sleepiness↗

Space Product Development of Commercial NLO Materials

Growth on selected substrates under various processing conditions have been useful for preparing highly oriented and otherwise promising films of organic compounds for optical thin films and waveguides. The significance of processing conditions to uniformity in thickness, degree of orientation, film quality, and optical properties for a specific processing technique is the general focus of work in this area. A study on the effect of processing conditions relevant to thin-film deposition by various techniques is particularly difficult because of the possibility that convection may play a major role in some cases. It is a goal of some researchers to produce good quality anisotropic films, therefore, an important, yet understudied, requirement should be to assess the role of gravity during certain processing methods. This may be particularly true for the vapor deposition of diacetylenes where subsequent polymerization in the crystal is topochemical and occurs readily only when neighboring monomer molecules are sufficiently close and suitably oriented. Likewise, this requirement is equally viable for the vapor deposition of certain materials such as Pcs in view of the results of microgravity experiments by 3M Corporation involving the preparation of thin films of copper Pc (CuPc). Microgravity-grown CuPc had several desirable features which indicate that the vapor growth of organic films in low-g may result in better quality films for optical and electrical applications. Indeed, other materials vapor deposited onto specific substrates in microgravity produce films potentially beneficial for electro-optic applications. A novel technique, recently discovered, for growing polydiacetylene thin films involves exposing a transparent substrate, in contact with diacetylene monomer solution, to ultraviolet (LTV) light. A polymer film deposits on the side of the substrate in contact with monomer in solution, and there are distinct gravitational effects, which influence film quality. Good quality thin films elude growth from solutions absent of uniform flow fields and homogeneous temperature distributions near the substrate surfaces. The flow fields and temperature distributions during the polymerization process by exposure to UV light details the nature of gravitational influences on this process.

Frazier, Donald O.↗

Optimized Umkehr Profile Algorithm for Ozone Trend Analyses

The long-term record of Umkehr measurements from four NOAA Dobson spectrophotometers was reprocessed after updates to the instrument calibration procedures. In addition, a new data quality-control tool was developed for the Dobson automation software (WinDobson). This paper presents a comparison of Dobson Umkehr ozone profiles from NOAA ozone network stations (Boulder, OHP, MLO, Lauder) against several satellite records, including Aura Microwave Limb Sounder (MLS; ver. 4.2), and combined SBUV and OMPS records (NASA AGG and NOAA COH). A subset of satellite data is selected to match Dobson Umkehr observations at each station spatially (distance less than 200 km) and temporally (within 24 hours). Umkehr Averaging Kernels (AKs) are applied to vertically smooth all overpass satellite profiles prior to comparisons. The station Umkehr record consists of several instrumental records, which have different optical characterizations, and thus instrument-specific stray light contributes to the data processing errors and creates step changes in the record. This work evaluates the overall quality of Umkehr long-term measurements at NOAA ground-based stations and assesses the impact of the instrumental changes on the stability of the Umkehr ozone profile record. This paper describes a method designed to correct biases and discontinuities in the retrieved Umkehr profile that originate from the Dobson calibration process, repair, or optical realignment of the instrument. The M2GMI and GMI CTM ozone profile model output matched to station location and date of observation is used to evaluate instrumental step changes in the Umkehr record. Homogenization of the Umkehr record and discussion of the apparent stray light error in retrieved ozone profiles are the focus of this paper. Homogenization of ground-based records is of great importance for studies of long-term ozone trends and climate change.

Umkehr↗