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At least 253 records · Page 14

Indistinguishable telecom band photons from a single Er ion in the solid state

Atomic defects in the solid state are a key component of quantum repeater networks for long-distance quantum communication1. Recently, there has been significant interest in rare earth ions, in particular Er 3+ for its telecom band optical transition that allows long-distance transmission in optical fibres. However, the development of repeater nodes based on rare earth ions has been hampered by optical spectral diffusion, precluding indistinguishable single-photon generation. Here, we implant Er 3+ into CaWO 4 , a material that combines a non-polar site symmetry, low decoherence from nuclear spins and is free of background rare earth ions, to realize significantly reduced optical spectral diffusion. For shallow implanted ions coupled to nanophotonic cavities with large Purcell factor, we observe single-scan optical linewidths of 150 kHz and long-term spectral diffusion of 63 kHz, both close to the Purcell-enhanced radiative linewidth of 21 kHz. This enables the observation of Hong–Ou–Mandel interference between successively emitted photons with a visibility of V = 80(4)%, measured after a 36 km delay line. We also observe spin relaxation times T 1,s = 3.7 s and T 2,s > 200 μs, with the latter limited by paramagnetic impurities in the crystal instead of nuclear spins. Furthermore, this represents a notable step towards the construction of telecom band quantum repeater networks with single Er 3+ ions.

42 ENGINEERING↗

Li-ion and Na-ion intercalation in layered MnO 2 cathodes enabled by using bismuth as a cation pillar

Low-cost batteries based on Earth-abundant materials are needed for large-scale electrical storage for the grid. Cathodes based almost entirely on Mn oxides would reduce overall battery cost but cycling of Mn oxides is often not stable. In Li-ion cells, most polymorphs of MnO 2 undergo irreversible transformation to spinel LiMn 2 O 4 during cycling, causing capacity loss. Doping MnO 2 with Bi is known to stabilize the structure, but previous reports have relied on low-crystallinity material making it impossible to pinpoint the Bi location in the structure or its mechanism. In this work, we report a series of hydrated Bi-doped layered MnO 2 compounds and characterize their structures as a function of Bi amount. Bi is shown to reside in the material interlayer, provoking higher long-range structural order even at a low doping level of 1.3%. Doped material improves the specific capacity and stability of cycling in both Li-ion and Na-ion cells. A high level of Bi doping, 4.3%, causes loss of the interlayer crystal water in non-aqueous electrolyte, and this reduces the interlayer distance. Crystal water is shown to be beneficial in a Na-ion system, while its loss improves Li-ion cycling. This provides fundamental insight into how pillaring by a heavy, multivalent cation stabilizes layered oxides.

25 ENERGY STORAGE↗

Developing low-cost rechargeable batteries: beyond traditional layered oxide cathodes for Li-ion and beyond Li-ion batteries

Here, the rising demand for energy storage systems, driven by the rapid adoption of electric vehicles and the global shift toward renewable energy, necessitates continuous efforts to lower the cost of current lithium-ion batteries (LIBs) and enhance the sustainability of existing battery chemistries. This feature article examines the key challenges associated with Ni- and Co-containing LIB cathodes and compares advancements in cathode development for non-traditional Li-ion and beyond Li-ion chemistries. First, a review of earth-abundant element containing disordered rock-salt cathodes is presented, with a discussion of key strategies such as compositional tuning and carbon coating to improve their electrochemical performance. Hurdles in developing oxide-based cathodes for Na- and K-ion batteries are also highlighted, followed by an in-depth overview of polyanion and Prussian blue cathodes for Na- and K-ion systems. Overall, this article provides a systematic perspective on the design of earth-abundant, low-cost, and sustainable cathode materials for both LIB and beyond LIB technologies.

Lohani, Harshita [Lawrence Berkeley National Labor↗

Novel internal measurements of ion cyclotron frequency range fast-ion driven modes

Abstract Novel internal measurements and analysis of ion cyclotron frequency range fast-ion driven modes in DIII-D are presented. Observations, including internal density fluctuation ( n ~ ) measurements obtained via Doppler backscattering, are presented for modes at low harmonics of the ion cyclotron frequency localized in the edge. The measurements indicate that these waves, identified as coherent ion cyclotron emission (ICE), have high wave number, k ⊥ ρ fast ≳ 1, consistent with the cyclotron harmonic wave branch of the magnetoacoustic cyclotron instability, or electrostatic instability mechanisms. Measurements show extended spatial structure (at least ∼1/6 the minor radius). These edge ICE modes undergo amplitude modulation correlated with edge localized modes (ELM) that is qualitatively consistent with expectations for ELM-induced fast-ion transport.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Multiscale Chirping Modes Driven by Thermal Ions in a Plasma with Reactor-Relevant Ion Temperature

A thermal ion driven bursting instability with rapid frequency chirping, considered as an Alfv´enic ion temperature gradient mode, has been observed in plasmas having reactor-relevant temperature in the DIII-D tokamak. The modes are excited over a wide spatial range from macroscopic device size to micro-turbulence size and the perturbation energy propagates across multiple spatial scales. The radial mode structure is able to expand from local to global in ~ 0.1 ms and it causes magnetic topology changes in the plasma edge, which can lead to a minor disruption event. Since the mode is typically observed in the high ion temperature ≳ 10 keV and high-! plasma regime, the manifestation of the mode in future reactors should be studied with development of mitigation strategies, if needed. In conclusion, this is the first observation of destabilization of the Alfv´en continuum caused by the compressibility of ions with reactor-relevant ion temperature.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ion heating via turbulent ion acoustic waves.

The ion acoustic turbulence in the turbulent-heating experiment reported is excited by the ion-ion beam instability. Graphs are presented, showing the spatial evolution of the parallel ion beam energy and the spatial evolution of the ion acoustic turbulent wave spectrum. The observed characteristics of test waves in a turbulent beam-plasma imply that wave saturation is a dynamic balance between the emission of waves by the beam and the destruction or damping of wave coherence by the turbulent diffusion of particle orbits.

Taylor, R. J.↗

Reactions of ions in excited electronic states - Excited N2/+/ ion reacting with N2 to yield N3/+/ and N

Study of the mechanism of formation of the N3(+) ion from the bimolecular reaction of excited N2(+) ions in gaseous N2. Using ion cyclotron resonance spectroscopy, an attempt is made to inquire more deeply than hitherto into the origin of the N3(+) ions and to determine the rate constant for their formation and the limits on the lifetime of the reactant excited N2(+) ions.

Bowers, M. T.↗

Experimental observation of the ion-ion beam instability in a cylindrical geometry

The ion-ion beam instability is investigated in a cylindrical geometry. In the presence of a cylindrically symmetric ion beam a coherent ion-ion beam instability is observed for a well-defined range of beam velocity. This instability gives rise to cylindrical standing waves whose frequency depends upon beam velocity. The beam distribution function is measured to be a ring in velocity space. The dispersion relation appropriate for the cylindrical standing waves is solved numerically and is shown to be in good agreement with the experimentally observed instability.

Romesser, T.↗

A doubly charged ion model for ion thrusters

A theoretical equilibrium model of doubly charged ion production and loss processes in electron bombardment ion thrusters is presented. The model is shown to predict double ion density levels accurately for 15 and 30 cm diameter thrusters operating with several different grid sets and at several different power levels. The model indicates the dominant mechanism of double ion production involves the singly charged ground state. This result is used to develop a much simpler model which, along with correlations of the average plasma properties, can be used to determine the double ion density in thrusters with acceptable accuracy.

Peters, R. R.↗

Application of ion thruster technology to a 30-cm multipole sputtering ion source

A 30-cm electron-bombardment ion source has been designed and fabricated for micromachining and sputtering applications. This source has a multipole magnetic field that employs permanent magnets between permeable pole pieces. An average ion current density of 1 ma/sq cm with 500-eV argon ions was selected as a design operating condition. The ion beam at this operating condition was uniform and well collimated, with an average variation of + or -5 percent over the center 20 cm of the beam at a distance up to 30 cm from the ion source.

Robinson, R. S.↗

Photoionization and ion cyclotron resonance studies of the ion chemistry of ethylene oxide

The formation of the ethylene oxide molecular ion and its subsequent ion-molecule reactions leading to the products C2H5O(+) and C3H5O(+) have been studied using time-resolved photoionization mass spectroscopy, ion cyclotron resonance spectroscopy, and photoelectron spectroscopy. An examination of the effects of internal energy on reactivity shows that the ratio of C3H5O(+) to C2H5O(+) increases by an order of magnitude with a single quantum of vibrational energy. The formation of (C2H4O/+/)-asterisk in a collision-induced isomerization is found which yields a ring-opened structure by C-C bond cleavage. The relaxed ring-opened C2H4O(+) ion reacts with neutral ethylene oxide by CH2(+) transfer to yield an intermediate product ion C3H6O(+) which gives C3H5O(+) by loss of H.

Corderman, R. R.↗

Ion beam plume and efflux measurements of an 8-cm mercury ion thruster

Measurements of the ion beam plume and efflux constituents of an 8-cm mercury ion thruster have been carried out in the TRW 5 x 10 foot testing chamber. Charged components (ion beam plume) were measured with an array of movable position Faraday cups and retarding potential analyzers yielding both current density and particle energy determinations. Neutral components (ion beam efflux) were determined with a movable position ionization gauge. Measurements of the ion beam plume were performed for a thruster both with and without a sputter shield. Analysis of data in terms of normalized effluxes has been carried out and has been applied to an example calculation of efflux compatibility with a communications spacecraft.

Komatsu, G. K.↗

Magnetospherically trapped ions as a source of magnetosheath energetic ions

It has been suggested that energetic ions observed in the magnetosheath may be due to the direct leakage of trapped magnetospheric ions. To test this hypothesis, three-dimensional ion spectra from the energetic particle experiment on ISEE 1 for a magnetopause crossing on Nov. 10, 1977 are utilized to construct three-dimensional distribution functions in the magnetosphere and in the sheath. Using the observed magnetic field, a simple one-dimensional model of the magnetopause is developed. Ions are then followed in the model, starting in the magnetosphere, through the magnetopause and ending up in the sheath. Using Liouville's Theorem a model sheath distribution function is then built up by following the magnetospheric distribution function through the model fields. The model distribution is then compared with the observed sheath distribution. For this case it is found that the main features of the observed ions in the sheath are consistent with direct leakage and with no energization or de-energization processes, and an inward-pointing normal component is required. The energetic particles mapped in this case apparently follow a flux tube which does not penetrate the magnetopause where local tangential electric fields have been reported.

Speiser, T. W.↗

Improved ion containment using a ring-cusp ion thruster

A 30-centimeter diameter ring-cusp ion thruster is described which operates at inert gas ion beam currents up to about 7 ampere, with significant improvements in discharge chamber performance over conventional divergent-field thrusters. The thruster has strong boundary ring-cusp magnetic fields, a diverging field on the cathode region, and a nearly field-free volume upstream of the ion extraction system. Minimum ion beam production costs of 90 to 100 watts per beam ampere (W/A) were obtained for argon, krypton and xenon. Propellant efficiencies in excess of 0.90 were achieved at 100 to 120 W/A for the three inert gases. The ion beam charge-state was documented with a collimating mass spectrometer probe to allow evaluation of overall thruster efficiencies.

Sovey, J. S.↗

Ion-neutral coupling in the high-latitude F region Evaluation of ion heating terms from Dynamics Explorer 2

Ion and neutral motions in the high latitude F layer were studied simultaneously during six passes of the Dynamics Explorer 2 spacecraft. The passes were made over the south polar cap in October 1981. An ion energy balance equation was defined to express the exchange of energy between the F layer and other atmospheric constituents. A momentum equation expressed the momentum exchange between the species. An approximate form of the energy balance equation was also formulated. The time constant for ion-neutral collisional momentum transfer significantly affected Joule heating in the F layer. Regions of large velocity disparities and ion temperature enhancements were detected as hot spots. The results indicate that a feedback mechanism may arise in terms of neutral compositional changes and enhanced ionospheric recombination. The approximate equation furnished values for ion heating rates which matched the data.

Killeen, T. L.↗

Fast ion mass spectrometry and charged particle spectrography investigations of transverse ion acceleration and beam-plasma interactions

Ion acceleration transverse to the magnetic field in the topside ionosphere was investigated. Transverse acceleration is believed to be responsible for the upward-moving conical ion distributions commonly observed along auroral field lines at altitudes from several hundred to several thousand kilometers. Of primary concern in this investigation is the extent of these conic events in space and time. Theoretical predictions indicate very rapid initial heating rates, depending on the ion species. These same theories predict that the events will occur within a narrow vertical region of only a few hundred kilometers. Thus an instrument with very high spatial and temporal resolution was required; further, since different heating rates were predicted for different ions, it was necessary to obtain composition as well as velocity space distributions. The fast ion mass spectrometer (FIMS) was designed to meet these criteria. This instrument and its operation is discussed.

Gibson, W. C.↗

The acceleration of ions and electrons by electromagnetic ion cyclotron waves

Test particle calculations of the interaction of electrons and ions with electromagnetic ion cyclotron waves are examined. It is observed that field-aligned electrons can be accelerated parallel to the magnetic fields by the cyclotron waves and that the ions can be accelerated perpendicular to the magnetic field. The data reveal that the ions can be accelerated more effectively when the wave frequency is half (.5) the ion gyrofrequency.

Temerin, M.↗