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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

High Efficiency Inverted GaAs and GaInP/GaAs Solar Cells With Strain-Balanced GaInAs/GaAsP Quantum Wells

High-efficiency solar cells are essential for high-density terrestrial applications, as well as space and potentially vehicle applications. The optimum bandgap for the terrestrial spectrum lies beyond the absorption range of a traditional dual junction GaInP/GaAs cell, with the bottom GaAs cell having higher bandgap energy than necessary. Lower energy bandgaps can be achieved with multiple quantum wells (QWs), but such a pathway requires advanced management of the epitaxial growth conditions in order to be useful. Strain-balanced GaAsP/GaInAs QWs are incorporated into a single junction GaAs solar cell and a dual junction GaInP/GaAs solar cell, leading to 27.2% efficiency in the single junction device and a one-sun record 32.9% efficiency in the tandem device. Good carrier collection and low non-radiative recombination are observed in the cells with up to 80 QWs. The GaAs cells employ a rear-heterojunction architecture to boost the open-circuit voltage to over 1.04 V in the quantum well device, despite the large number of QWs.

14 SOLAR ENERGY↗

Carbon-Nanotube-Bridging Strategy for Integrating Single Fe Atoms and NiCo Nanoparticles in a Bifunctional Oxygen Electrocatalyst toward High-Efficiency and Long-Life Rechargeable Zinc–Air Batteries

The development of highly efficient and robust bifunctional electrocatalysts for oxygen reduction (ORR) and evolution reactions (OER) is the key issue for realizing high-performance and long-life rechargeable zinc–air batteries (ZABs). However, it is still a great challenge to integrate independent ORR and OER sites in a catalyst with high activity. Here, a carbon nanotube-bridging strategy is proposed to synthesize such a bifunctional oxygen electrocatalyst enriched with highly active single-atom Fe sites for the ORR and high-performance nanosized NiCo hydroxides for the OER. Consequently, the developed catalyst shows a small overpotential difference of 0.686 V. When used as an oxygen electrode catalyst, the corresponding ZAB exhibits a large power density of 219.5 mW cm ₋2 , a small charge–discharge voltage gap of 0.72 V at 10 mA cm ₋2 , and outstanding discharge–charge durability without attenuation after more than 700 cycles. This work proposes a new idea to realize multifunctional catalysts and drives the practical application of ZABs.

25 ENERGY STORAGE↗

Effect of High-Speed Rotation on High-Temperature Superconducting Coils for High Efficiency Megawatt Motor

The use of a superconducting rotor in the High Efficiency Megawatt Motor (HEMM) comes with a number of challenges. The HEMM’s rotor must be designed so that the superconducting coil can tolerate the forces it will encounter during operation. These forces introduce considerable risk to the design of the HEMM. Because this risk cannot be adequately addressed through refined analysis, a set of experiments was deemed necessary to demonstrate that the HEMM’s superconducting coils can survive the stresses imparted by the centrifugal forces acting on the coil during full-speed operation of the machine. These experiments required spin testing a full-scale HEMM coil on a representative rotor structure at room temperature and sequentially higher rotation speeds and measuring the superconductivity response of the coil in liquid nitrogen (LN2) before and after each spin test. Tests were carried out to the full centripetal loading of a recent HEMM design. According to finite element analysis, this load produced stress components in the coil that exceed their design limit by a factor of 1 to 7.4. Although not yet confirmed, the current HEMM design is expected to produce even smaller stresses in the coil due to a 20 percent reduction in the coil’s mass and an increased volume of structural material. The only degradation of the coil that occurred during this testing resulted from a test rig failure and from the voltage taps, which are not part of the final coil design.

Electrified Aircraft Propulsion↗

Development of an Improved High Efficiency Thin Silicon Solar Cell

Breakage and front contact failure in high efficiency, textured ultrathin cells was reduced as a consequence of the introduction of process modifications. In a small production run, over one hundred ultrathin cells, having an average AMO efficiency of 13%, were fabricated from 10-25 ohm cm silicon. An in-house aluminum paste for back surface field formation was developed that resulted in cell efficiencies equivalent to those from commercial pastes. The quality of the back surface field was found to be dependent on the orientation of the silicon slice during alloying.

Storti, G.↗

High efficiency low cost solar cell power

A concept for generating high-efficiency, low-cost, solar-cell power is outlined with reference to solar cell parameters, optical concentrators, and thermal control procedures. A design for a 12.5-kw power module for space operation is discussed noting the optical system, spectrum splitter, light conversion system, cell cooling, power conditioner, and tracking mechanism. It is found that for an unconcentrated array, efficiency approaches 60% when ten or more bandgaps are used. For a 12-band system, a computer program distributed bandgaps for maximum efficiency and equal cell currents. Rigid materials and thin films have been proposed for optical components and prisms, gratings, and dichroic mirrors have been recommended for spectrum splitting. Various radiator concepts are noted including that of Weatherston and Smith (1960) and Hedgepeth and Knapp (1978). The concept may be suitable for the Solar Power Satellite.

Bekey, I.↗

High-efficiency silicon solar cell research

Progress reports on research in high-efficiency silicon solar cells were presented by eight contractors and JPL. The presentations covered the issues of Bulk and Surface Loss, Modeling, Measurements, and Proof of Concept.

Daud, T.↗

Design, Fabrication, and Critical Current Testing of No-Insulation Superconducting Rotor Coils for NASA's 1.4 MW High-Efficiency Megawatt Motor

NASA Glenn Research Center is developing a 1.4 MW high-efficiency electric machine for future electrified aircraft to reduce energy consumption, emissions, and noise. This wound-field, synchronous machine employs a self-cooled, superconducting rotor to achieve excellent specific power and efficiency. This paper discusses the design and fabrication of the no-insulation high temperature superconducting (HTS) rotor coils and compares them to conventionally insulated HTS coils. Two sub-scale test coils with epoxy on only one axial face were fabricated. Critical current testing of the coils at 77 K and self field was conducted to study the influence of thermal cycling on their critical current and n-value. After two or four aggressive thermal cycles between 77 K and about 278 K (5 degree C), the critical current and n-value were nearly unchanged, indicating very little to no degradation.

electric aircraft propulsion↗

Highly Efficient Surface Charge Transfer in Fe 2 TiO 5 Epitaxial Thin Film Photoanodes

Pseudobrookite (Fe 2 TiO 5 ) has attracted significant attention as an emerging photoanode for water oxidation due to reports of enhanced performance in polycrystalline heterostructures with α-Fe 2 O 3 or TiO 2 . However, the specific properties and contribution of Fe 2 TiO 5 remain unknown. Here, we present the first photoelectrochemical characterization of epitaxial thin film Fe 2 TiO 5 , an ideal platform for probing the inherent response of this earth-abundant photoanode for solar water splitting. Moreover, by using an electrolyte containing a hole scavenger, we find highly efficient charge transfer at the Fe 2 TiO 5 –electrolyte interface. This notable surface property is exploited in the form of an Fe 2 TiO 5 /α-Fe 2 O 3 heterostructure photoanode, for which we observe a photocurrent density increase by 1 order of magnitude and an onset potential improvement by ~300 mV. Establishing these fundamental properties elucidates the nature of reaction mechanisms on Fe 2 TiO 5 and informs the design of highly efficient water photo-oxidation devices by incorporating this material with other photoanodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ceramic High Efficiency Particulate Air (HEPA) Filter Research and Development at Lawrence Livermore National Laboratory

Ceramic high efficiency particulate air (HEPA) filter development program began at Lawrence Livermore National Laboratory (LLNL) over 20 years ago. Historical incidents motivated current safety systems at nuclear facilities. A ceramic filter that can survive a fire can provide robust, passive safety protection. Research has been conducted to improve the safety of nuclear facilities and to reduce operational and lifecycle costs, through ceramic filter technology that can survive fire conditions. Here, the research focused on applications in both new facilities as well as meeting operational requirements necessary to retrofit filters into existing DOE facilities. The research has developed multiple filter technologies spanning traditional HEPA filter materials to advanced manufacturing technologies (e.g., electrospinning, additive manufacturing, etc.). This communication will present highlights of selected development efforts for ceramic HEPA filter research, current state-of-the-art for ceramic filters, and future needs including technical, regulatory, and commercial efforts.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Hierarchical electrode design of highly efficient and stable unitized regenerative fuel cells (URFCs) for long-term energy storage

The unitized regenerative fuel cell (URFC) is a promising electrochemical device for intermittent renewable energy storage in chemical bonds. However, widespread application has been hindered due to low round-trip efficiencies (RTEs) and disappointing durability, in particular at high rates. In this study, we break through that barrier by demonstrating highly efficient, flexible, and stable URFCs via hierarchical design of the multiscale catalyst-layer structures. A more porous and less tortuous Pt and Ir catalyst layer is realized using a doctor blade fabrication method that significantly improves URFC performance. We demonstrate RTEs of 56% and 53% under constant-electrode and constant-gas mode, respectively, while operating at 1000 mA cm –2 , and significantly, a RTE of 45% at 2000 mA cm –2 , achievements that were previously viewed as unfeasible under the onerous demands of URFC operation. At the same time we demonstrate URFCs under both constant-electrode and constant-gas mode operated continuously for over 500 h with negligible degradation. These results demonstrate the viability of applying URFCs for long-term energy storage at previously unattainable efficiencies and cast new light on electrode design and optimization of URFCs.

25 ENERGY STORAGE↗

Additive-Mixing Fuel Injection (AMFI): A device for robust control and improved performance of high-efficiency LTGC engines

Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies with very low NOx and particulate emissions. Despite these major advantages, methods for controlling LTGC combustion timing, achieving robust autoignition, and good low-load performance have challenged the development of practical LTGC engines. A key reason is that the ideal reactivity of the fuel varies with operating conditions, with low-reactivity fuels working well at high loads and higher-reactivity fuels working better at low loads. This article introduces a new technique called Additive Mixing Fuel Injection (AMFI) that adjusts the reactivity of the gasoline to obtain good performance over the operating map. Moreover, AMFI can provide robust combustion-timing control because it precisely meters very small amounts (0.01–0.6 mm 3 ) of an ignition-enhancing additive into the fuel each engine cycle. The additive used was 2-ethylhexyl nitrate (EHN), a common, inexpensive diesel-fuel ignition improver, but other additives could be used. Because additive amounts are so small, a 2-gal reservoir would be sufficient for medium-duty applications with refilling only at service intervals of about 8000 mi. The AMFI system has been installed on a single-cylinder LTGC research engine and demonstrated to provide robust combustion-timing control over wide ranges of combustion phasing, fueling rate, intake boost, engine speed, and intake temperature. AMFI also increases the fuel’s reactivity sufficiently to greatly reduce or eliminate the need for charge heating, simplifying engine design and significantly increasing thermal efficiency and the maximum load at low-boost conditions. The nitrogen in the EHN produced a modest increase in NOx, but it was mitigated by lower intake temperatures, and NOx emissions remained very low. Finally, the additive increases the sensitivity of autoignition reactions to variations in the local fuel/air mixture within the charge. This allows the use of controlled fuel stratification for improved LTGC-engine performance, and its potential to improve low-load operation was demonstrated.

Dec, John E.↗

High efficiency solar photovoltaic power module concept

The investigation of a preliminary concept for high efficiency solar power generation in space is presented. The concept was a synergistic combination of spectral splitting, tailored bandgap cells, high concentration ratios, and cool cell areas.

Bekey, I.↗

Magnetron R&D for high efficiency CW RF sources for industrial accelerators

The scheme of using high-efficiency magnetrons to drive radiofrequency accelerators has been demonstrated at 2450 MHz in CW mode *. Magnetron test stands at JLab and GA have been set up to further test the noise figure and the locking speed of the injection phase-lock method. For higher power applications, power combining experiments using a TM010 cavity-type combiner and a magic tee for the binary combiner while using a single clean injection signal has been carried out at 2450 MHz. The frequency pulling effect between the magnetron and a low-Q cavity has been shown to enhance the frequency locking bandwidth compared to the injection phase-lock alone. The principle has been studied by the equivalent circuit simulation, analytical model, and finally confirmed experimentally on the magnetrons. Due to the pandemic delay in 2020, the equivalent high power tests using a 75kW, 915MHz industrial magnetron will be done in 2021 and will be reported in a future paper.

Wang, H.↗

Magnetron R&D Progress for High Efficiency CW RF Sources of Industrial Accelerators

After the demonstration of using high efficiency magnetron power to combine and aim to drive a radio frequency accelerator at 2450MHz in CW mode [1], we have used trim coils adding to a water-cooled magnetron and three amplitude modulation methods in an open-loop control to further suppress the 120Hz side-band noise to -46.7dBc level. We have also successfully demonstrated the phase-locking to an industrial grade cooking magnetron transmitter at 915MHz with a 75kW CW power delivered to a water load by using a -26.6dBc injection signal. The sideband noise at 360Hz from the 3-Phase SCRs DC power supply can be reduced to -16.2dBc level. Their power combing scheme and higher power application to industrial accelerators are foreseeing.

Wang, H.↗

High Efficiency Binary Blazed Grating Waveguide Couplers

Binary blazed gratings are investigated as highly efficient waveguide couplers. Equations are derived for the design of efficient binary blazed grating waveguide couplers. The design approach relates waveguide blazed grating equations to Artificial Index Grating (AIG) equations to emulate a blazed grating. Using these relationships, binary blazed gratings can be accurately designed to output a single mode at a desired output angle. Binary blazed grating couplers can achieve single mode cladding output without substrate" radiation output modes. Much higher output angles can be achieved than with rectangular grating couplers. The use of the AIG grating structure simplifies fabrication approaches. Waveguide couplers were designed using these equations.

Watson, Michael D.↗

Light-Induced Metastabilities in Highly Efficient MZO/CdSeTe/CdTe Thin Film Solar Cells

Metastability effects have been investigated in high efficiency MZO/CdSeTe/CdTe solar cells. Two different preconditioning procedures have been studied to recover the performance of the devices. These preconditioning procedures include light soaking, annealing and cooling down the device under different atmospheric conditions. J-V curves before any preconditioning showed a `S` shaped behavior and disappears after 15 minutes of light soaking under 1000 Wm-2. Both Atmospheric and Vacuum preconditioning showed similar recovery of the device performance. However, this recovery only lasts for 3 days when the devices were kept under vacuum in the dark.

14 SOLAR ENERGY↗