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At least 253 records · Page 14

Influence of MXene termination groups on hydrogen interactions

MXenes are a relatively new class of nanomaterial consisting of alternating layers of transition metals and carbon or nitrogen, capped off on either end by terminal groups, usually from the P-block. They have been considered for a wide range of purposes, including hydrogen storage. In this study, thermogravimetric analysis and mass spectrometry residual gas analysis are performed on Ti 3 C 2 T x and Ti 2 CT x to characterize their terminal groups. The hydrogen absorption capabilities of the heat-treated samples are measured using a Sievert apparatus and compared against untreated samples. This reveals that, during heating, the MXenes lose hydrogen, water, fluoride, hydrofluoric acid, and carbon dioxide. Isothermal absorption measurements suggest that the removal of termination groups might improve hydrogen uptake kinetics at high temperatures, but has little effect at room temperatures.

08 HYDROGEN↗

Demonstration of gold nanorod systems for enhanced total efficiency: Experimental and numerical analysis

This study investigates the photothermal performance of gold nanorods engineered to exhibit longitudinal plasmon resonances at 695 nm, 780 nm, and 970 nm. The work combines synthesis, structural characterization, extinction measurements, numerical modeling, and controlled temperature experiments to quantify how nanorod geometry, resonance tuning, concentration, and chamber shape jointly influence heat generation. Transmission electron microscopy confirms that increasing nanorod aspect ratio systematically shifts the longitudinal plasmon peak toward the near-infrared region. Extinction measurements show strong agreement with theoretical predictions, validating the numerical model across two independent datasets. Three chamber geometries were tested under laser excitation at 640 nm, 808 nm, and 980 nm: an ascending stepped base, a flat base, and a descending stepped base. Without nanorods, the ascending geometry produced the highest efficiency due to enhanced natural convection. After introducing gold nanorods, all geometries exhibited substantial thermal enhancement, with total efficiencies exceeding 20%. The strongest improvement was obtained for nanorods resonant at 780 nm with a mass concentration of 4.6 mg/mL implemented on the descending stepped-base geometry. This performance resulted from the combined effect of spectral overlapping with the 808 nm laser, the highest nanorod concentration, and localized heat accumulation that intensified buoyancy-driven flow. The findings demonstrate that total efficiency is governed by a synergistic interplay between optical resonance, nanoparticle concentration, and macroscopic chamber design, revealing the system-level coupling between nanoscale plasmonic absorption and macroscale heat-transfer phenomena. The results provide a validated framework for tuning nanoscale plasmonic absorbers and optimizing thermal systems for applications requiring efficient light-to-heat conversion.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Comparative analysis of energy deposition modes available in Serpent 2 within the framework of the supercritical water reactor - Fuel qualification test reactor physics benchmark

A joint European Canadian Chinese development of a supercritical water-cooled small modular reactor (SCW-SMR) technology is in progress since September 2020 in the framework of a Horizon 2020 project called ECC-SMART. As a main purpose of the project, proper estimates of energy deposition and its spatial distribution are prerequisites for the accurate analysis of safety related parameters of the SCW-SMR concept under development. A supercritical water reactor fuel computational benchmark model, provided by Canadian Nuclear Laboratories, was applied for detailed comparison of different energy deposition calculation options available in the Serpent 2 Monte Carlo code. The effect of energy deposition options on the normalization of the results as well as on the spatial distribution of the energy deposition are discussed. Consistent energy deposition calculation methods are presented between three Monte Carlo codes, viz., Serpent 2, MCNP6 and OpenMC. Although resource-intensive, the use of the coupled neutron-photon transport mode of Serpent 2 is recommended for accurate spatial and quantitative characterization of energy deposition in the SCW-SMR fuel assemblies, accounting for both neutron and photon heating of all the materials. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Turbulent heat transfer from a sparsely vegetated surface - Two-component representation

The conventional calculation of heat fluxes from a vegetated surface involving the coefficient of turbulent heat transfer which increases logarithmically with surface roughness, is inappropriate such highly structured surfaces as desert scrub or open forest. An approach is developed here for computing sensible heat flux from sparsely vegetated surfaces, where the absorption of insolation and the transfer of absorbed heat to the atmosphere are calculated separately for the plants and for the soil. This approach is applied to a desert-scrub surface in the northern Sinai, for which the turbulent transfer coefficient of sensible heat flux from the plants is much larger than that from the soil below, as shown by an analysis of plant, soil, and air temperatures. The plant density is expressed as the sum of products (plant-height) x (plant-diameter) of plants per unit horizontal surface area. The solar heat absorbed by the plants is assumed to be transferred immediately to the airflow. The effective turbulent transfer coefficient k(g-eff) for sensible heat from the desert-scrub/soil surface computed under this assumption increases sharply with increasing solar zenith angle, as the plants absorb a greater fraction of the incoming irradiation. The surface absorptivity (the coalbedo) also increases sharply with increasing solar zenith angle, and thus the sensible heat flux from such complex surfaces is a much broader function of time of day than when computed under constant k(g-eff) and constant albedo assumptions.

Otterman, J.↗

Laser-heated thruster

The development of a computer program for the design of the thrust chamber for a CW laser heated thruster was examined. Hydrodgen was employed as the propellant gas and high temperature absorber. The laser absorption coefficient of the mixture/laser radiation combination is given in temperature and species densities. Radiative and absorptive properties are given to determine radiation from such gas mixtures. A computer code for calculating the axisymmetric channel flow of a gas mixture in chemical equilibrium, and laser energy absorption and convective and radiative heating is described. It is concluded that: (1) small amounts of cesium seed substantially increase the absorption coefficient of hydrogen; (2) cesium is a strong radiator and contributes greatly to radiation of cesium seeded hydrogen; (3) water vapor is a poor absorber; and (4) for 5.3mcm radiation, both H2O/CO and NO/CO seeded hydrogen mixtures are good absorbers.

Kemp, N. H.↗

Study of the effects of MeV Ag, Cu, Au, and Sn implantation on the optical properties of LiNbO3

The authors present the results of characterization of linear absorption and nonlinear refractive index of Au, Ag, Cu and Sn ion implantation into LiNbO3. Ag was implanted at 1.5 MeV to fluences of 2 to 17 x 17(exp 16)/sq cm at room temperature. Au and Cu were implanted to fluences of 5 to 20 x 10(exp 16)/sq cm at an energy of 2.0 MeV. Sn was implanted to a fluence of 1.6 x 10(exp 17)/sq cm at 160 kV. Optical absorption spectrometry indicated an absorption peak for the Au implanted samples after heat treatment at 1,000 C at approx. 620 nm. The Ag implanted samples absorption peaks shifted from approx. 450 nm before heat treatment to 550 nm after 500 C for 1h. Heat treatment at 800 C returned the Ag implanted crystals to a clear state. Cu nanocluster absorption peaks disappears at 500 C. No Sn clusters were observed by optical absorption or XRD. The size of the Ag and Au clusters as a function of heat treatment were determined from the absorption peaks. The Ag clusters did not change appreciably in size with heat treatment. The Au clusters increased from 3 to 9 nm diameter upon heat treatment at 1000 C. TEM analysis performed on a Au implanted crystal indicated the formation of Au nanocrystals with facets normal to the c-axis. Measurements of the nonlinear refractive indices were carried out using the Z-scan method with a tunable dye laser pumped by a frequency doubled mode-locked Nd:YAG laser. The dye laser had a 4.5 ps pulse duration time and 76 MHz pulse repetition rate (575 nm).

Williams, E. K.↗

Infrared thermographic analysis of polymer composites during ballistic impact

An infrared thermographic system was used to measure the surface temperature profile of composite materials under ballistic impact. The heat deposited was calculated based on the temperature profiles. The extent of damage induced in the materials was determined qualitatively from the measured data. The relative contribution of frictional heat to total energy absorption was evaluated, and the effect of the shape of the projectile on the extent of damage and temperature distribution in the composites was examined. The results show that graphite and polyethylene composite are more effective than Kevlar composite in dissipating heat during the ballistic impact penetration process due to their higher thermal conductivity.

Hsieh, C. Y.↗

X-ray free electron laser heating of water and gold at high static pressure

Probing of reactive materials such as H 2 O ices and fluids at the high pressures and temperatures of planetary interiors is limited by unwanted chemical reactions and confinement failure. Faster experiments can mitigate such issues, but the common approach of adiabatic compression limits the conditions achieved. This study demonstrates a fast experimental strategy for the creation and probing of selected extreme states using static compression coupled with ultrafast X-ray laser heating. Indirect X-ray heating of H 2 O through the use of a gold absorber is evidenced by sample melting inferred from textural changes in the H 2 O diffraction lines and inter-dispersion of gold and H 2 O melts. Coupled with numerical analysis of femtosecond energy absorption, thermal equilibration, and heat transfer, all evidence indicates that temperatures in excess of an electron volt have been reached in the H 2 O at high pressure. Even after repeated heating, samples stayed chemically unchanged from the starting material.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Study of component technologies for fuel cell on-site integrated energy systems

Heating, ventilation and air conditioning equipment are integrated with three types of fuel cells. System design and computer simulations are developed to utilize the thermal energy discharge of the fuel in the most cost effective manner. The fuel provides all of the electric needs and a loss of load probability analysis is used to ensure adequate power plant reliability. Equipment cost is estimated for each of the systems analyzed. A levelized annual cost reflecting owning and operating costs including the cost of money was used to select the most promising integrated system configurations. Cash flows are presented for the most promising 16 systems. Several systems for the 96 unit apartment complex (a retail store was also studied) were cost competitive with both gas and electric based conventional systems. Thermal storage is shown to be beneficial and the optimum absorption chiller sizing (waste heat recovery) in connection with electric chillers are developed. Battery storage was analyzed since the system is not electric grid connected. Advanced absorption chillers were analyzed as well. Recommendations covering financing, technical development, and policy issues are given to accelerate the commercialization of the fuel cell for on-site power generation in buildings.

Lee, W. D.↗

Sodium tracer measurements of an expanded dense aluminum plasma from e-beam isochoric heating

Spatially and temporally resolved visible absorption spectroscopy is performed on sodium D-lines present as surface contaminants on an expanded dense aluminum plasma plume. An 80-ns FWHM, intense, relativistic electron beam deposits 5.4 J into a 100- μ m-thick Al foil, which isochorically heats and subsequently hydrodynamically expands the material through the warm dense matter state and into a classical-like plasma state, with a coupling parameter of approximately 0.2 and a degeneracy parameter of approximately 270. The Na contamination, carried along with the expanding plume, shows saturated absorption features in the dense Al continuum for λ > 450 nm. X-ray photoelectron spectroscopy and laser-induced breakdown spectroscopy confirm Na is a surface contaminant with an atomic concentration of ~ 0.1 % when interrogating identical foil samples. Additioanlly, a spectroscopic-quality radiation transport model is used to post-process 2D hydrodynamic simulations to interpret the plasma conditions based on the measured Na 3p-3s doublet line profiles. A sodium number density of 3 × 10 15 cm -3 best matches the experimental spectra, which originate from a dense surface plasma with n e = 3.0 ± 0.8 × 10 18 cm -3 .

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Photocell heat engine solar power systems

A combined photocell heat engine concept is proposed for high efficiency solar energy conversion in space. In this concept the short wavelength portion of the solar spectrum is split by a dichroic filter and sent to a bank of photocells. The long wave-length remainder of the spectrum is used by the heat engine. This technique allows the photocells to operate with the minimum amount of waste heat, increasing their efficiency and reducing the amount of cooling required. The heat engine operates by direct absorption in a working fluid containing broadband absorber molecules or particulates. A window in the heat engine admits the long wave-lengths from the solar spectrum. The window may also reflect a portion of the internal gaseous reradiation spectrum (e.g., a heat mirror) to help reduce radiation losses. Flow-induced thermal gradients may also reduce reradiation losses in the case of optically thick working fluids. The efficiencies computed for the photocell heat engine solar energy converter can be as high as 42 percent.

Taussig, R. T.↗

Effects of Aerosol on Atmospheric Dynamics and Hydrologic Processes during Boreal Spring and Summer

Global and regional climate impacts of present-day aerosol loading during boreal spring are investigated using the NASA finite volume General Circulation Model (fvGCM). Three-dimensional distributions of loadings of five species of tropospheric aerosols, i.e., sulfate, black carbon, organic carbon, soil dust, and sea salt are prescribed from outputs of the Goddard Ozone Chemistry Aerosol Radiation and Transport model (GOCART). The aerosol loadings are used to calculate the extinction coefficient, single scattering albedo, and asymmetric factor at eleven spectral wavelengths in the radiative transfer code. We find that aerosol-radiative forcing during boreal spring excites a wavetrain-like pattern in tropospheric temperature and geopotential height that emanates from Northern Africa, through Eurasia, to northeastern Pacific. Associated with the teleconnection is strong surface cooling over regions with large aerosol loading, i.e., China, India, and Africa. Low-to-mid tropospheric heating due to shortwave absorption is found in regions with large loading of dust (Northern Africa, and central East Asia), and black carbon (South and East Asia). In addition pronounced surface cooling is found over the Caspian Sea and warming over Eurasian and northeastern Asia, where aerosol loadings are relatively low. These warming and cooling are components of teleconnection pattern produced primarily by atmospheric heating from absorbing aerosols, i.e., dust from North Africa and.black carbon from South and East Asia. Effects of aerosols on atmospheric hydrologic cycle in the Asian monsoon region are also investigated. Results show that absorbing aerosols, i.e., black carbon and dust, induce large-scale upper-level heating anomaly over the Tibetan Plateau in April and May, ushering in an early onset of the Indian summer monsoon. Absorbing aerosols also enhance lower-level heating and anomalous ascent over northern India, intensifying the Indian monsoon. Overall, the aerosol-induced large-scale surface temperature cooling leads to a reduction of monsoon rainfall over the East Asia continent, and adjacent oceanic regions.

Lau, William K. M.↗

Effects of Aerosol on Atmospheric Dynamics and Hydrologic Processes During Boreal Spring and Summer

Global and regional climate impacts of present-day aerosol loading during boreal spring are investigated using the NASA finite volume General Circulation Model (fvGCM). Three-dimensional distributions of loadings of five species of tropospheric aerosols, i.e., sulfate, black carbon, organic carbon, soil dust, and sea salt are prescribed from outputs of the Goddard Ozone Chemistry Aerosol Radiation and Transport model (GOCART). The aerosol loadings are used to calculate the extinction coefficient, single scattering albedo, and asymmetric factor at eleven spectral wavelengths in the radiative transfer code. We find that aerosol-radiative forcing during boreal spring excites a wavetrain-like pattern in tropospheric temperature and geopotential height that emanates from Northern Africa, through Eurasia, to northeastern Pacific. Associated with the teleconnection is strong surface cooling over regions with large aerosol loading, i.e., China, India, and Africa. Low-to-mid tropospheric heating due to shortwave absorption is found in regions with large loading of dust (Northern Africa, and central East Asia), and black carbon (South and East Asia). In addition pronounced surface cooling is found over the Caspian Sea and warming over Eurasian and northeastern Asia, where aerosol loadings are relatively low. These warming and cooling are components of teleconnection pattern produced primarily by atmospheric heating from absorbing aerosols, i.e., dust from North Africa and black carbon from South and East Asia. Effects of aerosols on atmospheric hydrologic cycle in the Asian monsoon region are also investigated. Results show that absorbing aerosols, i.e., black carbon and dust, induce large-scale upper-level heating anomaly over the Tibetan Plateau in April and May, ushering in an early onset of the Indian summer monsoon. Absorbing aerosols also enhance lower-level heating and anomalous ascent over northern India, intensifying the Indian monsoon. Overall, the aerosol-induced large-scale surface tempera- cooling leads to a reduction of monsoon rainfall over the East Asia continent, and adjacent oceanic regions.

Lau, William K. M.↗

Time-Dependent Structure of the Upper Atmosphere

The physical properties of the upper atmosphere are determined mainly by heat conduction, the heat sources and the barometric law. An analysis of the integro-differential equation which describes these physical processes has been carried out. It is found that heating of the thermosphere due to absorption of the solar extreme ultraviolet (EUV) radiation alone cannot explain the observed diurnal variation of density and temperature, since it would yield a maximum of these properties at about 17h local time, instead of 14h where it is observed. Secondly, if the EUV flux is adjusted to give the observed average temperature, then the diurnal variation in density would be much too large compared with the observed amplitude. Thirdly, it would require an extremely high efficiency for the conversion of EUV radiation into heat, if we compare the required flux with Hinteregger's measurements of the EUV flux. Thus, it is necessary to have another heat source in addition to the heating due to absorption of EUV radiation. If an additional beat source is used, which has a maximum at about 9h local time and a flux of 1 erg cm−1 sec−1, a time-dependent model of the upper atmosphere is obtained that is in good agreement with the observed densities. There is evidence that this additional heat source derives its energy ultimately from the solar corpuscular radiation. In this paper we present the results of calculations for a model in the equatorial and temperature zones of the earth, for those times when the average solar activity corresponds to a solar radiation flux of 200×110−22 Wm−2 (cps)−1 at 10.7-cm wavelength. The physical properties (temperature, density, pressure, scale height, mean molecular weight and the number densities of N2, O2, O, He and H) are given as a function of local time and for the altitudes between 120 km and 2050 km.

ATMOSPHERE↗

Optical transmittance of fused silica during irradiation processes.

The level of irradiation-induced optical absorption and the resulting heat deposition in the transparent fused-silica wall of a nuclear light bulb engine during normal operation are investigated by means of a series of related experiments using available radiation sources, each of which simulates some aspect of the radiation flux or dose of the engine. A comparison of the results obtained in electron and reactor experiments indicates that the generation of optical absorption is due to ionizing effects and that neutron-caused displacement effects do not contribute significantly to optical absorption. The implications of these and other results obtained are discussed.

Palma, G. E.↗

Magnetoacoustic heating by ion Landau damping

The Vlasov-fluid model of Freidberg (1972) is used to study the resonance heating of a sharp-boundary screw pinch. The analysis provides the first treatment of the magnetoacoustic heating of a cylindrical plasma by means of ion Landau damping, which was identified as a viable dissipative mechanism for the conversion of magnetoacoustic wave energy into ion thermal energy. In addition, local and global energy conservation are considered, and formulae and numerical results for the thermal energy doubling time and the associated induced rf electric fields are presented. It is shown that collisionless absorption can provide a heating mechanism when an equilibrium plasma column is pumped by oscillations of the confining magnetic field at a frequency near the oblique magnetoacoustic frequency.

Turner, L.↗