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At least 253 records · Page 14

ACTS mobile propagation campaign

Preliminary results are presented for three propagation measurement campaigns involving a mobile receiving laboratory and 20 GHz transmissions from the Advanced Communications Technology Satellite (ACTS). Four 1994 campaigns were executed during weekly periods in and around Austin, Texas in February and May, in Central Maryland during March, and in Fairbanks, Alaska and environs in June. Measurements tested the following effects at 20 GHz: (1) attenuation due to roadside trees with and without foliage, (2) multipath effects for scenarios in which line-of-sight paths were unshadowed, (3) fades due to terrain and roadside obstacles, (4) fades due to structures in urban environs, (5) single tree attenuation, and (6) effects of fading at low elevation angles (8 deg in Fairbanks, Alaska) and high elevation angles (55 deg in Austin, Texas). Results presented here cover sampled measurements in Austin, Texas for foliage and non-foliage cases and in Central Maryland for non-foliage runs.

Goldhirsh, Julius↗

Rapid searches for counterparts of GRB 930131

A fading counterpart to a gamma-ray burst (GRB) would appear as a point source inside a GRB error region soon after the burst which dims on a timescale from minutes to days. The favorable circumstances of the burst GRB 930131 allowed for an international campaign to search for fading counterparts starting 6.8 hr after the burst. We report observations from many optical sites, two radio telescopes, and archival ROSAT data, including deep Schmidt exposures 35, 44, and 64 hr after the burst. No fading counterparts were detected with our observations.

Schaefer, Bradley E.↗

HST observations of the ring around SN 1987A

Hubble Space Telescope observations of SN 1987A show that the circumstellar material near the supernova forms a clumpy elliptical ring. We analyze six epochs of images made with the Faint Object Camera (FOC) imaging the lines of (O III) and H beta over the interval 1990 August-1993 October, and three epochs of observations with the Planetary Camera in the continuum and (N II) line over the interval 1992 April-1993 May. The elliptical ring in the (O III) images has a semimajor axis of 858 +/- 11 milliarcsec and a semiminor axis of 621 +/- 11 milliarsce (6.4 x 10(exp 17) and 4.6 x 10(exp 17) +/- 8.1 x 10(exp 15) cm, respectively, for a distance of 50 kpc), which implies an inclination angle of 44 +/- 1, if the ring is a circle inclined to our line of sight. The apparent width of the ring in (O III) is 121 +/- 22 milliarcsec (9.0 x 10(exp 16) +/- 1.6 x 10(exp 16) cm) based on our deconvolved image, which represents an upper limit to the width of the of the ring. The position angle of the major axis on the sky is 89 deg +/- 3 deg. One of the 'clumps' on the ring is a superposed star, whose energy distribution is consistent with an A-type dwarf (V = 20.2 mag) in the Large Magellanic Cloud (LMC) The radial profile of the ring is not symmetric, with the inner boundary sharper than the outer. Based on the radial profiles and the flux interior to the ring, we conclude that the ring is indeed a tilted ring, and not a spheroidal shell. While the observed width of the ring is approximately 10(exp 17) cm, we find that the average path length through the emitting gas is approximately 4 x 10(exp 15) cm, so the filling factor is small. The ring has faded by a factor of approximately equals 3.7 in (O III) from 1990 August to 1993 October. The characteristic electron density from the (O III) lambda 5007 emission line averages 1.2 x 10exp 4)/cu cm, based on recombination models of the emission. Because the fading rate is uncorrelated with the surface brightness, the density appears to be independent of the brightness, which implies significant path length differences through the ring. By assuming the current structure observed in optical lines applies to the early structure in ultraviolet lines, we construct light curve models to compare with early IUE observations. The clumpy structure of the ring has relatively little effect on the light curves. The (O III) images show faint arclike nebulosity probably associated with the bipolar nebula around SN 1987A and projected inside the ring, which may have affected previous observations of the ring. Finally, we find that the fading rate provides evidence, though weak, favoring an expanding ring over a contracting one.

Plait, Philip C.↗

Hubble Space Telescope observations of the dwarf Nova Z Chamaeleontis through two eruption cycles

We have obtained the first high-speed photometry of the eclipsing dwarf nova Z Cha at ultraviolet wavelengths with the Hubble Space Telescope (HST). We observed the eclipse roughly every 4 days over two cycles of the normal eruptions of Z Cha, giving a uniquely complete coverage of its outburst cycle. The accretion disk dominated the ultraviolet light curve of Z Cha at the peak of an eruption; the white dwarf, the bright spot on the edge of the disk, and the boundary layer were all invisible. We were able to obtain an axisymmetric map of the accretion disk at this time only by adopting a flared disk with an opening angle of approximately 8 deg. The run of brightness temperature with radius in the disk at the peak of the eruption was too flat to be consistent with a steady state, optically thick accretion disk. The local rate of mass flow through the disk was approximately 5 x 10(exp -10) solar masses/yr near the center of the disk and approximately 5 x 10(exp -9) solar masses/yr near the outer edge. The white dwarf, the accretion disk, and the boundary layer were all significant contributors to the ultraviolet flux on the descending branches of the eruptions. The temperature of the white dwarf during decline was 18,300 K less than T(sub wd) less than 21,800 K, which is significantly greater than at minimum light. Six days after the maximum of an eruption Z Cha has faded to near minimum light at ultraviolet wavelenghts, but was still approximately 70% brighter at minimum light in the B band. About one-quarter of the excess flux in the B band came from the accretion disk. Thus, the accretion disk faded and became invisible at ultraviolet wavelengths before it faded at optical wavelenghts. The disk did, however, remain optically thick and obscured the lower half of the white dwarf at ultraviolet and possibly at optical wavelenghts for 2 weeks after the eruption ended. By the third week after eruptiuons the eclipse looked like a simple occultation of an unobscured, spherical white dwarf by a dark secondary star. The center of the accretion disk was, therfore, optically thin at ultraviolet wavelenghts and the boundary layer was too faint to be visible.

Robinson, E. L.↗

A search for evolutionary changes in planetary nuclei: A continuation

This report summarizes the final results of an IUE investigation to search for signs of evolutionary changes in high-mass central stars of planetary nuclei, as evidenced by UV-optical fading over the lifetime of the satellite. The program is a continuation of an earlier investigation, expanding the target list to include more types of hot central stars and to obtain more spectra of previously observed stars. In order to compare the IUE fluxes of a central star obtained over a more-than-ten-year timespan, several steps were necessary, including reprocessing of very early spectra and correction for the sensitivity degradation of the SWP camera over time. The results indicate that while a few stars appear to have diminished UV fluxes compared to earlier IUE observations, the evidence for this is less than overwhelming due to the sparseness of the data. Those stars which emerge from this study as viable candidates for having faded are the cooler Of-type stars (O6f-O7f), i.e., those for which the change in spectral energy with increasing temperature is greatest. The report describes the data analysis steps and discusses the uncertainties in both the data and in the resulting fading rates. Estimates of stellar mass based on theoretical evolutionary rates are also provided.

Altner, Bruce↗

A Proposed Change to ITU-R Recommendation 681

Recommendation 681 of the International Telecommunications Union (ITU) provides five models for the prediction of propagation effects on land mobile satellite links: empirical roadside shadowing (ERS), attenuation frequency scaling, fade duration distribution, non-fade duration distribution, and fading due to multipath. Because the above prediction models have been empirically derived using a limited amount of data, these schemes work only for restricted ranges of link parameters. With the first two models, for example, the frequency and elevation angle parameters are restricted to 0.8 to 2.7 GHz and 20 to 60 degrees, respectively. Recently measured data have enabled us to enhance the range of the first two schemes. Moreover, for convenience, they have been combined into a single scheme named the extended empirical roadside shadowing (EERS) model.

Davarian, F.↗

The Decay of Optical Emission from the gamma-Ray Burst GRB970228

The origin of gamma-ray bursts has been one of the great unsolved mysteries in high-energy astrophysics for almost 30 years. The recent discovery of fading sources at X-ray and optical wavelengths coincident with the location of the gamma-ray burst GRB970228 therefore provides an unprecedented opportunity to probe the nature of these high-energy events. The optical counterpart appears to be a transient point source embedded in a region of extended nebulosity, the latter having been tentatively identified as a high-redshift galaxy. This would seem to favour models that place gamma-ray bursts at cosmological distances, although a range of mechanisms for producing the bursts is still allowed. A crucial piece of information for distinguishing between such models is how the brightness of the optical counterpart evolves with time. Here we re-evaluate the existing photometry of the optical counterpart of GRB970228 to construct an optical light curve for the transient event. We find that between 21 hours and six days after the burst, the R-band brightness decreased by a factor of approximately 40, with any subsequent decrease in brightness occurring at a much slower rate. As the point source faded, it also became redder. The initial behaviour of the source appears to be consistent with the 'fireball' model, but the subsequent decrease in the rate of fading may prove harder to explain.

Galama, T.↗

Turbo Trellis Coded Modulation With Iterative Decoding for Mobile Satellite Communications

In this paper, analytical bounds on the performance of parallel concatenation of two codes, known as turbo codes, and serial concatenation of two codes over fading channels are obtained. Based on this analysis, design criteria for the selection of component trellis codes for MPSK modulation, and a suitable bit-by-bit iterative decoding structure are proposed. Examples are given for throughput of 2 bits/sec/Hz with 8PSK modulation. The parallel concatenation example uses two rate 4/5 8-state convolutional codes with two interleavers. The convolutional codes' outputs are then mapped to two 8PSK modulations. The serial concatenated code example uses an 8-state outer code with rate 4/5 and a 4-state inner trellis code with 5 inputs and 2 x 8PSK outputs per trellis branch. Based on the above mentioned design criteria for fading channels, a method to obtain he structure of the trellis code with maximum diversity is proposed. Simulation results are given for AWGN and an independent Rayleigh fading channel with perfect Channel State Information (CSI).

Divsalar, D.↗

The Effect of Variable End of Charge Battery Management on Small-Cell Batteries

ABSL Space Products is the world leading supplier of Lithium-ion batteries for space applications and has pioneered the use of small capacity COTS cells within large arrays. This small-cell approach has provided many benefits to space application designers through increased flexibility and reliability over more traditional battery designs. The ABSL 18650HC cell has been used in most ABSL space battery applications to date and has a recommended End Of Charge Voltage (EOCV) of 4.2V per cell. For all space applications using the ABSL 18650HC so far, this EOCV has been used at all stages of battery life from ground checkout to in orbit operations. ABSL and NASA have identified that, by using a lower EOCV for the same equivalent Depth Of Discharge (DOD), battery capacity fade could be reduced. The intention of this paper is to compare battery performance for systems with fixed and variable EOCV. In particular, the effect of employing the blanket value of 4.2V per cell versus utilizing a lower EOCV at Beginning Of Life (BOL) before gradually increasing it (as the effects of capacity fade drive the End Of Discharge Voltage closer to the acceptable system level minimum) is analyzed. Data is compared from ABSL in-house and NASA GRC tests that have been run under fixed and variable EOCV conditions. Differences in capacity fade are discussed and projections are made as to potential life extension capability by utilizing a variable EOCV strategy.

Neubauer, Jeremy↗

A muiti-mode modulation and demodulation system and method

An improved system and method for modulation, demodulation and signal processing for single sideband communications systems which provides correction for the adverse effects of rapid fading characteristics in a mobile environment. The system provides modulation through a modified Weaver modulator in which the audio input is processed to produce an output in the form of an upper sideband having a pilot tone in a spectral gap at approximately midband. The receiver includes a modified Weaver demodulator and a correction signal generating circuit which processes the received faded audio input and pilot tone to produce a correcting signal. The correcting signal is mixed with the received signal to regenerate unfaded versions of both the signal and pilot by removing random amplitude and phase modulations imposed on them by the fading.

Stevenson, Carl R.↗

Nova V2362 Cygni (Nova Cygni 2006): Spitzer, Swift, and Ground-Based Spectral Evolution

Nova V2362 Cygni has undergone a number of very unusual changes. Ground-based spectroscopy initially revealed a normal sequence of events: the object faded and its near-infrared emission lines gradually shifted to higher excitation conditions until about day 100 when the optical fading reversed and the object slowly brightened. This was accompanied by a rise in the Swift X-ray telescope flux and a sudden shift in excitation of the visible and IR spectrum back to low levels. The new lower excitation spectrum revealed broad line widths and many P-Cygni profiles, all indicative of the ejection of a second shell. Eventually, dust formed, the X-ray brightness -- apparently unaffected by dust formation -- peaked and then declined, and the object faded at all wavelengths. The Spitzer dust spectra revealed a number of solid-state emission features that, at this time, are not identified.

Lynch, David K.↗

Mitigating Interference from Urban Air Mobility Vehicles on Satellite Communication Links by Using Vortex Radiometry

Vortex radiometers (VR) establish an early warning system for communication systems by generating concentric annular beam patterns around the active link. Received power peaks are monitored as interfering signals traverse overhead, allowing the VR to estimate source velocity. From this information the VR determines 1) when a fade will occur, 2) how long the fade will persist for and 3) how intense the fade will be. This paper demonstrates how VRs can be used to increase the resilience of communication systems used in urban air mobility applications.

vortex radiometry↗

Mitigating Interference from Urban Air Mobility Vehicles on Satellite Communication Links by Using Vortex Radiometry

Vortex radiometers (VRs) establish an early warning system for communication channels by generating concentric annular beam patterns around the active link. Peaks in received power are monitored as interfering signals traverse overhead, allowing the VR to estimate source velocity. From this information the VR determines 1) when a fade will occur, 2) how long the fade will persist for and 3) how intense the fade will be. This paper demonstrates how VRs can increase the resilience of communication systems used in urban air mobility applications.

Schemmel, Peter J.↗

Coupling Anionic Oxygen Redox with Selenium for Stable High‐Voltage Sodium Layered Oxide Cathodes

Utilizing anion redox reaction is crucial for developing the next generation of high-energy density, low-cost sodium-ion batteries. However, the irreversible oxygen redox reaction in Na-ion layered cathodes, which leads to voltage fading and reduced overall lifespan, has hindered their practical application. In this study, selenium is incorporated as a synergistic redox active center of oxygen to improve the stability of Na-ion cathodes. The redesigned cathode maintains stable voltage by demonstrating reversible oxygen redox while significantly suppressing the redox activity of manganese. The anionic redox contribution capacity of the selenium-doped Na 0.6 Li 0.2 Mn 0.8 O 2 cathode remains as high as 84% after 50 cycles, while the pristine Na 0.6 Li 0.2 Mn 0.8 O 2 cathode experiences a reduction to 39% of its initial capacity. The X-ray photoelectron spectroscopy data and computational analysis further revealed that selenium doping participates in redox as Se +4/5 which stabilizes the charged state and increases the energy step for O─O dimerization, thus improving the stability and lifespan of Na 0.6 Li 0.2 Mn 0.8 O 2 cathodes. In conclusion, the findings highlight the potential of redox coupling design to address the issue of voltage fade caused by irreversible anionic redox.

25 ENERGY STORAGE↗

Complex-Concentrated Anion Doping Enables Ultra-Stable Lattice Oxygen and Structural Integrity in Lithium-Rich Layered Oxide Cathodes

Lithium- and manganese-rich layered oxides (LMR) stand out as next-generation lithium-ion cathode chemistries, which harness both transition-metal and lattice-oxygen redox processes to deliver exceptional capacity and energy density. However, their full potential is hindered by intrinsic oxygen instability and structural degradation, resulting in pronounced voltage fade and capacity decay. Here, we present a complex-concentrated anion-doping paradigm in which multiple anions, F, Br, and S, are incorporated into the oxygen sublattice to enhance oxygen-redox and structural stability. X-ray absorption spectroscopy and aberration-corrected scanning transmission electron microscopy confirm ultra-stable local oxygen coordination environments during long-term cycling, with detrimental phase transformations and oxygen-loss-induced cavitation dramatically inhibited. Notably, we show that the characteristic LiTM6 transition metal (TM) honeycomb ordering is preserved even after electrochemical cycling. Concurrently, this strategy yields an unprecedented volume change of only 0.63% upon charging to 4.8 V vs. Li+/Li, achieving the first zero-strain LMR cathode. The resulting LMR cathode delivers ultralow voltage fade (1 mV per cycle during the first 100 cycles and becomes negligible in subsequent cycles) and outstanding energy retention (93% after 200 cycles) in a pouch cell configuration. Our complex-concentrated anion-doping concept establishes a broadly applicable strategy for resolving chemo-mechanical failure mechanisms in ceramic intercalation electrodes for next-generation energy storage.

Li-ion batteries↗

First Principles Study of Aluminum Doped Polycrystalline Silicon as a Potential Anode Candidate in Li‐ion Batteries

Addressing sustainable energy storage remains crucial for transitioning to renewable sources. While Li‐ion batteries have made significant contributions, enhancing their capacity through alternative materials remains a key challenge. Micro‐sized silicon is a promising anode material due to its tenfold higher theoretical capacity compared to conventional graphite. However, its substantial volumetric expansion during cycling impedes practical application due to mechanical failure and rapid capacity fading. A novel approach is proposed to mitigate this issue by incorporating trace amounts of aluminum into the micro‐sized silicon electrode using ball milling. Density functional theory (DFT) is employed to establish a theoretical framework elucidating how grain boundary sliding, a key mechanism involved in preventing mechanical failure is facilitated by the presence of trace aluminum at grain boundaries. This, in turn, reduces stress accumulation within the material, reducing the likelihood of failure. To validate the theoretical predictions, capacity retention experiments are conducted on undoped and Al‐doped micro‐sized silicon samples. In conclusion, the results demonstrate significantly reduced capacity fading in the doped sample, corroborating the theoretical framework and showcasing the potential of aluminum doping for improved Li‐ion battery performance.

25 ENERGY STORAGE↗

Cobalt-free and high-rate stable 5V lithium nickel manganese oxide spinel cathodes enabled via surface oxygen vacancies

Spinel LiNi 0.5 Mn 1.5 O 4 offers both the high-rate, low-cost and safety advantages of LiFePO 4 and the high energy density of LiNiₓMnᵧCo₁₋ₓ₋ᵧO₂ and LiNiₓCoᵧAlzO₂ cathodes. However, the large operating voltage of these materials induces electrolyte oxidation, which degrades the interface and drives Mn dissolution. These reactions are further exacerbated at high rates due to temperature rise. In this study, we discover that ammoniacal treatment followed by annealing introduces a high density of oxygen vacancies in the “near-surface region” of LiNi 0.5 Mn 1.5 O 4 particles. These vacancies release electrons changing the oxidation state of Mn and suppressing its tendency to oxidize the electrolyte. Further, these vacancies enhance the electrode’s electronic conductivity (by ∼3-fold) and Li + diffusivity (by ∼2-fold) greatly improving charge transport, especially when operated at high rates. This results in an across-the-board improvement in self-discharge, specific capacity, energy density, rate capability, coulombic efficiency and cycling stability. When cycled at ∼200 mA g −1 , the capacity fade averaged over 3000 cycles for the surface vacancy-enriched material is ∼0.0167% per cycle compared to an order of magnitude higher fade rate for the baseline material. In conclusion, these findings reveal the potential of targeted surface oxygen vacancy doping to develop cobalt-free and high energy density cathodes that tolerate fast charging and deliver improved cycle life.

Cobalt-free cathodes↗

Additively manufactured and cast high-temperature aluminum alloys for electric vehicle brake rotor application

Electric vehicle brake rotors demand lightweight, high thermal conductivity materials with good resistance to wear, creep, salt corrosion, and thermal fade, all of which present challenges to the traditionally used cast iron. In this work, we investigated the braking performance of recently developed high-temperature aluminum alloys in both cast and 3D printed forms, that possess excellent microstructural and mechanical stability at elevated temperatures. Three aluminum alloys, Al-6Cu-Mn-Zr, Al-9Cu-Mn-Zr, and Al-Ce-Ni-Mn-Zr and a reference cast iron were tested on a sub-scale brake tester against a commercial brake pad material over a range of sliding speeds between 2 and 15 m/s. The performance of these alloys was evaluated for wear resistance, friction behavior, temperature elevation, and surface morphological change. Although all three candidate alloys had lower wear-resistance than cast iron, Al-Ce-Ni-Mn-Zr showed a significantly reduced wear rate in comparison to the Al-Cu-Mn-Zr alloys. Moreover, Al-Ce-Ni-Mn-Zr alloy had the most consistent friction behavior at all sliding speeds and good fade resistance, as the coefficient of friction did not dramatically decrease with temperature rise but stayed within a desirable range of 0.35–0.50 instead. The superior wear resistance and braking performance of the Al-Ce-Ni-Mn-Zr alloy were attributed to its higher hardness, and high temperature yield strength and creep resistance compared with the Al-Cu-Mn-Zr alloys. In conclusion, the results suggest that the braking performance of these aluminum alloys could be further enhanced by increasing the hardness and forming a more stable transfer layer on the sliding surface.

36 MATERIALS SCIENCE↗