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At least 253 records · Page 14

Tropospheric ozone

Photochemical equilibrium models have been used to study the effect of recent revisions in important chemical reaction rates on the calculated tropospheric ozone concentration. Reasonable agreement with observed values is obtained if the NO(x) background is approximately 0.02 to 0.03 ppb, about an order of magnitude less than used in many previous model studies, but consistent with present nitrogen budget considerations and with observations of NO2. Chemical production and loss of ozone may dominate transport terms depending on values of key chemical rate constants and of the NO(x) background. This is consistent with the structure observed in the mean annual latitudinal distribution of ozone since ozone is its own chemical precursor and regions of enhanced stratosphere-troposphere exchange are also regions of enhanced photochemical activity.

Stewart, R. W.↗

Atmospheric lapse rate regimes and their parameterization

Lapse rates, moist adiabatic lapse rates and the critical lapse rate for baroclinic adjustment are calculated and compared for the mean annual, January and July states in the Northern Hemisphere. The small seasonal changes in hemispheric mean lapse rates can be attributed to counteracting seasonal changes in the strength of moist convection and baroclinic eddies. A major conclusion is that the vertical temperature structure may be well approximated by a radiative-convective equilibrium model with two critical lapse rates, viz. the moist adiabatic lapse rate and the critical lapse rate for baroclinic adjustment.

Stone, P. H.↗

A cluster ion chemistry for the mesospheric sodium layer

A cluster ion chemistry for sodium is developed which relates the Na(+) profile to the Na profile using reactions involving Na(+).N2, Na(+).CO2, and Na(+).H2O. Removal of sodium from the mesosphere is accomplished by the formation of higher order clusters of the form Na(+).(H2O)n which presumably precipitate to the lower atmosphere. This sink is most effective in the 80-85 km altitude range. The chemical equilibrium model is applied to experimental observations of the Na and Na(+) layers.

Richter, E. S.↗

X-ray observations of Algol

Observations of Algol using a solid state spectrometer onboard the Einstein Observatory are discussed. Two observations six months apart were made, both during a primary optical eclipse. No corresponding X-ray eclipses were seen. During the second observation the source was flaring and was on average a factor three brighter. The spectrum on both occasions was consistent with a two-component thermal equilibrium model with temperatures of approximately 7.5 and 40 million degrees. Attempts to insert a third component indicate the temperature distribution to be bimodal. Models for the X-ray emission are discussed and it is suggested that the emission most likely originates from an active corona surrounding the K star.

White, N. E.↗

X-ray evidence for electron-ion equilibrium and ionization nonequilibrium in Young supernova remnants

X-ray emission up to 25 keV from the supernova remnants Cas A and Tycho has been detected with the A-2 spectroscopy experiment on HEAO 1. The spectra must include continuum components with effective temperature of about 10 to the 8th K which could arise from optically thin plasmas in the collisionless shock fronts. This is the first indication of electron-ion temperature equilibrium in the expanding shell of young remnants. The equivalent widths of the K-alpha and K-beta iron line blends in Cas A have also been measured and it is found that their ratio is not compatible with the measured X-ray temperature in the collisional ionization equilibrium model. Finally, an unsuccessful search has been conducted for hard X-ray pulsars in both remnants.

Pravdo, S. H.↗

Spectrophotometry of Comet West

Postperihelion observations of Comet West (1975n = 1976 VI) have been made with a Fourier transform spectrometer at heliocentric distances from 0.57 to 1.68 AU. Measurements were made of the emission bands of C2, CN, C3, CH, and NH2, as well as the emission lines of Na D and forbidden (O I), and the flux in the continuum in nine different bandpasses. Several ratios of the band strengths of CN have been used to determine the two free parameters in the fluorescence equilibrium model of CN of Danks and Arpigny (1973). From the values of the parameters it is inferred that the vibrational transition probability for the ground electronic state is between 0.025 and 0.075 per sec and that the ratio of oscillator strengths between the (0-0) bands of the violet and red systems is between 25 and 30. When corrected for field-of-view effects, NH2 shows no systematic variation in abundance relative to C2 while CH shows a small increase. The cometary continuum is found to be slightly redder than the solar continuum, consistent with results for other bright, dusty comets. The equivalent width of the Delta u = 0 sequence of C2 shows a marked decrease at r(H) = 1.2 AU.

Ahearn, M. F.↗

X-ray observations of Algol

The Solid State Spectrometer on Einstein has been used to study Algol. Two observations six months apart were made, both including a primary optical eclipse. No corresponding X-ray eclipses were seen. During the second observation the source was flaring and was on the average a factor of three brighter. The spectrum on both occasions was consistent with a two-component thermal equilibrium model with temperatures of approximately 7.5 and 40 million degrees. Attempts to insert a third component indicate the temperature distribution to be bimodal. Models for the X-ray emission are discussed and it is suggested that it most likely originates from an active corona surrounding the K star.

White, N. E.↗

The latitudinal variation of the charge exchange induced atomic hydrogen escape flux

Using plasma data from the Isis 2 spacecraft and Arecibo radar, diffusive equilibrium models of the ionosphere were constructed for equinox conditions. These plasmaspheric models were combined with models of the neutral atmosphere to calculate the atomic hydrogen escape flux due to charge exchange between thermal protons and to calculate cooler hydrogen and oxygen atoms as a function of dipole latitude and local time. These calculations showed that the daytime escape flux increases as the absolute value of the dipole latitude decreases, reaching its maximum value at the magnetic equator. At 15 hours local time (LT) on March 23, 1972, the calculated escape flux varied from an insignificant amount at 55 deg dipole latitude, to 3 x 10 to the 8th atoms/sq cm sec at the magnetic equators.

Maher, L. J., Jr.↗

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for calcium and nickel ions in low-density high-temperature plasmas

The total dielectronic recombination rates for Ca and Ni ions were calculated taking into account autoionization to excited states of the recombining ion and stabilizing radiative transitions of the recombining electron. Radiative transitions of the recombining ion are found to be the dominant stabilizing processes, and the relative importance of Delta n = 0 and Delta n not equal to 0 transitions in the relevant temperature region is determined for each ion. The relative importance of the Delta n = 0 and Delta n not equal to 0 contributions is significantly altered for some ions by the inclusion of autoionization to excited levels. The relative abundance of the various ionization stages has been determined by using a corona equilibrium model in which collisional ionization and inner-shell excitation followed by autoionization are balanced by direct radiative and dielectronic recombination.

Jacobs, V. L.↗

Thermal Structure of Jupiter and Saturn

Temperatures in the sensible regions of the atmospheres of the outer planets are quite cold. The temperature structures for Jupiter, Saturn, Uranus and Neptune, derived from the equilibrium models are presented in preparation. The vertical temperature profiles for Jupiter and Saturn, the molecular spectroscopic data which form the basis for this type of analysis, and the problems involved with these models for molecular absorption and with the recovery technique in general, are discussed. Results for Jupiter and Saturn from the Pioneer and Voyager infrared experiments are also presented.

Orton, G.↗

A comparison of equatorial electron densities measured by whistlers and by a satellite radio technique

Magnetospheric equatorial electron densities determined from whistler observations are compared with in situ satellite measurements of electron density along near-equatorial orbits. Whistler data was recorded at Siple and Palmer, Antarctica, while the sweep frequency receiver on ISEE-1 was used to measure plasma densities during passes within about 15 deg of the whistler station longitudes at L values between 3 and 5.2. The whistler and satellite data sets are found to be in good agreement for the three rendezvous considered, suggesting that the diffusive equilibrium model applied to calculate electron densities from whistler measurements was appropriate for the description of electron density distributions along field lines in the outer plasmasphere. Data also indicate that density enhancements within the whistler ducts were not more than about 30% of the mean or interduct level, and that there were no significant east-west density gradients within about 15 deg of whistler station longitudes over the L range of the study.

Carpenter, D. L.↗

Stratospheric eddy diffusion coefficients from tracer data

Global distributions of nitrous oxide, methane, ozone, and carbon 14 are used to estimate four sets of stratospheric eddy diffusion coefficients. A photochemical equilibrium model calculates O(3P), O(1D), H, HO2, OH, H2O2, NO, and NO2 densities, as a function of altitude, latitude, and time. The calculated O(1D), OH, and observed Cl densities are used to obtain the eddy profiles associated with the methane and nitrous oxide distributions, for altitudes between 10 and 40 km. Application of a constant flux condition to the seasonally averaged ozone data yields eddy values below 20 km. Time-dependent carbon 14 calculations produce eddy coefficients between 13 and 27 km. A composite profile is obtained by comparing the four sets of coefficients. Further, carbon 14 computations are used to test these profiles as well as those recommended in reports issued by the National Academy of Sciences in 1976 and 1979. The composite eddy profile produces the best agreement.

Massie, S. T.↗

Plasmaspheric helium ion distribution from satellite observations of He II 304-A

High sensitivity and spatial resolution observations of the He II 304-A emission line intensity in the earth's nightglow have been carried out by the extreme ultraviolet telescope on the Apollo-Soyuz mission in July, 1975. The data, obtained over a wide range of plasmasphere parameters, are compared to the predictions of a kinetic equilibrium model of plasmaspheric ion density. Excellent agreement between observation and theory is found using as inputs a temperature model, solar flux and H(+) and O(+) number densities determined by extrapolating nearly simultaneous Atmospheric Explorer C measurements at 300 km. The observations in the Northern Hemisphere are well fit by a model having 285 He(+) ions/cu cm at 500 km independent of latitude or longitude, while those in the south require 430 He(+) ions/cu cm at the same altitude. This result is consistent with available information on the interhemispheric asymmetry of He(+) observed by a mass spectrometer on Explorer 32 and on the winter neutral helium bulge.

Chakrabarti, S.↗

Effective temperatures of A and F stars

Effective temperatures of late A and early F stars are determined from the observed fluxes in the visual at 1900 A and 1420 A. The observed ratios are compared with those calculated by Kurucz (1979). A correction of the theoretical fluxes at 1900 A brings the effective temperatures obtained from different ratios into reasonable agreement. The effective temperatures determined in this way for late A stars agree well with those obtained from the optical region. For F stars, however, the effective temperatures obtained from the UV are found to be higher than those obtained from the optical region if radiative equilibrium models are used for the comparison. It is thought that this discrepancy may derive from the effects of temperature, pressure, and absorption coefficient inhomogeneities caused by convection.

Boehm-Vitense, E.↗

Atmospheric structure of the outer planets from thermal emission data

Methods for determining atmospheric structure exploit the opacities provided by the collision induced H2 dipole and the nu4 fundamental of CH4. In addition to earth-based observations, useful measurements of thermal emission from Jupiter and Saturn have been or soon will be made by several spacecraft, with results cross-checked with independent radio occultaion results. For Uranus and Neptune, only a limited set of whole-disk earth-based data exists. All the outer planets show evidence for stratospheric temperature inversions; temperature minima range from about 105 K for Jupiter and 87 K for Saturn, to roughly 55 K for Uranus and Neptune. Remaining problems may be resolved by better quantitative understanding of gas and aerosol absorption and scattering properties, chemical composition, and non-LTE source functions. Ultimately, temperature structure results must be supplemented by quantitative energy equilibrium models which will allow some meaning to be given to the relationships between such characteristics as temperature, clouds, incident solar and planetary radiation, and chemical composition.

Orton, G. S.↗

Relative abundance of the light ions in the winter nighttime topside ionosphere

Ion concentration measurements with the retarding potential analyzer onboard OGO 6 satellite have served as basis for investigation of the distribution of the light ions, H(+) and He(+), relative to that of O(+) in the 500- to 800-km height range in the winter nighttime ionosphere. This concentration ratio exhibits distinct large-scale horizontal variations, with a relative depression in the ratio observed over a broad region about -45 deg longitude northward of approximately 40 deg dip latitude. The lower ratios are associated primarily with well-defined relative increases in the abundance of O(+), and occur in the same longitude sector that has been characterized in an earlier study by both an observed concurrent relative enhancement in ion temperature and the presence of large fluxes of energetic electrons. Comparisons are presented for the altitude distributions of the concentration ratio between regions representing extremes of the horizontal variation. A simple diffusive-equilibrium model demonstrates that the effects of ion temperature on the O(+) vertical distribution are a significant factor leading to the observed variation of the concentration ratio.

Sanatani, S.↗

Cloud optical thickness feedbacks in the CO2 climate problem

A radiative-convective equilibrium model is developed and applied to study cloud optical thickness feedbacks in the CO2 climate problem. The basic hypothesis is that in the warmer and moister CO2-rich atmosphere, cloud liquid water content will generally be larger too. For clouds other than thin cirrus the result is to increase the albedo more than to increase the greenhouse effect. Thus, the sign of the feedback is negative: cloud optical properties act as a thermostat and alter in such a way as to reduce the surface and tropospheric warming caused by the addition of CO2. This negative feedback can be substantial. When observational estimates of the temperature dependence of cloud liquid water content are employed in the model, the surface temperature change caused by doubling CO2 is reduced by about one half. This result is obtained for global and annual average conditions, no change in cloud amount or altitude, and constant relative humidity. These idealizations, together with other simplifications typical of one-dimensional radiative-convective climate models, render the result tentative. Further study of cloud optical property feedbacks is warranted, however, because the climate is apparently so sensitive to them.

Somerville, R. C. J.↗

Ionization equilibrium in isolated H II regions

Theoretical ionization equilibrium models are combined with Copernicus ultraviolet observations to study a particular H II region absorption-line component in the spectra of Lambda Sco and Upsilon Sco. The Lambda Sco observations imply that the region is characterized by a hydrogen density of approximately 0.2/cu cm and an extent along the line of sight of approximately 16 pc. Three choices for the relative placement of Lambda Sco and Upsilon Sco are considered. Conclusions are that Lambda Sco is the primary source of ionization and that there is a separation of approximately 5 pc between the H II region and Lambda Sco. Observational data support an enhanced dielectronic recombination rate for S III. Comparison of the Upsilon Sco and Lambda Sco observations suggests that spatial variations of density may be present.

Eder, D. C.↗