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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

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DOE OSTI2019

SimCCS: An open-source tool for optimizing CO 2 capture, transport, and storage infrastructure

Commercial-scale carbon capture and storage (CCS) technology will involve deploying infrastructure on a massive and costly scale. This effort will require careful and comprehensive planning to ensure that capture locations, storage sites, and the dedicated CO 2 distribution pipelines are selected in a robust and cost-effective manner. Presented in 2009, SimCCS is an optimization model for integrated system design that enables researchers, stakeholders, and policy makers to design CCS infrastructure networks. SimCCS 2.0 is a complete, ground-up redesign that is now a portable software package, useable and shareable by the CCS research, industrial, policy, and public communities. SimCCS 2.0 integrates multiple new capabilities including a refined optimization model, novel candidate network generation techniques, and optional integration with high-performance computing platforms. Accessing user-provided CO 2 source, sink, and transportation data, SimCCS 2.0 creates candidate transportation routes and formalizes an optimization problem that determines the most cost-effective CCS system design. This optimization problem is further solved either through a high-performance computing interface, or through third-party software on a local desktop computing platform. Finally, SimCCS 2.0 employs an open-access geographic information system framework to enable analysis and visualization capabilities. SimCCS 2.0 is written in Java and is publicly available via GitHub to encourage collaboration, modification, and community development.

42 ENGINEERING↗

DOE OSTI2018

Structure of Copper–Cobalt Surface Alloys in Equilibrium with Carbon Monoxide Gas

Here, we studied the structure of the copper–cobalt (CuCo) surface alloy, formed by Co deposition on Cu(110), in dynamic equilibrium with CO. Using scanning tunneling microscopy (STM), we found that, in vacuum at room temperature and at low Co coverage, clusters of a few Co atoms substituting Cu atoms form at the surface. At CO pressures in the Torr range, we found that up to 2.5 CO molecules can bind on a single Co atom, in carbonyl-like configurations. Based on high-resolution STM images, together with density functional theory calculations, we determined the most stable CuCo cluster structures formed with bound CO. Such carbonyl-like formation manifests in shifts in the binding energy of the Co core-level peaks in X-ray photoelectron spectra, as well as shifts in the vibrational modes of adsorbed CO in infrared reflection absorption spectra. The multiple CO adsorption on a Co site weakens the Co–CO bond and thus reduces the C–O bond scission probability. Our results may explain the different product distribution, including higher selectivity toward alcohol formation, when bimetallic CuCo catalysts are used compared to pure Co.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

How effective is the Brink–Axel hypothesis for astrophysical weak rates?

We explore the effectiveness of the Brink–Axel hypothesis (BAH) for the computation of stellar electron capture (EC) and β-decay (BD) rates, namely that the transition strength function depends only upon the transition energy and not upon the details of the initial state. For this purpose, we calculated Gamow–Teller (GT) strength distributions for a selection of sd-shell nuclides, using two different microscopic models, namely the proton–neutron quasiparticle random phase approximation and the full configuration-interaction shell model, taking into account the first 100 states of both the initial and final nuclides. The GT transition strengths among these levels evolve with initial state energy. These transition strength functions we folded into weak-interaction mediated rates in stellar matter, specifically EC and BD rates, for a range of densities 10 g cm –3 ≤ ρ ≤ 10 11 g cm –3 and range of temperatures 1 GK ≤ T ≤ 30 GK. When transitions from excited states were approximated using the BAH, augmented by so-called 'back-resonance' transitions, the rates were affected by up to three orders of magnitude or more at high temperatures and densities. Furthermore the BAH is not a reliable approximation for the calculation of stellar rates, especially in high temperature–density environments.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2023

The stellar mass of the Gaia -Sausage/Enceladus accretion remnant

The Gaia-Sausage/Enceladus (GS/E) structure is an accretion remnant that comprises a large fraction of the Milky Way’s stellar halo. We study GS/E using high-purity samples of kinematically selected stars from APOGEE DR16 and Gaia. Employing a novel framework to account for kinematic selection biases using distribution functions, we fit density profiles to these GS/E samples and measure their masses. We find that GS/E has a shallow density profile in the inner Galaxy, with a break between 15 and 25 kpc beyond which the profile steepens. We also find that GS/E is triaxial, with axis ratios 1:0.55:0.45 (nearly prolate), and the major axis is oriented about 80° from the Sun–Galactic centre line and 16° above the plane. We measure a stellar mass for GS/E of $1.45\, ^{+0.92}_{-0.51}\, \mathrm{(stat.)}\, ^{+0.13}_{-0.37} \mathrm{(sys.)}\ \times 10^{8}$ M ⊙ . Our mass estimate is lower than others in the literature, a finding we attribute to the excellent purity of the samples we work with. We also fit a density profile to the entire Milky Way stellar halo, finding a mass in the range of 6.7–8.4 × 10 8 M ⊙ , and implying that GS/E could make up as little as 15–25 per cent of the mass of the Milky Way stellar halo. Our lower stellar mass combined with standard stellar mass-to-halo mass relations implies that GS/E constituted a minor 1:8 mass-ratio merger at the time of its accretion.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2021

Whisper Use of Nuclear Data Covariances [Slides]

Whisper is statistical analysis code using sensitivity/uncertainty-based methods to determine baseline upper subcritical limit (USL) for nuclear criticality safety. Features of Whisper 1.1 include: GLLS method implemented to compute adjusted covariance based on current benchmark suite (1,100+ ICSBEP models), BLO “low-fidelity” covariance data used (44 energy groups), adjusted covariance is pre-computed and saved, and adjusted cross sections are NOT computed. Potential future efforts include: an extension to include angular distributions in benchmark selection and in GLLS adjustment, a move toward more modern covariance data (ENDF/B-VIII.0) and different group structure, and compute and store adjusted cross sections (trivial).

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2023

Technical Report on Waveform Fit Metrics for Global Models

The new WAVEFORMS Initiative in the Ground-based Nuclear Detonation Detection (GNDD) program includes an increased emphasis on the development of Earth models and methods to predict entire seismic and acoustic waveforms more accurately. In general, this increased emphasis is predicated on the need to better characterize seismic events and provide improved model-based discrimination between event types including earthquakes and explosions. More specifically, while current moment tensor inversion methods tend to work well for larger events (M>~4) using tuned 1-D Earth models, the development of state-of-the-art 3-D models and methods is required for the prediction of shorter period waves over large areas for discrimination of smaller events. There is no standard metric for model-based waveform prediction accuracy used in the waveform modeling/inversion community. However, there are several popular waveform misfit definitions; and minimizing the corresponding objective functions is the goal of waveform inversion. Some example misfit definitions employed for adjoint waveform tomography include measures of simple travel time differences (e.g. Tape et al., 2010), cross-correlation travel time differences (e.g. Luo and Schuster, 1991), multi-taper frequency dependent methods (e.g. Lei et al., 2020), time-frequency phase misfit functions (e.g. Fichtner 2010; Rodgers et al., 2022), normalized cross-correlation methods (e.g. Tao et al., 2018), and others. In some cases, these misfit definitions also involve complicated weighting schemes and summations over multiple frequency bands making it difficult to duplicate the misfit measurement with alternative models and datasets. Although each of the misfit definitions mentioned above are useful for developing waveform models, the actual misfit values are not usually meaningful outside of a given project, model, and/or dataset. Therefore, it is difficult to understand and communicate model performance for predicting waveforms and comparing to other models and/or new model iterations with a different dataset. Therefore, there is a need for a generalized method for evaluating overall model performance that is independent from the specific misfit chosen to develop the waveform models that is also intuitive and meaningful. In this report, we describe a new metric we refer to as ‘Percent of Correlated Signal’. The following sections describe and demonstrate the metric with a case study event and a more rigorous test using a random selection of globally distributed events. While the focus here is on global tomography models, the metric is meant to applicable to regional ‘wiggle-for-wiggle’ waveform models/studies as well.

58 GEOSCIENCES↗

DOE OSTI2026

Microwave-Assisted Methane Dehydroaromatization: Impact of Process Parameters

Flaring of associated natural gas is a significant challenge for oil and gas producers that often results in high amounts of lost revenue for the industry. One way to improve economics of this process is to convert natural gas into value-added chemicals using chemical conversion. Methane, which is the principal component of natural gas, can typically be converted into valuable aromatics using non-oxidative conversion routes such as dehydroaromatization. For the current work, methane dehydroaromatization was investigated in a microwave-assisted reactor and the effect of various parameters such as reaction temperature (550-750 °C) and space velocity (3-8 L/gcat/hr) were studied. Both the parameters had a very strong effect on the overall performance of the reaction. The variation in temperature had significant impact on the overall methane conversion, whereas the variation in space velocity had significant impact on the selectivity and product distribution.

methane dehydroaromatization↗

NASA NTRS1976

The solar spectrum at typical clear weather days

The solar spectrum in the range of 300 is less than lambda is less than 1500nm is given for five typical clear weather days. These days are selected to represent typical seasonal conditions in respect to airmass water vapor, ozone, and turbidity. Present data are reviewed, and specific conditions are selected. The spectral distribution of the irradiance is given for the direct component, the scattered skylight, the total flux on a horizontal surface, and the flux on an inclined surface normal to the direct beam.

Boer, K. W.↗

NASA NTRS1978

Advanced ceramic material for high temperature turbine tip seals

Ceramic material systems are being considered for potential use as turbine blade tip gas path seals at temperatures up to 1370 1/4 C. Silicon carbide and silicon nitride structures were selected for study since an initial analysis of the problem gave these materials the greatest potential for development into a successful materials system. Segments of silicon nitride and silicon carbide materials over a range of densities, processed by various methods, a honeycomb structure of silicon nitride and ceramic blade tip inserts fabricated from both materials by hot pressing were tested singly and in combination. The evaluations included wear under simulated engine blade tip rub conditions, thermal stability, impact resistance, machinability, hot gas erosion and feasibility of fabrication into engine components. The silicon nitride honeycomb and low-density silicon carbide using a selected grain size distribution gave the most promising results as rub-tolerant shroud liners. Ceramic blade tip inserts made from hot-pressed silicon nitride gave excellent test results. Their behavior closely simulated metal tips. Wear was similar to that of metals but reduced by a factor of six.

Solomon, N. G.↗

NASA NTRS1984

Pseudo-Random Number Generators

Package features comprehensive selection of probabilistic distributions. Monte Carlo simulations resorted to whenever systems studied not amenable to deterministic analyses or when direct experimentation not feasible. Random numbers having certain specified distribution characteristic integral part of simulations. Package consists of collector of "pseudorandom" number generators for use in Monte Carlo simulations.

Howell, L. W.↗

NASA NTRS1983

The Galileo spacecraft system design

The Galileo Orbiter differs markedly from its Mariner, Viking and Voyager predecessors in many aspects of its design, as dictated by its unique mission characteristics. Novel design features include a dual spin configuration, long life bipropellant propulsion, radioisotope thermoelectric generators, and a star scanner. Other major changes are related to Space Shuttle Orbiter compatibility. The selection of a distributed data system employing a high speed data bus represents a major advance over Voyager systems. The command, control and data handling functions for the Orbiter are merged into a single software-controlled subsystem. The paramount importance of software development in the design of Galileo subsystems is noted, in view of the requirement for total engineering and science data acquisition process reprogrammability.

Jones, C. P.↗

NASA NTRS1982

The variability of stratospheric nitrogen compounds observed by LIMS in the winter of 1978-1979

The LIMS experiment was launched on the Nimbus 7 satellite for the purpose of sounding the vertical structure of temperature and key upper atmosphere trace gases on a global scale. The technique of thermal infrared limb sounding was used to obtain measurements of O3, H2O, NO2, and HNO3. LIMS collected data almost continuously from late October to late May over the latitude range from 64 deg S to 84 deg N. Two of the gases, NO2 and HNO3, are important elements in the NO(x) chain of chemical reactions leading to ozone destruction. Results for these gases are described in terms of zonal mean profiles and latitudinal distributions. The period selected for study is January-May 1979, when a major stratospheric warming occurred.

Russell, J. M., III↗

NASA NTRS1983

Interpretation of radar returns from clear air: Discrimination against clutter

Different kinds of inteference may cause problems to the proper detection and analysis of the atmospheric signals, when using VHF and UHF radars. These are separated into passive and active contributions. Passive contributions are existent in the receiving system without the radar transmitter switched on. Active contributions are due to scatter and reflection of the own transmitted radar signal from unwanted targets, which are called clutter. Of major importance to radar systems are active interference contributions. Different methods can be applied for elimination or at least suppressing unwanted effects. These are; (1) Directional filtering, i.e., applying optimum suppression of antenna sidelobes, (2) Range filtering, i.e., suppressing unwanted signals only in affected range gates, (3) selection by amplitude distributions, (4) Temporal filtering, i.e., recognizing typical temporal variations of the clutter signals, through spectral characteristics, and applying matched filters.

Rottger, J.↗

NASA NTRS1986

Application of intersatellite links to domestic satellite systems

The results of a study on intersatellite link (ISL) applications for domestic satellite communications are presented. It was determined if any technical, economic, or performance benefits could be gained by introducing intersatellite links into a domestic satellite communication network. Several key systems issues of domestic ISL's are addressed. These include the effect of a skewed traffic distribution on the selection of ISL satellite orbit locations, tolerable satellite spacing, and crosslink traffic-handling requirements. An ISL technology assessment is made by performing a parametric link analysis for several microwave and optical implementations. The impact of the crosslink on the end-to-end link performance is investigated for both regenerative and nonregenerative ISL architectures. A comparison is made between single satellite systems operating at C-, and Ku-bands and the corresponding ISL systems in terms of ground segment cost, space segment cost, and net link performance. Results indicate that ISL's can effectively expand the CONUS orbital arc, with a 60 GHz ISL implementation being the most attractive.

Ponchak, D. S.↗

NASA NTRS1986

Space station 20-kHz power management and distribution system

During the conceptual design phase a 20-kHz power distribution system was selected as the reference for the space station. The system is single-phase 400 VRMS, with a sinusoidal wave form. The initial user power level will be 75 kW with growth to 300 kW. The high-frequency system selection was based upon considerations of efficiency, weight, safety, ease of control, interface with computers, and ease of paralleling for growth. Each of these aspects will be discussed as well as the associated trade-offs involved. An advanced development program has been instituted to accelerate the maturation of the high-frequency system. Some technical aspects of the advanced development will be discussed.

Hansen, I. G.↗

NASA NTRS1986

Application of intersatellite links to domestic satellite systems

Ponchak, D. S.↗

NASA NTRS1986

Space Station 20-kHz power management and distribution system

During the conceptual design phase a 20-kHz power distribution system was selected as the reference for the Space Station. The system is single-phase 400 VRMS, with a sinusoidal wave form. The initial user power level will be 75 kW with growth to 300 kW. The high-frequency system selection was based upon considerations of efficiency, weight, safety, ease of control, interface with computers, and ease of paralleling for growth. Each of these aspects will be discussed as well as the associated trade-offs involved. An advanced development program has been instituted to accelerate the maturation of the high-frequency system. Some technical aspects of the advanced development will be discussed.

Hansen, Irving G.↗

NASA NTRS1988

Acoustically excited heated jets. 3: Mean flow data

This is Part 3 of a report on the excitability of heated jets under the influence of acoustic excitation. The effects of upstream internal acoustic excitation on jet mixing were described in Part 1. Part 2 described the effects of external excitation on flow mixing. Part 3 contains quantitative results from the measurements of mean Mach number and temperature and consists of radial profiles and centerline distributions measured at selected jet operating conditions for internally excited and unexcited jets. The mean flow data are presented in both graphical and tabulated forms. For the sake of completeness, this part contains temperature probe calibration curves also.

Lepicovsky, J.↗