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At least 253 records · Page 14

Stable high-pressure phases in the H-S system determined by chemically reacting hydrogen and sulfur

Synchrotron x-ray diffraction and Raman spectroscopy have been used to study the chemical reactions of molecular hydrogen (H 2 ) with sulfur (S) at high pressures. We find theoretically predicted Cccm and Im3¯m H 3 S to be the reaction products at 50 and 140 GPa, respectively. Im3¯m H 3 S is a stable crystalline phase above 140 GPa and it transforms to R 3 m H 3 S on pressure release below 140 GPa. Here, the latter phase is (meta)stable down to at least 70 GPa where it transforms to Cccm H 3 S upon annealing (T < 1300 K) to overcome the kinetic hindrance. Cccm H 3 S has an extended structure with symmetric hydrogen bonds at 50 GPa, and upon decompression it experiences a transformation to a molecular mixed H 2 S – H 2 structure below 40 GPa without any apparent change in the crystal symmetry.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Measurement of the Inclusive $t\bar{t}$ Production Cross Section in $p\bar{p}$ Collisions at $\sqrt{s}=1.96$ TeV and Determination of the Top Quark Pole Mass

The inclusive cross section of top quark-antiquark pairs produced in pp¯ collisions at s=1.96 TeV is measured in the lepton+jets and dilepton decay channels. The data sample corresponds to 9.7 fb-1 of integrated luminosity recorded with the D0 detector during Run II of the Fermilab Tevatron Collider. Employing multivariate analysis techniques we measure the cross section in the two decay channels and we perform a combined cross section measurement. For a top quark mass of 172.5 GeV, we measure a combined inclusive top quark-antiquark pair production cross section of σtt¯=7.26±0.13(stat)-0.50+0.57(syst) pb which is consistent with standard model predictions. We also perform a likelihood fit to the measured and predicted top quark mass dependence of the inclusive cross section, which yields a measurement of the pole mass of the top quark. The extracted value is mt=172.8±1.1(theo)-3.1+3.3(exp) GeV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Tevatron combination of single-top-quark cross sections and determination of the magnitude of the Cabibbo-Kobayashi-Maskawa matrix element $\bf V_{tb}$

In this study, we present the final combination of CDF and D0 measurements of cross sections for single-top-quark production in proton-antiproton collisions at a center-of-mass energy of 1.96 TeV. The data correspond to total integrated luminosities of up to 9.7 fb -1 per experiment. The t-channel cross section is measured to be σ t = 2.25$+0.29\atop{-0.31}$ pb. We also present the combinations of the two-dimensional measurements of the s- vs t-channel cross section. In addition, we give the combination of the s+t channel cross section measurement resulting in σ s+t = 3.30$+0.52\atop{-0.40}$ pb, without assuming the standard model value for the ratio σ s /σ t . The resulting value of the magnitude of the top-to-bottom quark coupling is |V tb |= 1.02$+0.06\atop{-0.05}$, corresponding to |V tb | > 0.92 at the 95% C.L.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Potential Resolution to the Doping Puzzle in Iron Pyrite: Carrier Type Determination by Hall Effect and Thermopower.

Pyrite FeS2 has outstanding potential as an earth-abundant, low-cost, nontoxic photovoltaic, but underperforms dramatically in solar cells. While the full reasons for this are not clear, one certain factor is the inability to understand and control doping in FeS2. This is exemplified by the widely accepted but unexplained observation that unintentionally doped FeS2 single crystals are predominantly n type, whereas thin films are p type. Here we provide a potential resolution to this "doping puzzle," arrived at via Hall effect, thermopower, and resistivity measurements on a large set of FeS2 single crystals and films that span five orders of magnitude in mobility. The results reveal three main findings. First, in addition to crystals, the highest mobility thin films in this study are shown to be definitively n type, from both Hall effect and thermopower. Second, as mobility decreases an apparent crossover to p type occurs, first in thermopower, then in Hall measurements. This can be understood, however, in terms of the crossover from diffusive to hopping transport that is clearly reflected in resistivity. Third, universal behavior is found for both crystals and films, suggesting a common n dopant, possibly sulfur vacancies. We thus argue that n-type doping is facile in FeS2 films, that apparent p-type behavior in low mobility samples can be an artifact of hopping, and that the prevailing notion of predominantly p-type films must be revised. These conclusions have deep implications, both for interpretation of prior work on FeS2 solar cells and for the design of future studies.

Zhang, Xin↗