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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Development of High Alumina Glass Property Data for Hanford High-Level Waste Glass Models - 16231

Roughly half of the projected Hanford high-level waste batches will have waste loadings limited by relatively high concentration of Al2O3. Individual glasses have been formulated and tested to demonstrate that it is possible to increase the loading of these high-Al2O3 wastes in glass by as much as 50%. To implement such increases in waste loading in the Hanford Tank Waste Treatment and Immobilization Plant, the impact of composition on the properties of high-Al2O3 waste glasses must be quantified in the form of validated glass property-composition models. To collect the data necessary for glass property-composition models, a multi-phase experimental approach was developed. In the first phase of the study, a set of 46 glass compositions were statistically designed to most efficiently backfill existing data in the composition region for high-Al2O3 (15 to 30 wt%) waste glasses. The glasses were fabricated and key glass properties were tested: •Product Consistency Test (PCT) on quench (Q) and canister centerline cooled (CCC) samples •Toxicity Characteristic Leaching Procedure (TCLP) on Q and CCC samples •Crystallinity as a function of temperature (T) at equilibrium and of CCC samples •Viscosity and electrical conductivity as a function of T The measured properties of these glasses were compared to predictions from previously existing models developed over lower Al2O3 concentration ranges. Areas requiring additional testing and modeling were highlighted.

Vienna, John D.↗
DOE OSTI2016

Development of High Alumina Glass Property Data for Hanford High-Level Waste Glass Models - 16231

Roughly half of the projected Hanford high-level waste batches will have waste loadings limited by relatively high concentration of Al{sub 2}O{sub 3}. Individual glasses have been formulated and tested to demonstrate that it is possible to increase the loading of these high-Al{sub 2}O{sub 3} wastes in glass by as much as 50%. To implement such increases in waste loading in the Hanford Tank Waste Treatment and Immobilization Plant, the impact of composition on the properties of high-Al{sub 2}O{sub 3} waste glasses must be quantified in the form of validated glass property-composition models. To collect the data necessary for glass property-composition models, a multi-phase experimental approach was developed. In the first phase of the study, a set of 46 glass compositions were statistically designed to most efficiently backfill existing data in the composition region for high-Al{sub 2}O{sub 3} (15 to 30 wt%) waste glasses. The glasses were fabricated and key glass properties were tested: - Product Consistency Test (PCT) on quench (Q) and canister centerline cooled (CCC) samples - Toxicity Characteristic Leaching Procedure (TCLP) on Q and CCC samples - Crystallinity as a function of temperature (T) at equilibrium and of CCC samples - Viscosity and electrical conductivity as a function of T The measured properties of these glasses were compared to predictions from previously existing models developed over lower Al{sub 2}O{sub 3} concentration ranges. Areas requiring additional testing and modeling were highlighted. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Analysis of the Intrinsic Mid-infrared L band to Visible–Near-infrared Flux Ratios in Spectral Synthesis Models of Composite Stellar Populations

We analyze the intrinsic flux ratios of various visible–near-infrared filters with respect to 3.5 μm for simple and composite stellar populations (CSPs), and their dependence on age, metallicity, and star formation history (SFH). UV/optical light from stars is reddened and attenuated by dust, where different sightlines across a galaxy suffer varying amounts of extinction. Tamura et al. (2009) developed an approximate method to correct for dust extinction on a pixel-by-pixel basis, dubbed the “β{sub V}” method, by comparing the observed flux ratio to an empirical estimate of the intrinsic ratio of visible and ∼3.5 μm data. Through extensive modeling, we aim to validate the “β{sub V}” method for various filters spanning the visible through near-infrared wavelength range, for a wide variety of simple and CSPs. Combining Starburst99 and BC03 models, we built spectral energy distributions (SEDs) of simple (SSP) and composite (CSP) stellar populations for various realistic SFHs, while taking metallicity evolution into account. We convolve various 0.44–1.65 μm filter throughput curves with each model SED to obtain intrinsic flux ratios β{sub λ,0}. When unconstrained in redshift, the total allowed range of β{sub V,0} is 0.6–4.7, or almost a factor of eight. At known redshifts, and in particular at low redshifts (z ≲ 0.01), β{sub V,0} is predicted to span a narrow range of 0.6–1.9, especially for early-type galaxies (0.6–0.7), and is consistent with observed β{sub V} values. The β{sub λ} method can therefore serve as a first-order dust-correction method for large galaxy surveys that combine JWST (rest-frame 3.5 μm) and HST (rest-frame visible–near-IR) data.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1983

Simultaneous elastic and photoelastic calibration of birefringent orthotropic model materials

Transmission photoelastic analysis of composite models has been shown in recent years to be a viable stress analysis method for composite structures. However, difficulties in the fabrication of the model materials require the development of efficient mechanical and optical calibration procedures. In this paper, the methods for measuring elastic and photoelastic constants of composites are briefly reviewed. Then a new method, utilizing a relatively small calibration specimen, is described. In this method, electrical resistance strain gauges are mounted at selected points of a half-plane model and photoelastic measurements and strain readings are simultaneously taken. The data are processed by a least-squares procedure to yield the elastic and photoelastic constants. Comparison of results obtained by the proposed method with the results from conventional tests shows good agreement.

Prabhakaran, R.↗
DOE OSTI2017

High-Fidelity Microstructural Characterization and Performance Modeling of Aluminized Composite Propellant

Image processing and stereological techniques were used to characterize the heterogeneity of composite propellant and inform a predictive burn rate model. Composite propellant samples made up of ammonium perchlorate (AP), hydroxyl-terminated polybutadiene (HTPB), and aluminum (Al) were faced with an ion mill and imaged with a scanning electron microscope (SEM) and x-ray tomography (micro-CT). Properties of both the bulk and individual components of the composite propellant were determined from a variety of image processing tools. An algebraic model, based on the improved Beckstead-Derr-Price model developed by Cohen and Strand, was used to predict the steady-state burning of the aluminized composite propellant. In the presented model the presence of aluminum particles within the propellant was introduced. The thermal effects of aluminum particles are accounted for at the solid-gas propellant surface interface and aluminum combustion is considered in the gas phase using a single global reaction. In conclusion, properties derived from image processing were used directly as model inputs, leading to a sample-specific predictive combustion model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Integrated rheology model: Explosive Composition B-3

Composition B-3 (Comp B-3) is a high explosive formulation composed of 60/40wt% RDX (1,3,5-trinitroperhydro-1,3,5-triazine) /TNT (2,4,6 trinitrotoluene). Above approximately 78°C this formulation partially melts to form a multiphase system with solid RDX particles in a molten TNT matrix. This multiphase system presents a number of phenomena that influence its apparent viscosity. In an earlier study explosive Composition B-3 (Comp B-3, 60/40wt% RDX/TNT) was examined for evidence of yield stress using a non-isothermal falling ball viscometer and a yield stress model was proposed in this paper. An integrated viscosity model suitable for use in computational fluid dynamics (CFD) simulations is developed to capture the transition from a heterogeneous solid to a Bingham viscoplastic fluid. This viscosity model is used to simulate the motion of imbedded spheres falling through molten Comp B-3. Finally, comparison of the simulations to physical tests show agreement between the positions predicted by the model and the measured locations of the spheres as a function of temperature between 90C and 165C.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Enhanced Hanford Low-Activity Waste Glass Property Data Development (Phase 3)

This work was performed for the U.S. Department of Energy (DOE) Office of River Protection (ORP) to provide expert evaluation and experimental work in support of the River Protection Project vitrification technology development1. The long-term objective of this work is to expand the property-composition database for Hanford site low-activity waste (LAW) glasses and property-composition models to cover the balance of the mission for the Hanford Waste Treatment and Immobilization Plant (WTP). When this effort is complete, enhanced LAW glass property-composition models will be developed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1994

A Compositional Relevance Model for Adaptive Information Retrieval

There is a growing need for rapid and effective access to information in large electronic documentation systems. Access can be facilitated if information relevant in the current problem solving context can be automatically supplied to the user. This includes information relevant to particular user profiles, tasks being performed, and problems being solved. However most of this knowledge on contextual relevance is not found within the contents of documents, and current hypermedia tools do not provide any easy mechanism to let users add this knowledge to their documents. We propose a compositional relevance network to automatically acquire the context in which previous information was found relevant. The model records information on the relevance of references based on user feedback for specific queries and contexts. It also generalizes such information to derive relevant references for similar queries and contexts. This model lets users filter information by context of relevance, build personalized views of documents over time, and share their views with other users. It also applies to any type of multimedia information. Compared to other approaches, it is less costly and doesn't require any a priori statistical computation, nor an extended training period. It is currently being implemented into the Computer Integrated Documentation system which enables integration of various technical documents in a hypertext framework.

Mathe, Nathalie↗
NASA NTRS1995

Field lines and magnetic surfaces in a two-component slab/2D model of interplanetary magnetic fluctuations

A two-component model for the spectrum of interplanetary magnetic fluctuations was proposed on the basis of ISEE observations, and has found an intriguing level of application in other solar wind studies. The model fluctuations consist of a fraction of 'slab' fluctuations, varying only in the direction parallel to the locally uniform mean magnetic field B(0) and a complement of 2D (two-dimensional) fluctuations that vary in the directions transverse to B(0). We have developed an spectral method computational algorithm for computing the magnetic flux surfaces (flux tubes) associated with the composite model, based upon a precise analogy with equations for ideal transport of a passive scalar in planar two dimensional geometry. Visualization of various composite models will be presented, including the 80 percent 2D/ 20 percent slab model with delta B/B(0) approximately equals 1 and a minus 5/3 spectral law, that is thought to approximately represent a snapshot of solar wind turbulence. Characteristically, the visualizations show that flux tubes, even when defined as regular on some plane, shred and disperse rapidly as they are viewed along the parallel direction. This diffusive process, which generalizes the standard picture of field line random walk, will be discussed in detail. Evidently, the traditional picture that flux tubes randomize like strands of spaghetti with a uniform tangle along the axial direction is in need of modification.

Matthaeus, W. H.↗
NASA NTRS1977

Thermospheric temperature, density, and composition: New models

The models essentially consist of two parts: the basic static models, which give temperature and density profiles for the relevant atmospheric constituents for any specified exospheric temperature, and a set of formulae to compute the exospheric temperature and the expected deviations from the static models as a result of all the recognized types of thermospheric variation. For the basic static models, tables are given for heights from 90 to 2,500 km and for exospheric temperatures from 500 to 2600 K. In the formulae for the variations, an attempt has been made to represent the changes in composition observed by mass spectrometers on the OGO 6 and ESRO 4 satellites.

Jacchia, L. G.↗
NASA NTRS1990

Nondimensional impact models for composite laminates

The equations governing the problem of low-velocity impact of a simply supported rectangular laminated plate are nondimensionalized such that the problem is defined in terms of five dimensionless parameters. A parametric study using the Graeco-Latin Factorial Plan is performed. Semi-empirical formulas for maximum impact force, impact duration, and maximum back surface strains are obtained. It is found that some of the simple impact models provide the bounds for the case of impact on a finite extent plate.

Sankar, B. V.↗
DOE OSTI2019

Modeling Electrolyte Composition Effects on Anion-Exchange-Membrane Water Electrolyzer Performance

Anion-exchange-membrane (AEM) water electrolysis could allow inexpensive and greener hydrogen production than other alternatives, such as steam methane reforming. To increase performance, hydroxide salts are often added to the water feed, with the tradeoff of corrosivity and complexity. Recently, carbonate salts that are less corrosive have shown promise, but their specific functionality remains unknown. In this paper, we use a mathematical model to compare an AEM electrolyzer with added potassium carbonate to an AEM electrolyzer with added potassium hydroxide. Here, we show that the conductivity of the carbonate-form membrane has little impact on the performance of the device, but that carbonate ions replace hydroxide in the ionomer, which creates a Nernstian voltage difference across the membrane. The replacement of hydroxide anions with carbonate also reduces utilization of the catalyst in the anode, resulting in an additional voltage loss.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Office of River Protection Advanced Low-Activity Waste Glass Research and Development Plan

The U.S. Department of Energy Office of River Protection (ORP) has initiated and leads an integrated Advanced Waste Glass (AWG) program to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product performance requirements. The integrated ORP program is focused on providing a technical, science-based foundation for making key decisions regarding the successful operation of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) facilities in the context of an optimized River Protection Project (RPP) flowsheet. The fundamental data stemming from this program will support development of advanced glass formulations, key product performance and process control models, and tactical processing strategies to ensure safe and successful operations for both the low-activity waste (LAW) and high-level waste vitrification facilities. These activities will be conducted with the objective of improving the overall RPP mission by enhancing flexibility and reducing cost and schedule. The purpose of this advanced LAW glass research and development plan is to identify the near-term, mid-term, and longer-term research and development activities required to develop and validate advanced LAW glasses, property-composition models and their uncertainties, and an advanced glass algorithm to support WTP facility operations, including both Direct Feed LAW and full pretreatment flowsheets. Data are needed to develop, validate, and implement 1) new glass property-composition models and 2) a new glass formulation algorithm. Hence, this plan integrates specific studies associated with increasing the Na2O and SO3/halide concentrations in glass, because these components will ultimately dictate waste loadings for LAW vitrification. Of equal importance is the development of an efficient and economic strategy for 99Tc management. Specific and detailed studies are being implemented to understand the fate of Tc throughout the WTP flowsheet and the underlying mechanisms that dictate its partitioning between streams within the LAW vitrification facility. These studies are aimed at increasing the single-pass Tc retention in glass and the potential use of high-temperature mineral phases to capture Tc. The Tc-bearing mineral phases would be thermally stable and resistant to Tc release during feed melting reactions or they could serve as alternative waste forms. The LAW glass research and development is focused on reducing the total volume of LAW glass produced and minimizing the impact of (or potentially eliminating) the need for recycle.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Effect of Manufacturing-Induced Defects on Reliability of Composite Wind Turbine Blades

In support of DOE's efforts on developing affordable, reliable domestic wind power, this ARRA project brought together a strong, complementary team from academia (University of Massachusetts Lowell), two DOE laboratories (NREL and Sandia), and a major wind turbine blade manufacturer (TPI) to address one of the key issues affecting wind power cost and reliability manufacturing-induced defects in the blades. The complexity of this problem required the assembled team's expertise in materials specifically textile and composite structures finite element modeling, composites manufacturing, mechanical characterization, structural dynamics, nondestructive inspection (NDI) and structural health monitoring (SHM), sensors, and wind turbine blade testing. This final report summarizes the results of this project.

17 WIND ENERGY↗
NASA NTRS1985

The mass transfer rate in X1916-053 - It is driven by gravitational radiation?

A 50-minute period for a binary system harboring an X-ray burster would allow several alternatives for the mass-giving secondary, including an H-shell burning-plus-He degenerate core composite model. The burst properties of X1916-053 are presently used to argue against the He degenerate as well as the He main sequence solutions and to estimate whether, for any of the other solutions, the mass transfer rate could be consistent with that expected from gravitational radiation (GR). Within an uncertainty of a factor of 2, the transfer rate for the composite model solution is consistent with gravitational radiation, but enhancement by other mechanisms should be investigated.

Swank, J. H.↗
DOE OSTI2022

A new woven composite constitutive model validated by shock wave experiments

In this paper, we present results of plate impact simulations of shock compressed woven glass fiber-reinforced plastic (GRP) performed using the Arbitrary Lagrangian–Eulerian three-dimensional finite element code. A hyperelastic large-strain-based empirical Continuum Damage Mechanics (CDM) formulation is employed to describe damage initiation and growth in the shock-compressed GRP. The model parameters calibration scheme utilizes the Velocity Interferometer System for Any Reflector normal particle velocity measurements at the free surface of the GRP target plates. The impact velocity in the experiments ranged from 8.5 to 418 m/s. The finite element model considered planar 0°/90° bidirectional plies with an individual ply thickness of 0.68 mm, stacked to reach a total laminate thickness of 6.8 mm. The anisotropic elastic strains were estimated from the experimentally determined tetragonal symmetry stiffness matrix for the GRP. The strain-based damage model captures several salient features observed in the measured free surface particle wave profiles, including the shock rise time, onset of Elastic—Elastic Cracking, and the shape of the nonlinear portion of the experimental particle velocity profiles. Furthermore, the CDM model predicts the dominant damage mode to be matrix microcracking due to shear and the associated bulk expansion (bulking) under the global compressive loading in the plate impact configuration.

42 ENGINEERING↗
NASA NTRS1995

Micromechanical models for textile composites

Numerical and analytical micromechanical models are presented to predict the thermoelastic behavior of a textile composite. In the numerical model, the unit-cell is discretized with finite elements, and periodic boundary conditions are imposed between opposite faces of the unit-cell. For a thin textile composite, stress gradients effects through the thickness are demonstrated. The consequent difference in the stiffness and strength behavior of thick and thin composites are discussed. The numerical model is implemented to predict 3-D thermo-elastic constants for a thick textile composite, and the plate thermo-mechanical properties for a thin textile composite. The numerical model is extended to compute the thermal residual microstresses due to processing to predict the composite failure envelopes. An analytical model - Selective Averaging Method (SAM) - is proposed, which is based on a judicious combination of stiffness and compliance averaging to estimate the 3-D elastic constants. Both the models are tested and verified for several examples by comparing the stiffness properties with elasticity solutions and available results.

Sankar, Bhavani V.↗