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All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

The Formation Age of Comets: Predicted Physical and Chemical Trends

Dust grains in Herbig Ae/Be stars are continuously replenished by infalling comets. The IR spectra of these cometary grains appear to evolve temporally from initially amorphous astronomical silicates in young protostars to crystalline olivine in much older sources. Crystalline olivine can only be produced from amorphous silicates on a time scale of months-to-years via thermal annealing at temperatures near 1000 K. Since such sustained high temperatures only occur near the central star, dust annealed at 1000 K in inner nebular regions must be continuously transported beyond the nebular snowline to be incorporated into the next generation of cometesimals. The average formation age of a comet can therefore be measured as a ratio of the annealed crystalline olivine dust component to the total dust content of the comet. Comets formed from nearly pristine interstellar materials early in the protostellar nebula stage will contain very little crystalline dust whereas comets formed towards the end of the accretion period will incorporate a much higher percentage of annealed silicate. It is unlikely that only dust grains circulate from the inner to the outer nebula; the gas associated with such dust should also find its way beyond the snowline. Since this gas and dust will have equilibrated in the higher pressure-temperature regime of the inner nebula, it will contain a much higher proportion of hydrocarbons and ammonia than more pristine interstellar ices. Therefore, in addition to a higher fraction of crystalline dust, later forming comets should also contain higher ratios of hydrocarbons to CO and ammonia to N2 than do those formed early in the history of the nebula.

Nuth, Joseph A., III↗
NASA NTRS2001

Production, Outflow Velocity, and Radial Distribution of H2O and OH in the Coma of Comet C/1995 O1 [Hale-Bopp] from Wide Field Imaging of OH

Observations of OH are a useful proxy of the water production rate (Q(sub H2O)) and outflow velocity (V(sub out)) in comets. We use wide field images taken on 03/28/1997 and 04/08/1997 that capture the entire scale length of the OH coma of comet C/1995O1 (Hale-Bopp) to obtain Q(sub H2O) from the model-independent method of aperture summation. We also extract the radial brightness profile of OH 3080 angstroms out to cometocentric distances of up to 10(exp 6) km using an adaptive ring summation algorithm. Radial profiles are obtained as azimuthal averages and in quadrants covering different position angles relative to the comet-Sun line. These profiles are fit using both fixed and variable velocity two-component spherical expansion models to determine VOH with increasing distance from the nucleus. The OH coma of Hale-Bopp was more spatially extended than in previous comets, and this extension is best matched by a variable acceleration of H2O and OH that acted across the entire coma, but was strongest within 1-2 x 10(exp 4) km from the nucleus. This acceleration led to VOH at 10(exp 6) km that was 2-3 times greater than that obtained from a 1P/Halleytype comet at 1 AU, a result that is consistent with gas-kinetic models, extrapolation from previous observations of OH in comets with Q(sub H2O) > 10(exp 29)/s, and radio measurements of the outer coma Hale-Bopp OH velocity profile. When the coma is broken down by quadrant, we find an azimuthal asymmetry in the radial distribution that is characterized by an increase in the spatial extent of OH in the region between the orbit-trailing and anti-sunward directions. Model fits to this area and comparison with radio OH measurements suggest greater acceleration in this region, with VOH UP to 1.5 times greater at 10(exp 6) km radial distance than elsewhere in the coma.

Harris, Walter M.↗
NASA NTRS2003

Production, Outflow Velocity, and Radial Distribution of H2O and OH in the Coma of Comet C/1995 O1 [Hale-Bopp] from Wide Field Imaging of OH

Observations of OH are a useful proxy of the water production rate (Q(sub H2O)) and outflow velocity (V(sub out)) in comets. From wide field images taken on 03/28/1997 and 04/08/1997 that capture the entire scale length of the OH coma of comet C/1995 O1 (Hale-Bopp), we obtain Q(sub H2O) from the model-independent method of aperture summation. With an adaptive ring summation algorithm, we extract the radial brightness distribution of OH 0-0 band emission out to cometocentric distances of up to 10(exp 6) km, both as azimuthal averages and in quadrants covering different position angles relative to the comet-Sun line. These profiles are fit using both fixed and variable velocity 2-component spherical expansion models to estimate V(sub OH) with increasing distance from the nucleus. The OH coma of Hale-Bopp was more spatially extended than previous comets, and this extension is best matched by a variable acceleration of H2O and OH that acted across the entire coma, but was strongest within 1-2 x 10(exp 4) km from the nucleus. Our models indicate that V(sub OH) at the edge of our detectable field of view (10(exp 6) km) was approx. 2-3 times greater in Hale-Bopp than for a 1P/Halley-class comet at 1 AU, which is consistent with the results of more sophisticated gas-kinetic models, extrapolation from previous observations of OH in comets with Q(sub H2O) greater than 10(exp 29)/s , and direct radio measurements of the outer coma Hale-Bopp OH velocity. The most probable source of this acceleration is thermalization of the excess energy of dissociation of H2O and OH over an extended collisional coma. When the coma is broken down by quadrants in position angle, we find an azimuthal asymmetry in the radial distribution that is characterized by an increase in the spatial extent of OH in the region between the orbit-trailing and anti-sunward directions. Model fits specific to this area and comparison with radio OH measurements suggest greater acceleration here, with V(sub OH) approx. 1.5 times greater at a 10(exp 6) km cometocentric distance than elsewhere in the coma. We discuss several mechanisms that may have acted within the coma to produce the observed effect.

Harris, Walter M.↗
NASA NTRS2003

Comet Observations with SIRTF

Comet observations are included in the programs of the Guaranteed Time Observers (GTO) on the Space Infrared Telescope Facility (SIRTF), scheduled to be in space and operational for five years beginning in late 2003. SIRTF is a cryogenic telescope with three basic instruments for imaging, photometry and spectroscopy from 3.6 m to 160 m. All of these capabilities will be used in studies of comets. The intent is to study the infrared radiation (emission) from comets (and dust tails, where relevant) in all stages of evolution, starting with Kuiper Belt objects and Centaurs (thermal emission at 24,70, and 160 m to derive dimensions and albedos). Active comets will be observed spectroscopically and in deep thermal images. Several known or suspected extinct comets will be observed spectroscopically (5-37 m) for information on their surface compositions. There are opportunities for Guest Observers (GO) to propose additional comet work. .

Cruikshank, Dale P.↗
NASA NTRS2003

Solar Sail Application to Comet Nucleus Sample Return

Many comets have perihelions at distances within 1.0 Astronomical Unit (AU) from the sun. These comets typically are inclined out of the ecliptic. We propose that a solar sail spacecraft could be used to increase the inclination of the orbit to match that of these 1.0 AU comets. The solar sail spacecraft would match the orbit velocity for a short period of time, which would be long enough for a container to be injected into the comet's nucleus. The container would be extended from a long durable tether so that the solar sail would not be required to enter into the potentially degrading environment of the comet s atmosphere. Once the container has been filled with sample material, the tether is retracted. The solar sail would then lower its inclination and fly back to Earth for the sample return. In this paper, we describe the selection of cometary targets, the mission design, and the solar sailcraft design suitable for sail-comet rendezvous as well as possible rendezvous scenarios.

Taylor, Travis S.↗
NASA NTRS2003

Interaction of Comets and the Solar Wind

We had originally planned to analyze UVCS observations of Comet Machholz, but we obtained higher quality observations of Comet Kudo-Fujikawa in January 2003 at its 0.19 AU perihelion. Besides a large and rapidly increasing water outgassing rate, we detected a bright tail in doubly ionized carbon. The amount of carbon was greater than could be accounted for by GO photodissociation, and we attribute the carbon to evaporation of organics from dust. A spectacular disconnection event was apparent in the C III tail, and it coincides within the uncertainties with the position of the heliospheric current sheet. A paper is in press in Science, and it will be the subject of a press release. We are also analyzing two sungrazing comets. Comet C/2001 C2 shows evidence for sub-fragments and for a very long lasting source of neutrals, which we tentatively identify as evaporation of pyroxene dust grains. Comet C/2002 S2 shows a sudden 2 magnitude drop in optical brightness and an equally sudden recovery. UVCS observations during that time show a steadily increasing outgassing rate. We have derived solar wind densities for both comets, but we are still sorting out the ambiguities involving the fragmentation and optical behavior. We are collaborating with Philippe Lamy on the LASCO measurements.

Wagner, William↗
NASA NTRS1996

Spectroscopic evidence for interstellar ices in comet Hyakutake

Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar nebula. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

Non-NASA Center↗
NASA NTRS2005

Evidence for Liquid Water on Comets

We have reexamined the arguments for the existence of liquid water on comets, and believe that recent cometary flybys along with pre-Giotto data support its presence on short-period comets. Liquid water would affect cometary dynamics, leaving distinct signatures in precession, orbital dynamics, and potential splitting of comets. Liquid water geysers would affect cometary atmosphere, dust evolution, and non-gravitational forces that perturb the orbit. Liquid water would affect the composition of both the interior and exterior of the comet, producing geologic effects consistent with recent flyby photographs. And most importantly, liquid water suppork the growth of lifeforms, which would make a comet a biofriendly incubator for interplanetary transport. The major objection against liquid water is the necessity of a pressure vessel to prevent sublimation into space. We discuss how such a pressure vessel could naturally evolve as a pristine comet makes its first journey inside the orbit of Mars, and suggest that this type of vessel was observed by Giotto, Deep Space I, and Stardust.

Sheldon, Robert↗
NASA NTRS2005

CoMET: Cost and Mass Evaluation Tool for Spacecraft and Mission Design

New technology in space exploration is often developed without a complete knowledge of its impact. While the immediate benefits of a new technology are obvious, it is harder to understand its indirect consequences, which ripple through the entire system. COMET is a technology evaluation tool designed to illuminate how specific technology choices affect a mission at each system level. COMET uses simplified models for mass, power, and cost to analyze performance parameters of technologies of interest. The sensitivity analysis that CoMET provides shows whether developing a certain technology will greatly benefit the project or not. CoMET is an ongoing project approaching a web-based implementation phase. This year, development focused on the models for planetary daughter craft, such as atmospheric probes, blimps and balloons, and landers. These models are developed through research into historical data, well established rules of thumb, and engineering judgment of experts at JPL. The model is validated by corroboration with JpL advanced mission studies. Other enhancements to COMET include adding launch vehicle analysis and integrating an updated cost model. When completed, COMET will allow technological development to be focused on areas that will most drastically improve spacecraft performance.

Bieber, Ben S.↗
NASA NTRS2006

Comet Dust After Deep Impact

When the Deep Impact Mission hit Jupiter Family comet 9P/Tempel 1, an ejecta crater was formed and an pocket of volatile gases and ices from 10-30 m below the surface was exposed (A Hearn et aI. 2005). This resulted in a gas geyser that persisted for a few hours (Sugita et al, 2005). The gas geyser pushed dust grains into the coma (Sugita et a1. 2005), as well as ice grains (Schulz et al. 2006). The smaller of the dust grains were submicron in radii (0-25.3 micron), and were primarily composed of highly refractory minerals including amorphous (non-graphitic) carbon, and silicate minerals including amorphous (disordered) olivine (Fe,Mg)2SiO4 and pyroxene (Fe,Mg)SiO3 and crystalline Mg-rich olivine. The smaller grains moved faster, as expected from the size-dependent velocity law produced by gas-drag on grains. The mineralogy evolved with time: progressively larger grains persisted in the near nuclear region, having been imparted with slower velocities, and the mineralogies of these larger grains appeared simpler and without crystals. The smaller 0.2-0.3 micron grains reached the coma in about 1.5 hours (1 arc sec = 740 km), were more diverse in mineralogy than the larger grains and contained crystals, and appeared to travel through the coma together. No smaller grains appeared at larger coma distances later (with slower velocities), implying that if grain fragmentation occurred, it happened within the gas acceleration zone. These results of the high spatial resolution spectroscopy (GEMINI+Michelle: Harker et 4. 2005, 2006; Subaru+COMICS: Sugita et al. 2005) revealed that the grains released from the interior were different from the nominally active areas of this comet by their: (a) crystalline content, (b) smaller size, (c) more diverse mineralogy. The temporal changes in the spectra, recorded by GEMIM+Michelle every 7 minutes, indicated that the dust mineralogy is inhomogeneous and, unexpectedly, the portion of the size distribution dominated by smaller grains has a more diverse mineralogy. The lower spatial resolution, high sensitivity Spitzer IRS data reveal resonances of refractory minerals (those seen by GEMINI+Michelle plus ortho-pyroxene)) as well resonances that can be attributed to phillosilicates (layer lattice silicates such as Montmorillonite) (Lisse et al. 2006). Pre- and post-impact, micron to submicron grains were deciphered to be present in the coma by the modeling the high spatial resolution images to account for nucleus plus inner coma fluxes (Wooden et al. 2005, 2006; Harker et al. 2005, 2006a). Note also that crystalline silicates were released from the interior of 73P-B/SW-3 as it disintegrated (Harker et al. 2006b). From the Deep Impact and the disintegration of 73P-B, we are led to ask the questians: Why is the mineralogy of the dust released from a volatile-rich pocket beneath the surface different from the dust that is released from the nominally active areas? Could the most volatile pockets be exhausted quickly? Why would crystalline silicates be associated with more volatile materials? Perhaps the structure of the comet is so inhomogeneous, e.g., the layered pile mode2 of the nucleus (Belton et al. 2006), that a reservoir of crystalline silicate and submicron grains just happens to not be released by the nominally active areas of comet 9P? Perhaps comets lose matter through their mantles from below their surfaces, thus preserving ancient topographic structures and radiation damaged silicates and carbon? We will discuss and ponder different scenarios. We will discuss future directions for coordinated observations of JF comets.

Wooden, Diane H.↗
NASA NTRS2007

Comets, Carbonaceous Meteorites, and the Origin of the Biosphere

Evidence for indigenous microfossils in carbonaceous meteorites suggests that the paradigm of the endogenous origin of life on Earth should be reconsidered. It is now widely accepted that comets and carbonaceous meteorites played an important role in the delivery of water, organics and life critical biogenic elements to the early Earth and facilitated the origin and evolution of the Earth's Biosphere. However; the detection of embedded microfossils and mats in carbonaceous meteorites implies that comets and meteorites may have played a direct role in the delivery of intact microorganisms and that the Biosphere may extend far into the Cosmos. Recent space observations have found the nuclei of comets to have very low albedos (approx.0.03) and. these jet-black surfaces become very hot (T approx. 400 K) near perihelion. This paper reviews recent observational data-on comets and suggests that liquid water pools could exist in cavities and fissures between the internal ices and rocks and the exterior carbonaceous crust. The presence of light and liquid water near the surface of the nucleus enhances the possibility that comets could harbor prokaryotic extremophiles (e.g., cyanobacteria) capable of growth over a wide range of temperatures. The hypothesis that comets are the parent bodies of the CI1 and the CM2 carbonaceous meteorites is advanced. Electron microscopy images will be presented showing forms interpreted as indigenous-microfossils embedded' in freshly. fractured interior surfaces of the Orgueil (CI1) and Murchison (CM2) meteorites. These forms are consistent in size and morphologies with known morphotypes of all five orders of Cyanobacteriaceae: Energy Dispersive X-ray Spectroscopy (EDS) elemental data shows that the meteoritic forms have anomalous C/O; C/N; and C/S as compared with modern extremophiles and cyanobacteria. These images and spectral data indicate that the clearly biogenic and embedded remains cannot be interpreted as recent biological contaminants and'therefore are indigenous'microfossils in the meteorites.

Hoover, Richard B.↗
NASA NTRS2011

Ground-Based Centimeter, Millimeter, and Submillimeter Observations of Comet 103P/Hartley 2

Comets provide important clues to the physical and chemical processes that occurred during the formation and early evolution of the Solar System, and could also have been important for initiating prebiotic chemistry on the early Earth [1]. Comets are comprised of molecular ices, that may be pristine interstellar remnants of Solar System formation, along with high-temperature crystalline silicate dust that is indicative of a more thermally varied history in the protosolar nebula [2]. Comparing abundances of cometary parent volatiles, and isotopic fractionation ratios, to those found in the interstellar medium, in disks around young stars, and between cometary families, is vital to understanding planetary system formation and the processing history experienced by organic matter in the so-called interstellar-comet connection [3]. We have conducted observations, at primarily millimeter and submillimeter wavelengths, where molecular emission is easily resolved, towards comets to determine important cosmogonic quantities, such as the ortl1o:pal'a ratio and isotope ratios, as well as probe the origin of cometary organics. Comets provide important clues to the processes that occurred during the formation and early evolution of the Solar System. Past observations, as well as laboratory measurements of cometary material obtained from Stardust, have shown that comets appear to contain a mixture of the products from both interstellar and nebular chemistries. A major observational challenge in cometary science is to quantify the extent to which chemical compounds can be linked to either reservoir.

Milam, S. N.↗
NASA NTRS2011

Interpreting Methanol v(sub 2)-Band Emission in Comets Using Empirical Fluorescence g-Factors

For many years we have been developing the ability, through high-resolution spectroscopy targeting ro-vibrational emission in the approximately 3 - 5 micrometer region, to quantify a suite of (approximately 10) parent volatiles in comets using quantum mechanical fluorescence models. Our efforts are ongoing and our latest includes methanol (CH3OH). This is unique among traditionally targeted species in having lacked sufficiently robust models for its symmetric (v(sub 3) band) and asymmetric (v(sub 2) and v(sub 9) bands) C-H3 stretching modes, required to provide accurate predicted intensities for individual spectral lines and hence rotational temperatures and production rates. This has provided the driver for undertaking a detailed empirical study of line intensities, and has led to substantial progress regarding our ability to interpret CH3OH in comets. The present study concentrates on the spectral region from approximately 2970 - 3010 per centimeter (3.367 - 3.322 micrometer), which is dominated by emission in the (v(sub 7) band of C2H6 and the v(sub 2) band of CH3OH, with minor contributions from CH3OH (v(sub 9) band), CH4 (v(sub 3)), and OH prompt emissions (v(sub 1) and v(sub 2)- v(sub 1)). Based on laboratory jet-cooled spectra (at a rotational temperature near 20 K)[1], we incorporated approximately 100 lines of the CH3OH v(sub 2) band, having known frequencies and lower state rotational energies, into our model. Line intensities were determined through comparison with several comets we observed with NIRSPEC at Keck 2, after removal of continuum and additional molecular emissions and correcting for atmospheric extinction. In addition to the above spectral region, NIRSPEC allows simultaneous sampling of the CH3OH v(sub 3) band (centered at 2844 per centimeter, or 3.516 micrometers and several hot bands of H2O in the approximately 2.85 - 2.9 micrometer region, at a nominal spectral resolving power of approximately 25,000 [2]. Empirical g-factors for v(sub 2) lines were based on the production rate as determined from the v(sub 3) Q-branch intensity; application to comets spanning a range of rotational temperatures (approximately 50 - 90 K) will be reported. This work represents an extension of that presented for comet 21P/Giacobini-Zinner at the 2010 Division for Planetary Sciences meeting [3]. Our empirical study also allows for quantifying CH3OH in comets using IR spectrometers for which the v(sub 3) and v(sub 2) bands are not sampled simultaneously, for example CSHELL/NASA IRTF or CRIRES/VLT.

DiSanti, Michael↗
NASA NTRS2012

Radio Observations of Organics in Comets

A major observational challenge in cometary science is to quantify the extent to which chemical compounds can be linked to either interstellar or nebular chemistry. Recently, there have been complimentary observations from multiple facilities to try to unravel the chemical complexity of comets and their origins. Incorporating results from various techniques can gain further insight into the abundances, production rates, distributions, and formation mechanisms of molecules in these objects [I]. Such studies have provided great detail towards molecules with a-typical chemistries, such as H2CO [2]. We report multiwavelength spectral observations of comets from two dynamical families including the JFC 103P/Hartley 2 and a long period comet C/2009 PI (Garradd) with the Arizona Radio Observatory's SMT and 12-m telescopes, as well as the NRAO Greenbank telescope, and the James Clerk Maxwell Telescope. Multiple parent volatiles (e.g. HCN, CH30H, CO) as well as daughter products (e.g, CS and 01-1) have been detected in these objects. We will present a comparison of molecular abundances in these comets to those observed in others, supporting a long-term effort of building a comet taxonomy based on composition. Previous work has revealed a range of abundances of parent species (from "organics-poor" to "organics-rich") with respect to water among comets [3,4,5], however the statistics are not well constrained.

Milam, Stefanie N.↗
NASA NTRS2012

The Rotation Temperature of Methanol in Comet 103P/Hartley 2

Considered to be relics from Solar System formation, comets may provide the vital information connecting Solar Nebula and its parent molecular cloud. Study of chemical and physical properties of comets is thus important for our better understanding of the formation of Solar System. In addition, observing organic molecules in comets may provide clues fundamental to our knowledge on the formation of prebiotically important organic molecules in interstellar space, hence, may shed light on the origin of life on the early Earth. Comet 103PIHartley 2 was fIrst discovered in 1986 and had gone through apparitions in 1991, 1997, and 2004 with an orbital period of about 6 years, before its latest return in 2010. 2010 was also a special year for Comet 103PIHartley 2 because of the NASA EPOXI comet-flyby mission.

Chuang, Yo-Ling↗
NASA NTRS2012

Development of Primary Volatile Production in COMET C/20O9 Pl (GARRADD) During its 2011-2O12 Apparition

We quantified primary volatiles in comet C/2009 Pl (Garradd) through pre- and post-perihelion observations acquired during its apparition in 2011-12 [1,2,3]. Detected volatiles include H2O, CO, CH4, C2H2, C2H6, HCN, NH3, H2CO, and CH3OH. We present production rates and chemical abundance ratios (relative to water) for all species, and I-D spatial profiles for multiple primary volatiles. We discuss these findings in the context of an emerging taxonomy based on primary volatiles in comets [4]. We used three spectrometer/telescope combinations. On UT 20ll August 7 (Rh 2.4 AU) and September 17-21 (Rh 2.0 AU), we used CRIRES at ESO's Very Large Telescope (VLT) [1]. On September 8 and 9 (Rh 2.1 AU), we used NIRSPEC at Keck-2 and CSHELL at IRTF [2]. Using NIRSPEC on October 13 and 2012 January 08 (Rh 1.83 and 1.57 AU, respectively), we detected nine primary volatiles pre-perihelion, and six post-perihelion [3]. CO was enriched in Garradd while C2H2 was strongly depleted. C2H6 and CH3OH displayed abundances close to those measured for the majority of Oort cloud comets observed to date. The high fractional abundance of CO identifies comet C12009 P1 as a CO-rich comet. Spatial profiles revealed notable differences among individual primary species. Given the relatively large heliocentric distance of C/2009 Pl, we explored the effect of water not being fully sublimated within our field of view and we identi$, the "missing" water fraction needed to reconcile the retrieved abundance ratios with the mean values found for "organics-normal" comets.

Mumma, M. J.↗
NASA NTRS2011

Navigation of the EPOXI Spacecraft to Comet Hartley 2

On November 4, 2010, the EPOXI spacecraft flew by the comet Hartley 2, marking the fourth time that a NASA spacecraft successfully captured high resolution images of a cometary nucleus. EPOXI is the extended mission of the Deep Impact mission, which delivered an impactor on comet Tempel-1 on July 4, 2005. EPOXI officially started in September 2007 and eventually took over 3 years of flight time and had 3 Earth gravity assists to achieve the proper encounter conditions. In the process, the mission was redesigned to accommodate a new comet as the target and changes in the trajectory to achieve better imaging conditions at encounter. Challenges in navigation of the spacecraft included precision targeting of several Earth flybys and the comet encounter, uncertainties in determining the ephemeris of the comet relative to the spacecraft, and the high accuracy trajectory knowledge needed to image the comet during the encounter. This paper presents an overview of the navigation process used for the mission.

Deep Impact (DI)↗
NASA NTRS2016

Comet Dust: The Diversity of "Primitive" Particles and Implications

Comet dust is primitive and shows significant diversity. Our knowledge of the properties of primitive particles has expanded significantly through microscale investigations of cosmic dust samples ( IDP's(Interplanetary Dust Particles) and AMM's (Antarctic Micrometeorites)) and of comet dust samples (Stardust and Rosetta's COSIMA), as well as through remote sensing (spectroscopy and imaging) via Spitzer and via spacecraft encounters with 103P/Hartley 2 and 67P/Churyumov-Gerasimenko. Microscale investigations show that comet dust and cosmic dust are particles of unequilibrated materials, including aggregates of materials unequilibrated at submicron scales. We call unequilibrated materials "primitive" and we deduce they were incorporated into ice-rich (H2O-, CO2-, and CO-ice) parent bodies that remained cold, i.e., into comets, because of the lack of aqueous or thermal alteration since particle aggregation; yet some Stardust olivines suggest mild thermal metamorphism. Primitive particles exhibit a diverse range of: structure and typology; size and size distribution of constituents; concentration and form of carbonaceous and organic matter; D-, N-, and O- isotopic enhancements over solar; Mg-, Fe-contents of the silicate minerals; the compositions and concentrations of sulfides, and of less abundant mineral species such as chondrules, CAIs and carbonates. The uniformity within a group of samples points to: aerodynamic sorting of particles and/or particle constituents; the inclusion of a limited range of oxygen fugacities; the inclusion or exclusion of chondrules; a selection of organics. The properties of primitive particles imply there were disk processes that resulted in different comets having particular selections of primitive materials. The diversity of primitive particles has implications for the diversity of materials in the protoplanetary disk present at the time and in the region where the comets formed.

Wooden, Diane H.↗