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At least 253 records · Page 14

Convergence Analysis of a Cascade Architecture Neural Network

In this paper, we present a mathematical foundation, including a convergence analysis, for cascading architecture neural networks. From this, a mathematical foundation for the casade correlation learning algorithm can also be found. Furthermore, it becomes apparent that the cascade correlation scheme is a special case of an efficient hardware learning algorithm called Cascade Error Projection.

Neural Network↗

Recent progress in development of mid-IR interband cascade lasers

Type-II interband cascade lasers are promising in becoming efficient and compact mid-infrared light sources for many applications. Significant progress toward such a goal has recently been made in terms of lowering their threshold current densities and raising operation temperature. Also, continuous wave operation of single-mode distributed feedback interband cascade lasers has been demonstrated. We review the recent progress of the Sb-based mid-IR interband cascade lasers and present some latest results.

lasers↗

Cascaded Photoenhancement: Implications for Photonic Chemical and Biological Sensors

Our analysis shows that coupling of gold nanoparticles to microspheres will evoke a cascading effect from the respective photoenhancement mechanisms. We refer to this amplification process as cascaded photoenhancement, and the resulting cavity amplification of surface-enhanced Raman scattering (SERS) and fluorescence as CASERS and CAF, respectively. Calculations, based on modal analysis of scattering and absorption by compound spheres, presented herein indicate that the absorption cross sections of metal nanoparticles immobilized onto dielectric microspheres can be greatly enhanced by cavity resonances in the microspheres without significant degradation of the resonators. Gain factors associated with CSP of 10(exp 3) - 10(exp 4) are predicted for realistic experimental conditions using homogenous microspheres. Cascaded surface photoenhancement thus has the potential of dramatically increasing the sensitivities of fluorescence and vibrational spectroscopies.

Fuller, Kirk A.↗

Heat cascading regenerative sorption heat pump

A simple heat cascading regenerative sorption heat pump process with rejected or waste heat from a higher temperature chemisorption circuit (HTCC) powering a lower temperature physisorption circuit (LTPC) which provides a 30% total improvement over simple regenerative physisorption compression heat pumps when ammonia is both the chemisorbate and physisorbate, and a total improvement of 50% or more for LTPC having two pressure stages. The HTCC contains ammonia and a chemisorbent therefor contained in a plurality of canisters, a condenser-evaporator-radiator system, and a heater, operatively connected together. The LTPC contains ammonia and a physisorbent therefor contained in a plurality of compressors, a condenser-evaporator-radiator system, operatively connected together. A closed heat transfer circuit (CHTC) is provided which contains a flowing heat transfer liquid (FHTL) in thermal communication with each canister and each compressor for cascading heat from the HTCC to the LTPC. Heat is regenerated within the LTPC by transferring heat from one compressor to another. In one embodiment the regeneration is performed by another CHTC containing another FHTL in thermal communication with each compressor. In another embodiment the HTCC powers a lower temperature ammonia water absorption circuit (LTAWAC) which contains a generator-absorber system containing the absorbent, and a condenser-evaporator-radiator system, operatively connected together. The absorbent is water or an absorbent aqueous solution. A CHTC is provided which contains a FHTL in thermal communication with the generator for cascading heat from the HTCC to the LTAWAC. Heat is regenerated within the LTAWAC by transferring heat from the generator to the absorber. The chemical composition of the chemisorbent is different than the chemical composition of the physisorbent, and the absorbent. The chemical composition of the FHTL is different than the chemisorbent, the physisorbent, the absorbent, and ammonia.

Jones, Jack A.↗

Aerodynamic Design of Axial-Flow Compressors. VII - Blade-Element Flow in Annular Cascades

Annular blade-element data obtained primarily from single-stage compressor installations are correlated over a range of inlet Mach numbers and cascade geometry. The correlation curves are presented in such a manner that they are related directly to the low-speed two-dimensional-cascade data of part VI of this series. Thus, the data serve as both an extension and a verification of the two-dimensional-cascade data. In addition, the correlation results are applied to compressor design.

Robbins, William H.↗

Cascade and Dissipation of Solar Wind Turbulence at Electron Scales: Whistlers or Kinetic Alfv\'en Waves?

Over the past few decades, large-scales solar wind (SW) turbulence has been studied extensively, both theoretically and observationally. Observed power spectra of the low frequency turbulence, which can be described in the magnetohydrodynamic (MHD) limit, are shown to obey the Kolmogorov scaling, $k"{ -5/3 }$, down the local proton gyrofrequency ($C{ci} \sim O.l$-Hz). Turbulence at frequencies above $C{ci}$ has not been thoroughly investigated and remains far less well understood. Above $C{ ci}$ the spectrum steepens to $\sim f"{ -2.5}$ and a debate exists as to whether the turbulence has become dominated by dispersive kinetic Alfven waves (KA W) or by whistler waves, before it is dissipated at small scales, In a case study Sahraoui et al., PRL (2009) have reported the first direct determination of the dissipation range of solar wind turbulence near the electron gyroscale using the high resolution Cluster magnetic and electric field data (up to $10"2$-Hz in the spacecraft reference frame). Above the Doppler-shifted proton scale $C{\rho i}$ a new inertial range with a scaling $\sim f"{ -2.3}$ has been evidenced and shown to remarkably agree with theoretical predictions of a quasi-two-dimensional cascade into KA W turbulence. Here, we use a wider sample of data sets of small scale SW turbulence under different plasma conditions, and investigate under which physical criteria the KA W (or the whistler) turbulence may be observed to carry out the cascade at small scales, These new observations/criteria are compared to the predictions on the cascade and the (kinetic) dissipation from the Vlasov theory. Implications of the results on the heating problem of the solar wind will be discussed.

Sahraoui, Fouad↗

Magnetic-Field-Assisted Terahertz Quantum Cascade Laser Operating up to 225 K

Advances in semiconductor bandgap engineering have resulted in the recent development of the terahertz quantum cascade laser1. These compact optoelectronic devices now operate in the frequency range 1.2-5 THz, although cryogenic cooling is still required2.3. Further progress towards the realization of devices operating at higher temperatures and emitting at longer wavelengths (sub-terahertz quantum cascade lasers) is difficult because it requires maintaining a population inversion between closely spaced electronic sub-bands (1 THz approx. equals 4 meV). Here, we demonstrate a magnetic-field-assisted quantum cascade laser based on the resonant-phonon design. By applying appropriate electrical bias and strong magnetic fields above 16 T, it is possible to achieve laser emission from a single device over a wide range of frequencies (0.68-3.33 THz). Owing to the suppression of inter-landau-level non-radiative scattering, the device shows magnetic field assisted laser action at 1 THz at temperatures up to 215 K, and 3 THz lasing up to 225 K.

Wade, A.↗

Pair Cascades and Deathlines in Offset Magnetic Dipole Fields

We investigate electron-positron pair cascades in a dipole magnetic field whose axis is offset from the neutron star center. In such a field geometry, the polar cap is displaced from the neutron star symmetry axis and the field line radius of curvature is modified. Using the modified parallel electric field near the polar cap of an offset dipole, we simulate pair cascades to determine the pair deathlines and pair multiplicities as a function of the offset parameter. We find that the pair multiplicity can change dramatically with a modest offset, with a significant increase on one side of the polar cap. Lower pair deathlines allow a larger fraction of the pulsar population, that include old and millisecond pulsars, to produce cascades with high multiplicity.

Harding, Alice↗

Pair Cascades and Deathlines in Magnetic Fields with Offset Polar Caps

We present results of electron-positron pair cascade simulations in a dipole magnetic field whose polar cap is offset from the dipole axis. In such a field geometry, the polar cap is displaced a small fraction of the neutron star radius from the star symmetry axis and the field line radius of curvature is modified. Using the modified parallel electric field near the offset polar cap, we simulate pair cascades to determine the pair deathlines and pair multiplicities as a function of the offset. We find that the pair multiplicity can change dr;unatically with a modest offset, with a significant increase on one side of the polar cap. Lower pair deathlines allow a larger fraction of the pulsar population, that include old and millisecond pulsars, to produce cascades with high multiplicity. The results have some important implications for pulsar particle production, high-energy emission and cosmic-ray contribution.

Harding, Alice K.↗

Aerodynamic Measurements of an Incidence Tolerant Blade in a Transonic Turbine Cascade

An overview of the recent facility modifications to NASA s Transonic Turbine Blade Cascade Facility and aerodynamic measurements on the VSPT incidence-tolerant blade are presented. This work supports the development of variable-speed power turbine (VSPT) speed-change technology for the NASA Large Civil Tilt Rotor (LCTR) vehicle. In order to maintain acceptable main rotor propulsive efficiency, the VSPT operates over a nearly 50% speed range from takeoff to altitude cruise. This results in 50 or more variations in VSPT blade incidence angles. The Transonic Turbine Blade Cascade Facility has the ability to operate over a wide range of Reynolds numbers and Mach numbers, but had to be modified in order to accommodate the negative incidence angle variation required by the LCTR VSPT operation. Details of the modifications are described. An incidence-tolerant blade was developed under an RTPAS study contract and tested in the cascade to look at the effects of large incidence angle and Reynolds number variations. Recent test results are presented which include midspan exit total pressure and flow angle measurements obtained at three inlet angles representing the cruise, take-off, and maximum incidence flight mission points. For each inlet angle, data were obtained at five flow conditions with exit Reynolds numbers varying from 2.12 106 to 2.12 105 and two isentropic exit Mach numbers of 0.72 and 0.35. Three-dimensional flowfield measurements were also acquired at the cruise and take-off points. The flowfield measurements were acquired using a five-hole and three-hole pneumatic probe located in a survey plane 8.6% axial chord downstream of the blade trailing edge plane and covering three blade passages. Blade and endwall static pressure distributions were also acquired for each flow condition.

McVetta, Ashlie B.↗

Photoproduction of Cascade Baryons Using the GlueX Detector at Jefferson Laboratory

Multi-strange baryons have played an important role in understanding the strong interaction. Despite their importance to advancing quantum chromodynamics (QCD), little is known about such hyperons due to the lack of a strange probe. Almost all knowledge of Cascade baryons today stems from kaon-nucleon interactions in bubble chamber experiments performed in the 1960s and 1970s. The 1980s saw advancement in electronics and computational resources allowing for higher statistic experiments such as the MultiParticle Spectrometer (MPS) at Brookhaven National Laboratory. From these previous experiments, the octet and decuplet ground states, Xi(1320) and Xi(1530) respectively, were well established with known properties and four excited states were well established. This research uses the GlueX experiment at Jefferson Laboratory to extend photoproduction cross section measurements for Xi(1320)- to higher beam energies to further understand the production mechanism, as well as to search for the first excited Cascade resonance observation in photoproduction through the decay Xi-* -> K-Lambda. The GlueX Spectrometer is a nearly hermetic detector used to study exclusive photoproduction reactions with photon beam energies up to 12 GeV. The first phase of GlueX running has recently been completed. Preliminary results for the total cross section and differential cross sections in terms of momentum transfer -t are shown within. Additionally, the first observation of an excited Cascade baryon, in particular Xi(1820)-, is shown.

Ernst, Ashley↗

Modeling and control of cascaded bridgeless multilevel rectifier under unbalanced load conditions

The goal of this project is to model and control a novel unidirectional cascaded multilevel bridgeless rectifier as an active front end in medium and high voltage applications. This topology has many advantages over a conventional cascaded H-bridge rectifier, such as lower implementation cost, higher reliability, and greater flexibility with similar power quality. The complete design process of the proposed converter is developed step by step in order to meet all the desired objectives. The steady-state mathematical model is used to develop a method for the voltage balancing of dc cells. Power factor analysis is discussed to mathematically derive requirements for the number of partially controlled and fully controlled H-bridges in the proposed H-bridge converter. Power loss, efficiency, and cost comparison studies between the traditional cascaded H-Bridge converter and the proposed bridgeless converter demonstrate the advantages. After exploring various well-established control methods, a novel control strategy is proposed to achieve dc voltage balancing, fast and robust grid synchronization, power factor correction, and elimination of zero crossing current distortion under both balanced and unbalanced load conditions. The converter can also be used for reactive power compensation in a grid tied power system if a sufficient number of fully controlled H-bridge modules are included. Processor-In-the-Loop (PIL) simulation has been the utilized to validate the performance of discrete control structure. Simulation and experimental results validate the models and control method.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Heat Transfer Experiments of a 1st Stage Blade Cascade for Supercritical CO2 Oxy-Combustion Turbine Application

The results of internally cooled 1st stage blade (S1B) cascade testing in a supercritical CO2 environment is presented. The turbine blade design has been previously established for the end application of an oxy-combustion turbine operating in the Allam-Fetvedt cycle with turbine inlet conditions of 305 bar and 1150°C. The internally cooled blade features leading edge (LE) region impingement cooling, mid-section ribbed serpentine passages, and a pin-finned trailing edge (TE) region before cooling ejection holes. The geometry for the tested blade cascade has a cooled central blade with un-cooled blades on either side to match flowpath areas of the actual turbine. The flowpath reuses internal components previously employed for mid-section region ribbed serpentine passage experiments that established Nusselt number enhancement ratios over a range of Reynolds numbers from 100,000-400,000. New components include flow conditioning plates upstream and downstream of the blade cascade to adequately represent the flow field and blade external heat transfer coefficient profiles for the actual turbine. The cooled central blade utilizes uniform crystal temperature sensors (UCTS) with six sensors each on the blade pressure and suction surfaces distributed radially and from LE to TE. The post-processed UCTS quantified the maximum wall temperature seen at each installed sensor location. The test procedure consisted of establishing supercritical CO2 cooling flow temperature and flow rate and maintaining it throughout the test. The flow rate aims to match that for the actual in-service turbine blade design and is maintained through an orifice restriction to keep the pressure differential between internal cooling flow and external hot flow nearly constant. For the sCO2 flow path external to the blade, temperatures were ramped throughout the test via control of the test loop’s natural gas burner heater. The maximum temperature seen was 468°C and held constant for a duration of 10 minutes at which the blade metal temperature was predicted to be at its maximum before ramping down. For the turbine blade design for service inlet conditions, external flow path computational fluid dynamics (CFD) results and an internal cooling 1-D thermal and hydraulic flow network model using experimentally validated correlations served as thermal finite element (FE) boundary conditions to predict blade metal temperatures. These predicted temperatures were subsequently utilized in a structural FE model to predict blade life ratings dictated by Haynes 282 creep strength data, having a strong dependence on temperature. The boundary conditions experienced during testing are used in the same workflow and compared to the experimental results, with the goal of validating the analysis methodology and providing insight on the uncertainty in local metal temperature predictions.

20 FOSSIL-FUELED POWER PLANTS↗

Room-Temperature Formate Ester Transfer Hydrogenation Enables an Electrochemical/Thermal Organometallic Cascade for Methanol Synthesis from CO 2

The reduction of CO 2 to synthetic fuels is a valuable strategy for energy storage. However, the formation of energy-dense liquid fuels such as methanol remains rare, particularly under low-temperature and low-pressure conditions that can be coupled to renewable electricity sources via electrochemistry. Here, in this study, a multicatalyst system pairing an electrocatalyst with a thermal organometallic catalyst is introduced, which enables the reduction of CO 2 to methanol at ambient temperature and pressure. The cascade methanol synthesis proceeds via CO 2 reduction to formate by electrocatalyst [Cp*Ir(bpy)Cl] + (Cp*=pentamethylcyclopentadienyl, bpy=2,2'-bipyridine), Fischer esterification of formate to isopropyl formate catalyzed by trifluoromethanesulfonic acid (HOTf), and thermal transfer hydrogenation of isopropyl formate to methanol facilitated by the organometallic catalyst (H-PNP)Ir(H) 3 (H-PNP=HN(C 2 H 4 P i Pr 2 ) 2 ). The isopropanol solvent plays several crucial roles: activating formate ion as isopropyl formate, donating hydrogen for the reduction of formate ester to methanol via transfer hydrogenation, and lowering the barrier for transfer hydrogenation through hydrogen bonding interactions. In addition to reporting a method for room-temperature reduction of challenging ester substrates, this work provides a prototype for pairing electrochemical and thermal organometallic reactions that will guide the design and development of multicatalyst cascades.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evaluation of phase change thermal storage in a cascade heat pump

Here this study proposes a low-global warming potential cascade heat pump system with integrated phase change material (PCM) for combined space heating and cooling. PCM is embedded in the intermediate heat exchanger that couples an outdoor R290 refrigerant circuit and an indoor CO 2 circuit. We used a clustering method to develop seasonally representative load and ambient temperature profiles for residential buildings in Minneapolis, Minnesota. We simulated the system peak shaving performance on the selected representative days, assuming three different PCM options including ice (0 °C), tetradecane (5.6 °C), and a commercially available PCM, SP9 (10.5 °C). The baseline was the same cascade system without thermal storage. We investigated the effect of both thermal energy storage capacity (kWh th ) and PCM transition temperature on system performance. The results show that higher thermal energy storage capacity shaves more electric energy until it reaches a maximum value set by the load characteristics of the building. SP9, with the highest transition temperature, shaves the most electric energy, while ice shaves the least. Moreover, ice has the highest charging cost, especially in the cooling season when the outdoor circuit has to operate at an evaporating temperature lower than 0 °C to make ice. Our results show that SP9 presents the lowest levelized cost of storage, closely followed by ice. A lower off-peak electricity rate benefits ice more than SP9 or tetradecane because ice has the largest charging cost penalty.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis

The emergence of porous liquids (PLs) opened opportunities to form unique antagonistic systems capable of fulfilling cascade reactions promoted by incompatible active sites in one pot, which is a long-term challenging subject in catalysis. Herein, unique bifunctional type III PL-based systems were facilely fabricated via assembly of zeolite nanosheets with ionic liquids. Rational structural design afforded PLs that feature high zeolite concentration, stable dispersion after 2 years, abundant cavity distribution, and involvement of antagonistic groups (acid and base sites) in separated and active form via steric hindrance control and electronic repulsion regulation. These unique properties worked cooperatively to fulfill the cascade deacetalization-Knoevenagel/Aldol condensation in one pot with superior catalytic efficiency outperforming the traditional systems. The key to success lies in the formation of bifunctional composites, transformation of zeolite from heterogeneous to homogeneous via surface modification, as well as rapid mass transfer ensured by the rigid porous architecture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A hybrid robust-stochastic optimization approach for day-ahead scheduling of cascaded hydroelectric system in restructured electricity market

Uncertainties arising from complicated natural and market environments pose great challenges for the efficient operation of cascaded hydroelectric systems. To overcome these challenges, this paper studies the day-ahead scheduling of cascaded hydroelectric systems in a restructured electricity market with the presence of uncertainties in electricity price and natural water inflow. To properly model the uncertainty, we consider the unique characteristics of these two types of uncertainties and capture them via the uncertainty set and stochastic scenarios, respectively. Further, a hybrid robust-stochastic optimization model is developed to simultaneously hedge against these two types of uncertainties, which is formulated as a large-scale non-convex optimization problem with mixed integer recourse. After introducing linearization of nonlinear terms, a tailored hybrid decomposition scheme combining Lagrangian relaxation and Dantzig-Wolfe decomposition is adopted to achieve efficient computation of the proposed model. Two real-world cases are conducted to demonstrate the capability and characteristics of the proposed model and algorithms.

13 HYDRO ENERGY↗

Multistage Stochastic optimization for mid-term integrated generation and maintenance scheduling of cascaded hydroelectric system with renewable energy uncertainty

The uncertainties resulting from the escalating penetration of renewable energy resources pose severe challenges to the efficient operation of modern power systems. Hydroelectricity is characterized by its flexibility, controllability, and reliability, and thus becomes one of the most ideal energy resources to hedge against such uncertainties. This paper studies the mid-term integrated generation and maintenance scheduling of a cascaded hydroelectric system (CHS) consisting of multiple cascaded reservoirs and hydroelectric units. To precisely describe the mid-term water regulation policies, the hydraulic coupling relationship and water-energy nexus of CHS are incorporated into the proposed optimization model. The uncertainties of natural water inflow and the power outputs of wind/solar energy generation are taken into consideration and captured via a stochastic process modeled by a scenario tree. A multistage stochastic optimization (MSO) approach is developed to coordinate the complementary operations of multiple energy resources, by optimizing the mid-term water resource management, generation scheduling, and maintenance scheduling of CHS. The proposed MSO model is formulated as a large-scale mixed-integer linear program that presents significant computational intractability. To address this issue, a tailored Benders decomposition algorithm is developed. Two real-world case studies are conducted to demonstrate the capability and characteristics of the proposed model and algorithm. The computational results show that the proposed MSO model can exploit the flexibility of hydroelectricity to efficiently respond to variable wind and solar power, and reserve water resources for the generation in peak months to reduce the consumption of fossil fuel. Furthermore, the proposed solution approach also exhibits promising computational efficiency when handling large-scale models.

13 HYDRO ENERGY↗