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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Bursting Bubbles from Combustion of Thermoplastic Materials in Microgravity

Many thermoplastic materials in common use for a wide range of applications, including spacecraft, develop bubbles internally as they burn due to chemical reactions taking place within the bulk. These bubbles grow and migrate until they burst at the surface, forceably ejecting volatile gases and, occasionally, molten fuel. In experiments in normal gravity, Kashiwagi and Ohlemiller observed vapor jets extending a few centimeters from the surface of a radiatively heated polymethylmethacrylate (PMMA) sample, with some molten material ejected into the gas phase. These physical phenomena complicated the combustion process considerably. In addition to the non-steady release of volatiles, the depth of the surface layer affected by oxygen was increased, attributed to the roughening of the surface by bursting events. The ejection of burning droplets in random directions presents a potential fire hazard unique to microgravity. In microgravity combustion experiments on nylon Velcro fasteners and on polyethylene wire insulation, the presence of bursting fuel vapor bubbles was associated with the ejection of small particles of molten fuel as well as pulsations of the flame. For the nylon fasteners, particle velocities were higher than 30 cm/sec. The droplets burned robustly until all fuel was consumed, demonstrating the potential for the spread of fire in random directions over an extended distance. The sequence of events for a bursting bubble has been photographed by Newitt et al.. As the bubble reaches the fluid surface, the outer surface forms a dome while the internal bubble pressure maintains a depression at the inner interface. Liquid drains from the dome until it breaks into a cloud of droplets on the order of a few microns in size. The bubble gases are released rapidly, generating vortices in the quiescent surroundings and transporting the tiny droplets. The depression left by the escaping gases collapses into a central jet, which rises with a high velocity and may break up, releasing one or more relatively large drops (on the order of a millimeter in these experiments). A better understanding of bubble development and bursting processes, the effects of bursting behavior on burning rate of the bulk material, and the circumstances under which large droplets are expelled, as well as their trajectories, sizes, and burning rates, is sought through computer modeling compared with experiment.

Butler, K. B.↗
NASA NTRS1999

The Extinction of Low Strain Rate Diffusion Flames by a Suppressant

This paper describes plans for an experimental and computational study on the structure and extinction of low strain rate diffusion flames by a suppressant added to the oxidizer stream. Stable low strain rate flames will be established through ground based reduced gravity experiments using the 2.2 s drop tower. A variety of agents will be investigated, including both physically and chemically acting agents (He, N2, CO2, and CF3Br) for flames burning methane and propane. A computational model of flame structure and extinction will be modified to include radiative losses, which is thought to be a significant heat loss mechanism at low strain rates.

Hamins, A.↗
NASA NTRS2006

An Unusual Precursor Burst with Oscillations from SAX J1808.4-3658

We report the finding of an unusual, weak precursor to a thermonuclear X-ray burst from the accreting millisecond pulsar SAX 51808.4-3658. The burst in question was observed on Oct. 19, 2002 with the Rossi X-Ray Timing Explorer (RXTE) proportional counter array (PCA). The precursor began approx. equal to 1 s prior to the onset of a strong radius expansion burst, lasted for about 0.4 s, and exhibited strong oscillations at the 401 Hz spin frequency. Oscillations are not detected in the approx. equal to 0.5 s interval between the precursor and the main burst. The estimated peak photon flux and energy fluence of the precursor are about 1/25, and 1/500 that of the main burst, respectively. From joint spectral and temporal modeling, we find that an expanding burning region with a relatively low temperature on the spinning neutron star surface can explain the oscillations, as well as the faintness of the precursor with respect to the main part of the burst. We discuss some of the implications of our findings for the ignition and spreading of thermonuclear flames on neutron stars.

Bhattacharyya, Sudip↗
NASA NTRS2013

Direct Top-down Estimates of Biomass Burning CO Emissions Using TES and MOPITT Versus Bottom-up GFED Inventory

In this study, we utilize near-simultaneous observations from two sets of multiple satellite sensors to segregate Tropospheric Emission Spectrometer (TES) and Measurements of Pollution in the Troposphere (MOPITT) CO observations over active fire sources from those made over clear background. Hence, we obtain direct estimates of biomass burning CO emissions without invoking inverse modeling as in traditional top-down methods. We find considerable differences between Global Fire Emissions Database (GFED) versions 2.1 and 3.1 and satellite-based emission estimates in many regions. Both inventories appear to greatly underestimate South and Southeast Asia emissions, for example. On global scales, however, CO emissions in both inventories and in the MOPITT-based analysis agree reasonably well, with the largest bias (30%) found in the Northern Hemisphere spring. In the Southern Hemisphere, there is a one-month shift between the GFED and MOPITT-based fire emissions peak. Afternoon tropical fire emissions retrieved from TES are about two times higher than the morning MOPITT retrievals. This appears to be both a real difference due to the diurnal fire activity variations, and a bias due to the scarcity of TES data.

bias↗
NASA NTRS2014

Mechanical Behavior of Microelectromechanical Microshutters

A custom micro-mechanical test system was constructed using off-the-shelf components to characterize the mechanical properties of microshutters. Microshutters are rectangular microelectromechanical apertures which open and close about a narrow torsion bar hinge. Displacement measurements were verified using both capacitive and digital image correlation techniques. Repeatable experiments on Si3N4 cantilever beams verified that the test system operates consistently. Using beam theory, the modulus of elasticity of the low stress Si3N4 was approximately 150 GPa, though significant uncertainty exists for this measurement due primarily to imprecise knowledge of the cantilever thickness. Tests conducted on microshutter arrays concluded that reducing the Si3N4 thickness from 250 nm to 500 nm reduces the torsional stiffness by a factor of approximately four. This is in good agreement with analytical and finite element models of the microshutters.

silicon nitride↗
NASA NTRS1987

Estimating regional evapotranspiration from remotely sensed data by surface energy balance models

Spatial and temporal variations of surface radiative temperatures of the burned and unburned areas of the Konza tallgrass prairie were studied. The role of management practices, topographic conditions and the uncertainties associated with in situ or airborne surface temperature measurements were assessed. Evaluation of diurnal and seasonal spectral characteristics of the burned and unburned areas of the prairie was also made. This was accomplished based on the analysis of measured spectral reflectance of the grass canopies under field conditions, and modelling their spectral behavior using a one dimensional radiative transfer model.

Asrar, Ghassem↗
NASA NTRS1999

Hydrodynamic Instability and Thermal Coupling in a Dynamic Model of Liquid-Propellant Combustion

For liquid-propellant combustion, the Landau/Levich hydrodynamic models have been combined and extended to account for a dynamic dependence of the burning rate on the local pressure and temperature fields. Analysis of these extended models is greatly facilitated by exploiting the realistic smallness of the gas-to-liquid density ratio rho. Neglecting thermal coupling effects, an asymptotic expression was then derived for the cellular stability boundary A(sub p)(k) where A(sub p) is the pressure sensitivity of the burning rate and k is the disturbance wavenumber. The results explicitly indicate the stabilizing effects of gravity on long-wave disturbances, and those of viscosity and surface tension on short-wave perturbations, and the instability associated with intermediate wavenumbers for critical negative values of A(sub p). In the limit of weak gravity, hydrodynamic instability in liquid-propellant combustion becomes a long-wave, instability phenomenon, whereas at normal gravity, this instability is first manifested through O(1) wavenumbers. In addition, surface tension and viscosity (both liquid and gas) each produce comparable effects in the large-wavenumber regime, thereby providing important modifications to the previous analyses in which one or more of these effects was neglected. For A(sub p)= O, the Landau/Levich results are recovered in appropriate limiting cases, although this typically corresponds to a hydrodynamically unstable parameter regime for p << 1. In addition to the classical cellular form of hydrodynamic stability, there exists a pulsating form corresponding to the loss of stability of steady, planar burning to time-dependent perturbations. This occurs for negative values of the parameter A(sub p), and is thus absent from the original Landau/Levich models. In the extended model, however, there exists a stable band of negative pressure sensitivities bounded above by the Landau type of instability, and below by this pulsating form of hydrodynamic instability. Indeed, nonsteady modes of combustion have been observed at low pressures in hydroxylammonium nitrate (HAN)-based liquid propellants, which often exhibit negative pressure sensitivities. While nonsteady combustion may correspond to secondary and higher-order bifurcations above the cellular boundary, it may also be a manifestation of this pulsating type of hydrodynamic instability. In the present work, a nonzero temperature sensitivity is incorporated into our previous asymptotic analyses. This entails a coupling of the energy equation to the previous purely hydrodynamic problem, and leads to a significant modification of the pulsating boundary such that, for sufficiently large values of the temperature-sensitivity parameter, liquid-propellant combustion can become intrinsically unstable to this alternative form of hydrodynamic instability. For simplicity, further attention is confined here to the inviscid version of the problem since, despite the fact that viscous and surface-tension effects are comparable, the qualitative nature of the cellular boundary remains preserved in the zero-viscosity limit, as does the existence of the pulsating boundary. The mathematical model adopts the classical assumption that there is no distributed reaction in either the liquid or gas phases, but now the reaction sheet, representing either a pyrolysis reaction or an exothermic decomposition at the liquid/gas interface, is assumed to depend on local conditions there.

Margolis, S. B.↗
NASA NTRS1991

Wolf-Rayet stars of type WN/WC and mixing processes during core helium burning of massive stars

Consequences of the recent finding that most WN/WC spectra probably originate from individual Wolf-Rayet stars for the internal structure of massive stars are discussed. Numerical models including the effect of slow-down or prevention of convective mixing due to molecular weight gradients are presented, in which a transition layer with a composition mixture of H- and He-burning ashes is formed above the convective He-burning core. These models are able to qualitatively account for the observed WN/WC frequency and agree quantitatively with the only WN/WC-composition determination so far. It is argued that the same transition layer may be responsible for the final blue loop which the SN 1987 A progenitor performed some 10,000 yr before explosion. These results indicate that composition barriers may be efficient in restricting convection during central helium burning, in contrast to computations relying on the Schwarzschild criterion for convection, with or without overshooting.

Langer, N.↗
NASA NTRS2017

Description and Evaluation of the Multiscale Online Nonhydrostatic AtmospheRe CHemistry Model (NMMB-MONARCH) Version 1.0: Gas-Phase Chemistry at Global Scale

This paper presents a comprehensive description and benchmark evaluation of the tropospheric gas-phase chemistry component of the Multiscale Online Nonhydrostatic AtmospheRe CHemistry model (NMMBMONARCH), formerly known as NMMB/BSC-CTM, that can be run on both regional and global domains. Here, we provide an extensive evaluation of a global annual cycle simulation using a variety of background surface stations (EMEP, WDCGG and CASTNET), ozonesondes (WOUDC, CMD and SHADOZ), aircraft data (MOZAIC and several campaigns), and satellite observations (SCIAMACHY and MOPITT).We also include an extensive discussion of our results in comparison to other state-of-the-art models. We note that in this study, we omitted aerosol processes and some natural emissions (lightning and volcano emissions). The model shows a realistic oxidative capacity across the globe. The seasonal cycle for CO is fairly well represented at different locations (correlations around 0.3-0.7 in surface concentrations), although concentrations are underestimated in spring and winter in the Northern Hemisphere, and are overestimated throughout the year at 800 and 500 hPa in the Southern Hemisphere. Nitrogen species are well represented in almost all locations, particularly NO2 in Europe (root mean square error - RMSE - below 5 ppb). The modeled vertical distributions of NOx and HNO3 are in excellent agreement with the observed values and the spatial and seasonal trends of tropospheric NO2 columns correspond well to observations from SCIAMACHY, capturing the highly polluted areas and the biomass burning cycle throughout the year. Over Asia, the model underestimates NOx from March to August, probably due to an underestimation of NOx emissions in the region. Overall, the comparison of the modeled CO and NO2 with MOPITT and SCIAMACHY observations emphasizes the need for more accurate emission rates from anthropogenic and biomass burning sources (i.e., specification of temporal variability).

atmospheric chemistry↗
NASA NTRS2020

A Nucleosynthetic Origin for the Southwestern Fe-rich Structure in Kepler's Supernova Remnant

Chandra X-ray observations of Kepler's supernova remnant indicate the existence of a high-speed Fe-rich ejecta structure in the southwestern region. We report strong K-shell emission from Fe-peak elements (Cr, Mn, Fe, Ni), as well as Ca, in this Fe-rich structure, implying that those elements could be produced in the inner area of the exploding white dwarf. We found Ca/Fe, Cr/Fe, Mn/Fe, and Ni/Fe mass ratios of 1.0%–4.1%, 1.0%–4.6%, 1%–11%, and 2%–30%, respectively. In order to constrain the burning regime that could produce this structure, we compared these observed mass ratios with those in 18 one-dimensional Type Ia nucleosynthesis models (including both near-M Ch and sub-M Ch explosion models). The observed mass ratios agree well with those around the middle layer of incomplete Si burning in Type Ia nucleosynthesis models with a peak temperature of ~(5.0–5.3) × 10(exp 9) K and a high metallicity, Z > 0.0225. Based on our results, we infer the necessity for some mechanism to produce protruding Fe-rich clumps dominated by incomplete Si-burning products during the explosion. We also discuss the future perspectives of X-ray observations of Fe-rich structures in other Type Ia supernova remnants.

Toshiki Sato↗
NASA NTRS2000

Search for Extraterrestrial Origin of Atmospheric Trace Molecules Radio Sub-MM Observations During The Leonids

HCN is a minor constituent of the Earth atmosphere, with a typical volume mixing ratio around 10(exp -10) HCN per air molecule. At present, the main source of HCN in the lower atmosphere is expected to be biomass burning. The atmospheric HCN has been observed since 1981, first in the infrared, then at microwave radio frequencies. Globally, above 30 km, HCN measurements are in excess of model predictions based on standard photochemistry and biomass burning as the only HCN source. This excess has been explained by: 1) ion-catalyzed reactions in the entire stratosphere, involving CH.3CN as a precursor and/or 2) a high altitude source as a result of chemical production from the methyl radical CH3, or from injection or production by meteors. HCN is a minor constituent of cometary ices. HCN polymers or copolymers have been suggested as constituents of cometary refractory organic matter, and would thus be present in the incoming meteoroids, if these polymers survived their stay in interplanetary space after ejection. HCN may also be created from the CN radical decomposition product of organic carbon, after reaction with hydrogen-bearing molecules. To test the hypothesis of HCN input by meteoroids or the formation in the upper atmosphere from meteoric ablation products, we decided to monitor the HCN submillimeter lines around a major shower: the Leonids.

Depois, D.↗
NASA NTRS2003

Aerosol Models for the CALIPSO Lidar Inversion Algorithms

We use measurements and models to develop aerosol models for use in the inversion algorithms for the Cloud Aerosol Lidar and Imager Pathfinder Spaceborne Observations (CALIPSO). Radiance measurements and inversions of the AErosol RObotic NETwork (AERONET1, 2) are used to group global atmospheric aerosols using optical and microphysical parameters. This study uses more than 105 records of radiance measurements, aerosol size distributions, and complex refractive indices to generate the optical properties of the aerosol at more 200 sites worldwide. These properties together with the radiance measurements are then classified using classical clustering methods to group the sites according to the type of aerosol with the greatest frequency of occurrence at each site. Six significant clusters are identified: desert dust, biomass burning, urban industrial pollution, rural background, marine, and dirty pollution. Three of these are used in the CALIPSO aerosol models to characterize desert dust, biomass burning, and polluted continental aerosols. The CALIPSO aerosol model also uses the coarse mode of desert dust and the fine mode of biomass burning to build a polluted dust model. For marine aerosol, the CALIPSO aerosol model uses measurements from the SEAS experiment 3. In addition to categorizing the aerosol types, the cluster analysis provides all the column optical and microphysical properties for each cluster.

Omar, Ali H.↗
NASA NTRS2003

Coherent Anti-Stokes Raman Scattering (CARS) as a Probe for Supersonic Hydrogen-Fuel/Air Mixing

The dual-pump coherent anti-Stokes Raman spectroscopy (CARS) method was used to measure temperature and the absolute mole fractions of N2, O2 and H2 in a supersonic non-reacting fuel-air mixing experiment. Experiments were conducted in NASA Langley Research Center s Direct Connect Supersonic Combustion Test Facility. Under normal operation of this facility, hydrogen and air burn to increase the enthalpy of the test gas and O2 is added to simulate air. This gas is expanded through a Mach 2 nozzle and into a combustor model where fuel is then injected, mixes and burns. In the present experiment the O2 of the test gas is replaced by N2. The lack of oxidizer inhibited combustion of the injected H2 fuel jet allowing the fuel/air mixing process to be studied. CARS measurements were performed 427 mm downstream of the nozzle exit and 260 mm downstream of the fuel injector. Maps were obtained of the mean temperature, as well as the N2, O2 and H2 mean mole fraction fields. A map of mean H2O vapor mole fraction was also inferred from these measurements. Correlations between different measured parameters and their fluctuations are presented. The CARS measurements are compared with a preliminary computational prediction of the flow.

Danehy, P. M.↗
NASA NTRS2019

Progress Towards Modeling the Ablation Response of NuSil-Coated PICA

The Mars Science Laboratory (MSL) Entry, Descent and Landing Instrumentation (MEDLI) collected in-flight data largely used by the ablation community to verify and validate physics-based models for the response of the Phenolic Impregnated Carbon Ablator (PICA) material [1-4]. MEDLI data were recently used to guide the development of NASA’s high-fidelity material response models for PICA, implemented in the Porous material Analysis Toolbox based on OpenFOAM (PATO) software [5-6]. A follow-up instrumentation suite, MEDLI2, is planned for the upcoming Mars 2020 mission [7] after the large scientific impact of MEDLI. Recent analyses performed as part of MEDLI2 development draw the attention to significant effects of a protective coating to the aerothermal response of PICA. NuSil, a silicone-based overcoat sprayed onto the MSL heatshield as contamination control, is currently neglected in PICA ablation models. To mitigate the spread of phenolic dust from PICA, NuSil was applied to the entire MSL heatshield, including the MEDLI plugs. NuSil is a space grade designation of the siloxane copolymer, primarily used to protect against atomic oxygen erosion in the Low Earth Orbit environment. Ground testing of PICA-NuSil (PICA-N) models all exhibited surface temperature jumps of the order of 200 K due to oxide scale formation and subsequent NuSil burn-off. It is therefore critical to include a model for the aerothermal response of the coating in ongoing code development and validation efforts.

Meurisse, Jeremie B.↗
NASA NTRS1990

Application of mixing-controlled combustion models to gas turbine combustors

Gas emissions were studied from a staged Rich Burn/Quick-Quench Mix/Lean Burn combustor were studied under test conditions encountered in High Speed Research engines. The combustor was modeled at conditions corresponding to different engine power settings, and the effect of primary dilution airflow split on emissions, flow field, flame size and shape, and combustion intensity, as well as mixing, was investigated. A mathematical model was developed from a two-equation model of turbulence, a quasi-global kinetics mechanism for the oxidation of propane, and the Zeldovich mechanism for nitric oxide formation. A mixing-controlled combustion model was used to account for turbulent mixing effects on the chemical reaction rate. This model assumes that the chemical reaction rate is much faster than the turbulent mixing rate.

Nguyen, Hung Lee↗
NASA NTRS2022

Low-Earth Orbit Trajectory Optimization in the Presence of Atmospheric Uncertainty

The previous 20 to 25 years have seen a tremendous increase in space exploration, and with that an increase in the level of logistics planning needed to ensure mission success. For spacecraft that are designed to be periodically re-supplied, a key logistics consumable is propellant, as it constitutes the greatest up-mass on re-supply vehicles. A trajectory design strategy is therefore desired that minimizes propellant usage in order to ease the demand for propellant re-supply missions. This thesis develops such a strategy in three stages, and uses the International Space Station (ISS) as its testbed, as no other LEO spacecraft is more challenging from a space logistics standpoint. First, the ISS trajectory planning problem is formulated as a constrained burn optimization problem assuming a deterministic atmosphere. The cost function is total ∆v, with constraints imposed on longitude of ascending viii node (LAN) and semi-major axis (SMA) altitude. Analytic derivatives are constructed for both the cost and constraints, which are necessary given the 6-week to 2-year time frames being considered. A gradient-based optimizer is then utilized to find locally-optimal solutions to real-world ISS trajectory planning problems. Second, atmospheric uncertainty is addressed by constructing a probabilistic model of space weather data using Gaussian Processes (GPs). Bayesian inference is performed using the GP model to generate mean and covariance estimates for space weather predictions, whose pedigree is assessed against test data. The predictions are then mapped into atmospheric density via the analytic Jacchia-Roberts density model, and the effect of space weather uncertainty on orbital lifetime is examined. Third, an ISS burn execution uncertainty model is developed. This model, along with the space weather uncertainty model, are deployed in a linear covariance analysis to ascertain their combined effect on LAN and SMA altitude dispersions. The deterministic constraints from the original problem are re-formulated as stochastic constraints, where now the constraint uncertainty interval is required to fall within specified bounds. An updated optimization framework is constructed using the original ∆v cost function along with the stochastic constraints to solve the trajectory optimization problem under atmospheric uncertainty. Finally, the complete architecture is summarized for deployment in an operational setting.

Trajectory Optimization↗
NASA NTRS2021

Biomass Burning and Water Balance Dynamics in the Lake Chad Basin in Africa

The present study investigates the effect of biomass burning on the water cycle using a case study of the Chari-Logone Catchment of Lake Chad Basin. The Chari-Logone catchment was selected since it supplies over 90% of the water input to the Lake, which is the largest basin in the NSSA. Two water balance simulations, one considering burning and one without, were compared from the years 2003 to 2011. For a more comprehensive assessment of the effects of burning, albedo change, which has been shown to have a significant impact on a number of environmental factors, was used as a model input for calculating potential evapotranspiration. Analysis of the burning scenario show that burning grassland, which composes almost 75% of Chari-Logone total land cover, causes increased ET and runoff during winter months. Recent studies have demonstrated the increasing trend in LCB of converting shrubland, grassland, and wetlands to cropland. This change from grassland to cropland has the potential of decreasing water available to water bodies during the winter. All vegetative classes in a burning scenario showed a decrease in ET during the wet season, supporting the idea that, with increased burning, there would be a severe decrease of precipitation.

africa↗