The Brine Availability Test in Salt (BATS) Heater Test at WIPP - 23358
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This technical report presents a preliminary study for CBI implementation in the Pena Creek pilot site in Dimmit County, Texas, targeting the Edwards Limestone Formation for SWD, in collaboration with NGL Energy Partners. The objective of this study is to find the conservative CO 2 molality for safe storage and potential risks for CBI at this pilot site. Geomodel was performed to get site-specific reservoir geology information. Reservoir modeling was performed to investigate dissolved CO 2 molality and pressure changes at relevant injection conditions. Wellbore corrosion and compatibility was discussed with corrosion modeling. Dissolved CO 2 long-term fate in the reservoir was examined with reactive transport modeling. This plan would set the scientific foundation as the initial step for future implementation in the field.
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The Waste Isolation Pilot Plant (WIPP) is the only active deep geological repository in the United States for the disposal of defense-related transuranic (TRU) waste, located in the northern part of the Delaware Basin in southeastern New Mexico, approximately 26 miles east of Carlsbad. The repository is situated 2,150 feet (about 610 meters) underground within the Salado Formation, a thick layer of stable salt deposits. This unique geological formation provides a secure and long-term environment for isolating TRU waste, ensuring its safe containment for thousands of years.
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The question of adaptivity to extremely saline water environments is discussed, with attention given to the evolutionary performance of four common organisms including Cladonia skottsbergii, Penicillium notatum, Nostoc, and Dunaliella salina. Samples of each organism were collected and subjected to experimental conditions similar to extreme marine and limnetic environments in the Dead Sea and Don Juan Pond in the upper Wright valley of Antarctica. Measurements were made of isotope uptake and carbon dioxide production, and photoautotrophs were taken. It is found that all of the organisms responded quickly to the need to adapt to the extreme environments. It is concluded that a degree of uncertainty exists in the perception that the abundance of bulk water on the earth is in itself essential for life.
Evaporites, particularly carbonates, nitrates, and sulfates, may be major sinks of volatiles scavenged from the martian atmosphere. Mars is thought to have once had a denser, warmer atmosphere that permitted the presence of liquid surface water. The conversion of atmospheric CO2 into carbonate is hypothesized to have degraded the martian climate to its present state of a generally subfreezing, desiccated desert. The rate for such a conversion under martian conditions is poorly known, so the time scale of climate degradation by this process cannot be easily evaluated. If some models are correct, carbonate formation may have been fast at geological time scales. The experiments of Booth and Kieffer also imply fast (10(exp 6) - 10(exp 7) yr) removal of the missing CO2 inventory, estimated to be 1 - 5 bar, by means of carbonate formation. The timing of formation of many of the fluvial features observed on Mars is, in large part, dependent on when and how fast the atmosphere changed. A knowledge of the rate at which carbonates and nitrates formed is also essential for assessing the probability that life, or its chemical precursors, could have developed on Mars. No previous experiments have quantitatively evaluated the rate of solution for a suite of mobile anions and cations from unaltered minerals and atmospheric gases into liquid water under Mars-like conditions. Such experiments are the focus of this task.
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The Thermal Emission Spectrometer (TES) onboard the Mars Global Surveyor (MGS) orbiter discovered a large area at Meridiani Planum (MP) covered with the Fe-oxide hematite (alpha-Fe2O3) [1,2]. This discovery and favorable landing site characteristics led to selection of MP as the landing site for the Opportunity Mars Exploration Rover (MER) [3]. The Athena science payload onboard the Opportunity rover identified hematite-rich spherules (mean spherule diameter approx.4.2+/-0.8 mm) embedded in S-rich outcrop rock and also as lag deposits of whole and broken spherules [4,5,6,7,8,9]. Although the chemical and mineralogical compositions of spherules are not fully constrained, Moessbauer spectrometer (MB) Miniature Thermal Emission Spectrometer (Mini-TES) and chemical analyses from the Alpha Particle X-Ray Spectrometer (APXS) are consistent with a hematite mineralogical composition and an oxide bulk chemical composition consisting of Fe2O3. MGS-TES, also provides an important constraint that emission from the hematite-rich spherules is dominated by emission along the crystallographic c-axis [1,2,10,11]. The formation of hematite-rich spherules with similar chemical, mineralogical, morphological, and crystallographic properties to the MP spherules is rare on Earth, to date, only two natural analogs have been proposed; one from Utah (Navaho Concretions) and the other from Mauna Kea, Hawaii [12,13]. In this study, we synthesized in the laboratory hematite-rich spherules using conditions that may have existed on Early Mars [14] and compared their properties to those for MP hematite spherules of Mars and the analog spherules from Utah and Mauna Kea in order to assess their relative merit as MP hematite spherule analogs. Such comparisons yield clues to the formation pathway for MP spherules.
Introduction: Brecciated H chondrites host a variety of xenoliths, including unshocked, phyllo- silicate-rich carbonaceous chondrites (CCs). The brecciated H chondrite Zag (H3-6) is one of two chondrites to host macroscopic (1 - 5mm), xenolithic crystals of halite (NaCl) with aqueous fluid inclusions and organics. A ~1cm CC xenolith in Zag (Zag clast) has mineralogy similar to CI chondrites, but it has a unique bulk oxygen isotopic composition among all meteorites (Δ(exp 17)O = 1.49 ± 0.04 ‰, δ(exp 18)O = 22.38 ± 0.17 ‰). The Zag clast encloses halite in its matrix, linking the coarse, matrix halite and the xenolith to the same parent object, suggested to be hydrovolcanically active. Its bulk C and N contents are the highest among chondrites and bulk δ(exp 15)N is similar to CR chondrites and Bells. Insoluble organic material (IOM) in the Zag clast has δD and δ(exp 15)N “hotspots”, also similar to CR chondrites and Bells (C2-ung.). We provide further isotopic characterization of the Zag clast to constrain the formation temperature and origin of its primary and secondary components.
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