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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Seismology on Venus with infrasound observations from balloon and orbit

The study of Venus' evolution is inexorably linked with studying its interior properties, which can be investigated by performing seismic studies on the planet. However, seismology on Venus has long eluded planetary scientists due to technological challenges presented by high surface temperature and pressure, which limit lifetimes of surface-based instrumentation. In this white paper, we present two complementary techniques for performing seismology on Venus by measuring the low-frequency acoustic signature (infrasound) produced by seismic activity through coupling between the solid planet and the atmosphere. These techniques may be implemented with technology available today, without the use of high-temperature electronics.

79 ASTRONOMY AND ASTROPHYSICS↗

Lithium–Divertor Interactions and Helium/Hydrogen Trapping in Lithiated Metals (Final Technical Report)

The goal of this project was to develop a fundamental understanding of helium and hydrogen behavior in lithium, both in bulk and at interfaces with tungsten, in order to inform the design of lithium based plasma facing components for fusion devices. Over the course of the award, the project produced the first comprehensive, peer reviewed dataset describing helium energetics, migration behaviors, and defect interactions in lithium. The research demonstrated that helium behaves in ways not previously observed in any other body centered cubic (BCC) metal: its interstitial configurations are more stable than substitutional ones, and its migration barriers are extraordinarily low, in some cases more than an order of magnitude below those in tungsten or iron. These discoveries reveal that helium in lithium diffuses so rapidly that its transport may be dominated by translational motion rather than the vibrationally activated mechanisms that underpin conventional solid state diffusion. This work lays a scientific foundation for understanding gas retention, bubble formation, and wall evolution in lithium based fusion environments and provides new computational tools, most notably a newly developed Li–He interatomic potential, for advancing future modeling efforts.

36 MATERIALS SCIENCE↗

Polymer research

Estimating solubility parameters from refractive index data, cationic crosslinking agents, and activated carrier mobility in organic solids

Source record↗

Analytical investigations employing dynamic mechanical properties

Dynamic mechanical spectroscopy has emerged as an effective laboratory method for analytical investigations of polymers. These methods were applied in investigating the property changes of silicone poppets implanted in artificial heart valves, and for exploring the cause of hardening of certain solid propellants. As a research activity, the property-structure relations which lead to the ability to superimpose dynamic data for epoxy resins were investigated.

Cuddihy, E. F.↗

Research study on multi-KW-DC distribution system

A detailed definition of the HVDC test facility and the equipment required to implement the test program are provided. The basic elements of the test facility are illustrated, and consist of: the power source, conventional and digital supervision and control equipment, power distribution harness and simulated loads. The regulated dc power supplies provide steady-state power up to 36 KW at 120 VDC. Power for simulated line faults will be obtained from two banks of 90 ampere-hour lead-acid batteries. The relative merits of conventional and multiplexed power control will be demonstrated by the Supervision and Monitor Unit (SMU) and the Automatically Controlled Electrical Systems (ACES) hardware. The distribution harness is supported by a metal duct which is bonded to all component structures and functions as the system ground plane. The load banks contain passive resistance and reactance loads, solid state power controllers and active pulse width modulated loads. The HVDC test facility is designed to simulate a power distribution system for large aerospace vehicles.

Berkery, E. A.↗

Storage Stability and Improvement of Intermediate Moisture Foods, Phase 3

Methods were determined for the improvement of shelf-life stability of intermediate moisture foods (IMF). Microbial challenge studies showed that protection against molds and Staphylococcus aureus could be achieved by a combination of antimicrobial agents, humectants and food acids. Potassium sorbate and propylene glycol gave the best results. It was also confirmed that the maximum in heat resistance shown by vegetative pathogens at intermediate water activities also occurred in a solid food. Glycols and sorbitol both achieve browning inhibition because of their action as a medium for reaction and effect on viscosity of the adsorbed phase. Chemical availability results showed rapid lysine loss before visual discoloration occurred. This is being confirmed with a biological test using Tetrahymena pyriformis W. Accelerated temperature tests show that effectiveness of food antioxidants against rancidity development can be predicted; however, the protection factor changes with temperature. BHA was found to be the best antioxidant for iron catalyzed oxidation.

Labuza, T. P.↗

Instrumentation of sampling aircraft for measurement of launch vehicle effluents

An aircraft was selected and instrumented to measure effluents emitted from large solid propellant rockets during launch activities. The considerations involved in aircraft selection, sampling probes, and instrumentation are discussed with respect to obtaining valid airborne measurements. Discussions of the data acquisition system used, the instrument power system, and operational sampling procedures are included. Representative measurements obtained from an actual rocket launch monitoring activity are also presented.

Wornom, D. E.↗

Examples of realistic aerosol particles collected in a cascade impactor

In this paper some scanning electron microscope photomicrographs showing examples of a variety of particulate aerosol shapes are presented. Compositions of particles also are presented. These particles represent samples from a number of different sources and locations including: solid propellant rocket motor plumes, active volcano plumes, the lower stratosphere over Sondrestrom, Greenland, and the upper troposphere over northern Texas. The particles were collected from aboard an aircraft with a cascade impactor which classified them according to aerodynamic size into 10 size intervals ranging from submicron to greater than 25 micrometers in diameter. The cascade impactor also served to measure the mass concentration as a function of particle size. The variety of shapes and compositions found among these particles suggest difficulties in obtaining reliable size distribution data from light scattering measurements.

Woods, D. C.↗

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamic maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of Region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicon carbide is the single stable solid phase in Region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4, and SiH. Analysis of the kinetics of reaction for Region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to Regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamics maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicone carbide is the single stable solid phase in region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4 and SiH. Analyses of the kinetics of reaction for region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗

Effect of surface condition on the formation of solid lubricating films at high temperatures

Solid films were produced on active metal or ceramic surfaces using lubricants (such as tricresyl phosphate) delivered as a vapor at high temperatures, and the lubricity of these deposits under different dynamic wear conditions was investigated. A method is described for chemically activating ceramic surfaces resulting in a surface that could promote the formation of lubricating polymeric derivative of TCP. Experiments were carried out to evaluate the wear characteristics of unlubricated cast iron and of Sialon ceramic at 25 and 280 C, and lubricated with a vapor of TCP at 280 C. It is shown that continuous vapor phase lubrication of chemically treated Sialon reduced its coefficient of friction from 0.7 to less than 0.1.

Hanyaloglu, Bengi↗

Design and manufacture of solid ZrO2 electrolyte

The following project assignment was given to the students: 'design and build a suitable YSZ solid electrolyte cell. Describe advantages of the design and fabrication method. Finally, to the limits of available resources, fabricate the design. Explain why it would be superior to other designs.' Clemson University students definitely benefitted from this experience with USRA/NASA. The challenge that this project gave the students was both exciting and attention-getting. Students spent far more time per credit hour on this project than on their other course. This project advanced the art of making efficient oxygen generators as well. Clemson students are now well on the way to designing a solid electrolyte with a large active surface area and comparatively small volume. Previous devices have had to endure the limitation of using only simple shapes such as tubes. The results of this project have demonstrated that better configurations are not only possible but practical.

Source record↗

Monolith catalysts for closed-cycle carbon dioxide lasers

The general subject area of the project involved the development of solid catalysts that have high activity at low temperature for the oxidation of gases such as CO. The original application considered was CO oxidation in closed-cycle CO2 lasers. The scope of the project was subsequently extended to include oxidation of gases in addition to CO and applications such as air purification and exhaust gas emission control. The primary objective of the final phase grant was to develop design criteria for the formulation of new low-temperature oxidation catalysts utilizing Monte Carlo simulations of reaction over NASA-developed catalysts.

Herz, Richard K.↗

Contractors Road Heavy Equipment Area (SWMU 055) 2021 Annual Groundwater Monitoring Report

This document presents a summary of activities completed at the Contractors Road Heavy Equipment (CRHE) Area, located at Kennedy Space Center (KSC), Florida, from January through December 2021. The activities conducted at the CRHE Area include: - Annual groundwater sampling activities associated with site-wide plume monitoring and Underground Injection Control (UIC) monitoring in the former bioremediation Interim Measures (IM) Hot Spot 1 (HS1) area; - Direct push technology (DPT) groundwater investigation; and - Semi-annual vapor intrusion (VI) evaluation activities. This facility is designated Solid Waste Management Unit (SWMU) Number 055 (SWMU 055) under KSC’s Resource Conservation and Recovery Act Corrective Action program. This report was prepared by HydroGeoLogic, Inc. (HGL) for the National Aeronautics and Space Administration (NASA) under contract number 80KSC019F0096. The annual groundwater sampling results demonstrated that the footprint where chlorinated volatile organic compounds (VOC) are present above their State of Florida groundwater cleanup target levels (GCTLs) is not expanding overall. One non-chlorinated VOC (1,4-dioxane) is found above its GCTL at isolated points within the chlorinated VOC plume. The DPT groundwater investigation is being used to delineate the horizontal and vertical boundaries where chlorinated VOCs are present at levels above natural attenuation default concentrations. That data supports an evaluation of potential additional remedial actions. The potential for VI into the CRHE Area Office (K6-1996H) is evaluated by collected sub-slab vapor samples from four locations twice a year (once in the wet season and once in the dry season). The results for 2021 were all below the Environmental Protection Agency's vapor intrusion screening levels (VISLs) for both commercial and residential settings. The path forward for the site is to continue annual monitoring for chlorinated VOCs and 1,4-dioxane until additional remedies are implemented or the site is transitioned to long-term monitoring.

Contractors Road Heavy Equipment↗

Contractors Road Heavy Equipment Area (SWMU 055) 2022 Annual Groundwater Monitoring Report

This document presents a summary of activities completed at the Contractors Road Heavy Equipment (CRHE) Area, located at Kennedy Space Center (KSC), Florida, from June through December 2022. The activities conducted at the CRHE Area include: - Annual groundwater sampling activities associated with sitewide plume monitoring and Underground Injection Control (UIC) monitoring in the former bioremediation Interim Measures (IM) Hot Spot 1 (HS1) area; - Direct push technology (DPT) groundwater investigation; - Semiannual vapor intrusion (VI) evaluation activities. This facility is designated Solid Waste Management Unit (SWMU) Number 055 (SWMU 055) under KSC’s Resource Conservation and Recovery Act (RCRA) Corrective Action program. HydroGeoLogic, Inc. (HGL) prepared this report for the National Aeronautics and Space NASA) under contract number 80KSC019F0096/80KSC019D0012, Technical Directive-03. An Advance Data Package (ADP) presentation of the elements of this report received Team (KSCRT) agreement at the April 5, 2023, KSCRT meeting. The chlorinated volatile organic compound plume appears to be stable vertically and horizontally. Additional DPT groundwater sampling will be completed to support a remedial alternatives evaluation for potential means to expedite groundwater cleanup. There are per- and polyfluorinated alkyl substances in site groundwater, and assessment is planned in the future. Sub-slab soil gas monitoring results do not indicate any concerns with indoor vapor intrusion. Based on the 2022 annual groundwater sampling results, it is recommended that annual sampling continue to alternate with the wet and dry season, with the next sampling event planned for December 2023.

groundwater↗

Ka-band MMIC array feed development for deep space applications

Ka-band MMIC transmitter arrays are under development at NASA Jet Propulsion Laboratory for future deep space and ground communication needs. A high efficiency full aperture active antenna array is desired to demonstrate solid state array technology for future NASA missions. This paper reports on a 5 watt Ka-band phased array feed and a full aperture active array for a mobile terminal which are being developed to characterize the design tradeoffs and potential of solid state Ka-band MMIC array communication systems.

Cooley, T. W.↗

On the kinetics of the pack - Aluminization process

An investigation has been made of the aluminization of unalloyed Ni in fluoride-activated packs of varying Al activity. In packs of low Al activity, in which the ratio of Al to Ni was less than 50 at. pct, the specimen surface quickly came to equilibrium with the pack and remained close to equilibrium for the duration of normal coating runs. In these packs the kinetics of aluminization was controlled by diffusion in the solid. In packs of higher Al activity the surface of the specimen did not come to equilibrium with the pack and the kinetics of the process was governed by a combination of solid and gas diffusion rates. Under most conditions however, the surface composition was time-invariant and a steady-state appeared to exist at the pack-coating interface. By combining Levine and Caves' model for gaseous diffusion in pure-Al packs with calculations of solid diffusion rates some success has been achieved in explaining the results.

Sivakumar, R.↗