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At least 253 records · Page 14

LX-17 Thermal Decomposition-Characterization of Solid Residues from Cook-Off in a Small-Scale Vessel Under Confinement

Concerns surround whether insensitive (or any) energetic materials are more dangerous to handle when exposed to abnormal thermal environments. This study characterizes the residual material remaining after LX-17 (92.5 % 1,3,5-triamino 2,4,6-trinitro benzene (TATB) and 7.5 % Kel-F) is exposed to various thermal environments in a sealed small-scale vessel cook-off test reactor (heated at 0.1 to 100 °C/min until the reactor opened at 3000 psi (20.7 MPa)). Previous work has shown no additional sensitivity of these residues as evaluated by small-scale safety analysis, but characterization on the molecular scale indicates the TATB is transformed to more reactive compounds as well as the residue could be precursors to toxic gases. The solids and chars were characterized by various analytical methods. Heat-flow measurements indicated exothermic release is due to a mixture of residual TATB and related decomposition products (which may be more energetic). The N/C and O/N ratios indicated a material much more degraded than TATB. Primarily, the solids were a network of amorphous C inter-dispersed with N and O. Types of bonding include C–C, C–N, N–H, N–C, N=C, N≡C, C–O=, and –OH. Solvent extracts of the solids showed TATB decomposition intermediates benzo-furazans and benzo-furoxans, substituted TATB (mono-nitroso, hydroxyl, and chlorinated) along with several unidentified smaller molecules. These results indicate thermal treatment produces an amorphous carbon residue with heteroatoms incorporated through differing functionality, varying depending upon the thermal severity of exposure. These structures also could further decompose producing toxic light gases (such as cyanide).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cryogenics and Fluids at NASA-Goddard Space Flight Center

Abstract: Spacecraft thermal design presents unique thermal and fluid challenges caused by a variety of harsh spacecraft thermal environments. In addition, at cryogenic temperatures (i.e., less than 123 K (-150° C), and sometimes as low as 50 milliKelvin), more challenges arise, such as the increasing importance of mitigating thermal radiation, the effects of coefficient of thermal expansion mismatches between different materials, changes in the physics behavior of materials, and increasing thermodynamic difficulty of lifting heat up large temperature gradients. In this talk, Dr. Rueger will present a broad overview of spacecraft thermal environments; cryogenic design practices; components of interest for the Cryogenics and Fluids Branch (e.g., cryocoolers, adiabatic demagnetization refrigerators, heat switches, and superconducting leads); cryogenic considerations in some current NASA mission examples (e.g., the DragonFly mission to Titan and the X-ray Imaging and Spectroscopy Mission); and capabilities of the Cryogenics and Fluids Branch at NASA.

Paul Rueger↗

Open quantum systems and Schwinger-Keldysh holograms

We initiate the study of open quantum field theories using holographic methods. Specifically, we consider a quantum field theory (the system) coupled to a holographic field theory at finite temperature (the environment). We investigate the effects of integrating out the holographic environment with an aim of obtaining an effective dynamics for the resulting open quantum field theory. The influence functionals which enter this open effective action are determined by the real-time (Schwinger-Keldysh) correlation functions of the holographic thermal environment. To evaluate the latter, we exploit recent developments, wherein the semiclassical gravitational Schwinger-Keldysh saddle geometries were identified as complexified black hole spacetimes. We compute real-time correlation functions using holographic methods in these geometries, and argue that they lead to a sensible open effective quantum dynamics for the system in question, a question that hitherto had been left unanswered. In addition to shedding light on open quantum systems coupled to strongly correlated thermal environments, our results also provide a principled computation of Schwinger-Keldysh observables in gravity and holography. In particular, these influence functionals we compute capture both the dissipative physics of black hole quasi- normal modes, as well as that of the fluctuations encoded in outgoing Hawking quanta, and interactions between them. We obtain results for these observables at leading order in a low frequency and momentum expansion in general dimensions, in addition to determining explicit results for two dimensional holographic CFT environments.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Modeling Heat-Transfer in Animal Habitats in the Shuttle Orbiter Middeck

A mathematical model has been developed to evaluate the heat transfer characteristics of an Animal Enclosure Module (AEM) in the microgravity environment. The AEM is a spaceflight habitat that provides life support for up to six rodents in the Space Shuttle Middeck. Currently, temperatures within the AEM are recorded in real time using a solid state data recorder; however, the data are only available for analysis post-flight. This temperature information is useful for characterizing the thermal environment of the AEM for researchers, but is unavailable during flight operations. Because animal health in microgravity is directly linked to the thermal environment, the ability to predict internal AEM temperatures is extremely useful to life science researchers. NASA flight crews typically carry hand-held temperature measurement devices which allow them to provide ground researchers with near real time readings of AEM inlet temperature; however, higher priority operations limit the frequency at which these measurements can be made and subsequently downlinked. The mathematical model developed allows users to predict internal cage volume temperatures based on knowledge of the ambient air temperature entering the AEM air intake ports. Additionally, an average convective heat transfer coefficient for the AEM has been determined to provide engineers with the requisite information to facilitate future design improvements and product upgrades. The model has been validated using empirical data from a series of three Space Shuttle missions.

Eodice, Michael T.↗

Not even 6 dB: Gaussian quantum illumination in thermal background

Abstract In analyses of target detection with Gaussian state transmitters in a thermal background, the thermal occupation is taken to depend on the target reflectivity in a way which simplifies the analysis of the symmetric quantum hypothesis testing problem. However, this assumption precludes comparison of target detection performance between an arbitrary transmitter and a vacuum state transmitter, i.e. ‘detection without illumination’, which is relevant in a bright thermal background because a target can be detected by its optical shadow or some other perturbation of the background. Using a target-agnostic thermal environment leads to the result that the oft-claimed 6 dB possible reduction in the quantum Chernoff exponent for a two-mode squeezed vacuum transmitter over a coherent state transmitter in high-occupation thermal background is an unachievable limiting value, only occurring in a limit in which the target detection problem is ill-posed. Further analyzing quantum illumination in a target-agnostic thermal environment shows that a weak single-mode squeezed transmitter performs worse than ‘no illumination’, which is explained by the noise-increasing property of reflected low-intensity squeezed light.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Photoheliograph thermal concepts study. Volume 1: Summary

The performances of thermal subsystem concepts for each of three photoheliograph designs oriented toward unique solar observation missions are defined. These designs and missions may be categorized as: (1) A 150-centimeter photoheliograph for large Solar Observatory (LSO) missions; (2) a 100-centimeter photoheliograph for shuttle sorties; and (3) a 100-centimeter photoheliograph for balloon missions. For each of these photoheliograph designs are the basic thermal environments, boundary conditions, and applicable thermal control concepts defined, the interactions between concepts and environments determined, and a baseline thermal control concept for the three classes of photoheliographs selected. A set of experimental work plans describing the major efforts required to further the detailed design and to confirm analytical performance predictions is included.

Source record↗

Unsteady Three-Dimensional Simulation of a Shear Coaxial GO2/GH2 Rocket Injector with RANS and Hybrid-RAN-LES/DES Using Flamelet Models

Historically, the analysis and design of liquid rocket engines (LREs) has relied on full‐scale testing and one‐dimensional empirical tools. The testing is extremely expensive and the one‐dimensional tools are not designed to capture the highly complex, and multi‐dimensional features that are inherent to LREs. Recent advances in computational fluid dynamics (CFD) tools have made it possible to predict liquid rocket engine performance, stability, to assess the effect of complex flow features, and to evaluate injector‐driven thermal environments, to mitigate the cost of testing. Extensive efforts to verify and validate these CFD tools have been conducted, to provide confidence for using them during the design cycle. Previous validation efforts have documented comparisons of predicted heat flux thermal environments with test data for a single element gaseous oxygen (GO2) and gaseous hydrogen (GH2) injector. The most notable validation effort was a comprehensive validation effort conducted by Tucker et al. [1], in which a number of different groups modeled a GO2/GH2 single element configuration by Pal et al [2]. The tools used for this validation comparison employed a range of algorithms, from both steady and unsteady Reynolds Averaged Navier‐Stokes (U/RANS) calculations, large‐eddy simulations (LES), detached eddy simulations (DES), and various combinations. A more recent effort by Thakur et al. [3] focused on using a state‐of‐the‐art CFD simulation tool, Loci/STREAM, on a two‐dimensional grid. Loci/STREAM was chosen because it has a unique, very efficient flamelet parameterization of combustion reactions that are too computationally expensive to simulate with conventional finite‐rate chemistry calculations. The current effort focuses on further advancement of validation efforts, again using the Loci/STREAM tool with the flamelet parameterization, but this time with a three‐dimensional grid. Comparisons to the Pal et al. heat flux data will be made for both RANS and Hybrid RANSLES/ Detached Eddy simulations (DES). Computation costs will be reported, along with comparison of accuracy and cost to much less expensive two‐dimensional RANS simulations of the same geometry.

Westra, Doug G.↗

Determining Thermal Capabilities for External Transfer Operations on the International Space Station

External transfers on the International Space Station (ISS) have a degree of difficulty caused by the severity of the radiative thermal environment and the complexity of the operational choreography to perform the installation and activation of the hardware. These transfers can be performed robotically, by astronauts during an Extra Vehicular Activity (EVA - spacewalk), or combination of robotic/crew operations. Robotic transfers may include capability to intermittently power the hardware; while the hardware remains unpowered for EVA operations. Robotic transfers can be staged to occur in a favorable thermal environment, though typically take longer than a transfer by crew during an EVA where the hardware may not be robotically compatible. The hardware is under passive thermal control, use of optics/multi-layer insulation/heaters, while being transferred from/to a visiting vehicle, airlock, stowage platform, or external ISS structure and may include additional design components, such as removable protective blankets, to meet the transfer requirements. Thermal analysis must be performed to determine the capability of the hardware being transferred to provide the Mission Control team the products necessary to plan and execute the operation while establishing an awareness for any contingency response. An overview of the thermal aspects in planning these types of transfer operations, the analytical approaches and assumptions, and examples of results are provided in this paper.

Thermal↗

Photoheliograph thermal concepts study. Volume 2: Detailed analysis

The photoheliograph thermal concepts study which was to define and compare the performance of thermal subsystem concepts for each of three photoheliograph designs oriented toward unique solar observation missions is reported. These design and missions are categorized as: (1) A 150-centimeter photoheliograph for large solar observatory (LSO) missions. This design is intended for multiyear orbital operations as a part of a complement of solar telescopes in a free-flying LSO configuration. (2) A 100-centimeter photoheliograph for shuttle sorties. This design is intended for observation periods of up to 2 weeks while mounted in the cargo bay of the shuttle orbiter vehicle. (3) A 100-centimeter photoheliograph for balloon missions. This design is intended to be a design verification unit and precursor to the orbital flight designs. Mission duration is on the order of a single day at an altitude of approximately 24.4 kilometers. For each of these photoheliograph designs, the basic thermal environments, boundary conditions, and applicable thermal control concepts were defined and the interactions between concepts and environments were determined. A baseline thermal control concept was selected for the three classes of photoheliographs described.

Source record↗

Operation of a Thin-Film Inflatable Concentrator System Demonstrated in a Solar Thermal Vacuum Environment

Thin-film inflatable solar concentrators offer significant advantages in comparison to stateof- the-art rigid panel concentrators, including low weight, low stowage volume, and simple gas deployment. From June 10 to 22, 2001, the ElectroMagnetic Radiation Control Experiment (EMRCE) Team used simulated solar energy to demonstrate the operation of an inflatable concentrator system at NASA Glenn Research Center's Tank 6 thermal vacuum facility. The joint Government/industry test team was composed of engineers and technicians from Glenn, the Air Force Research Laboratory, SRS Technologies, and ATK Thiokol Propulsion. The research hardware consisted of the following: 1) A thin-film inflatable concentrator; 2) The hexapod pointing and focus control system; 3) Two rigidized support struts using two candidate technologies - ultraviolet-rigidized glass and radiation-cured isographite.

Wong, Wayne A.↗

Development of a Space Irradiance Simulator for Advanced Studies and Materials Research

A lab-scale experimental apparatus that mimics the solar-thermal environment of space has recently been developed and tested at NASA Kennedy Space Center in support of novel materials research for future space science and exploration applications. The Space Irradiance Simulator (SIRS) apparatus exposes specimens up to roughly 61 mm in diameter to a similar thermal environment that exists at distances as close as 0.4 AU from the Sun. This includes a high vacuum environment, access to a deep cryogenic background temperature with optical properties that closely imitate a blackbody, and irradiance from a broadband solar “point” source at fluxes as high as 9300 W/m2. Cooling is provided by a Gifford-McMahon cryocooler capable of 25 W of cooling power at 20 K, with a base temperature of 14 K. A commercially available Xeon lamp acts as the solar source, creating broadband electromagnetic radiation with a spectrum similar to that of the Sun. Light is beamed through the vacuum chamber and onto a sample suspended within the cold-mass via a flexible quartz fiber bundle in conjunction with a custom vacuum feedthrough. The system design, fabrication, and operation are discussed; and results from the initial checkout testing of the system are presented.

A. M. Swanger↗

A computer program to perform flow and thermal analysis during pressurization of the Space Shuttle Solid Rocket Motor field joint

A computational technique for prediction of the flow and thermal environment in the SRM field joint cavities is described. The SRM field joint hardware was tested with a defect in the insulation, and due to this defect, the O-ring gland cavities are pressurized during the early part of the ignition. A computer model is developed to predict the thermal environment and flow through the simulated flaw, during the pressurization of the field joint. The transient mass, momentum, and energy conservation equations in the flow passage together with the thermodynamic equation of state are solved by a fully implicit iterative numerical procedure.

Clayton, J. Louie↗

Investigating Diurnal Changes in the Normal Albedo of the Lunar Surface at 1064 nm: A New Analysis with the Lunar Orbiter Laser Altimeter

The thermal environment of the lunar surface is extreme. At the equator, temperatures drop ~300 K between local noon and night. Laboratory studies demonstrate that minerals common to the lunar surface (e.g.,pyroxene, olivine) show spectral changes with respect to temperature in near infrared wavelengths. Over temperature changes equivalent to the lunar thermal environment (ΔT ≈ 300K), the reflectance of pure pyroxene samples can vary by a factor of two.

Deutsch, Ariel N.↗

A Software Upgrade of the NASA Aeroheating Code "MINIVER"

Computational Fluid Dynamics (CFD) is a powerful and versatile tool simulating fluid and thermal environments of launch and re-entry vehicles alike. Where it excels in power and accuracy, however, it lacks in speed. An alternative tool for this purpose is known as MINIVER, an aeroheating code widely used by NASA and within the aerospace industry. Capable of providing swift, reasonably accurate approximations of the fluid and thermal environment of launch vehicles, MINIVER is used where time is of the essence and accuracy need not be exact. However, MINIVER is an old, aging tool: running on a user-unfriendly, legacy command-line interface, it is difficult for it to keep pace with more modem software tools. Florida Institute of Technology was tasked with the construction of a new Graphical User Interface (GUI) that implemented the legacy version's capabilities and enhanced them with new tools and utilities. This thesis provides background to the legacy version of the program, the progression and final version of a modem user interface, and benchmarks to demonstrate its usefulness.

Louderback, Pierce Mathew↗

Mission Life Thermal Analysis and Environment Correlation for the Lunar Reconnaissance Orbiter

Standard thermal analysis practices include stacking worst-case conditions including environmental heat loads, thermo-optical properties and orbital beta angles. This results in the design being driven by a few bounding thermal cases, although those cases may only represent a very small portion of the actual mission life. The NASA Goddard Space Flight Center Thermal Branch developed a procedure to predict the flight temperatures over the entire mission life, assuming a known beta angle progression, variation in the thermal environment, and a degradation rate in the coatings. This was applied to the Global Precipitation Measurement core spacecraft. In order to assess the validity of this process, this work applies the similar process to the Lunar Reconnaissance Orbiter. A flight-correlated thermal model was exercised to give predictions of the thermal performance over the mission life. These results were then compared against flight data from the first two years of the spacecraft s use. This is used to validate the process and to suggest possible improvements for future analyses.

Garrison, Matthew B.↗

Aerothermodynamic environment and thermal protection for a Titan aerocapture vehicle

This paper presents thermal protection system (TPS) requirements for a potential Titan aerocapture vehicle. Shock-layer solutions are obtained for a nominal trajectory through the current Titan model atmosphere. Fully laminar and fully turbulent solutions are presented along the blunted fore-cone in the windward symmetry plane of a bent-biconic vehicle. Using these solutions to define the aerothermodynamic environment, transient material-response solutions are obtained for a Galileo-type TPS with a carbon-phenolic ablator heat shield. Shock-layer results indicate that turbulent flow is the more realistic flow condition. They also show that the lengthy aerocapture heating pulse is dominated by convective heating. The TPS results show that the required insulation thickness is uniformly about 4 cm along the fore-cone because of the long heat-soak period. The total heat-shield thickness is 6.4 cm at the stagnation point, and 4.7 cm near the end of the fore-cone. These TPS requirements are greater than those presented in a previous Titan aerocapture study.

Green, M. J.↗