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Molecules of significance in planetary aeronomy

This monograph is basically devoted to spectroscopic information of the molecules of planetary interest. Only those molecules have been dealt with which have been confirmed spectroscopically to be present in the atmosphere of major planets of our solar system and play an important role in the aeronomy of the respective planets. An introduction giving the general conditions of planets and their atmospheres including the gaseous molecules is given. Some typical planetary spectra is presented and supported with a discussion on some basic concepts of optical absorption and molecular parameters that are important to the study of planetary atmospheres. Quantities like dipole moments, transition probabilities, Einstein coefficients and line strengths, radiative life times, absorption cross sections, oscillator strengths, line widths and profiles, equivalent widths, growth curves, bond strengths, electronic transition moments, Franck-Condon factors and r-centroids, etc., are discussed. Spectroscopic information and relevant data of 6 diatomic (HF, HCL, CO, H2, O2, N2) and 6 polyatomic (CO2, N2), O3, HeO, NH3, CH4) molecules are presented.

Mohan, H.↗

Solar-terrestrial influences on weather and climate; Proceedings of the Symposium, Ohio State University, Columbus, Ohio, August 24-28, 1978

The book contains most of the invited papers and contributions presented at the symposium/workshop on solar-terrestrial influences on weather and climate. Four main issues dominate the activities of the symposium: whether solar variability relationships to weather and climate is a fundamental scientific question to which answers may have important implications for long-term weather and climate prediction; the sun-weather relationships; other potential solar influences on weather including the 11-year sunspot cycle, the 27-day solar rotation, and special solar events such as flares and coronal holes; and the development of practical use of solar variability as a tool for weather and climatic forecasting, other than through empirical approaches. Attention is given to correlation topics; solar influences on global circulation and climate models; lower and upper atmospheric coupling, including electricity; planetary motions and other indirect factors; experimental approaches to sun-weather relationships; and the role of minor atmospheric constituents.

Mccormac, B. M.↗

The role of earth radiation budget studies in climate and general circulation research

The use of earth radiation budget (ERB) data for climate and general circulation research is studied. ERB measurements obtained in the 1960's and 1970's have provided data on planetary brightness, planetary global energy balances, the greenhouse effect, solar insolation, meridional heat transport by oceans and atmospheres, regional forcing, climate feedback processes, and the computation of albedo values in low latitudes. The role of clouds in governing climate, in influencing the general circulation, and in determining the sensitivity of climate to external perturbations needs to be researched; a procedure for analyzing the ERB data, which will address these problems, is described. The approach involves estimating the clear-sky fluxes from the high spatial resolution scanner measurement and defining a cloud radiative forcing; the global average of the sum of the solar and long-wave cloud forcing yields the net radiative effect of clouds on the climate.

Ramanathan, V.↗

Effective mie-scattering and CO2 absorption in the dust-laden Martian atmosphere and its impact on radiative-convective temperature changes in the lower scale heights

A time dependent computer model of radiative-convective-conductive heat transfer in the Martian ground-atmosphere system was refined by incorporating an intermediate line strength CO2 band absorption which together with the strong-and weak-line approximation closely simulated the radiative transmission through a vertically inhomogeneous stratification. About 33,000 CO2 lines were processed to cover the spectral range of solar and planetary radiation. Absorption by silicate dust particulates, was taken into consideration to study its impact on the ground-atmosphere temperature field as a function of time. This model was subsequently attuned to IRIS, IR-radiometric and S-band occultation data. Satisfactory simulations of the measured IRIS spectra were accomplished for the dust-free condition. In the case of variable dust loads, the simulations were sufficiently fair so that some inferences into the effect of dust on temperature were justified.

Pallmann, A. J.↗

Aeolian geomorphology from the global perspective

Any planet or satellite having a dynamic atmosphere and a solid surface has the potential for experiencing aeolian (wind) processes. A survey of the Solar System shows at least four planetary objects which potentially meet these criteria: Earth, Mars, Venus, and possibly Titan, the largest satellite of Saturn. While the basic process is the same among these four objects, the movement of particles by the atmosphere, the aeolian environment is drastically different. It ranges from the hot (730 K), dense atmosphere of Venus to the extremely cold desert (218 K) environment of Mars where the atmospheric surface pressure is only approximately 7.5 mb. In considering aeolian processes in the planetary perspective, all three terrestrial planets share some common areas of attention for research, especially in regard to wind erosion and dust storms. Relevant properties of planetary objects potentially subject to aeolian processes are given in tabular form.

Greeley, R.↗

An Impact Triggered Runaway Greenhouse on Mars

When a planet is in radiative equilibrium, the incoming solar flux balances the outgoing longwave flux. If something were to perturb the system slightly, say the incoming solar flux increased, the planet would respond by radiating at a higher surface temperature. Since any radiation that comes in must go out, if the incoming is increased, the outgoing must also increase, and this increase manifests itself as a warmer equilibrium temperature. The increase in solar flux would correspond to an increase in temperature, which would increase the amount of water vapor in the atmosphere due to increased evaporation. Since water vapor is a greenhouse gas, it would absorb more radiation in the atmosphere leading to a yet warmer equilibrium temperature. The planet would reach radiative equilibrium at this new temperature. There exists a point, however, past which this positive feedback leads to a "runaway" situation. In this case, the planet does not simply evaporate a little more water and eventually come to a slightly higher equilibrium temperature. Instead, the planet keeps evaporating more and more water until all of the planet's available liquid and solid water is in the atmosphere. The reason for this is generally understood. If the planet's temperature increases, evaporation of water increases, and the absorption of radiation increases. This increases the temperature and the feedback continues until all water is in the atmosphere. The resulting equilibrium temperature is very high, much higher than the equilibrium temperature of a point with slightly lower solar flux. One can picture that as solar flux increases, planetary temperature also increases until the runaway point where temperature suddenly "jumps" to a higher value, in response to all the available water now residing in the atmosphere. This new equilibrium is called a "runaway greenhouse" and it has been theorized that this is what happened to the planet Venus, where the surface temperature is more than 700 K (427 C).

Segura, T. L.↗

Hierarchies of Models: Toward Understanding Planetary Nebulae

Stars like our sun (initial masses between 0.8 to 8 solar masses) end their lives as swollen red giants surrounded by cool extended atmospheres. The nuclear reactions in their cores create carbon, nitrogen and oxygen, which are transported by convection to the outer envelope of the stellar atmosphere. As the star finally collapses to become a white dwarf, this envelope is expelled from the star to form a planetary nebula (PN) rich in organic molecules. The physics, dynamics, and chemistry of these nebulae are poorly understood and have implications not only for our understanding of the stellar life cycle but also for organic astrochemistry and the creation of prebiotic molecules in interstellar space. We are working toward generating three-dimensional models of planetary nebulae (PNe), which include the size, orientation, shape, expansion rate and mass distribution of the nebula. Such a reconstruction of a PN is a challenging problem for several reasons. First, the data consist of images obtained over time from the Hubble Space Telescope (HST) and spectra obtained from Kitt Peak National Observatory (KPNO) and Cerro Tololo Inter-American Observatory (CTIO). These images are of course taken from a single viewpoint in space, which amounts to a very challenging tomographic reconstruction. Second, the fact that we have two disparate and orthogonal data types requires that we utilize a method that allows these data to be used together to obtain a solution. To address these first two challenges we employ Bayesian model estimation using a parameterized physical model that incorporates much prior information about the known physics of the PN. In our previous works we have found that the forward problem of the comprehensive model is extremely time consuming. To address this challenge, we explore the use of a set of hierarchical models, which allow us to estimate increasingly more detailed sets of model parameters. These hierarchical models of increasing complexity are akin to scientific theories of increasing sophistication, with each new model/theory being a refinement of a previous one by either incorporating additional prior information or by introducing a new set of parameters to model an entirely new phenomenon. We apply these models to both a simulated and a real ellipsoidal PN to initially estimate the position, angular size, and orientation of the nebula as a two-dimensional object and use these estimates to later examine its three-dimensional properties. The efficiency/accuracy tradeoffs of the techniques are studied to determine the advantages and disadvantages of employing a set of hierarchical models over a single comprehensive model.

Knuth, Kevin H.↗

Hierarchies of Models: Toward Understanding Planetary Nebulae

Stars like our sun (initial masses between 0.8 to 8 solar masses) end their lives as swollen red giants surrounded by cool extended atmospheres. The nuclear reactions in their cores create carbon, nitrogen and oxygen, which are transported by convection to the outer envelope of the stellar atmosphere. As the star finally collapses to become a white dwarf, this envelope is expelled from the star to form a planetary nebula (PN) rich in organic molecules. The physics, dynamics, and chemistry of these nebulae are poorly understood and have implications not only for our understanding of the stellar life cycle but also for organic astrochemistry and the creation of prebiotic molecules in interstellar space. We are working toward generating three-dimensional models of planetary nebulae (PNe), which include the size, orientation, shape, expansion rate and mass distribution of the nebula. Such a reconstruction of a PN is a challenging problem for several reasons. First, the data consist of images obtained over time from the Hubble Space Telescope (HST) and spectra obtained from Kitt Peak National Observatory (KPNO) and Cerro Tololo Inter-American Observatory (CTIO). These images are of course taken from a single viewpoint in space, which amounts to a very challenging tomographic reconstruction. Second, the fact that we have two disparate and orthogonal data types requires that we utilize a method that allows these data to be used together to obtain a solution. To address these first two challenges we employ Bayesian model estimation using a parameterized physical model that incorporates much prior information about the known physics of the PN. In our previous works we have found that the forward problem of the comprehensive model is extremely time consuming. To address this challenge, we explore the use of a set of hierarchical models, which allow us to estimate increasingly more detailed sets of model parameters. These hierarchical models of increasing complexity are akin to scientific theories of increasing sophistication, with each new model/theory being a refinement of a previous one by either incorporating additional prior information or by introducing a new set of parameters to model an entirely new phenomenon. We apply these models to both a simulated and a real ellipsoidal PN to initially estimate the position, angular size, and orientation of the nebula as a two-dimensional object and use these estimates to later examine its three-dimensional properties. The efficiency/accuracy tradeoffs of the techniques are studied to determine the advantages and disadvantages of employing a set of hierarchical models over a single comprehensive model.

Knuth, Kevin H.↗

A Congeries of Absorption Cross Sections for Wavelengths Less Than 3000 degrees Angstrom

The absorption of ultraviolet solar radiation is of prime importance for the study of planetary atmospheres.The absorption coefficients of most of the atmospheric gases have been measured by a number of investigators, but the results are scattered throughout the literature. This report contains a detailed collection of absorption cross sections of the gases listed in Table 1 for wavelengths less than 3000 degrees angstroms. The data on each gas are given together with a historical sketch of the study of the gas and a list of the pertinent references. Also included is a study of the absorption and photoionization coefficients of the major atmospheric gases at intense solar emission lines.

Sullivan, J. O.↗

Relating terrestrial atmospheric circulation to solar disturbances

Presented are models of two proposed mechanisms for transferring angular momentum from ionospheric heights to the vicinity of the tropopause. The first mechanism consist of a vicious coupling of the upper atmosphere to the troposphere and the second requires changes in the reflection of planetary waves by the thermosphere. This second mechanism is very appealing because it makes use only of energy derived from the lower atmosphere itself, with solar activity directly modifying only the thermospheric reflectivity.

Hines, C. O.↗

Occultation studies of the solar system

Because of their high spatial resolution, stellar occultations have proven extremely effective for learning about planetary upper atmospheres, asteroids, and planetary rings. The occultation program at MIT involves the following: (1) identifying the scientific questions that can be answered by occultation events; (2) predicting the zone of visibility for the useful events; (3) maintaining and improving a high speed CCD camera for observing occultations; (4) obtaining the observations; and (5) reducing the data and interpreting the results.

Elliot, James L.↗

Solar-wind interaction with planetary ionospheres

Planetary encounters by numerous spacecraft have furnished information concerning the solar wind interaction with the planets Mercury, Venus, Mars, and Jupiter. While direct measurements have indicated a wide range of atmospheric densities and intrinsic magnetic field strengths, the data seem to indicate that the flow pattern around nonmagnetized or weakly magnetized planets with atmospheres optically thick at ionizing wavelengths is basically the same as that around a strongly magnetized planet's magnetosphere, such as the earth's. The planetary ionosphere apparently presents a hard obstacle to the flow, with bow shock formation required in the supersonic, super-Alfvenic flow to slow and direct most of the solar wind plasma around the planetary ionosphere. Various aspects of the interaction are examined in the context of theoretical models in an attempt to explain observed details of the interaction regions of Venus and Mars.

Cloutier, P. A.↗

Mercury's atmosphere - A perspective after Mariner 10

Implications of Mariner 10 observations are discussed regarding the composition and structure of Mercury's atmosphere as well as its interaction with the solar wind. The Mariner 10 data cited indicate that Mercury's atmosphere is apparently similar to that on the moon. It is shown that helium could be supplied to the atmosphere either by the radioactive decay of uranium and thorium in the planetary crust or by accretion of a small fraction of the solar-wind flux. It is noted that the absence of argon could be explained by a potassium-deficient crust, but this conclusion is by no means firm. Upper limits for outgassing of H2O and CO2 are estimated which suggest that either the planet is deficient in volatiles or is relatively inactive in comparison with earth.

Kumar, S.↗

The twilight zone of venus.

Twilight zone of venus, examining cusps, brightness, refraction at solar transit, atmospheric circulation, uv clouds and dichotomy

TWILIGHT↗

Submillimeter and millimeter observations of solar system objects

Microwave spectroscopy of solar system objects was supported. It necessarily involves millimeter and submillimeter wavelengths where rotational transitions reside. The existing national facilities are at OVRO, the 12-meter at Kitt Peak, UC array at Hat Creek, the Caltech CSO on Mauna Kea, and the 14-meter at the Univ. of Massachusetts, near Amherst. The group used all of these instruments in the last year except the Univ. of Massachusetts 14-meter. This wavelength range (0.3 to 3 mm) is about to enjoy an explosion of interest as submillimeter receivers become better and easier to use. This region of the spectrum is rich in transitions of molecules that exist in the planetary atmospheres which can be studied for temperature-pressure profiles, wind tracers, and atmospheric chemistry. The list of solar system objects that have been recently addressed with these techniques include: (1) Venus: CO studies of T-P profiles, winds, and photochemistry; SO2 detections; Continuum mapping remains to be done at 1 mm; (2) Earth H2O, CO, NO, NO2, O(18)O, etc. as a test bed for other atmospheres; (3) Mars: H2O, CO, O(18)O studies of T-P profiles, winds (fall of 1990), and photochemistry; (4) Saturn: Same as Jupiter plus submillimeter and millimeter mapping of the ring system; (5) Uranus and Neptune: Continuum thermal mapping; and (6) Titan: CO, HCN, and HC3NT-P information and photochemistry. Recent results are given.

Muhleman, Duane O.↗

Inferring surface solar absorption from broadband satellite measurements

An atmospheric solar radiation model and surface albedo models that include wavelength dependence and surface anisotropy are combined to study the possibility of inferring the surface solar absorption from satellite measurements. The model includes ocean, desert, pasture land, savannah, and bog surface categories. Problems associated with converting narrowband measurements to broadband quantities are discussed, suggesting that it would be easier to infer surface solar absorption from broadband measurements directly. The practice of adopting a linear relationship between planetary and surface albedo to estimate surface albedos from satellite measurements is examined, showing that the linear conversion between broadband planetary and surface albedos is strongly dependent on vegetation type. It is suggested that there is a linear slope-offset relationship between surface and surface-atmosphere solar absorption.

Cess, Robert D.↗

Direct detection of C4H2 photochemical products - Possible routes to complex hydrocarbons in planetary atmospheres

The photochemistry of diacetylene (C4H2), the largest hydrocarbon to be unambiguously identified in planetary atmospheres, is of considerable importance to understanding the mechanisms by which complex molecules are formed in the solar system. In this work, the primary products of C4H2's ultraviolet photochemistry were determined in a two-laser pump-probe scheme in which the products of C4H2 photoexcitation are detected by vacuum ultraviolet photoionization in a time-of-flight mass spectrometer. Three larger hydrocarbon primary products were observed with good yield in the C4H2 + C4H2 reaction: C6H2, C8H2, and C8H3. Neither C6H2 or C8H3 is anticipated by current photochemical models of the atmospheres of Titan, Uranus, Neptune, Pluto, and Triton. The free hydrogen atoms that are released during the formation of the C8H3 and C8H2 products also may partially offset the role of C4H2 in catalyzing the recombination of free hydrogen atoms in the planetary atmospheres.

Bandy, Ralph E.↗

Pickup Ion Mass Spectrometry for Surface Bounded Exospheres and Composition Mapping of Lunar and Planetary Surfaces

Many of the small to medium sized objects in the solar system can be characterized as having surface bounded exospheres, or atmospheres so tenuous that scale lengths for inter-particle collisions are much larger than the dimensions of the objects. The atmospheres of these objects are the product of their surfaces, both the surface composition and the interactions that occur on them and also their interiors when gases escape from there. Thus by studying surface bounded exospheres it is possible to develop insight into the composition and processes that are taking place on the surface and interiors of these objects. The Moon and Mercury are two examples of planetary bodies with surface bounded exospheres that have been studied through spectroscopic observations of sodium, potassium, and, on the moon, mass spectrometric measurements of lunar gases such as argon and helium.

Keller, J. W.↗