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At least 253 records · Page 14

Molecular abundances and low-mass star formation. 1: Si- and S-bearing species toward IRAS 16293-2422

Results from millimeter and submillimeter spectral line surveys of the protobinary source Infrared Astronomical Satellite (IRAS) 16293-2422 are presented. Here we outline the abundances of silicon- and sulfur-containing species. A combination of rotation diagram and full statistical equilibrium/radiative transfer calculations is used to constrain the physical conditions toward IRAS 16293 and to construct its beam-averaged chemical composition over a 10 to 20 sec (1600 to 3200 AU) scale. The chemical complexity as judged by species such as SiO, OCS, and H2S, is intermediate between that of dark molecular clouds such as L134N and hot molecular cloud cores such as Orion KL. From the richness of the spectra compared to other young stellar objects of similar luminosity, it is clear that molecular abundances do not scale simply with mass; rather, the chemistry is a strong function of evolutionary state, i.e., age.

Blake, Geoffrey A.↗

Infrared spectra of crystalline phase ices condensed on silicate smokes at T less than 20 K

Infrared spectra of H2O, CH3OH, and NH3 condensed at T less than 20 K on amorphous silicate smokes reveal that predominantly crystalline phase ice forms directly on deposit. Spectra of these molecules condensed on aluminum substrates at T less than 20 K indicate that amorphous phase ice forms. On aluminum, crystalline phase H2O and CH3OH are formed by annealing amorphous deposits to 155 K and 130 K, respectively (or by direct deposit at these temperatures); crystalline NH3 is formed by direct deposit at 88 K. Silicate smokes are deposited onto aluminum substrates by evaporation of SiO solid or by combustion of SiH4 with O2 in flowing H2 followed by vapor phase nucleation and growth. Silicate smokes which are oxygen-deficient may contain active surface sites which facilitate the amorphous-to-crystalline phase transition during condensation. Detailed experiments to understand the mechanism are currently in progress. The assumption that amorphous phase ice forms routinely on grains at T less than 80 K is often used in models describing the volatile content of comets or in interpretations of interstellar cloud temperatures. This assumption needs to be reexamined in view of these results.

Moore, Marla H.↗

The 8-13 micron spectra of comets and the composition of silicate grains

We have analyzed the existing spectra of seven comets which show an emission feature at 7.8-13 micrometers. Most have been converted to a common calibration, taking into account the SiO feature in late-type standard stars. The spectra are compared with spectra of the Trapezium, interplanetary dust particles (IDPs), laboratory mineral samples, and small particle emission models. The emission spectra show a variety of shapes; there is no unique 'cometary silicate'. A peak at 11.20-11.25 micrometers, indicative of small crystalline olivine particles, is seen in only three comets of this sample, P/Halley, Bradfield 1987 XXIX, and Levy 1990 XX. The widths of the emission features range from 2.6 to 4.1 micrometers (FWHM). To explain the differing widths and the broad 9.8 micrometers maximum, glassy silicate particles, including both pyroxene and olivine compositions, are the most plausible candidates. Calculations of emission models confirm that small grains of glassy silicate well mixed with carbonaceous material are plausible cometary constituents. No single class of chondritic aggregate IDPs exhibits spectra closely matching the comet spectra. A mixture of IDP spectra, particularly the glass-rich aggregates, approximately matches the spectra of comets P/Halley, Levy, and Bradfield 1987 XXIX. Yet, if comets are simply a mix of IDP types, it is puzzling that the classes of IDPs are so distinct. None of the comet spectra match the spectrum of the Trapezium. Thus, the mineralogy of the cometary silicates is not the same as that of the interstellar medium. The presence of a component of crystalline silicates in comets may be evidence of mixing between high- and low-temperature regions in the solar nebula.

Hanner, Martha S.↗

Multiple outflows in the bipolar planetary nebula M1-16: A molecular line study

Extensive observations of the molecular gas in the young, compact planetary nebula M1-16 have been made, using the Swedish-ESO-Submillimeter Telescope. A map of the CO J = 2-1 emission shows that the molecular envelope contains both a slow and a fast outflow with expansion velocities of 19 km/s and greater than 34 km/s, respectively. The slow outflow is mildly elliptical, while the fast molecular outflow is bipolar. This fast outflow is roughly aligned with the very fast outflows recently found in the optical, while the long axis of the slow elliptical outflow is roughly orthogonal to the optical outflow axis. The kinematic timescales for the CO fast outflow and the optical very fast outflow agree closely, supporting the view that the former represents material in the slow outflow accelerated by the very fast outflow. The kinematic signature of a disk expanding with about 15.5 km/s can also be seen in the CO J = 2-1 data. The mass-loss rate (a) for the slow outflow is greater than or equal to 2.8 x 10(exp -5) solar mass/yr and possibly as large as 9 x 10(exp -5) solar mass/yr, (b) for the fast outflow is greater than or equal to 5 x 10(exp -6) solar mass/yr, and (c) for the very fast optically visible outflow is approximately equal 5 x 10(exp -7) solar mass/yr. The disk mass is approximately equal 6 x 10(exp -3) solar mass. Grain photoelectric heating results in temperatures of 20-70 K in molecular gas of the slow outflow. The (13)C/(12)C abundance ratio in M1-16 is found to be 0.33, quite possibly the highest found for any evolved object. Upper limits for the (18)O/(16)O and (17)O/(16)O ratios were found to be consistent with the values found in AGB stars. A search for other molecular species in M1-16 resulted in the detection of the high-excitation species HCN, CN, (13)CN, HCO(+), and H(13)CO(+) and possibly N2H(+). Both the HCO(+)/HCN and CN/HCN line-intensity ratios are enhanced, the former by a very large factor, over the values found in the envelopes of AGB stars, probably as a result of enhancement of the CN and HCO(+) abundances due to photochemistry induced by the stellar UV. The CS J = 2-1, SiO J = 2-1 (v = 0), and SiS J = 6-5 lines were not detected to low levels. For the high-excitation molecules, adequate collisional excitation of rotational levels and survival against photodissociation by the UV radiation requires significant clumping of the molecular gas into clumps with H2 densities approximately 10(exp 5)/cu cm. The IRAS fluxes of M1-16, assuming negligible contribution from line emission, imply the presence of about (1.7-0.4) x 10(exp -3) solar mass of cool dust (temperature around 50 K) and a smaller quantity, (2.7-3.1) x 10(exp -6) solar mass, of warmer dust (temperature around 125 K) for a power-law emissivity index p = 1-2. The evolutionary nature of M1-16 cannot be explained by existing single-star models of post-AGB evolution. The very high (13)C/(12)C abundance ratio in M1-16 suggests a possible evolutionary connection between M1-16 and the rare class of J-type silicate-carbon stars which also have high (13)C/(12)C ratios and are thought to be binary systems with accretion disks.

Sahai, Raghvendra↗

Thermal emission measurements 2000-400/cm (5-25 micrometers) of Hawaiian palagonitic soils and their implications for Mars

The thermal emision of two palagonitic soils, common visible and near infrared spectral analogs for bright soils on Mars, was measured over the wavelength range of 5 to 25 micrometers (2000 to 400/cm) for several partical size separates. All spectra exhibit emissivity features due to vibrations associated with H2O and SiO. The maximum variability of emissivity is approximately 20% in the short wavelength region (5 to 6.5 mirometers, 2000 to 1500/cm), and is more subdued, less than 4%, at longer wavelengths. The strengths of features present in the infrared spectra of Mars cannot be solely provided by emissivity variations of palagonite; some other material or mechanism must provide additional absorptions(s).

Roush, Ted L.↗

First 2.2 micrometer results from the iota interferometer

We present the first infrared fringe visibility measurements made with the Infrared Optical Telescope Array on Mt. Hopkins. Effective temperatures are derived for RX Boo, RS Cnc, and Beta Peg. RX Boo is the coolest small-amplitude variable giant star to have an effective temperature determination. We compare the size of its photosphere at infrared wavelengths with the sizes of its SiO and H20 radio emission regions. We also discuss initial performance parameters for the interferometer.

Dyck, H. M.↗

Model atmospheres for M (sub)dwarf stars. 1: The base model grid

We have calculated a grid of more than 700 model atmospheres valid for a wide range of parameters encompassing the coolest known M dwarfs, M subdwarfs, and brown dwarf candidates: 1500 less than or equal to T(sub eff) less than or equal to 4000 K, 3.5 less than or equal to log g less than or equal to 5.5, and -4.0 less than or equal to (M/H) less than or equal to +0.5. Our equation of state includes 105 molecules and up to 27 ionization stages of 39 elements. In the calculations of the base grid of model atmospheres presented here, we include over 300 molecular bands of four molecules (TiO, VO, CaH, FeH) in the JOLA approximation, the water opacity of Ludwig (1971), collision-induced opacities, b-f and f-f atomic processes, as well as about 2 million spectral lines selected from a list with more than 42 million atomic and 24 million molecular (H2, CH, NH, OH, MgH, SiH, C2, CN, CO, SiO) lines. High-resolution synthetic spectra are obtained using an opacity sampling method. The model atmospheres and spectra are calculated with the generalized stellar atmosphere code PHOENIX, assuming LTE, plane-parallel geometry, energy (radiative plus convective) conservation, and hydrostatic equilibrium. The model spectra give close agreement with observations of M dwarfs across a wide spectral range from the blue to the near-IR, with one notable exception: the fit to the water bands. We discuss several practical applications of our model grid, e.g., broadband colors derived from the synthetic spectra. In light of current efforts to identify genuine brown dwarfs, we also show how low-resolution spectra of cool dwarfs vary with surface gravity, and how the high-regulation line profile of the Li I resonance doublet depends on the Li abundance.

Allard, France↗

Instabilities and the transport of polarized astrophysical maser radiation

Time-dependent, radiative instabilities in the creation and transport of polarized astrophysical maser radiation in the presence of a magnetic field are calculated. The instabilities are similar to and occur under the same conditions as those found previously by Scappaticci & Watson for unpolarized maser radiation. The common limits in which the Zeeman splitting is much greater than, and much less than, the spectral line breadths are both considered in the current investigation. The resulting fluctuations in the emergent radiation are potentially relevant for the OH 1665 MHz masers which have been reported to fluctuate on timescales of 1000 s and which tend to be polarized. Instabilities occur and alter the transport of maser radiation only under a quite limited range of conditions. In particular, we find here that the instabilities do not occur for conditions that are appropriate for astrophysical masers with small Zeeman splittings such as the SiO and H2O masers. The time-independent, numerical solutions to the GKK equations of radiative transfer that have been obtained in previous investigations are thus essentially always valid except within a narrow range of conditions relevant for the OH masers.

Wallin, Bradley K.↗

Delayed detonation models for normal and subluminous type Ia sueprnovae: Absolute brightness, light curves, and molecule formation

We compute optical and infrared light curves of the pulsating class of delayed detonation models for Type Ia supernovae (SN Ia's) using an elaborate treatment of the Local Thermodynamic Equilbrium (LTE) radiation transport, equation of state and ionization balance, expansion opacity including the cooling by CO, Co(+), and SiO, and a Monte Carlo gamma-ray deposition scheme. The models have an amount of Ni-56 in the range from approximately or equal to 0.1 solar mass up to 0.7 solar mass depending on the density at which the transition from a deflagration to a detonation occurs. Models with a large nickel production give light curves comparable to those of typical Type Ia supernovae. Subluminous supernovae can be explained by models with a low nickel production. Multiband light curves are presented in comparison with the normally bright event SN 1992bc and the subluminous events Sn 1991bg and SN 1992bo to establish the principle that the delayed detonation paradigm in Chandrasekhar mass models may give a common explosion mechanism accounting for both normal and subluminous SN Ia's. Secondary IR-maxima are formed in the models of normal SN Ia's as a photospheric effect if the photospheric radius continues to increase well after maximum light. Secondary maxima appear later and stronger in models with moderate expansion velocities and with radioactive material closer to the surface. Model light curves for subluminous SN Ia's tend to show only one 'late' IR-maximum. In some delayed detonation models shell-like envelopes form, which consist of unburned carbon and oxygen. The formation of molecules in these envelopes is addressed. If the model retains a C/O-envelope and is subluminous, strong vibration bands of CO may appear, typically several weeks past maximum light. CO should be very weak or absent in normal Sn Ia's.

Hoflich, P.↗

Design of a three-layer antireflection coating for high efficiency indium phosphide solar cells using a chemical oxide as first layer

It is well known that the behavior of III-V compound based solar cells is largely controlled by their surface, since the majority of light generated carriers (63% for GaAs and 79% for InP) are created within 0.2 mu m of the surface of the illuminated cell. Consequently, the always observed high surface recombination velocity (SRV) on these cells is a serious limiting factor for their high efficiency performance, especially for those with p-n junction made by either thermal diffusion or ion implantation. A good surface passivation layer, ideally a grown oxide as opposed to a deposited one, will cause a significant reduction in the SRV without adding interface problems, thus improving the performance of III-V compound based solar cells. Another significant benefit to the overall performance of the solar cells can be achieved by a substantial reduction of their large surface optical reflection by the use of a well designed antireflection (AR) coating. In this paper, we demonstrate the effectiveness of using a chemically grown thermally and chemically stable oxide, not only for surface passivation but also as an integral part of a 3-layer AR coating for thermally diffused p+n InP solar cells. A phosphorus-rich interfacial oxide, In(PO3)3, is grown at the surface of the p+ emitter using an etchant based on HNO3, o-H3PO4 and H2O2. This oxide has the unique properties of passivating the surface as well as serving as an efficient antireflective layer yielding a measured record high AMO open-circuit voltage of 890.3 mV on a thermally diffused InP(Cd,S) solar cell. Unlike conventional single layer AR coatings such as ZnS, Sb2O3, SiO or double layer AR coatings such as ZnS/MgF2 deposited by e-beam or resistive evaporation, this oxide preserves the stoichiometry of the InP surface. We show that it is possible to design a three-layer AR coating for a thermally diffused InP solar cell using the In(PO3)3 grown oxide as the first layer and Al2O3 and MgF2 as the second and third layers respectively, so as to yield an overall theoretical reflectance of less than 2%. Since chemical oxides are readily grown on III-V semiconductors materials, the technique of using the grown oxide layer to both passivate the surface as well as serve as the first of a multilayer AR coating should work well for all III-V compound-based solar cells.

Moulot, Jacques↗

Durability of Silica-Protected Ceramics in Combustion Atmospheres

This overview of oxidation and corrosion effects on silica-protected ceramics and composites is divided into two parts: (1) External effects and (2) Internal effects. In regard to the first part, the literature indicates silica the best of the common protective oxides in pure oxygen. However in actual applications, there are four major degradation routes which must be considered: (1) Formation of SiO(g); (2) water vapor enhancement of oxidation rate of Si(OH)4 volatiles; (3) low level metal cation enhancement of oxidation rate; and (4) molten salt and slag corrosion. Several protective coating concepts have been discussed, which may minimize these effects. Internal effects deal with a microcrack providing a path for oxygen ingress to the oxygen sensitive fiber and fiber coating. This is a critical area of study for theses materials. Possible solutions involve a fluid glass to fill the cracks and/or oxygen getting along the walls of the crack.

Jacobson, Nathan S.↗

Spectral Irradiance Calibration in the Infrared: New Composite Spectra, Comparison with Model Atmospheres, and Far-Infrared Extrapolations - Part 7

We present five new absolutely calibrated continuous stellar spectra constructed as far as possible from spectral fragments observed from the ground, the Kuiper Airborne Observatory (KAO), and the IRAS Low Resolution Spectrometer. These stars-alpha Boo, gamma Dra, alpha Cet, gamma Cru, and mu UMa-augment our six, published, absolutely calibrated spectra of K and early-M giants. All spectra have a common calibration pedigree. A revised composite for alpha Boo has been constructed from higher quality spectral fragments than our previously published one. The spectrum of gamma Dra was created in direct response to the needs of instruments aboard the Infrared Space Observatory (ISO); this star's location near the north ecliptic pole renders it highly visible throughout the mission. We compare all our low-resolution composite spectra with Kurucz model atmospheres and find good agreement in shape, with the obvious exception of the SiO fundamental, still lacking in current grids of model atmospheres. The CO fundamental seems slightly too deep in these models, but this could reflect our use of generic models with solar metal abundances rather than models specific to the metallicities of the individual stars. Angular diameters derived from these spectra and models are in excellent agreement with the best observed diameters. The ratio of our adopted Sirius and Vega models is vindicated by spectral observations. We compare IRAS fluxes predicted from our cool stellar spectra with those observed and conclude that, at 12 and 25 microns, flux densities measured by IRAS should be revised downwards by about 4.1% and 5.7%, respectively, for consistency with our absolute calibration. We have provided extrapolated continuum versions of these spectra to 300 microns, in direct support of ISO (PHT and LWS instruments). These spectra are consistent with IRAS flux densities at 60 and 100 microns.

Cohen, Martin↗

Hydrogen Molecules in SN 1987A

The observations of CO and SiO in the infrared spectrum of SN 1987A clearly indicate that molecules can form in the debris of a supernova explosion. Since H2 is not easily observable we compute its abundance theoretically. For conditions typical of the inner (v less than 2500 km/s) envelope of SN 1987A, the fraction of H that is in molecular form rises to approx. 1% by t approx. 800 days. For t less than 500 days the formation is dominated by the gas-phase reactions H + H(+) yields H2(+) + hv; H2(+) + H yields H2 + H(+). Thereafter, the formation is dominated by the reactions H + e yields H(-) + hv; H(-) + H yields H2 + e. At early times the H(-) may absorb approx. 10%-30% of visible photons, contributing to the apparent paucity of H alpha emission. For t greater than 1000 days the abundance of H2 'freezes out' due to the slowing of all reactions. The opacity of the supernova envelope in the range 912 less than lambda less than or approx. equal to 1400 A (the upper limit depending on temperature) is dominated by resonance scattering in the Lyman and Werner bands of H2. The resulting fluorescence emission bands of H2 in the range 1150 less than lambda less than 1650 A may be observable in the UV spectra of supernovae at late times.

Culhane, Michael↗

Thermal emission measurements 2000-400 cm(exp -1) (5-25 microns) of Hawaiian palagonitic soils and their implications for Mars

The thermal emission of two palagonitic soils, common visible and near infrared spectral analogs for bright soils on Mars, was measured over the wavelength range of 5 to 25 microns (2000 to 400 cm(exp -1) for several particle size separates. All spectra exhibit emissivity features due to vibrations associated with H2O and SiO. The maximum variability of emissivity is approx. = 20% in the short wavelength region (5 to 6.5 microns, 2000 to 1500 cm(exp -1)), and is more subdued, < 4%, at longer wavelengths. The strengths of features present in infrared spectra of Mars cannot be solely provided by emissivity variations of palagonite; some other material or mechanism must provide additional absorption(s).

Roush, Ted L.↗

"CHON" particles: The interstellar component of cometary dust

Interstellar dust is characterized by strong absorption in the ultraviolet and the mid-IR. Current models of interstellar dust are based on three chemically distinct components: a form of carbon (usually graphite), a silicate, and a blend of polycyclic aromatic hydrocarbons or other carbonaceous material. Previous work using effective medium theories to understand the optical properties of cometary dust suggested that an amalgam of materials could reproduce the observed interstellar and cometary dust features. Recently, Lawler and Brownlee (1992) re-analyzed the PIA and PUMA-1 data sets from the Giotto flyby of P/Halley and discovered that the so-called "CHON" particles were actually composed of a blend of carbon-bearing and silicon-bearing materials. Based on effective medium theories, the absorption spectrum of such a material would display the spectral features of each of the components - strong UV absorption from the carbonaceous component and strong absorption in the IR from the silicate component. To test this idea, vapor-deposited samples were created using two different deposition techniques: sputtering with an argon RF magnetron and deposition from an argon plasma torch. Two different compositions were tested: a blend of graphite and silica in a 7:1 ratio and an amalgam of materials whose approximate composition matches the "CHON"-silicate abundances for the uncompressed PIA data set of Lawler and Brownlee: graphite, iron oxide, magnesium oxide, ammonium sulfate, calcium carbonate, and silica in mass ratios of 6:4.3:4:2.2:1:9. The samples were finely ground and pressed into 2" diameter disks using a 40 ton press. In all, four different experiments were performed: one with each of the compositions (C:SiO and "CHON") in both the RF magnetron and the plasma torch chambers. The RF magnetron created a uniform dark thin film on the substrate surface, and the plasma torch created a coating of small (<100 micron) diameter grey particles. The spectra of all four samples show a strong, broad absorption feature at around 220 nm as well as a strong but narrower absorption peak near 10 microns. The RF magnetron sputtered samples showed some sub-structure in the UV, and the peak of the absorption was shifted toward longer wavelengths. The UV absorption in the plasma torch deposited samples have no sub-structure, and the peak absorption is very near 220 nm. Strong absorption near 9 microns is seen in the spectra from both sample preparation techniques, and is consistent with the IR spectra of some terrestrial silicates. Other features, particularly at 6.2 and 8.6 microns, are seen in the interstellar medium. A strong feature near 2 microns is due to absorbed water in the sample. Based on the results of these experiments, there is evidence that a material with a composition similar to that detected in "CHON" particles in the coma of P/Halley have a spectral signature which reproduces the main absorption features of interstellar dust. This suggests that the "CHON" particles could be the interstellar component of cometary dust.

Lien, David J.↗

Evaluation of Low Earth Orbit Environmental Effects on International Space Station Thermal Control Materials

Samples of International Space Station (ISS) thermal control coatings were exposed to simulated low Earth orbit (LEO) environmental conditions to determine effects on optical properties. In one test, samples of the white paint coating Z-93P were coated with outgassed products from Tefzel(R) (ethylene tetrafluoroethylene copolymer) power cable insulation as-may occur on ISS. These samples were then exposed, along with an uncontaminated Z-93P witness sample, to vacuum ultraviolet (VUV) radiation to determine solar absorptance degradation. The Z-93P samples coated with Tefzel(R) outgassing products experienced greater increases in solar absorptance than witness samples not coated with Tefzel(R) outgassing products. In another test, samples of second surface silvered Teflon(R) FEP (fluorinated ethylene propylene), SiO. (where x=2)-coated silvered Teflon(R) FEP, and Z-93P witness samples were exposed to the combined environments of atomic oxygen and VLTV radiation to determine optical properties changes due to these simulated ISS environmental effects. This test verified the durability of these materials in the absence of contaminants.

Dever, Joyce A.↗

SiC Recession Due to SiO2 Scale Volatility Under Combustion Conditions: Thermodynamics and Gaseous Diffusion Model - Part 2

In combustion environments, volatilization of SiO2 to Si-O-H(g) species is a critical issue. Available thermochemical data for Si-O-H(g) species were used to calculate boundary layer controlled fluxes from SiO2. Calculated fluxes were compared to volatilization rates Of SiO2 scales grown on SiC which were measured in Part 1 of this paper. Calculated volatilization rates were also compared to those measured in synthetic combustion gas furnace tests. Probable vapor species were identified in both fuel-lean and fuel-rich combustion environments based on the observed pressure, temperature and velocity dependencies as well as the magnitude of the volatility rate. Water vapor is responsible for the degradation of SiO2 in the fuel-lean environment. Silica volatility in fuel-lean combustion environments is attributed primarily to the formation of Si(OH)4(g) with a small contribution of SiO(OH)2(g).

Opila, Elizabeth J.↗

Evaluation of Space Power Materials Flown on the Passive Optical Sample Assembly

Evaluating the performance of materials on the exterior of spacecraft is of continuing interest, particularly in anticipation of those applications that will require a long duration in low Earth orbit. The Passive Optical Sample Assembly (POSA) experiment flown on the exterior of Mir as a risk mitigation experiment for the International Space Station was designed to better understand the interaction of materials with the low Earth orbit environment and to better understand the potential contamination threats that may be present in the vicinity of spacecraft. Deterioration in the optical performance of candidate space power materials due to the low Earth orbit environment, the contamination environment, or both, must be evaluated in order to propose measures to mitigate such deterioration. The thirty two samples of space power materials studied here include solar array blanket materials such as polyimide Kapton H and SiO(x) coated polyimide Kapton H, front surface aluminized sapphire, solar dynamic concentrator materials such as silver on spin coated polyimide and aluminum on spin coated polyimide, CV 1144 silicone, and the thermal control paint Z-93-P. The physical and optical properties that were evaluated prior to and after the POSA flight include mass, total, diffuse, and specular reflectance, solar absorptance, and infrared emittance. Additional post flight evaluation included scanning electron microscopy to observe surface features caused by the low Earth orbit environment and the contamination environment, and variable angle spectroscopic ellipsometry to identify contaminant type and thickness. This paper summarizes the results of pre- and post-flight measurements, identifies the mechanisms responsible for optical properties deterioration, and suggests improvements for the durability of materials in future missions.

Jaworske, Donald A.↗