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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

NASA/IEEE MSST 2004 Twelfth NASA Goddard Conference on Mass Storage Systems and Technologies in cooperation with the Twenty-First IEEE Conference on Mass Storage Systems and Technologies

MSST2004, the Twelfth NASA Goddard / Twenty-first IEEE Conference on Mass Storage Systems and Technologies has as its focus long-term stewardship of globally-distributed storage. The increasing prevalence of e-anything brought about by widespread use of applications based, among others, on the World Wide Web, has contributed to rapid growth of online data holdings. A study released by the School of Information Management and Systems at the University of California, Berkeley, estimates that over 5 exabytes of data was created in 2002. Almost 99 percent of this information originally appeared on magnetic media. The theme for MSST2004 is therefore both timely and appropriate. There have been many discussions about rapid technological obsolescence, incompatible formats and inadequate attention to the permanent preservation of knowledge committed to digital storage. Tutorial sessions at MSST2004 detail some of these concerns, and steps being taken to alleviate them. Over 30 papers deal with topics as diverse as performance, file systems, and stewardship and preservation. A number of short papers, extemporaneous presentations, and works in progress will detail current and relevant research on the MSST2004 theme.

Kobler, Ben↗

A Magnetic Solid-State Storage Technology: Vertical Bloch Line Storage

No storage technology is known to exist today which simultaneously offers high-storage density, nonvolatility, and a solid-state form factor. For example, common random access memories are solid-state, but are volatile and typically offer modest density. Alternatively, mainstream magnetic disk and magnetic tape systems offer high storage density and nonvolatility, but are fundamentally not solid-state. A number of applications exist which would be suited well with high performance solid- state technology. NASA, for example, is beginning baseline solid-state recorders for upcoming space missions, such as the Cassini mission to Saturn.

Katti, R. R.↗

3D printing technologies for electrochemical energy storage

Fabrication of electrodes and electrolytes play an important role in promoting the performance of electrochemical energy storage (EES) devices such as batteries and supercapacitors. Traditional fabrication techniques have limited capability in controlling the geometry and architecture of the electrode and solid-state electrolytes, which would otherwise compromise the performance. 3D printing, a disruptive manufacturing technology, has emerged as an innovative approach to fabricating EES devices from nanoscale to macroscale and from nanowatt to megawatt, providing great opportunities to accurately control device geometry (e.g., dimension, porosity, morphology) and structure with enhanced specific energy and power densities. Moreover, the additive manufacturing nature of 3D printing provides excellent controllability of the electrode thickness with much simplified process in a cost effective manner. With the unique spatial and temporal material manipulation capability, 3D printing can integrate multiple nanomaterials in the same print, and multi-functional EES devices (including functional gradient devices) can be fabricated. Herein, we review recent advances in 3D printing of EES devices. We focused on two major 3D printing technologies including direct writing and inkjet printing. The direct material deposition characteristics of these two processes enable them to print on a variety of flat substrates, even a conformal one, well suiting them to applications such as wearable devices and on-chip integrations. Other potential 3D printing techniques such as freeze nano-printing, stereolithography, fused deposition modeling, binder jetting, laminated object manufacturing, and metal 3D printing are also introduced. The advantages and limitations of each 3D printing technology are extensively discussed. More importantly, we provide a perspective on how to integrate the emerging 3D printing with existing technologies to create structures over multiple length scale from macro to nano for EES applications.

3D printing↗

2D metal carbides and nitrides (MXenes) for energy storage

The family of 2D transition metal carbides, carbonitrides and nitrides (collectively referred to as MXenes) has expanded rapidly since the discovery of Ti 3 C 2 in 2011. The materials reported so far always have surface terminations, such as hydroxyl, oxygen or fluorine, which impart hydrophilicity to their surfaces. About 20 different MXenes have been synthesized, and the structures and properties of dozens more have been theoretically predicted. Furthermore, the availability of solid solutions, the control of surface terminations and a recent discovery of multi-transition-metal layered MXenes offer the potential for synthesis of many new structures. The versatile chemistry of MXenes allows the tuning of properties for applications including energy storage, electromagnetic interference shielding, reinforcement for composites, water purification, gas- and biosensors, lubrication, and photo-, electro- and chemical catalysis. Attractive electronic, optical, plasmonic and thermoelectric properties have also been shown. Here, we present the synthesis, structure and properties of MXenes, as well as their energy storage and related applications, and an outlook for future research.

25 ENERGY STORAGE↗

Two-dimensional heterostructures for energy storage

Two-dimensional (2D) materials provide slit-shaped ion diffusion channels that enable fast movement of lithium and other ions. However, electronic conductivity, the number of intercalation sites, and stability during extended cycling are also crucial for building high-performance energy storage devices. While individual 2D materials, such as graphene, show some of the required properties, none of them can offer all properties needed to maximize energy density, power density, and cycle life. Here we argue that stacking different 2D materials into heterostructured architectures opens an opportunity to construct electrodes that would combine the advantages of the individual building blocks while eliminating the associated shortcomings. We discuss characteristics of common 2D materials and provide examples of 2D heterostructured electrodes that showed new phenomena leading to superior electrochemical performance. As a result, we also consider electrode fabrication approaches and finally outline future steps to create 2D heterostructured electrodes that could greatly expand current energy storage technologies.

25 ENERGY STORAGE↗

Asymmetric pathways in the electrochemical conversion reaction of NiO as battery electrode with high storage capacity

Electrochemical conversion reactions of transition metal compounds create opportunities for large energy storage capabilities exceeding modern Li-ion batteries. However, for practical electrodes to be envisaged, a detailed understanding of their mechanisms is needed, especially vis-à-vis the voltage hysteresis observed between reduction and oxidation. Here, we present such insight at scales from local atomic arrangements to whole electrodes. NiO was chosen as a simple model system. The most important finding is that the voltage hysteresis has its origin in the differing chemical pathways during reduction and oxidation. This asymmetry is enabled by the presence of small metallic clusters and, thus, is likely to apply to other transition metal oxide systems. The presence of nanoparticles also influences the electrochemical activity of the electrolyte and its degradation products and can create differences in transport properties within an electrode, resulting in localized reactions around converted domains that lead to compositional inhomogeneities at the microscale.

25 ENERGY STORAGE↗

Assigning value to energy storage systems at multiple points in an electrical grid

The ability to define the potential value that energy storage systems (ESS) could generate through various applications in electric power systems, and an understanding of how these values change due to variations in locations, ESS performance and parameters, market structure, utility structures, and valuation methodologies is highly important in advancing ESS deployment. This paper presents the outcome of an effort to assign benefits values, or more precisely ranges of values, to major ESS applications, and summarize and evaluate the capabilities of several available tools currently used to estimate value for specific ESS deployments.

energy storage valuation, balducci, energy storage↗

Practical Operations of Energy Storage Providing Ancillary Services: From Day-Ahead to Real-Time

As renewable resources are increasingly penetrating power systems, energy storage systems (ESSs) become essential in providing both energy arbitrage and ancillary services. Because of its high flexibility, ESSs have been taken into account in the daily operation of the bulk power system in many places. This paper proposes a general framework in the current electricity market environment to help system operators model the participation of multi-type ESSs and evaluate the performance of both energy arbitrage and reserve provision. We discuss different levels of ESSs' flexibility in providing ancillary services and also consider a deliberate and practical implementation of the modeling. This framework can be seamlessly integrated into the daily market operation without sacrificing computational efficiency. Numerical experiments validate the efficacy of the proposed framework and show that ESSs possess excellent potential in providing ancillary services for the bulk power system.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Fort Nelson Carbon Capture and Storage Feasibility Study: A Best Practices Manual for Storage in a Deep Carbonate Saline Formation

The Plains CO 2 Reduction (PCOR) Partnership, led by the Energy & Environmental Research Center, and Spectra Energy Transmission (SET) have investigated the feasibility of a carbon capture and storage (CCS) project to mitigate carbon dioxide (CO 2 ) emissions produced by SET's Fort Nelson Gas Plant (FNGP). The PCOR partnership applied geologic characterization; modeling; risk assessment (RA), and monitoring, verification, and accounting (MVA) strategies using an integrated, iterative process to produce superior-quality results during the project feasibility period. The Fort Nelson efforts serve as the basis for a Best Practices Manual (BPM) that offers stakeholders insight and guidance on geological storage of CO 2 in a deep carbonate saline formation.

54 ENVIRONMENTAL SCIENCES↗

Grid-Scale Electricity Storage at Lowest Possible Cost Enabled by Pumped Heat Electricity Storage (Final Report)

Grid-scale energy storage technologies that can provide greater than 10 hours of electricity at full power address a critical need for full penetration of renewables on electricity grids worldwide, minimize renewable curtailment, and maximize grid security and reliability. Pumped Heat Energy Storage (PHES) systems can store energy thermally in any location at the low costs necessary for displacing fossil fuels, reducing foreign fuel imports, and reducing emissions to maintain the energy security of the United States. The award allowed Southwest Research Institute® (SwRI®) and Malta, Inc. (Malta) to advance the PHES concept to a proof-of-concept demonstration for a kW-scale system. The project focused on system operation and integration. The main project objectives were: 1. Address first implementation challenges 2. Explore system control strategies and operation 3. Translate lessons learned to the full-scale system Through these objectives the project completes a first demonstration of this technology and reduces the technical risk associated with a full-scale system.

25 ENERGY STORAGE↗

A Play-Based Exploration of CO 2 Storage in the Illinois Basin: Community Baseline Assessment for Carbon Storage Engagement Planning in the Illinois Basin

This report presents a stakeholder mapping analysis conducted as part of the Play-Based Exploration of CO 2 Storage in the Illinois Basin project (DOE Cooperative Agreement DE-FE0032366). The analysis was undertaken to systematically identify, categorize, and characterize stakeholder groups and community conditions relevant to the planning and deployment of carbon capture and storage (CCS) infrastructure across the Illinois Basin. Its purpose is to establish a contextual baseline that informs targeted engagement strategies, supports equitable project planning, and strengthens the social dimensions of CCS site screening.

01 COAL, LIGNITE, AND PEAT↗

RCRA Part A Permit Application for Waste Management Activities at the Nevada National Security Site Hazardous Waste Storage Unit (HWSU), Explosive Ordnance Disposal Unit (EODU), Mixed Waste Storage Unit (MWSU), and Mixed Waste Disposal Unit (MWDU)

This document is the first volume in a Resource Conservation Recovery Act (RCRA) Permit Application to the Nevada Division of Environmental Protection for continued operation of certain facilities on the Nevada National Security Site (NNSS), owned by the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO). This RCRA permit application pertains to the Hazardous Waste Storage Unit (HWSU), the Explosive Ordnance Disposal Unit (EODU), the Mixed Waste Storage Unit (MWSU), and the Mixed Waste Disposal Unit (MWDU). This volume lists the relevant permits for each of these facilities and provides maps and drawings of many aspects of them. The companion volumes, which provide descriptive text and discussion and additional graphics, are jointly considered Part B of the permit application. Those volumes are identified by the following document numbers: DOE/NV/25946--2442, DOE/NV/25946--2448, DOE/NV/25946--2425, and DOE/NV/25946--2429.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Imaging the Phase Evolution of the Li-N-H Hydrogen Storage System

Complex metal hydrides provide high-density hydrogen storage, which is essential for vehicular applications. However, the utility of these materials has been limited by thermodynamic and kinetic barriers present during the dehydrogenation and rehydrogenation processes as new phases form inside parent phases. Better understanding of the mixed-phase mesostructures and their interfaces may assist in improving cyclability. In this work, the evolution of the phases during hydrogenation of lithium nitride and dehydrogenation of lithium amide with lithium hydride are probed with scanning-transmission X-ray microscopy at the nitrogen K edge. With this technique, intriguing core-shell structures were observed in particles of both partially hydrogenated Li 3 N and partially dehydrogenated LiNH 2 + 2 LiH. The potential contributions of both internal hydrogen mobility and interfacial energies on the generation of these structures are discussed.

08 HYDROGEN↗

TiO 2 Microboxes with Controlled Internal Porosity for High‐Performance Lithium Storage

Abstract Titanium dioxide (TiO 2 ) is considered a promising anode material for high‐power lithium ion batteries (LIBs) because of its low cost, high thermal/chemical stability, and good safety performance without solid electrolyte interface formation. However, the poor electronic conductivity and low lithium ion diffusivity of TiO 2 result in poor cyclability and lithium ion depletion at high current rates, which hinder them from practical applications. Herein we demonstrate that hierarchically structured TiO 2 microboxes with controlled internal porosity can address the aforementioned problems for high‐power, long‐life LIB anodes. A self‐templating method for the synthesis of mesoporous microboxes was developed through Na 2 EDTA‐assisted ion exchange of CaTiO 3 microcubes. The resulting TiO 2 nanorods were organized into microboxes that resemble the microcube precursors. This nanostructured TiO 2 material has superior lithium storage properties with a capacity of 187 mAh g −1 after 300 cycles at 1 C and good rate capabilities up to 20 C.

Gao, Xuehui↗