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At least 253 records · Page 14

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NASA NTRS1990

Phase compatibilities of YBa2Cu3O(9-delta) type structure in quintenary systems Y-Ba-Cu-O-X (impurity)

Electrical transport properties of the oxidic high T(sub c) superconductors are significantly affected by the presence of minor amounts of various elements adventing as impurities, e.g., from the chemical environment during manufacturing. YBa2Cu3O(9-delta) is prone to an extinction of the superconductivity on (partial) substitution of all four elemental components. E.g., Pr (for Y), La (for Ba), Zn (for Cu) or peroxygroup (for O) substituents will alter some of the superconductivity preconditions, like mixed valence state in Cu3O7/O(9-delta) network or structural distortion of the network. Although various pseudoternary chemical equilibrium phase diagrams of the Y(O)-Ba(O)-Cu(O) system now are available, no consensus is generally shown, however, this is partly due to lack of compatible definitions of the equilibrium conditions. Less information is available about the phase compatibilities in the appropriate quaternary phase diagram (including oxygen) and virtually no information exists about any pentenary phase diagrams (including one impurity). Unfortunately, complexity of such systems, stemming both from number of quaternary or pentenary compounds and from visualizing the five-component phase system, limits this presentation to more or less close surroundings of the YBa2Cu3O(9-delta) type phase in appropriate pseudoquaternary or pseudopseudoternary diagrams, involving Y-Ba-Cu and O, O-CO2, alkaline metals, Mg and alkaline earths, and Sc and most of the 3-d and 4-f elements. The systems were investigated by means of x ray diffraction, neutron diffraction and chemical analytical methods on samples prepared by sol-gel technique from citrates. The superconductivity was characterized by measuring the diamagnetic susceptibility by SQUID.

Karen, P.↗

NASA NTRS1990

Synthesis of Y1Ba2Cu3O(sub x) superconducting powders by intermediate phase reaction

One of the more striking problems for the synthesis of the Y1Ba2Cu3Ox compound is the high-temperature decomposition of the BaCO3. This compound is present as raw material or as an intermediate compound in chemical processes such as amorphous citrate, coprecipitation oxalate, sol-gel process, acetate pyrolisis, etc. This fact makes difficult the total formation reaction of the Y1Ba2Cu3Ox phase and leads to the presence of undesirable phases such as the BaCuO2 phase, the 'green phase', Y2BaCuO5 and others. Here, a new procedure to overcome this difficulty is studied. The barium cation is previously combined with yttrium and/or copper to form intermediate compounds which can react between them to give Y1Ba2Cu3Ox. BaY2O4 and BaCu2O3 react according to the equation BaY2O4+3BaCu2O3 yields 2Y1Ba2Cu3Ox. BaY2O4 is a stable compound of the Y2O3-BaO system; BaCu2O3 is an intimate mixture of BaCuO2 and uncombined CuO. The reaction kinetics of these phases have been established between 860 and 920 C. The phase evolution has been determined. The crystal structure of the Y1Ba2Cu3Ox obtained powder was studied. According to the results obtained from the kinetics study the Y1Ba2Cu3Ox the synthesis was performed at temperatures of 910 to 920 C for short treatment times (1 to 2 hours). Pure Y1Ba2Cu3Ox was prepared, which develops orthorombic type I structure despite of the cooling cycle. Superconducting transition took place at 91 K. The sintering behavior and the superconducting properties of sintered samples were studied. Density, microstructure and electrical conductivity were measured. Sintering densities higher than 95 percent D(sub th) were attained at temperatures below 940 C. Relatively fine grained microstructure was observed, and little or no-liquid phase was detected.

Moore, C.↗

NASA NTRS1989

Mars Observer mission design

The spacecraft for the Mars Observer mission is described, and an interplanetary trajectory design maximizing the spacecraft dry mass delivered into its mapping orbit is presented, along with an orbit insertion strategy minimizing spacecraft propulsive requirements. Emphasis is placed on the mapping orbit designed to meet the science requirements for a low-altitude near-circular near-polar orbit which is sun-synchronous with the dayside equatorial crossing at 2 PM local mean solar time. Additional requirements on the design are that the mapping orbit have a repeating groundtrack of no more than 7 sols and comply with the NASA Planetary Protection requirements. It is planned to operate the spacecraft and instruments in a repetitive fashion to minimize mission operation complexity and cost.

Beerer, Joseph G.↗

NASA NTRS1990

Phase transformations in xerogels of mullite composition

Monophasic and diphasic xerogels have been prepared as precursors for mullite (3Al203-2Si02). Monophasic xerogel was synthesized from tetraethyl orthosilicate and aluminum nitrate nanohydrate and the diphasic xerogel from colloidal suspension of silica and boehmite. The chemical and structural evolutions, as a function of thermal treatment, in these two types of sol-gel derived mullite precursor powders have been characterized by DTA, TGA, X-ray diffraction, SEM and infrared spectroscopy. Monophasic xerogel transforms to an Al-Si spinel from an amorphous structure at approximately 980 C. The spinel then changes into mullite on further heating. Diphasic xerogel forms mullite at approximately 1360 C. The components of the diphasic powder react independently up to the point of mullite formation. The transformation in the monophasic powder occurs rapidly and yields strongly crystalline mullite with no other phases present. The diphasic powder, however, transforms rather slowly and contains remnants of the starting materials (alpha-Al203, cristobalite) even after heating at high temperatures for long times (1600 C, 6 hr). The diphasic powder could be sintered to high density but not the monophasic powder in spite of its molecular level homogeneity.

Hyatt, Mark J.↗

NASA NTRS1990

Observations of Martian surface winds at the Viking Lander 1 site

Martian surface winds at the Viking Lander 1 have been reconstructed using signals from partially failed wind instrumentation. Winds during early summer were controlled by regional topography, and then underwent a transition to a regime controlled by the Hadley circulation. Diurnal wind oscillations were controlled primarily by regional topography and boundary layer forcing, although a global mode may have been influencing them during two brief episodes. Semidiurnal wind oscillations were controlled by the westward-propagating semidiurnal tide from sol 210 onward. Comparison of the synoptic variations at the two sites suggests that the same eastward propagating wave trains were present at both sites.

Murphy, James R.↗

NASA NTRS1990

A polar orbit for the Mars Global Network Mission

The purpose of the Global Network Mission (GNM) is to deploy simple landers on the Martian surface in late 1998. The objective is to create a globally distributed network of ground stations which will collect environmental data, perhaps for as long as several years. The GNM presents unique mission design challenges, which are addressed by the following essay. The GNM mission concept calls for two carrier spacecraft, each equipped with a number of simple landers. Some of the landers may be deployed from approach, either to reduce carrier mass prior to orbit insertion, or to reach latitudes not available from the carrier orbit. The remaining landers are deployed from orbit. One configuration for the Global Network Mission was proposed in a report from the Exploration Precursors Task Team to the Office of Space Science and Applications. This formed the basis of a previous orbit design for the GNM. This mission scenario is used as a point of reference, but results from the current study are generally applicable to a wide range of GNM mission variants. The analysis concluded that a 1/5 sol, polar orbit with a periapse altitude of 275 km offers the best circumstances for orbital deployment of the Global Network Mission landers. It allows easy polar access at nominal entry angles, and global dispersal of landing sites at lighting angles suitable for descent imaging. The polar orbit allows the option of deploying all the landers from orbit. A wait interval of 160 days after arrival is required before deployment can commence.

Knocke, Philip↗

NASA NTRS1990

Radio emission in peculiar galaxies

During the last decades a number of surveys of peculiar galaxies have been carried out and accurate positions become available. Since peculiarities are a possible evidence of radio emission (Wright, 1974; Sulentic, 1976; Stocke et al., 1978), the authors selected a sample of 24 peculiar galaxies with optical jet-like features or extensions in different optical catalogues, mainly the Catalogue of Southern Peculiar Galaxies and Associations (Arp and Madore, 1987) and the ESO/Uppsala Survey of the ESO(B) Atlas (Lauberts, 1982) for observation at the radio continuum frequency of 22 GHz. The sample is listed in a table. Sol (1987) studied this sample and concluded that the majority of the jet-like features seem to admit an explanation in terms of interactive galaxies with bridges and/or tails due to tidal effects. Only in a few cases do the jets seem to be possibly linked to some nuclear activity of the host galaxy. The observations were made with the 13.7m-radome enclosed Itapetinga Radiotelescope (HPBW of 4.3 arcmin), in Brazil. The receiver was a 1 GHz d.s.b. super-heterodine mixer operated in total-power mode, with a system temperature of approximately 800 K. The observational technique consisted in scans in right ascention, centralized in the optical position of the galaxy. The amplitude of one scan was 43 arcmin, and its duration time was 20 seconds. The integration time was at least 2 hours (12 ten-minute observations) and the sensibility limit adopted was an antenna temperature greater than 3 times the r.m.s. error of the baseline determination. Virgo A was used as the calibrator source. Three galaxies were detected for the first time as radio sources and four other known galaxies at low frequencies had their flux densities measured at 22 GHz. The results for these sources are presented.

Demellorabaca, Dulia F.↗

NASA NTRS1992

Lightweight Protective Coatings For Titanium Alloys

Lightweight coating developed to protect titanium and titanium aluminide alloys and titanium-matrix composite materials from attack by environment when used at high temperatures. Applied by sol-gel methods, and thickness less than 5 micrometers. Reaction-barrier and self-healing diffusion-barrier layers combine to protect titanium alloy against chemical attack by oxygen and nitrogen at high temperatures with very promising results. Can be extended to protection of other environmentally sensitive materials.

Wiedemann, Karl E.↗

NASA NTRS1991

Mars Sample Return mission: Two alternate scenarios

Two scenarios for accomplishing a Mars Sample Return mission are presented herein. Mission A is a low cost, low mass scenario, while Mission B is a high technology, high science alternative. Mission A begins with the launch of one Titan IV rocket with a Centaur G' upper stage. The Centaur performs the trans-Mars injection burn and is then released. The payload consists of two lander packages and the Orbital Transfer Vehicle, which is responsible for supporting the landers during launch and interplanetary cruise. After descending to the surface, the landers deploy small, local rovers to collect samples. Mission B starts with 4 Titan IV launches, used to place the parts of the Planetary Transfer Vehicle (PTV) into orbit. The fourth launch payload is able to move to assemble the entire vehicle by simple docking routines. Once complete, the PTV begins a low thrust trajectory out from low Earth orbit, through interplanetary space, and into low Martian orbit. It deploys a communication satellite into a 1/2 sol orbit and then releases the lander package at 500 km altitude. The lander package contains the lander, the Mars Ascent Vehicle (MAV), two lighter than air rovers (called Aereons), and one conventional land rover. The entire package is contained with a biconic aeroshell. After release from the PTV, the lander package descends to the surface, where all three rovers are released to collect samples and map the terrain.

Source record↗

NASA NTRS1992

Mechanical properties of coated titanium Beta-21S after exposure to air at 700 and 800 C

Mechanical properties of Beta-21S (Ti-15Mo-3Al-2.7Nb-0.2Si, wt percent) with glass, aluminide, and glass-on-aluminide coatings less than 3-micron thick were studied. Coatings were deposited by sol-gel processing or electron-beam evaporation onto 4.5-mil (113-micron) thick Beta-21S sheet from which, after oxidizing in air at 700 or 800 C, tensile test specimens were machined. Plastic elongation was the most severely degraded of the tensile properties; the glass-on-aluminide coatings were the most effective in preventing degradation. It was found that oxygen trapping by forming oxides in the coating, and reactions between the coatings and the Beta-21S alloy played significant roles.

Wiedemann, Karl E.↗

NASA NTRS1992

Flight-vehicle materials, structures, and dynamics - Assessment and future directions. Vol. 3 - Ceramics and ceramic-matrix composites

The present volume discusses ceramics and ceramic-matrix composites in prospective aerospace systems, monolithic ceramics, transformation-toughened and whisker-reinforced ceramic composites, glass-ceramic matrix composites, reaction-bonded Si3N4 and SiC composites, and chemical vapor-infiltrated composites. Also discussed are the sol-gel-processing of ceramic composites, the fabrication and properties of fiber-reinforced ceramic composites with directed metal oxidation, the fracture behavior of ceramic-matrix composites (CMCs), the fatigue of fiber-reinforced CMCs, creep and rupture of CMCs, structural design methodologies for ceramic-based materials systems, the joining of ceramics and CMCs, and carbon-carbon composites.

Levine, Stanley R.↗

NASA NTRS1991

Thin film processing of photorefractive BaTiO3

The principle objectives of this ongoing research involve the preparation and characterization of polycrystalline single-domain thin films of BaTiO3 for photorefractive applications. These films must be continuous, free of cracks, and of high optical quality. The two methods proposed are sputtering and sol-gel related processing.

Schuster, Paul R.↗

NASA NTRS1993

Thin film processing of photorefractive BaTiO3

During the period covered by this report, October 11, 1991 through October 10, 1992, the research has progressed in a number of different areas. The sol-gel technique was initially studied and experimentally evaluated for depositing films of BaTiO3. The difficulties with the precursors and the poor quality of the films deposited lead to the investigation of pulsed laser deposition as an alternative approach. The development of the pulsed laser deposition technique has resulted in continuous improvements to the quality of deposited films of BaTiO3. The initial depositions of BaTiO3 resulted in amorphous films, however, as the pulsed laser deposition technique continued to evolve, films were deposited in the polycrystalline state, then the textured polycrystalline state, and most recently heteroepitaxial films have also been successfully deposited on cubic (100) oriented SrTiO3 substrates. A technique for poling samples at room temperature and in air is also undergoing development with some very preliminary but positive results. The analytical techniques, which include x-ray diffraction, ferroelectric analysis, UV-Vis spectrophotometry, scanning electron microscopy with x-ray compositional analysis, optical and polarized light microscopy, and surface profilometry have been enhanced to allow for more detailed evaluation of the samples. In the area of optical characterization, a pulsed Nd:YAG laser has been incorporated into the experimental configuration. Now data can also be acquired within various temporal domains resulting in more detailed information on the optical response of the samples and on their photorefractive sensitivity. The recent establishment of collaborative efforts with two departments at Johns Hopkins University and the Army Research Lab at Fort Belvoir has also produced preliminary results using the metallo-organic decomposition technique as an alternative method for thin film processing of BaTiO3. RF and DC sputtering is another film deposition approach that should be initiated in the near future. Other techniques for optical characterization, which may even allow for intragrannular (within single grains) investigations, are also being considered.

Schuster, Paul R.↗

NASA NTRS1992

STS-42 Space Shuttle mission report

The STS-42 Space Shuttle Program Mission Report contains a summary of the vehicle subsystem operations during the forty-fifth flight of the Space Shuttle Program and the fourteenth flight of the Orbiter vehicle Discovery (OV-103). In addition to the Discovery vehicle, the flight vehicle consisted of the following: an External Tank (ET) designated as ET-52 (LWT-45); three Space Shuttle main engines (SSME's), which were serial numbers 2026, 2022, and 2027 in positions 1, 2, and 3, respectively; and two Solid Rocket Boosters (SRB's) designated as BI-048. The lightweight redesigned Solid Rocket Motors (RSRM's) installed in each one of the SRB's were designated as 360L020A for the left SRM and 360Q020B for the right SRM. The primary objective of the STS-42 mission was to complete the objectives of the first International Microgravity Laboratory (IML-1). Secondary objectives were to perform all operations necessary to support the requirements of the following: Gelation of Sols: Applied Microgravity Research (GOSAMR); Student Experiment 81-09 (Convection in Zero Gravity); Student Experiment 83-02 (Capillary Rise of Liquid Through Granular Porous Media); the Investigation into Polymer Membrane Processing (IPMP); the Radiation Monitoring Equipment-3 (RME-3); and Get-Away Special (GAS) payloads carried on the GAS Beam Assembly.

Fricke, Robert W.↗

NASA NTRS1991

Mars sample return mission: Two alternate scenarios

Two scenarios for accomplishing a Mars Sample Return mission are presented. Mission A is a low-cost, low-mass scenario, while Mission B is a high-technology, high-science alternative. Mission A begins with the launch of one Titan 4 rocket with a Centaur G' upper stage. The Centaur performs the trans-Mars injection burn and is then released. The payload consists of two lander packages and the orbital transfer vehicle, which is responsible for supporting the landers during launch and interplanetary cruise. Near Mars, the landers separate - one bound for a polar site and the other for an equatorial site. After descending to the surface, the landers deploy small, local rovers to collect samples. The rovers return these samples to the landers for loading on the direct return rockets, which return the samples directly to the Earth's surface. Mission B starts with four Titan 4 launches, used to place the components of the planetary transfer vehicle (PTV) into orbit. The fourth launch payload is able to move to assemble the entire vehicle by simple docking routines. Once complete, the PTV begins a low-thrust trajectory out from low Earth orbit, through interplanetary space, and into low Mars orbit. It deploys a communications satellite into a one half sol orbit and then releases the lander pad cage at 500 km altitude. The lander package contains the lander, the Mars ascent vehicle (MAV), two lighter-than-air rovers (called Aereons), and one conventional land rover. The entire package is contained within a biconic aeroshell. After release from the PTV the lander package descends to the surface, where all three rovers are released to collect samples and map the terrain. The Aereons attempt to circumnavigate Mars and collect samples from a wide variety of sites, while the land rover examines a local area more thoroughly. The Aereons are equipped with small sample return rockets that can return their samples to the lander in the event that an Aereon is incapable of returning to the lander itself. Once all samples have been collected they are loaded onto the MAV and launched into orbit. The PTV then collects the samples and returns them to Earth orbit for recovery.

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NASA NTRS1993

New materials: Fountainhead for new technologies and new science

The role of materials as the benchmark technologies which give epochs of human history their names continues into the present. The discovery of new materials has nearly always been the source of new materials science, and frequently of new technologies. This paper analyzes the actual processes by which new materials are synthesized, i.e. whether driven by serendipitous observations, new knowledge is pulled by the market, or integrated into a technological thrust. This analysis focuses on modern ceramic materials discoveries, since World War 2 and uses 45 years experience in materials synthesis in the author's own laboratory as case studies. A dozen different families of materials or processes are involved: hydrothermal reactions; sol-gel processing; clays and zeolites; electroceramics; zero expansion ceramics; diamond films; and radioactive waste host phases. Nanocomposite concepts introduced by the author a decade ago offer an entire, large, new class of materials which will dominate synthesis for the next period. The future of materials research for the next 25 years cannot be extrapolated from the past 25 years. We are near the asymptote for materials utilization in most metals. Likewise we are approaching saturation in improvement of many useful properties. Justifying much further 'basic' R/D for incremental improvement in civilian-oriented industries will not be easy. In materials synthesis, the near-term future is sure to emphasize not new phases, but tailored micro- and nanocomposites for chemical, electrical, optical, and magnetic uses. Unexpected new discoveries such as the Lanxide process may offer rarer chances for step function advances. The new structure of knowledge management will rely less on local research than on integration of worldwide inputs. Better scientific and technological opportunities will lie in designing knowledge intensive materials to meet the new environmental and conservation goals, and the human needs of the very large numbers at the bottom of the socio-economic structures of the world.

Rustum, Roy↗

NASA NTRS1991

Thin coatings for protecting titanium aluminides in high-temperature oxidizing environments

Titanium aluminides have high specific strengths at high temperatures but are susceptible to environmental attack. Their use in many aerospace applications would require that they be protected with coatings that, for structural efficiency, must be thin. It is conceivable that acceptable coatings might be found in several oxide systems, and consequently, oxide coatings of many compositions were prepared from sol-gels for study. Response-surface methodology was used to refine coating compositions and factorial experiments were used to develop coating strategies. Oxygen permeability diagrams of two-layer coatings for several oxide systems, an analysis of multiple-layer coatings on rough and polished surfaces, and modeling of the oxidation weight gain are presented.

Wiedemann, K. E.↗

NASA NTRS1993

A coupled subsurface-boundary layer model of water on Mars

A 1D numerical model of the exchange of H2O between the atmosphere and subsurface of Mars through the PBL is employed to explore the mechanisms of H2O exchange and to elucidate the role played by the regolith in the local H2O budget. The atmospheric model includes effects of Coriolis, pressure gradient, and frictional forces for momentum: radiation, sensible heat flux, and advection for heat. It is suggested that in most cases, the flux through the Martian surface reverses twice in the course of each sol. The effects of surface albedo, thermal inertia, solar declination, atmospheric optical depth, and regolith pore structure are explored. It is proposed that higher thermal inertia forces more H2O into the atmosphere because the regolith is warmer at depth.

Zent, Aaron P.↗