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At least 253 records · Page 14

Populating the brown dwarf and stellar boundary: Five stars with transiting companions near the hydrogen-burning mass limit

We report the discovery of five transiting companions near the hydrogen-burning mass limit in close orbits around main sequence stars originally identified by the Transiting Exoplanet Survey Satellite (TESS) as TESS objects of interest (TOIs): TOI-148, TOI-587, TOI-681, TOI-746, and TOI-1213. Using TESS and ground-based photometry as well as radial velocities from the CORALIE, CHIRON, TRES, and FEROS spectrographs, we found the companions have orbital periods between 4.8 and 27.2 days, masses between 77 and 98 MJup , and radii between 0.81 and 1.66 RJup . These targets have masses near the uncertain lower limit of hydrogen core fusion (~73-96 MJup ), which separates brown dwarfs and low-mass stars. We constrained young ages for TOI-587 (0.2 ± 0.1 Gyr) and TOI-681 (0.17 ± 0.03 Gyr) and found them to have relatively larger radii compared to other transiting companions of a similar mass. Conversely we estimated older ages for TOI-148 and TOI-746 and found them to have relatively smaller companion radii. With an effective temperature of 9800 ± 200 K, TOI-587 is the hottest known main-sequence star to host a transiting brown dwarf or very low-mass star. We found evidence of spin-orbit synchronization for TOI-148 and TOI-746 as well as tidal circularization for TOI-148. These companions add to the population of brown dwarfs and very low-mass stars with well measured parameters ideal to test formation models of these rare objects, the origin of the brown dwarf desert, and the distinction between brown dwarfs and hydrogen-burning main sequence stars.

Nolan Grieves↗

2024 roadmap on magnetic microscopy techniques and their applications in materials science

Considering the growing interest in magnetic materials for unconventional computing, data storage, and sensor applications, there is active research not only on material synthesis but also characterisation of their properties. In addition to structural and integral magnetic characterisations, imaging of magnetisation patterns, current distributions and magnetic fields at nano- and microscale is of major importance to understand the material responses and qualify them for specific applications. In this roadmap, we aim to cover a broad portfolio of techniques to perform nano- and microscale magnetic imaging using superconducting quantum interference devices, spin centre and Hall effect magnetometries, scanning probe microscopies, x-ray- and electron-based methods as well as magnetooptics and nanoscale magnetic resonance imaging. The roadmap is aimed as a single access point of information for experts in the field as well as the young generation of students outlining prospects of the development of magnetic imaging technologies for the upcoming decade with a focus on physics, materials science, and chemistry of planar, three-dimensional and geometrically curved objects of different material classes including two-dimensional materials, complex oxides, semi-metals, multiferroics, skyrmions, antiferromagnets, frustrated magnets, magnetic molecules/nanoparticles, ionic conductors, superconductors, spintronic and spinorbitronic materials.

2D materials↗

Identifying point defects and ordering in the high-entropy layered oxide Li 1.5 MO 3-δ (M=Mn, Al, Fe, Co, Ni) for energy storage applications

High-entropy layered oxides (HELOs) represent a very promising class of next-generation battery cathodes, combining the well-studied properties of layered cathode materials such as LiCoO 2 with the chemical tunability and stability of high-entropy materials. HELO materials often form particles with complex defects and domain structures, complicating accurate characterization of structure and cation mixing. Understanding disorder and order in HELO materials is necessary for understanding their performance and utility as cathodes. Here we demonstrate the characterization of the HELO Li 1.5 MO 3-δ (M = Mn, Al, Fe, Co, Ni), wherein X-ray powder diffraction, transmission electron microscopy imaging, and electron diffraction patterns are analyzed to reveal the presence of ordering in the HELO, with imaging and diffraction simulation employed to compare experimental results to atomic modeling. Finally, without rigorous characterization at the atomic scale, important features such as defect ordering can be easily overlooked and therefore remain unconsidered when interpreting experimental results.

36 MATERIALS SCIENCE↗

Discovery and characterization of two Neptune-mass planets orbiting HD 212729 with TESS

ABSTRACT We report the discovery of two exoplanets orbiting around HD 212729 (TOI 1052, TIC 317060587), a Teff = 6146 K star with V = 9.51 observed by TESS in Sectors 1 and 13. One exoplanet, TOI-1052b, is Neptune-mass and transits the star, and an additional planet TOI-1052c is observed in radial velocities but not seen to transit. We confirm the planetary nature of TOI-1052b using precise radial velocity observations from HARPS and determined its parameters in a joint RV and photometry analysis. TOI-1052b has a radius of $2.87^{+0.29}_{-0.24}$ R⊕, a mass of 16.9 ± 1.7 M⊕, and an orbital period of 9.14 d. TOI-1052c does not show any transits in the TESS data, and has a minimum mass of $34.3^{+4.1}_{-3.7}$ M⊕ and an orbital period of 35.8 d, placing it just interior to the 4:1 mean-motion resonance. Both planets are best fit by relatively high but only marginally significant eccentricities of $0.18^{+0.09}_{-0.07}$ for planet b and $0.24^{+0.09}_{-0.08}$ for planet c. We perform a dynamical analysis and internal structure model of the planets as well as deriving stellar parameters and chemical abundances. The mean density of TOI-1052b is $3.9^{+1.7}_{-1.3}$ g cm−3 consistent with an internal structure similar to Neptune. A nearby star is observed in Gaia DR3 with the same distance and proper motion as TOI-1052, at a sky projected separation of $\scriptstyle \sim$1500 au, making this a potential wide binary star system.

Armstrong, David J. (ORCID:0000000250804117)↗

Lossless Phonon Transition Through GaN‐Diamond and Si‐Diamond Interfaces

Abstract Advancing Silicon (Si) technology beyond Moore's law through 3D architectures requires highly efficient heat management methods compatible with foundry processes. While continued increases in transistor density can be achieved through 3D architectures, self‐heating in the upper tiers degrades the performance. Self‐heating is a critical problem for high‐power, high‐frequency, wide bandgap, and ultra‐wide bandgap devices as well. Diamond, known for its exceptional thermal conductivity, offers a viable solution in both these cases. Since thermal boundary resistance (between the channel/junction and diamond plays a crucial role in overall thermal resistance, this study investigates various dielectrics for interface engineering, such as Silicon dioxide (SiO 2 ), amorphous‐ Silicon Carbide (a‐SiC), and Silicon Nitride (SiN x ), to make a phonon bridge at gallium nitride (GaN)‐diamond and Si‐diamond interfaces. The a‐SiC interlayer reduces diamond/GaN (<5 m 2 K per GW) and diamond/Si (<2 m 2 K per GW) thermal boundary resistances by linking low‐ and high‐frequency phonons, boosting phonon transport through the interface. Engineered interfaces enhance heat spreading from the channel/junction and rule out premature failure.

Malakoutian, Mohamadali↗

Combustion and Flammability Characteristics of Solids at Microgravity in very Small Velocity Flows

Fires still remain as one of the most important safety risks in manned spacecraft. This problem will become even more important in long endurance non orbital flights in which maintenance will be non existing or very difficult. The basic process of a fire is the combustion of a solid at microgravity conditions in O2/N2 mixtures. Although a large number of research programs have been carried out on this problem, especially on flame spreading, several aspects of these processes are not yet well understood. It may be mentioned, for example, the temperature and characteristic of low emissivity flames in the visual range that take place in some conditions at microgravity; and there exists a lack of knowledge on the influence of key parameters, such as convective flow velocities of the order of magnitude of typical oxygen diffusion velocities. The "Departamento de Motopropulsion y Termofluidodinamica" of the "Universidad Politecnica de Madrid, Escuela Tecnica Superior de Ingenieros Aeronauticos" is conducting a research program on the combustion of solids at reduced gravity conditions within O2/N2 mixtures. The material utilized has been polymethylmethacrylate (PMMA) in the form of rectangular slabs and hollow cylinders. The main parameters of the process have been small convective flow velocities (including velocity angle with the direction of the spreading flame) and oxygen concentration. Some results have also been obtained on the influence of material thickness and gas pressure.

Sanchez-Tarifa, C.↗

Pangenomes suggest ecological-evolutionary responses to experimental soil warming

ABSTRACT Below-ground carbon transformations that contribute to healthy soils represent a natural climate change mitigation, but newly acquired traits adaptive to climate stress may alter microbial feedback mechanisms. To better define microbial evolutionary responses to long-term climate warming, we study microorganisms from an ongoing in situ soil warming experiment where, for over three decades, temperate forest soils are continuously heated at 5°C above ambient. We hypothesize that across generations of chronic warming, genomic signatures within diverse bacterial lineages reflect adaptations related to growth and carbon utilization. From our bacterial culture collection isolated from experimental heated and control plots, we sequenced genomes representing dominant taxa sensitive to warming, including lineages of Actinobacteria, Alphaproteobacteria, and Betaproteobacteria. We investigated genomic attributes and functional gene content to identify signatures of adaptation. Comparative pangenomics revealed accessory gene clusters related to central metabolism, competition, and carbon substrate degradation, with few functional annotations explicitly associated with long-term warming. Trends in functional gene patterns suggest genomes from heated plots were relatively enriched in central carbohydrate and nitrogen metabolism pathways, while genomes from control plots were relatively enriched in amino acid and fatty acid metabolism pathways. We observed that genomes from heated plots had less codon bias, suggesting potential adaptive traits related to growth or growth efficiency. Codon usage bias varied for organisms with similar 16S rrn operon copy number, suggesting that these organisms experience different selective pressures on growth efficiency. Our work suggests the emergence of lineage-specific trends as well as common ecological-evolutionary microbial responses to climate change. IMPORTANCE Anthropogenic climate change threatens soil ecosystem health in part by altering below-ground carbon cycling carried out by microbes. Microbial evolutionary responses are often overshadowed by community-level ecological responses, but adaptive responses represent potential changes in traits and functional potential that may alter ecosystem function. We predict that microbes are adapting to climate change stressors like soil warming. To test this, we analyzed the genomes of bacteria from a soil warming experiment where soil plots have been experimentally heated 5°C above ambient for over 30 years. While genomic attributes were unchanged by long-term warming, we observed trends in functional gene content related to carbon and nitrogen usage and genomic indicators of growth efficiency. These responses may represent new parameters in how soil ecosystems feedback to the climate system.

Choudoir, Mallory J. (ORCID:0000000291175150)↗

Enhancements supporting IC usage of PEM libraries on next-gen platforms

This milestone reports on the culmination of several years of effort by multiple PEM support software development teams to provide capabilities for use in LLNL-developed integrated codes on next-gen ASC platforms, including GPU support. We will provide a survey of relevant Application Program Interfaces (API) that are required to support LLNL IC code capability on relevant architectures, with a focus on Sierra and El Capitan. We will identify and summarize all dependencies between PEM supported libraries and IC supported physics codes. We will provide an assessment of algorithmic improvements that have been deployed, as well as future developments that are required to complete the GPU porting efforts. This assessment will include a description of programming models adopted by each of the PEM projects, distinct algorithmic challenges for each of the capabilities, and information about sharing GPU memory between the APIs and host codes. We will develop targeted test problems to assess computational performance. Finally, this milestone will result in identification of gaps in our effort to assist the LLNL ASC program in prioritization of effort for porting software to El Capitan.

97 MATHEMATICS AND COMPUTING↗

Water-promoted interfacial pathways in methane oxidation to methanol on a CeO 2 -Cu 2 O catalyst

Highly selective oxidation of methane to methanol has long been challenging in catalysis. Here, we reveal key steps for the pro­motion of this reaction by water when tuning the selectivity of a well-defined CeO 2 /Cu 2 O/Cu(111) catalyst from carbon monoxide and carbon dioxide to methanol under a reaction environment with methane, oxygen, and water. Ambient-pressure x-ray photoelectron spectroscopy showed that water added to methane and oxygen led to surface methoxy groups and accelerated methanol production. These results were consistent with density functional theory calculations and kinetic Monte Carlo simulations, which showed that water preferentially dissociates over the active cerium ions at the CeO 2 –Cu 2 O/Cu(111) interface. The adsorbed hydroxyl species blocked O-O bond cleavage that would dehydrogenate methoxy groups to carbon monoxide and carbon dioxide, and it directly converted this species to methanol, while oxygen reoxidized the reduced surface. Water adsorption also displaced the produced methanol into the gas phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Multifrequency-spectral behavior of the BL Lacertae objects OI 90.4 and 3C 66A

Single-epoch multifrequency data for the BL Lac objects OI 90.4 and 3C 66A, spanning radio through ultraviolet wavelengths, are presented, as well as other measurements relevant to intensity and spectral-shape variability. Both BL Lac objects exhibit spectral curvature in the infrared-to-ultraviolet region, a properity that is inferred to be usual for this object class. Variability in the ultraviolet spectral index of OI 90.4 is found, whereas the spectral index of 3C 66A is the same in two observations 17 months apart. A synchrotron self-Compton jet model is applied to each BL Lac object. The OI 90.4 data are found to be best satisfied by a jet with a relatively high degree of relativistic beaming, but emission at frequencies below about 50 GHz is not described by the model. Furthermore, 3C 66A may not always undergo strong relativistic beaming, and the model may incorporate the small fraction of the total radio emission below about 20 GHz that is from within about 1.5 milliarcsec of the core.

Worrall, D. M.↗

Simulation of radiation damage via alpha decay in BFS:PC grouts using 4 He 2+ ion acceleration

The impact of alpha radiation on cements used to encapsulate intermediate-level waste (ILW) is not well understood. ILW wastes can contain high levels of alpha-emitting radionuclides, meaning that the grouts used to encapsulate them are exposed to significant ionising radiation. Thus, a damaged region could develop in the grout adjacent to the alpha-emitting species. This work attempted to recreate this behaviour through nonradioactive 4 He 2+ ion-accelerator experiments, which have not previously been applied to common encapsulation grouts. The influence of this irradiation on a slag-Portland cement was investigated at different ages via transmission electron microscopy energy-dispersive x-ray spectroscopy (TEM-EDX) and supporting techniques, to assess whether 4 He 2+ irradiation caused textural or chemical zonation. No significant changes in hydrate phases or textures were observed, other than minor variations associated with carbonation. This paper provides a proof of concept for using ion acceleration techniques on cements and furthers knowledge on their radiation response.

36 MATERIALS SCIENCE↗

Not all platinum surfaces are the same: Effect of the support on fundamental properties of platinum adlayer and its implications for the activity toward hydrogen evolution reaction

The adsorption of atomic hydrogen on a platinum monolayer supported on orthorhombic Mo 2 C(100) surface has been investigated, considering different hydrogen surface coverages. Calculations have been performed using density functional theory with the Perdew-Burke-Ernzerhof exchange correlation functional and a D3 Van der Waals corrections. The theoretical insight has been gained into atomic hydrogen interaction with Pt monolayer, supported on both molybdenum and well-studied tungsten carbide, and considering hydrogen surface coverage. Fundamental properties of Pt adlayer depend on the support, affecting hydrogen evolution activity of the resulting systems. At low hydrogen coverage all systems, with the exception of Pt supported on the molybdenum-terminated Mo 2 C, adsorb H comparably to a pristine Pt(111) surface and their high activity for the hydrogen evolution reaction is predicted. Additionally, at higher coverages supported Pt monolayers interact with atomic hydrogen unlike the Pt(111), suggesting that the activity of the supported and unsupported platinum toward hydrogen evolution reaction have different origins. Furthermore, the position of the supported platinum monolayers on the volcano curve is a function of the surface coverage, more so than for extended metal surfaces. Therefore, hydrogen surface coverage is a key variable to understand the catalytic potential, approaching towards an improved model for screening of electrocatalytic systems.

36 MATERIALS SCIENCE↗

Quantifying Quantum Chaos through Microcanonical Distributions of Entanglement

A characteristic feature of “quantum chaotic” systems is that their eigenspectra and eigenstates display universal statistical properties described by random matrix theory (RMT). However, eigenstates of local systems also encode structure beyond RMT. To capture this feature, we introduce a framework that allows us to compare the properties of eigenstates in local systems with those of pure random states. In particular, our framework defines a notion of distance between quantum state ensembles that utilizes the Kullback-Leibler divergence to compare the microcanonical distribution of entanglement entropy (EE) of eigenstates with a reference RMT distribution generated by pure random states (with appropriate constraints). This notion gives rise to a quantitative metric for quantum chaos that not only accounts for averages of the distributions but also higher moments. The differences in moments are compared on a highly resolved scale set by the standard deviation of the RMT distribution, which is exponentially small in system size. As a result, the metric can distinguish between chaotic and integrable behaviors and, in addition, quantify and compare the of chaos (in terms of proximity to RMT behavior) between two systems that are assumed to be chaotic. We implement our framework in local, minimally structured, Floquet random circuits, as well as a canonical family of many-body Hamiltonians, the mixed-field Ising model (MFIM). Importantly, for Hamiltonian systems, we find that the reference random distribution must be appropriately constrained to incorporate the effect of energy conservation in order to describe the ensemble properties of midspectrum eigenstates. The metric captures deviations from RMT across all models and parameters, including those that have been previously identified as strongly chaotic, and for which other diagnostics of chaos such as level spacing statistics look strongly thermal. In Floquet circuits, the dominant source of deviations is the second moment of the distribution, and this persists for all system sizes. For the MFIM, we find significant variation of the KL divergence in parameter space. Notably, we find a small region where deviations from RMT are minimized, suggesting that “maximally chaotic” Hamiltonians may exist in fine-tuned pockets of parameter space. Published by the American Physical Society 2024

Physics↗

TOI-2109: An Ultrahot Gas Giant on a 16 hr Orbit

We report the discovery of an ultrahot Jupiter with an extremely short orbital period of 0.67247414 ± 0.00000028 days (∼16 hr). The 1.347 ± 0.047 RJup planet, initially identified by the Transiting Exoplanet Survey Satellite (TESS) mission, orbits TOI-2109 (TIC 392476080)—a T(eff) ∼ 6500 K F-type star with a mass of 1.447 ± 0.077 Mꙩ, a radius of 1.698 ± 0.060 Rꙩ, and a rotational velocity of v sin i =81.9 ± 1.7 km/s. The planetary nature of TOI-2109b was confirmed through radial-velocity measurements, which yielded a planet mass of 5.02 ± 0.75 M(Jup). Analysis of the Doppler shadow in spectroscopic transit observations indicates a well-aligned system, with a sky-projected obliquity of λ = 1.°7± 1.°7. From the TESS full-orbit light curve, we measured a secondary eclipse depth of 731 ± 46 ppm, as well as phase-curve variations from the planet's longitudinal brightness modulation and ellipsoidal distortion of the host star. Combining the TESS-band occultation measurement with a K(s)-band secondary eclipse depth (2012 ± 80 ppm) derived from ground-based observations, we find that the dayside emission of TOI-2109b is consistent with a brightness temperature of 3631 ± 69 K, making it the second hottest exoplanet hitherto discovered. By virtue of its extreme irradiation and strong planet–star gravitational interaction, TOI-2109b is an exceptionally promising target for intensive follow-up studies using current and near-future telescope facilities to probe for orbital decay, detect tidally driven atmospheric escape, and assess the impacts of H2 dissociation and recombination on the global heat transport.

Ian Wong↗

The Dynamic Atmospheric and Aeolian Environment of Jezero Crater, Mars

Despite the importance of sand and dust to Mars geomorphology, weather, and exploration, the processes that move sand and that raise dust to maintain Mars’s ubiquitous dust haze have not been well quantified in situ, with missions lacking either thenecessary sensors and/or a sufficiently active aeolian environment. Perseverance rover’s novel environmental sensors and Jezero crater’s dusty environment remedy this. In Perseverance’s first 216 sols, four convective vortices raised dust locally, while on average four passed the rover daily, over 25% of which were significantly dusty (‘dust devils’). More rarely, dust lifting by non-vortex wind gusts was produced by daytime convection cells advected over the crater by strong upslope winds, which also control aeolian surface features. One such event covered ten times more area than the largest dust devil, suggesting dust devils and wind gusts could raise equal dust.

Claire E Newman↗

Nonmagnetic fractional conductance in high mobility InAs quantum point contacts

In this paper, we report the magnetoelectronic properties of high mobility InAs quantum point contacts grown on InP substrates. The InAs quantum well is embedded between In 0.72 ⁢Ga 0.28 ⁢As cladding layers and In 0.81 ⁢Al 0.19 ⁢As barrier layers, and is populated via self-accumulation. The one-dimensional (1D) conductance reaches a maximum value of 17 plateaus, quantized in units of 2⁢𝑒 2 /ℎ, where 𝑒 is the fundamental unit of charge and ℎ is Planck's constant. The in-plane effective 𝑔 factor was estimated to be −10.9 ± 1.5 for subband 𝑁 = 1 and −10.8 ± 1.6 for subband 𝑁 = 2. Furthermore, a study of the nonmagnetic fractional conductance states at 0.2 (𝑒 2 /ℎ) and 0.1 (𝑒 2 /ℎ) is provided. While their origin remains under discussion, evidence suggests that they arise from strong electron-electron interactions and momentum-conserving backscattering between electrons in two distinct channels within the 1D region. This phenomenon may also be interpreted as an entanglement between the two channel directions facilitated by momentum-conserving backscattering.

Ballistic transport↗

Thiol post-translational modifications modulate allosteric regulation of the OpcA–G6PDH complex through conformational gate control

In cyanobacteria, the redox-sensitive protein OpcA acts as a metabolic switch for G6PDH, enabling rapid adjustment of reducing power generation from glycogen catabolism and thereby precisely regulating carbon flux between anabolic and catabolic pathways. Although redox-sensitive cysteines in OpcA are known to regulate G6PDH, the mechanisms by which redox post-translational modifications (PTMs) on OpcA control G6PDH structure and activity remain unclear. Here, we combine computational modeling with experimental redox proteomics in Synechococcus elongatus PCC 7942 to dissect this mechanism. Experimentally, redox proteome analysis revealed differential redox PTM patterns, particularly on cysteines within the G6PDH-binding site of OpcA. These environmentally sensitive PTM changes at the interface suggest that thiol modifications in this region form a key regulatory node. More broadly, redox proteomics identified site-specific cysteine modifications under light/dark transitions and circadian cycling, linking distinct redox regimes to discrete PTM states. We employed PTM-Psi simulations to show that thiol PTMs near the OpcA–G6PDH interface are critical for allosteric regulation of G6PDH. The thiol PTMs on OpcA affect a putative gate region in G6PDH for substrate ingress and product egress as well as key hydrogen-bond networks within the active site. We infer that PTMs on OpcA tune the conformational landscapes of individual G6PDH subunits toward functionally relevant configurations according to environmental gradients, biasing the enzyme toward catalytically favorable states. Together, our results reveal a molecular mechanism in which thiol PTMs on OpcA modulate G6PDH structure and function through PTM-induced reorganization of conformational dynamics and allosteric communication. These findings demonstrate that PTM-level regulation provides a critical control layer from genotypes to phenotypes that enables cyanobacteria to rapidly adapt to environmental fluctuations through precise metabolic fine-tuning.

Allosteric regulation↗

From lab to table: Expanding gastronomic possibilities with fermentation using the edible fungus Neurospora intermedia

Fermentation is a powerful tool for enhancing flavor, improving sustainability, and expanding creative possibilities in the kitchen. However, most fermentations done in gastronomic contexts are restricted to a small set of readily available microbial species. Expanding beyond this limited biological diversity holds promise to unlock new gastronomic innovation. Here, we explore novel culinary applications of Neurospora intermedia, an edible fungus traditionally used in Java, Indonesia to produce the fermented food oncom. Our work demonstrates that N. intermedia can be readily used in the production of oncom-like meat alternatives with non-traditional substrates, as well as in the production of enzymes for starch-to-sugar conversion. As an example, we harness secreted N. intermedia starch-degrading enzymes to produce an amazake that has a distinct volatile aroma composition compared to traditional amazake produced with Aspergillus oryzae. In addition to providing texture and flavor, N. intermedia can be used to add an orange color to dishes due to the development of brightly colored spores and aerial mycelia. This property, along with its secreted enzymes, was utilized to create a dish for fine-dining restaurant Alchemist in Copenhagen, Denmark. Overall, the novel foods produced in this study were rated favorably in consumer trials, indicating a broad sensory appeal of N. intermedia across different culinary applications and cultural contexts. The protocols and approaches presented in this study represent a new addition to the chef's toolbox that hold promise to expand gastronomic possibilities with fermentation in restaurants and beyond.

59 BASIC BIOLOGICAL SCIENCES↗