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At least 253 records · Page 14

The Synchrotron Low-energy Spectrum Arising from the Cooling of Electrons in Gamma-Ray Bursts

This work is a continuation of a previous effort (Panaitescu) to study the cooling of relativistic electrons through radiation (synchrotron and self-Compton) emission and adiabatic losses, with application to the spectra and light curves of the synchrotron gamma-ray burst (GRB) produced by such cooling electrons. Here, we derive the low-energy slope β LE of a GRB pulse-integrated spectrum and quantify the implications of the measured distribution of β LE . Radiative processes that produce soft integrated spectra can accommodate the harder slopes measured by CGRO/BATSE and Fermi/GBM only if the magnetic field lifetime t B is shorter than the time during which the typical GRB electrons cool to radiate below 1–10 keV, which is less than (at most) 10 radiative cooling timescales t rad of the typical GRB electron. In this case, there is a one-to-one correspondence between t B and β LE . To account for low-energy slopes β LE > -3/4, the adiabatic electron-cooling requires a similar restriction on t B . In this case, the diversity of slopes arises mostly from how the electron-injection rate varies with time (temporal power-law injection rates yield power-law low-energy GRB spectra) and not from the magnetic field timescale.

79 ASTRONOMY AND ASTROPHYSICS↗

Properties of the Prompt Optical Counterpart Arising from the Cooling of Electrons in Gamma-Ray Bursts

This work extends a contemporaneous effort to study the properties of the lower-energy counterpart synchrotron emission produced by the cooling of relativistic gamma-ray burst (GRB) electrons through radiation (synchrotron and self-Compton) emission and adiabatic losses. We derive the major characteristics (pulse duration, lag time after burst, and brightness relative to the burst) of the prompt optical counterpart (POC) occurring during or after the GRB. Depending on the magnetic field lifetime, duration of electron injection, and electron transit time Δt o from hard X-ray (GRB) to optical-emitting energies, a POC may appear during the GRB pulse (of duration δt γ ) or after (delayed OC). The signature of counterparts arising from the cooling of GRB electrons is that POC pulses (Δto < δtγ) last as long as the corresponding GRB pulse (δt o ≃ δt γ ), while delayed OC pulses (Δt o > δt γ ) last as long as the transit time (δt o ≃ Δt o ). If OC variability can be measured, then another signature for this OC mechanism is that the GRB variability is passed on to POCs but not to delayed OCs. Within the GRB electron cooling model for counterparts, POCs should be on average dimmer than delayed ones (consistent with the data), and harder GRB low-energy slopes β LE should be associated more often with the dimmer POCs. The latter sets an observational bias against detecting POCs from (the cooling of electrons in) GRBs with a hard slope β LE , making it more likely that the detected POCs of such bursts arise from another mechanism.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Cross-sections for 43 Sc, 44 m Sc, and 44 g Sc from two heavy ion reactions

Two different heavy ion reactions were used to produce 43 Sc (t$_{\frac12}$ = 3.891 h), 44g Sc (t$_{\frac12}$ = 4.042 h), and 44m Sc (t$_{\frac12}$ = 58.61 h) among other stable or long-lived chemically separable products. Production cross sections for 19 F + 27 Al and the reverse kinematic reaction 35 Cl + nat B were measured using an MC-SNICS ion source and the Notre Dame FN Tandem Accelerator. 19 F beams from 35 to 60 MeV were produced with beam currents between 40–80 pnA and 35 Cl beams were produced at six entrance energies with comparable beam currents. This work reports nuclear reaction cross sections 27 Al ( 19 F, x) 43 Sc, 27 Al ( 19 F, pn) 44g Sc, and 27 Al ( 19 F, pn) 44m Sc at six energies between 35 and 60 MeV lab energy. Cross sections within the same energy range were measured for 27 Al ( 19 F, 3pn) 42 K and 27 Al ( 19 F, 3p) 43 K. Comparative measurements were performed for the same compound nucleus produced from nat B( 35 Cl, x) 43 Sc, nat B( 35 Cl, pn) 44g Sc, and nat B( 35 Cl, pn) 44m Sc. The measured thin target cross sections show an overestimation by several statistical models for the scandium radioisotopes. This is corroborated by the measured thick target production rates for both entrance channels. This may be due to angular momentum effects of a heavy ion entrance channel compared to light-ion production, but additional work is required to understand this discrepancy. Finally, these measurements demonstrate that the medically useful 43 Sc, 44g Sc, and 44m Sc radioisotopes can be free of the long-lived contaminant 46 Sc without the use of enriched targets, using heavy ion beams and robust target materials.

07 ISOTOPE AND RADIATION SOURCES↗

CHARACTERIZATION OF RADIATION DAMAGES TO POSITRON SOURCE MATERIALS

The secondary beam production target at future positron sources at the Continuous Electron Beam Accelerator Facility (CEBAF), the International Linear Collider (ILC) or the Future Circular Collider (FCC), features unprecedented mechanical and thermal stresses which may compromise sustainable and reliable operation. Candidate materials are required to possess high melting temperature together with excellent thermal conductivity, elasticity and radiation hardness properties. In order to substantiate the material choice for the CEBAF and ILC positron sources, the response of candidate materials such as titanium alloys, tungsten, and tantalum to electron beam irradiation was experimentally investigated. CEBAF and ILC expected operating conditions were mimicked using the 3.5 MeV electron beam of the MAMI facility injector. The material degradations were precisely analyzed via high energy X-ray diffraction at the HEMS beamline operated by the Helmholtz-Zentrum Hereon at the PETRA III synchrotron facility. This work reports the results of these measurements and their interpretation.

Lengler, T.↗

Effect of pressure cycling and compression rate on the bcc-hcp transition in an FeNi alloy

Here, we investigate the body-centered cubic (bcc) to hexagonal close-packed (hcp) phase transition in Fe-10wt. %Ni alloy, combining pressure cycling and fast compression with time-resolved synchrotron x-ray diffraction in a dynamic diamond anvil cell. Three pressure cycles were conducted with compression rates ranging from 0.1 to nearly 10 3 GPa/s. During the first cycle with the slowest compression, the observed orientations in the bcc and hcp phases are consistent with the Burgers mechanism, followed by c-axis rotation of the hcp phase consistent with {$10$ $\bar{1}2$} twinning. During the following cycles with fast compression at 10 2 –10 3 GPa/s, the hcp phase exhibits negligible c-axis rotation with a nearly constant c/a ratio of ∼1.61 up to ∼30 GPa, indicating suppression of plastic deformation (especially, twinning) due to sample confinement from the gasket. Notably, the onset pressure of the transition decreases with additional pressure cycling and faster compression, which normally leads to over-pressurization. This suggests that defects or shear induced from the pressure cycling reduces the transition kinetics even during fast compression. These insights into the deformation and transition behavior in an FeNi alloy under multiple dynamic loading cycles can offer guidance for future design of advanced structural alloys and improve our understanding of planetary core processes.

FeNi alloy↗

Extending tetrahedral network similarity to carbon: A type-I carbon clathrate stabilized by boron

Clathrates are guest/host framework compounds composed of polyhedral cages, yet despite their prevalence among tetrahedral network formers, clathrates with a carbon host lattice remain unrealized synthetic targets. Here, we report a type-I carbon-based framework—a ubiquitous clathrate structure type found throughout compounds containing tetrahedral building blocks. Following a boron-stabilization scheme based on first-principles predictions in the Ca–B–C system at high pressure, type-I Ca 8 B x C 46−x (x ≈ 9) was synthesized in the archetypal $Pm\bar{3}n$ lattice with stability derived from substitutionally disordered boron atoms on hexagonal ring framework positions. The synthesized clathrate, which is recoverable to ambient conditions, expands topological network similarity across tetrahedral systems and opens possibilities for a broad family of diamond-like, carbon-based compounds with tunable properties based on the wide potential for guest/host-atom substitutions and framework versatility.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cross-Section Comparison for Pu-238 Production in the Advanced Test Reactor at Idaho National Laboratory

Qualification of Advanced Test Reactor (ATR) positions for Pu-238 production has been ongoing at Idaho National Laboratory (INL). The ATR qualifications have stretched over multiple years during which new techniques have been developed and made available for ATR experiment neutronic analysis. As part of the transition to newer codes, new cross-section libraries have been evaluated for use in the Pu-238 production experiment analysis. A comparative study was done using the MCNP ORGIEN Activation Analysis (MOAA) tool between ENDF/B-VII.0 and ENDF/B-VIII.0 cross sections to capture the impact of the change in cross-sections on the analysis needed to qualify Pu-238 production targets. All comparisons were done assuming the ATR GEN-I targets were located in the south flux trap of the ATR. Finally, an overview of how this qualification and potential irradiation fits into Pu-238 is discussed.

07 ISOTOPE AND RADIATION SOURCES↗

The HRA/Solarium Project: Feedback Based on 20 Years of Experience in Treatment of Medium Level Waste - 20185

Since the 1980's the management of the historical site of Mol has been transferred to the National Agency for Radioactive Waste and Enriched Fissile Materials (ONDRAF/NIRAS). Belgoprocess is entrusted by ONDRAF/NIRAS with the operational waste management and site remediation. One of the major challenges has been the characterization, treatment and conditioning of approximately 200 m{sup 3} of medium level waste. These waste packages were stored in poor conditions in storage vaults ('HRA') or concrete containers ('Solarium'). They have been produced in various research programs and reactor operations at the Belgian nuclear energy research centre SCK.CEN, isotope production, decontamination and dismantling operations from the 1960's up to the 1980's. Despite the limited volume, this historical waste consists of a great variation of waste characteristics and waste configurations. To tackle these liabilities, a new processing facility was built in the 1990's to allow safe transfers, handling, characterization and treatment of these packages. Also some auxiliary facilities have been built to deal with the by-products, like emptied concrete containers. The engineering of the installation, safety procedures and (characterization) methodology that has been developed generically have been proved to be successful. Nevertheless, the specific nature of some items made it necessary to organize a step-by-step treatment in distinct campaigns in which some relevant extra (safety) measures had to be taken into account. This dynamic approach made it possible to process a great variety of waste types in order to to ensure that this legacy is no longer left for subsequent generations. After about 20 years of operations, there has been a great build-up of experience and feed-back concerning the waste management of these specific waste streams. Some cases will be highlighted to specify the approach followed for treatment of e.g.: - Na/NaK containing equipment; - spent radioactive sources; - fuel element residues; - medium level waste originating from activation experiments; - radium bearing medium level waste originating from Ac-227 production research. (authors)

07 ISOTOPE AND RADIATION SOURCES↗

S&TR September 2025: Computing Grand Challenge Turns 20

Livermore’s Computing Grand Challenge Program enters its 20th year with more unclassified high-performance computing (HPC) power than ever before. This unique, peer-reviewed competition awards HPC allocations on top supercomputers to multidisciplinary teams with high-impact projects. The Grand Challenge encourages researchers to innovate, pushes scientific discovery to new heights, improves the Laboratory’s HPC capabilities, and extends HPC accessibility to collaborators. Awardees must adapt to successive generations of HPC hardware and learn to run simulations at scale. The feature article spotlights three Grand Challenge teams whose research broke new ground in key scientific pursuits—the essence of dark matter, explosion-generated seismic waves, and protein interactions linked to cancer—while underscoring the importance of academic partnerships and considering the program’s future.

07 ISOTOPE AND RADIATION SOURCES↗

X-ray-diffraction and electrical-transport imaging of superconducting superhydride (La,Y)H 10

Understanding how microscopic structural domains govern macroscopic electronic properties is central to advancing hydride superconductors, yet such correlations remain poorly resolved under pressure. We report the synthesis and characterization of (La 0.9 Y 0.1 )H 10 superhydrides exhibiting coexisting cubic $Fm\bar{3}m$ and $P6_3/mmc$ hexagonal clathrate phases observed over the pressure range from 168 GPa down to 136 GPa. Using synchrotron-based X-ray diffraction imaging at the upgraded Advanced Photon Source, we spatially resolved μm-scale distributions of these phases, revealing structural inhomogeneity across the sample. Four-probe resistance measurements confirmed superconductivity with two distinct transitions: an onset at 244 K associated with the cubic phase and a second near 220 K linked to the hexagonal phase. Notably, resistance profiles collected from multiple current and voltage permutations showed variations in transition width and onset temperature that correlated with the spatial phase distribution. These findings demonstrate a direct connection between local structural domains and superconducting behavior.

Materials science↗

Reduction and Agglomeration of Supported Metal Clusters Induced by High-Flux X-ray Absorption Spectroscopy Measurements

Supported metal clusters are widely used in catalysis for many important reactions. To understand the catalytic properties, in situ/operando characterization techniques, such as X-ray absorption spectroscopy (XAS), provide essential details of the size, shape, and chemical composition of the cluster and the nature of the active sites. New-generation synchrotrons combined with focusing beamlines provide high-flux-density X-rays for improved detection sensitivity as well as higher time and spatial resolution. Understanding the effects of a high-flux-density X-ray beam on the catalyst during the actual measurement, whether XAS or another synchrotron-based technique, is crucial. This is especially important for in situ and operando studies where both the high flux density and reaction conditions can affect the catalyst structure. In this work, we investigated the effect of the flux density on rhodium clusters supported on Al 2 O 3 at two different beamlines: National Synchrotron Light Source II beamline 08-ID and Stanford Synchrotron Radiation Light Source (SSRL) beamline 4-1. We show that the higher flux density at beamline 08-ID causes the reduction of the highly dispersed RhO x /Al 2 O 3 catalyst, even at room temperature. Additionally, exposure to the higher flux density X-rays at beamline 08-ID during in situ reduction results in significant agglomeration of the Rh clusters. The final size of the Rh nanoparticles reduced at 310 °C is equivalent to that of particles formed after the reduction at 600–650 °C in the absence of the beam. Significant beam-induced reduction and agglomeration is also shown for Ni supported on beta zeolite during in situ reduction at an intermediate-flux-density beamline 9-3 at SSRL, indicating that beam-induced changes in heterogeneous catalysts could be common at intermediate- and high-flux-density beamlines. We provide precautions and recommendations for detecting and minimizing beam damage during in situ/operando XAS measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Radiation Shielding Analysis of Niowave’s Uranium Target Assembly 2 (UTA-2) Facility for Molybdenum-99 Production

Niowave is seeking to develop a commercial medical isotope production process using a low-enriched uranium accelerator-driven subcritical reactor (ADSR) system to produce molybdenum-99. As part of the US Department of Energy national laboratory support to develop low enriched uranium molybdenum-99 production technologies, Oak Ridge National Laboratory is providing research and development resources to assist Niowave in the design and licensing process of its technology. The goals of this work under the radiation shielding task are to assist Niowave in developing a methodology and framework for efficient radiation shielding simulations of their Uranium Target Assembly 2 facility and to provide preliminary radiation shielding calculations and design recommendations for the facility.

07 ISOTOPE AND RADIATION SOURCES↗

Radiolysis and radionuclide production in a flowing-water target during fast 40 Ca 20+ irradiation

Here, a flowing-water target was irradiated with a 140 MeV/u, 8 nA 40Ca20+ beam to test the feasibility of isotope harvesting at the upcoming Facility for Rare Isotope Beams. Among other radionuclides, 2.6(2)E-6 48Cr and 5.6(5)E-6 28 Mg nuclei were formed for every impingent 40Ca and were collected through ion exchange. Radiolysis-induced molecular hydrogen evolved from the target at an initial rate of 0.91(9) H2 molecules per 100 eV of beam energy deposited. No radiation-accelerated corrosion of the target material was determined.

07 ISOTOPE AND RADIATION SOURCES↗

A detailed experimental and modeling comparison of molecular radiative heat loss in a spark-ignition engine

Radiative heat transfer has been chiefly considered negligible in internal combustion engines, except for Diesel engines where soot radiation was recognized as a significant radiative transfer source. Only more recently, detailed simulations have shown that molecular radiation can be substantial as well. In extension to this, molecular radiative heat transfer can reach detectable levels of about 5–10% of the total heat transfer in spark-ignited engines. The broadband radiative nature of the significant emitting molecules, carbon dioxide and water, makes it necessary to address whether radiative trapping plays a substantial role in either total heat loss or energy redistribution within the cylinder. An experimental setup that allows measurements of the infrared emissions at a 2-crank-angle-degree resolution was developed to determine the importance of radiative trapping by carbon dioxide and water. Measurements were conducted in the well-characterized and documented TCC-III engine at the University of Michigan. The engine operated on a stoichiometric propane/air mixture at a speed of 1,300 RPM. Large Eddy Simulations with added line-by-line photon Monte-Carlo simulations of the molecular radiation were an integral part of this study to plan and devise the measurements. Post-processing of the simulation data included an accurate representation of the experimental volume from where infrared signals are collected. Additionally, the experimental data were used for validation of the photon Monte-Carlo simulations. Joint analysis of experimental and simulated spectra allowed quantifying the significance of radiative trapping. Results show the significant role of radiative trapping when predicting radiative heat transfer in the TCC-III engine.

42 ENGINEERING↗

The ENDF/B-VIII.0 Compendium Volume I: Neutron Cross Section Plots

Version 8 of the Evaluated Nuclear Data File (ENDF/B-VIII.0) contains a wealth of nuclear data representing the most recent collection of evaluated neutron cross section measurements, isotopic radioactive decay, and much more. This Compendium has been prepared as a easily-navigable reference of the contents of the ENDF/B-VIII.0 library, while making no statement regarding the accuracy of those contents. The Compendium is split into four volumes.

07 ISOTOPE AND RADIATION SOURCES↗

The ENDF/B-VIII.0 Compendium Volume IV: Radioactive Decay Rank-Order Analyses

Version 8 of the Evaluated Nuclear Data File (ENDF/B-VIII.0) contains a wealth of nuclear data representing the most recent collection of evaluated neutron cross section measurements, isotopic radioactive decay, and much more. This Compendium has been prepared as a easily-navigable reference of the contents of the ENDF/B-VIII.0 library, while making no statement regarding the accuracy of those contents. The Compendium is split into four volumes. In Volume IV, radioactive decay properties are presented in tabular form, sorted by isotope, energy, element-then- energy, and probability of emission.

07 ISOTOPE AND RADIATION SOURCES↗