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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Tropical Tropospheric Ozone from SHADOZ (Southern Hemisphere ADditional Ozonesondes) Network: A Project for Satellite Research, Process Studies, Education

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole and convective mixing. Pollution transport from Africa and South America is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Thompson, Anne M.↗
DOE OSTI2026

Inundation and Sediment Supply Predict Annual but Not Centennial Carbon Accumulation in Tidal Wetlands Across Land‐Use Types

Despite growing interest in the contributions of tidal wetlands to natural climate solutions, data remain scarce on how land use affects their carbon accumulation rates (CAR). Additionally, environmental factors driving the large observed variability in CAR among sites are poorly understood. To address these knowledge gaps, we measured short-term (∼1 year) and long-term (∼100 years) CAR using feldspar marker horizons, 210 Pb profiles, and surface elevation tables from 39 sites in seven estuaries in Oregon and Washington, USA. Sites varied in wetland type (tidal marsh, tidal swamp, nontidal pasture), land-use history (reference, restored, and disturbed), and salinity (fresh to polyhaline). Across both timescales, CAR was lowest in disturbed pastures and highest in restored marshes, reflecting patterns in sediment accretion rates. Short-term CAR exceeded long-term CAR by approximately 50% on average and was only weakly correlated with long-term CAR, with differences among hydrogeomorphic setting. Short-term CAR was well predicted by summer inundation frequency and relative sediment load, together explaining 60% of variance, whereas long-term CAR was poorly predicted by contemporary environmental conditions. These findings highlight the importance of aligning predictor and response timescales when modeling blue carbon dynamics, and reinforce the climate mitigation potential of tidal wetland restoration.

land use and land cover change↗
DOE OSTI2026

Integration of ultra-low coverage whole-genome sequences for reconstructing the evolutionary history of Galapagos giant tortoises

Genomic data from contemporary and historical samples often need to be coupled for evolutionary reconstructions of multitaxon complexes. However, the genetic data recovered from historical samples may result only in ultra-low coverage whole-genome sequences (ulcWGS; <0.15× depth), leading to inaccurate evolutionary inferences given a preponderance of missing data. Using the Galapagos giant tortoise radiation as a study system (Chelonoidis spp., composed of 13 extant and four extinct lineages), we assembled a novel methodological pipeline that removes potential noise introduced by the missing data and enhances the evolutionary signal from ulcWGS samples. We leveraged existing tools for phylogenomic placement (EPA-ng), population genomic structure (smartsnp) and admixture (Admixfrog, NGSadmix) to demonstrate that the evolutionary history of samples can be uncovered with sequencing depths as low as 0.008–0.139×. Importantly, these approaches do not use genotype imputation of the ulcWGS samples, which would require extensive reference datasets. Our application to two cases of extinct lineages of Galapagos giant tortoises, with and without references from the same lineage, demonstrates the general value of the approach. We confirm where the extinct lineages from San Cristóbal and Santa Fe islands fit into the Galapagos giant tortoise radiation, and that these lineages were evolutionarily distinct entities.

ancient DNA↗
DOE OSTI2024

Intrinsic and environmental drivers of pairwise cohesion in wild Canis social groups

Animals within social groups respond to costs and benefits of sociality by adjusting the proportion of time they spend in close proximity to other individuals in the group (cohesion). Variation in cohesion between individuals, in turn, shapes important group-level processes such as subgroup formation and fission–fusion dynamics. Although critical to animal sociality, a comprehensive understanding of the factors influencing cohesion remains a gap in our knowledge of cooperative behavior in animals. We tracked 574 individuals from six species within the genus Canis in 15 countries on four continents with GPS telemetry to estimate the time that pairs of individuals within social groups spent in close proximity and test hypotheses regarding drivers of cohesion. Pairs of social canids (Canis spp.) varied widely in the proportion of time they spent together (5%–100%) during seasonal monitoring periods relative to both intrinsic characteristics and environmental conditions. The majority of our data came from three species of wolves (gray wolves, eastern wolves, and red wolves) and coyotes. For these species, cohesion within social groups was greatest between breeding pairs and varied seasonally as the nature of cooperative activities changed relative to annual life history patterns. Across species, wolves were more cohesive than coyotes. For wolves, pairs were less cohesive in larger groups, and when suitable, small prey was present reflecting the constraints of food resources and intragroup competition on social associations. Pair cohesion in wolves declined with increased anthropogenic modification of the landscape and greater climatic variability, underscoring challenges for conserving social top predators in a changing world. We show that pairwise cohesion in social groups varies strongly both within and across Canis species, as individuals respond to changing ecological context defined by resources, competition, and anthropogenic disturbance. Our work highlights that cohesion is a highly plastic component of animal sociality that holds significant promise for elucidating ecological and evolutionary mechanisms underlying cooperative behavior.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2026

Coordinated Natural Gas and Electric Planning: Case Studies of Current Approaches and Practices

This paper examines how natural gas and electric utilities across eight U.S. states and two Canadian provinces are beginning to coordinate historically separate planning processes in response to growing system interdependencies, policy mandates, aging infrastructure, and changing customer energy choices. Electricity planning has long relied on robust integrated resource planning frameworks that weigh numerous objectives, risks, and costs. Natural gas planning, on the other hand, is typically less transparent and more narrowly focused on safety and system integrity. As economic, reliability, and policy drivers place new and shared demands on both systems, jurisdictions and utilities are experimenting with approaches such as coordinated forecasting, non pipeline alternatives, and combined planning pilots. A few have issued regulatory or statutory directives for greater data sharing and methodological alignment. Case studies from British Columbia, California, Colorado, Illinois, Massachusetts, Minnesota, New York, Québec, Rhode Island, and Washington illustrate a wide range of approaches to rethinking siloed planning. The paper identifies several common themes across the jurisdictions examined. It provides observations on the methods, processes, and organizational steps that may be needed in the future to address the challenges being faced by states and utilities. Lastly, it identifies some initial steps that states and utilities can consider if they would like to pursue more integrated, cost-effective, policy-aligned energy system planning.

03 NATURAL GAS↗
NASA NTRS2004

Variability in Tropical Tropospheric Ozone as Observed by SHADOZ

The SHADOZ (Southern Hemisphere Additional Ozonesondes) ozone sounding network was initiated in 1998 to improve the coverage of tropical in-situ ozone measurements for satellite validation, algorithm development and related process studies. Over 2000 soundings have been archived at the central website, , for 12 stations: Ascension Island; Nairobi and Malindi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil; Paramaribo, Surinam. Some results to date indicate reliability of the measurement and highly variable interactions between ozone and tropical meteorology. For example: 1. By using ECC sondes with similar procedures, 5-10% accuracy and precision (1-sigma) of the sonde total ozone measurement was achieved [Thompson et al., 2003al; 2. Week-to-week variability in tropospheric ozone is so great that statistics are frequently not Gaussian and most stations vary up to a factor of 3 in column amount over the course of a year [Thompson et al., 2002b]. 3. Longitudinal variability in tropospheric ozone profiles is a consistent feature, with a 10- 15 DU column-integrated difference between Atlantic and Pacific sites; this is the cause of the zonal wave-one feature in total ozone [Shiotani, 1992]. The ozone record from Paramaribo, Surinam (6N, 55W) is a marked contrast to southern tropical ozone because Surinam is often north of the Intertropical Convergence Zone. Interpretations of SHADOZ time-series and approaches to classification suggested by SHADOZ data over Africa and the Indian Ocean will be described.

Thompson, Anne M.↗
NASA NTRS2002

SHADOZ (Southern Hemisphere ADditional Ozonesondes): What Have We Learned About Tropical Tropospheric Ozone from the First Three Years' (1998-2000) Data?

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; RCunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, and convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Thompson, Anne M.↗
NASA NTRS2002

SHADOZ (Southern Hemisphere ADditional Ozonesondes}: What Have We Learned About Tropical Tropospheric Ozone from the First Three Years (1998-2000) Data

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on an Trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approximately 7 hPa and relative humidity to approximately 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, and convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Thompson, Anne M.↗
DOE OSTI2024

New species and records of the symbiotic shrimp genus Leptalpheus Williams, 1965, with notes on Fenneralpheus Felder & Manning, 1986, and preliminary molecular analysis of phylogenetic relationships (Crustacea: Decapoda: Alpheidae)

The shrimp genera Leptalpheus Williams, 1965 and Fenneralpheus Felder & Manning, 1986 are composed entirely of symbiotic species that co-inhabit burrows of infaunal macrocrustaceans. We report extensive collections of these genera from western Atlantic, eastern Pacific and Indo-West Pacific regions. Integrative taxonomy methods, including morphological comparisons and analysis of three mitochondrial genetic markers, are used to test species hypotheses and evolutionary relationships among members of these genera. Our molecular analysis failed to recover Leptalpheus or Fenneralpheus as monophyletic groups. Our results strongly supported the monophyly of three clades composed of species of Leptalpheus, loosely corresponding to previously proposed species groups. Three new species closely related to Leptalpheus forceps Williams, 1965, L. marginalis Anker, 2011, and L. mexicanus Ríos & Carvacho, 1983 are described. Leptalpheus ankeri n. sp., from the Caribbean Sea, Atlantic coast of Florida, and Gulf of Mexico, is a polymorphic species that exhibits two major cheliped morphotypes. Leptalpheus sibo n. sp., from the Pacific coast of Nicaragua, is morphologically very similar to L. ankeri n. sp., likely its transisthmian sister species, and shares its cheliped polymorphism. A reassessment of L. forceps concluded that records of this species from the Caribbean Sea and Brazil are not conspecific with L. forceps sensu stricto from the Atlantic coast of the USA and the Gulf of Mexico, and they are herein described as Leptalpheus degravei n. sp. Based on both molecular and morphological evidence, we found Leptalpheus bicristatus Anker, 2011 to be a junior synonym of L. mexicanus and Leptalpheus canterakintzi Anker & Lazarus, 2015 to be a junior synonym of Leptalpheus azuero Anker, 2011. First reports of Leptalpheus axianassae Dworschak & Coelho, 1999 in Texas and Mexico, Leptalpheus denticulatus Anker & Marin, 2009 in the Mariana Islands, Leptalpheus felderi Anker, Vera Caripe & Lira, 2006 and Leptalpheus lirai Vera Caripe, Pereda & Anker, 2021 in the USA, and Leptalpheus pereirai Anker & Vera Caripe, 2016 in Cuba are included.

Zoology↗
NASA NTRS1992

Crustal deformation measurements in central Japan determined by a Global Positioning System fixed-point network

Results are presented from temporally dense measurements of crustal deformation associated with the convergence of the Eurasian (EUR), Pacific, North American, and Philippine Sea (PHS) plates, carried out in April 1988 by a 10-station GPS fixed-point network established in central Japan. Using regional orbit relaxation methods, the analysis of the first 17-month data revealed significant horizontal deformation across the Suruga trough. Namely, it was found that a site in the northern tip of PHS plate moved nearly westward with a velocity of 28 +/-5 mm per year, and a site at the southeastern tip of EUR plate moved south-southwestward with a velocity of 18 +/-5 mm per year. A significant vertical uplift with a velocity of 20 mm/yr was detected at a site inland of the Tokai district located in the Akaishi uplift zone and at a site on the Hatsushima Island in Sagami Bay.

Shimada, Seiichi↗
NASA NTRS2001

SHADOZ (Southern Hemisphere ADditional Ozonesondes): A Look at the First Three Years' (1998-2000) Tropospheric Ozone Data

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere ADditional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; RCunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natai, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at an open archive: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, ENSO, and Madden-Julian circulation on convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude.

Thompson, Anne M.↗
NASA NTRS2002

Atmospheric Chemistry Insights from the SHADOZ Data: An IGAC Paradigm

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from ten sites comprising the Southern Hemisphere Additional Ozonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a Trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: http://code9l6.gsfc.nasa.gov/ Data-services/shadoz. SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, and convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Thompson, Anne M.↗
NASA NTRS2022

Wave Setup at the Minamitorishima Tide Gauge

A tide gauge situated on the western shore of Minamitorishima, a small atoll in the western Pacific, has measured sea levels significantly impacted by wave setup. Evidence for this rests with (a) strong correlations between sea level anomalies and high swell and (b) sea-level differences with satellite altimetry that display near-linear dependence on offshore swell heights (regression coefficient 30 cm per meter of swell). Setup is primarily induced by swell from the northwest. We develop models of wave setup which lead to corrected sea levels better reflecting the surrounding ocean, and thus more readily useful to studies of regional sea level and practical applications such as altimetry calibration. The wave setup is also evidently affecting measurements of the tide, with suppressed tide amplitudes in winter when swell is generally largest. In February 2020 the tide gauge was relocated to the southern shore of the island, and the wave setup is now markedly reduced.

Wave setup↗
DOE OSTI2025

Data for Kim et al., "Variations in the optical and molecular composition of dissolved organic matter exported from coastal wetlands"

Knowledge about sources and composition of marsh-derived dissolved organic matter (DOM) is critical for understanding the role of marshes in coastal biogeochemical cycling and the fate of marsh-derived DOM in the ocean. To investigate tidal variability in composition of marsh-derived DOM, Kim et al. examined the optical and molecular characteristics of hourly surface water samples at three tidal creeks in the Chesapeake Bay. Groundwater samples along the terrestrial landscape gradient as well as estuarine water from the adjacent estuary at each site were also collected to help resolve sources of surface water DOM. Samples were collected in summer 2024 at three sites – SWH: Sweet Hall Marsh, GCW: Kirkpatrick Marsh, and GWI: Goodwin Islands – which are part of synoptic sites in the Chesapeake Bay region of the COMPASS-FME (Coastal Observations, Mechanisms, and Predictions Across Systems and Scales - Field, Measurements, and Experiments) project. Surface water samples were collected hourly over a 48-hour period at each site. Groundwater and estuarine water samples were collected once. This dataset includes- Surface water depth and salinity- Dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) concentrations- Optical indices and relative composition of parallel factor analysis (PARAFAC) components- High resolution mass spectrometry data.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Harnessing Chemical Short‐Range Disorder to Improve Lithium Retention in Epitaxial LLTO Solid‐Electrolyte Thin Films

Lithium lanthanum titanate Li 3x La 2/3-x TiO 3 (LLTO) is a promising perovskite-based solid-state electrolyte for next-generation lithium-ion batteries, but controlling crystallinity and Li stoichiometry in thin-film form is challenging because high growth temperatures are required to achieve good crystallinity while Li remains strongly volatile. Here, we systematically investigate the effect of substrate temperature on epitaxial LLTO thin films grown by pulsed laser deposition. We identify a narrow growth window (750–800°C) in which LLTO films grow as c-axis oriented with atomically flat surfaces. Lower growth temperatures (<750°C) stabilize laterally extended, chemically disordered stripe domains that coexist with ordered LLTO regions, whereas higher temperatures (≥825°C) suppress these defects but promote island morphologies and Al/Ti interdiffusion. While spectroscopy measurements show that Ti remains in the 4+ oxidation state and Li is globally deficient for all films, our depth-resolved time-of-flight secondary ion mass spectrometry studies reveal that the 700°C film retains the highest Li content across its thickness. These results clarify how growth temperature controls crystallinity, chemical short-range disorder, and Li retention, and highlight moderate growth temperatures (∼700°C) as a route to mitigate Li loss in epitaxial solid-electrolyte films.

chemical short-range disorder↗
DOE OSTI2021

Tidal Stream Energy Resource Characterization in the Salish Sea

Tidal stream energy holds great potential as a renewable energy source in regions of the world where tidal currents are strong and predictable. The tidal stream energy resource of a region is strongly controlled by its tidal wave characteristics, the local bathymetry, and coastal geometric features. The Salish Sea, a large estuary on the Pacific Northwest coast, represents a great tidal stream resource because of its strong tidal currents in many tidal channels. However, the tidal resource in the Salish Sea has not been systematically characterized, primarily because of its large area and complex bathymetry and coastlines. This paper presents a modeling study conducted to characterize the tidal energy resource of the Salish Sea based on a high-resolution three-dimensional tidal hydrodynamic model of the Salish Sea, which was extensively validated using data derived from 10 tidal gauge stations and 132 Acoustic Doppler Current Profiler stations. Model validation results indicated the Salish Sea hydrodynamic model is skillful in simulating tidal wave propagation and velocity distributions in the Salish Sea. Based on model results, a total of 16 tidal channels with strong tidal currents, 9 in the San Juan Islands and Rosario Strait regions and 7 in the Puget Sound, were identified as hotspots for potential tidal energy development. Velocity probability distributions and exceedance curves of cross-channel average velocity magnitudes were calculated at all 16 channels based on the recommendations of the International Electrotechnical Commission Technical Specifications for tidal energy resource characterization. The tidal energy resource at the 16 hotspots was also characterized using power density distributions and kinetic energy fluxes. The ranking of the kinetic energy fluxes suggested that Admiralty Inlet, Rosario Strait, and Middle Channel are the top three hotspot sites in the Salish Sea for tidal stream energy development. The study demonstrated the need for a high-resolution 3-D modeling framework for accurate simulation of tidal currents in large complex estuarine systems, in the context of tidal energy resource characterization.

tidal stream energy, resource characterization, Sa↗
DOE OSTI2022

On the circulation, water mass distribution, and nutrient concentrations of the western Chukchi Sea

Substantial amounts of nutrients and carbon enter the Arctic Ocean from the Pacific Ocean through the Bering Strait, distributed over three main pathways. Water with low salinities and nutrient concentrations takes an eastern route along the Alaskan coast, as Alaskan Coastal Water. A central pathway exhibits intermediate salinity and nutrient concentrations, while the most nutrient-rich water enters the Bering Strait on its western side. Towards the Arctic Ocean, the flow of these water masses is subject to strong topographic steering within the Chukchi Sea with volume transport modulated by the wind field. In this contribution, we use data from several sections crossing Herald Canyon collected in 2008 and 2014 together with numerical modelling to investigate the circulation and transport in the western part of the Chukchi Sea. We find that a substantial fraction of water from the Chukchi Sea enters the East Siberian Sea south of Wrangel Island and circulates in an anticyclonic direction around the island. This water then contributes to the high-nutrient waters of Herald Canyon. The bottom of the canyon has the highest nutrient concentrations, likely as a result of addition from the degradation of organic matter at the sediment surface in the East Siberian Sea. The flux of nutrients (nitrate, phosphate, and silicate) and dissolved inorganic carbon in Bering Summer Water and Winter Water is computed by combining hydrographic and nutrient observations with geostrophic transport referenced to lowered acoustic Doppler current profiler (LADCP) and surface drift data. Even if there are some general similarities between the years, there are differences in both the temperature–salinity and nutrient characteristics. To assess these differences, and also to get a wider temporal and spatial view, numerical modelling results are applied. According to model results, high-frequency variability dominates the flow in Herald Canyon. This leads us to conclude that this region needs to be monitored over a longer time frame to deduce the temporal variability and potential trends.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Strontium‐Enriched Barite for Enhanced PbSO 4 Nucleation in Lead‐Acid Batteries

Abstract Barite (BaSO 4 ) crystals are an important additive in lead acid batteries due to their ability to promote the controlled nucleation and growth of anglesite (PbSO 4 ) during battery cycling. This is due to BaSO 4 ’s isostructural match with PbSO 4 , which facilitates epitaxial nucleation. However, BaSO 4 ’s efficacy as a nucleation promoter is limited by lattice mismatches between the two phases of 1–5%. Here, strontium‐enriched barite, (Ba,Sr)SO 4 , is synthesized to produce a nucleating promoter that displays an improved lattice match with PbSO 4 . Nucleation of PbSO 4 from Pb‐rich sulfuric acid solutions on strontium‐free and strontium‐enriched barite (up to 17 mol% Sr) is investigated using in‐situ atomic force microscopy and optical microscopy. At low strontium concentrations, PbSO 4 forms by the Stranski–Krastanov growth pathway (monolayer + island formation), with most nucleation occurring on edges and surface defects. At higher concentrations, the layer‐by‐layer growth mechanism known as Frank van‐der‐Merwe growth is observed, which allows for facile growth of continuous PbSO 4 films across the BaSO 4 surface. These films are successfully re‐dissolved on exposure to Pb‐free sulfuric acid. The results show that strontium incorporation fundamentally alters the mechanism of PbSO 4 nucleation on BaSO 4 , and thus provides a potential avenue for creating improved nucleation promoters in lead‐acid batteries.

Campbell, Colin T. [Pacific Northwest National Lab↗