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At least 253 records · Page 14

An Overview of Production and Validation of the SMAP Passive Soil Moisture Product

The Soil Moisture Active Passive (SMAP) mission is an L-band mission scheduled for launch in Jan. 2015. The SMAP instruments consist of a radar and a radiometer to obtain complementary information from space for soil moisture and freeze/thaw state research and applications. By utilizing novel designs in antenna construction, retrieval algorithms, and acquisition hardware, SMAP provides a capability for global mapping of soil moisture and freeze/thaw state with unprecedented accuracy, resolution, and coverage. This improvement in hydrosphere state measurement is expected to advance our understanding of the processes that link the terrestrial water, energy and carbon cycles, improve our capability in flood prediction and drought monitoring, and enhance our skills in weather and climate forecast. For swath-based soil moisture measurement, SMAP generates three operational geophysical data products: (1) the radiometer-only soil moisture product (L2_SM_P) posted at 36-kilometer resolution, (2) the radar-only soil moisture product (L2_SM_A) posted at 3-kilometers resolution, and (3) the radar-radiometer combined soil moisture product (L2_SM_AP) posted at 9-kilometers resolution. Each product draws on the strengths of the underlying sensor(s) and plays a unique role in hydroclimatological and hydrometeorological applications. A full suite of SMAP data products is given in Table 1.

passive microwave↗

AIRS-Only Product in Giovanni for Exploring Up-to-Date AIRS Observation and Comparing with AIRS+AMSU Product

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has been the home of processing, archiving, and distribution services for the Atmospheric Infrared Sounder (AIRS) mission since its launch in 2002 for global observations of the atmospheric state. Giovanni, a Web-based application developed by the GES DISC, provides a simple and intuitive way to visualize, analyze, and access vast amounts of Earth science remote sensing data without having to download the data. Most important AIRS variables, including temperature and humidity profiles, outgoing longwave radiation, cloud properties, and trace gases, are available in Giovanni. AIRS is an instrument suite comprised of a hyperspectral infrared instrument (AIRS) and two multichannel microwave instruments, the Advanced Microwave Sounding Unit (AMSU) and the Humidity Sounder for Brazil (HSB). As HSB ceased operation in the very early stages of the AIRS mission, the AIRS project operates two parallel retrieval algorithms: one using both IR and MW measurements (AIRS+AMSU) and the other using only IR measurements (AIRS-only), which covers most of the mission duration. The AIRS+AMSU product is better quality, and the variables in Giovanni are from this product. However, generation of the AIRS+AMSU product has been suspended since the AMSU instrument anomaly occurred in late September 2016. To continue exploring up-to-date AIRS observations, the same set of variables from the AIRS-only product have been added to Giovanni by the GES DSIC. This will also support comparison of AIRS-only with AIRS+AMSU retrievals. In this presentation, we demonstrate the visualization of the AIRS-only product and plots/statistics of comparison with AIRS+AMSU product using Giovanni.

AIRS↗

GEONEX Data Products: Geostationary Satellite Derived Land Surface and Atmospheric Public Data Products

The latest generation of geostationary satellites carry sensors such as the Advanced Baseline Imager (GOES-16/17) and the Advanced Himawari Imager (Himawari-8/9) that closely mimic the spatial and spectral characteristics of MODIS and VIIRS, useful for monitoring land surface conditions. The NASA Earth Exchange (NEX) team at Ames Research Center has embarked on a collaborative effort among scientists from NASA and NOAA exploring the feasibility of producing operational land surface products similar to those from MODIS/VIIRS. The team built a processing pipeline called GEONEX that is capable of converting raw geostationary data into routine products of Fires, surface reflectances, vegetation indices, LAI/FPAR, ET and GPP/NPP using algorithms adapted from both NASA/EOS and NOAA/GOES-R programs. The GEONEX pipeline will begin to produce provisional data products to be consumed by external collaborators and the academic community. In order to better inform and introduce the GEONEX products to the science community, the provisional products shall be distributed from the NAS data portal, located at data.nas.nasa.gov, and simple webpage at www.nasa.gov/geonex has been deployed, which describes any algorithms used in deriving the products, user manuals and data file information. We will also update the status of the data processing, on the website and provide links to the latest datasets, and use a geonex mailing list, using lists.nasa.gov.

Wang, Weile↗

Vertical Structure in Phytoplankton Growth and Productivity Inferred From Biogeochemical-Argo Floats and the Carbon-Based Productivity Model

Estimates of marine net primary production (NPP) commonly rely on limited in situ 14C incubations or satellite-based algorithms mainly constrained to the surface ocean. Here we combine data from biogeochemical Argo floats with a carbon-based productivity model (CbPM) to compute vertically-resolved estimates of NPP. Inferred NPP profiles derived by informing the CbPM with float-based, depth-resolved, bio-optical data are able to qualitatively reproduce the vertical structure in NPP inferred from in situ 14C incubations at various ocean regions. At station ALOHA, float-based estimates agree within uncertainty with productivity observations at depth, but underestimate surface NPP. We test the ability of the CbPM to infer the depth-resolved structure in NPP from bio-optical properties in the mixed layer, in similar fashion as how remote sensing algorithms of ocean productivity operate. In Southern Ocean waters, the depth-reconstructing implementation of the CbPM overestimates phytoplankton division rates and Chl:C below the mixed layer, resulting in artificially high subsurface NPP when compared with the fully float-informed implementation of the model. The CbPM subsurface extrapolation of phytoplankton Chl, Chl:C division rates, and NPP improves by accounting for deep nutrient (iron) stress impacts on photoacclimation in the Southern Ocean. This improvement is also observed in vertically- integrated NPP, where the mean bias between model implementations in depth-integrated productivity south of 30◦S is reduced by 62 % when account for deep iron limitation. Our results demonstrate that profiling data from biogeochemical Argo floats can serve to inform regional adjustments that lead to the improvement of marine productivity algorithms.

NPP↗

Side-reaction products identified for photo-nuclear production of 99 Mo

Production of 99 Mo by the 100 Mo (γ, n) 99 Mo reaction through the bremsstrahlung process using an electron accelerator is one of the feasible options currently pursued by several countries. In this work, we report experimental results on identification of side-reaction products after the irradiation of natural and enriched 100 Mo targets. Side-reaction products identified include various Mo, Nb and Zr isotopes. Comparison of experimentally determined reaction production rates with those determined based on theoretical cross-sections will be presented. Moreover, activation products formed due to presence of impurities introduced during the manufacturing of the Mo targets will also be discussed.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Production Pathways and Separation Procedures for High-Diagnostic-Value Activation Species, Fission Products, and Actinides Required for Preparation of Realistic Synthetic Post-Detonation Nuclear Debris: Status Report and FY16 Project Plan

The objective of this project is to provide a comprehensive study on the production routes and chemical separation requirements for activation products, fission products, and actinides required for the creation of realistic post-detonation surrogate debris. Isotopes that have been prioritized by debris diagnosticians will be examined for their ability to be produced at existing irradiation sources, production rates, and availability of target materials, and chemical separation procedures required to rapidly remove the products from the bulk target matrix for subsequent addition into synthetic debris samples. The characteristics and implications of the irradiation facilities on the isotopes of interest will be addressed in addition to a summary of the isotopes that are already regularly produced. This is a planning document only.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

GPM Data Products, Their Availability, and Production Status

On February 28, 2014, Japan Standard Time, the Global Precipitation Measurement (GPM) mission was launched in a picture-perfect launch activity. On March 4, 2014, the GPM Microwave Imager (GMI) was put into science observation mode. The Dual-Frequency Radar (DPR) was put in science observation mode on March 8, 2014. The Precipitation Processing System (PPS) produced products immediately upon receiving the data. Both regular science products and Near-realtime (NRT) products were produced. These were made immediately available to a group of early adopters. In mid-June 2014, GMI level-1 brightness temperature products were made publicly available. In mid-July 2014, GMI and partner-radiometer precipitation retrievals were made public. GMI public availability was several months ahead of the planned release. The DPR products became publicly available on the planned release date of September 2, 2014. Data continues to be available to any user desiring it.

Data Products↗

Effect of final state interactions on particle production in d+Au collisions at energies available at the BNL Relativistic Heavy Ion Collider

We show that particle species dependence of enhanced hadron production at intermediate transverse momentum (p{sub T}) for d+Au collisions at RHIC can be understood in terms of the hadronization from string fragmentation and the subsequent hadronic rescatterings in the final state. A multiphase transport model (AMPT) with two different hadronization mechanisms, string fragmentation or parton coalescence, is used in our study. When the hadrons are formed from string fragmentation, the subsequent hadronic rescatterings will result in particle mass dependence of the nuclear modification factor R{sub CP}, which is consistent with the present experimental data. On the other hand, in the framework of parton coalescence, the mass dependence disappears and the strangeness plays an important role in hadron production.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Synergistic Electrocatalytic Syngas Production from Carbon Dioxide by Bi‐Metallic Atomically Dispersed Catalysts

Abstract The production of syngas by traditional processes such as steam methane reforming is energetically intensive and produces a large amount of CO 2 emissions. In contrast, the electrochemical CO 2 reduction reaction (CO 2 RR) enables the carbon neutral production of syngas at ambient conditions. Among non‐precious metal catalysts, metal‐nitrogen‐carbon electrocatalysts are inexpensive and highly selective towards syngas production. This study examined the selectivity of mono‐ and bi‐metallic (M−N−C, M=Fe, Mo or FeMo) electrocatalysts towards syngas production. The ratio of the CO : H 2 in the syngas was tuned by modifying the ratio of the metallic precursors in the bi‐metallic FeMo−N−C catalysts, tailoring the catalysts’ selectivity towards the CO 2 RR or the hydrogen evolution reaction (HER). The catalyst synthesis temperature(s) were considered as they influence the catalyst morphology and activity. Further, the dependence of the ratio of CO : H 2 in the syngas as a function of the potential was explored for the different bi‐metallic catalysts. This work showed that by tailoring both the ratio of Fe : Mo in the bi‐metallic catalyst and optimizing the reductive potential, a CO : H 2 ratio between 0.25 to 5 was achievable. This study demonstrated a novel approach in which the ratio of the product syngas composition could be tailored in a single reaction, without the need for further downstream processing to reach a desired composition.

Delafontaine, Laurent↗

Measurements of the Higgs boson production and decay rates and constraints on its couplings from a combined ATLAS and CMS analysis of the LHC pp collision data at $ \sqrt{s}=7 $ and 8 TeV

Combined ATLAS and CMS measurements of the Higgs boson production and decay rates, as well as constraints on its couplings to vector bosons and fermions, are presented. The combination is based on the analysis of five production processes, namely gluon fusion, vector boson fusion, and associated production with a W or a Z boson or a pair of top quarks, and of the six decay modes H → ZZ, W W , γγ, ττ, bb, and μμ. All results are reported assuming a value of 125.09 GeV for the Higgs boson mass, the result of the combined measurement by the ATLAS and CMS experiments. The analysis uses the CERN LHC proton-proton collision data recorded by the ATLAS and CMS experiments in 2011 and 2012, corresponding to integrated luminosities per experiment of approximately 5 fb$^{−1}$ at $ \sqrt{s}=7 $ TeV and 20 fb$^{−1}$ at $ \sqrt{s}=8 $ TeV. The Higgs boson production and decay rates measured by the two experiments are combined within the context of three generic parameterisations: two based on cross sections and branching fractions, and one on ratios of coupling modifiers. Several interpretations of the measurements with more model-dependent parameterisations are also given. The combined signal yield relative to the Standard Model prediction is measured to be 1.09 ± 0.11. The combined measurements lead to observed significances for the vector boson fusion production process and for the H → ττ decay of 5.4 and 5.5 standard deviations, respectively. The data are consistent with the Standard Model predictions for all parameterisations considered.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Activation product analysis in a mixed sample containing both fission and neutron activation products

Activation analysis of gold (Au) is used to estimate neutron fluence resulting from a criticality event; however, such analyses are complicated by simultaneous production of other gamma-emitting fission products. Confidence in neutron fluence estimates can be increased by quantifying additional activation products such as platinum (Pt), tantalum (Ta), and tungsten (W). This work describes a radiochemical separation procedure for the determination of these activation products. Anion exchange chromatography is used to separate anionic forms of these metals in a nitric acid matrix; thiourea is used to isolate the Au and Pt fraction, followed by removal of the Ta fraction using hydrogen peroxide. W, which is not retained on the first anion exchange column, is transposed to an HCl/HF matrix to enhance retention on a second anion exchange column and finally eluted using HNO3/HF. Chemical separations result in a reduction in the minimum detectable activity by a factor of 287, 207, 141, and 471 for 182Ta, 187W, 197Pt, and 198Au respectively, with greater than 90% recovery for all elements. These results represent the highest recoveries and lowest minimum detectable activities for 182Ta, 187W, 197Pt, and 198Au from mixed fission-activation product samples to date, enabling considerable refinement in the measurement uncertainties for neutron fluences in highly complex sample matrices.

anion exchange↗

Muconic acid production from algae hydrolysate as a high-value co-product of an algae biorefinery

Muconic acid is an attractive bio-derived product because it can be easily converted to adipic acid, a high-value and high-volume monomer used in the production of nylon and other valuable consumer plastics. As such, production of muconic acid from algae hydrolysate was explored to expand the suite of products available from algal biomass. Here we have established initial performance parameters and have shown that the range of substrates present in algae hydrolysate that are consumed by Pseudomonas putida includes at least glucose, mannose, glycerol, acetic acid, and lactic acid. We achieved complete utilization of these major carbon sources found in Scenedesmus acutus hydrolysate with a maximum muconic acid productivity of 0.25 g/L h. Final titer was 13.0 g/L (27% molar process yield) at approximately 50 h. In addition, algae hydrolysate does not require any additional nutrients to achieve these performance metrics. Techno-economic analysis showed the potential to support up to 150 algal biorefineries at this yield with significant greenhouse gas reductions.

09 BIOMASS FUELS↗

Lipid production from non-sugar compounds in pretreated lignocellulose hydrolysates by Rhodococcus jostii RHA1

Valorization of all carbon sources from biorefinery wastes to biofuels and bioproducts is an attractive but challenging strategy to improve the carbon efficiency of the entire biorefinery process for economic competitiveness. Rhodococcus jostii RHA1 is considered as a promising candidate for conversion of non-sugar compounds in pretreated lignocellulose hydrolysate, which contain aromatic monomers, furans and acids derived from biomass. However, the insufficient understanding of the strain’s complex metabolism network limits its application. In this study, furans (furfural, 5-hydroxymethylfurfural), phenols (vanillin, vanillate), and organic acids (acetic acid), which mimic the complex components of the non-sugar compounds in pretreated biomass hydrolysate, were mixed with benzoate or used individually as carbon sources to investigate the growth and lipid accumulation of R. jostii RHA1. Fermentation kinetics, specific growth rates (h-1) and lipid yield (g(g) -1, g(mmol)-1), for each selected biomass-derived compound were compared for lipid production. The order of the specific growth rates (h-1) was benzoate > acetic acid > vanillate > vanillin. Higher consumption rate of benzoate than that of vanillate, as well as different lipid yield from them, suggested the preference of strain employing two branches of ß-ketoadipate pathway and plausibly distinct carbon routing to lipid biosynthesis. And acetic acid showed the lowest lipid yield (g(mmol)-1) indicating less carbon contributed to lipid production. The highest lipid content (0.46 g lipid/g CDW) was achieved using benzoate as a main carbon source in the presence of 5-hydroxymethylfurfural (5-HMF). The generated lipids predominantly contained C16:0 and C17:0 fatty acids. The concentration of furfural and 5-HMF in fermentation broth decreased individually or simultaneously with benzoate catabolism. NMR results revealed the oxidation of furfural and 5-HMF by R. jostii RHA1. This study provides new insights into the catabolism and metabolism of non-sugar compounds derived from biomass by Rhodococcus in terms of growth and lipid production, facilitating its application to 2nd generation biofuel production.

Li, Xiaolu↗

Modular Plasma Microreactor for Intensified Hydrogen Peroxide Production

Sustainable and decentralized manufacturing of hydrogen peroxide (H 2 O 2 ) has been extensively sought to replace the energy- and waste-intensive anthraquinone process. We introduce a helical biphasic microreactor in a coaxial dielectric barrier discharge (DBD) configuration as a modular, adaptable, and scalable intensified unit for H 2 O 2 production. Geometric and operating parameters such as electrode length, applied voltage, and gas and liquid flow rates can be tuned to regulate the residence time, delivered power, and gas–liquid interfacial area. In turn, these affect the key output parameters, i.e., H 2 O 2 concentration, production rate, and energy yield. We found a direct correlation between the H 2 O 2 production rate and the product of the interfacial area and residence time in the plasma region. We investigated the H 2 O 2 formation pathways using DMSO as an ·OH radical scavenger and found that H 2 O 2 forms by the dissolution of gaseous H 2 O 2 at low interfacial areas and is enhanced probably due to the interfacial recombination of ·OH radicals at a large gas–liquid interfacial area. The reactor temperature can also be externally controlled to intensify the production rate and energy yield of H 2 O 2 . Concentrations of up to 33 mM can be attained with a small footprint reactor that features a maximum energy yield of 4 g kWh –1 . Here, the plasma microreactor could epitomize a powerful process intensification tool for sustainable and distributed chemical manufacturing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydrocarbon liquid production via the bioCRACK process and catalytic hydroprocessing of the product oil

Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

09 BIOMASS FUELS↗