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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS2010

Detecting Thin Cirrus in Multiangle Imaging Spectroradiometer Aerosol Retrievals

Thin cirrus clouds (optical depth (OD) < 03) are often undetected by standard cloud masking in satellite aerosol retrieval algorithms. However, the Mu]tiangle Imaging Spectroradiometer (MISR) aerosol retrieval has the potential to discriminate between the scattering phase functions of cirrus and aerosols, thus separating these components. Theoretical tests show that MISR is sensitive to cirrus OD within Max{0.05 1 20%l, similar to MISR's sensitivity to aerosol OD, and MISR can distinguish between small and large crystals, even at low latitudes, where the range of scattering angles observed by MISR is smallest. Including just two cirrus components in the aerosol retrieval algorithm would capture typical MISR sensitivity to the natural range of cinus properties; in situations where cirrus is present but the retrieval comparison space lacks these components, the retrieval tends to underestimate OD. Generally, MISR can also distinguish between cirrus and common aerosol types when the proper cirrus and aerosol optical models are included in the retrieval comparison space and total column OD is >-0.2. However, in some cases, especially at low latitudes, cirrus can be mistaken for some combinations of dust and large nonabsorbing spherical aerosols, raising a caution about retrievals in dusty marine regions when cirrus is present. Comparisons of MISR with lidar and Aerosol Robotic Network show good agreement in a majority of the cases, but situations where cirrus clouds have optical depths >0.15 and are horizontally inhomogeneous on spatial scales shorter than 50 km pose difficulties for cirrus retrieval using the MISR standard aerosol algorithm..

Pierce, Jeffrey R.↗
NASA NTRS2014

James Webb Space Telescope Orbit Determination Analysis

The James Webb Space Telescope (JWST) is designed to study and answer fundamental astrophysical questions from an orbit about the Sun-Earth/Moon L2 libration point, 1.5 million km away from Earth. This paper describes the results of an orbit determination (OD) analysis of the JWST mission emphasizing the challenges specific to this mission in various mission phases. Three mid-course correction (MCC) maneuvers during launch and early orbit phase and transfer orbit phase are required for the spacecraft to reach L2. These three MCC maneuvers are MCC-1a at Launch+12 hours, MCC-1b at L+2.5 days and MCC-2 at L+30 days. Accurate OD solutions are needed to support MCC maneuver planning. A preliminary analysis shows that OD performance with the given assumptions is adequate to support MCC maneuver planning. During the nominal science operations phase, the mission requires better than 2 cm/sec velocity estimation performance to support stationkeeping maneuver planning. The major challenge to accurate JWST OD during the nominal science phase results from the unusually large solar radiation pressure force acting on the huge sunshield. Other challenges are stationkeeping maneuvers at 21-day intervals to keep JWST in orbit around L2, frequent attitude reorientations to align the JWST telescope with its targets and frequent maneuvers to unload momentum accumulated in the reaction wheels. Monte Carlo analysis shows that the proposed OD approach can produce solutions that meet the mission requirements.

Libration Point Orbit↗
NASA NTRS2019

Why Do Antarctic Ozone Recovery Trends Vary?

We use satellite ozone records and Global Modeling Initiative (GMI) chemistry transport model (CTM) simulations integrated with MERRA2 meteorology to identify a metric that accurately captures the trend in Antarctic ozone attributable to the decline in ozone depleting substances (ODSs). The GMI CTM Baseline simulation with realistically varying ODS levels closely matches observed interannual to decadal scale variations in Antarctic September ozone over the past 4 decades. The expected increase or recovery trend is obtained from the differences between the Baseline simulation and one with identical meteorology and fixed 1995 ODS levels. The differences show that vortex-averaged column O3 has the greatest sensitivity to ODS change from 1-20 Sep. The observed vortex-averaged column O3 during this period produces a trend consistent with the expected recovery attributable to ODS decline. Trends from dates after 20 Sep have smaller sensitivity to ODS decline and are more uncertain due to transport variability. Simulations show that the greatest decrease in O3 loss (i.e., recovery) occurs inside the vortex near the edge. The polar cap metrics have vortex size-dependent bias and do not consistently sample this region. Because the 60-90oS 220 DU O3 mass deficit (OMD) metric does not sample the edge region, its trend is lower than the expected trend; this is improved by area weighting. The 250 DU OMD metric samples more of the edge region, which increases its trend. Approximately 25% of the September Antarctic O3 increase is due to higher O3 levels in June prior to winter depletion.

Antarctic ozone↗
NASA NTRS2023

Cracking the Code: An Integrated Approach to Meeting Client Needs at NASA’s Langley Research Center

Organizational development (OD) is an interdisciplinary field that encourages the integration of many different concepts and theories in meeting client requirements. However, OD practitioners often maintain a significant amount of knowledge and lack specific guidance on how to combine concepts into a unified approach to drive change, thus making the selection and integration of disparate approaches challenging. To assist OD practitioners in navigating these challenges, a theory synthesizing approach is used to demonstrate the incremental insights that can be gained through the innovative integration of concepts, rather than being restricted to one perspective. More specifically, a novel Integrated Approach Decision-Making Tool is presented that offers specific steps to take to reach an effective, innovative solution. To further illustrate how this tool can be used in practice, an example is provided that details how this tool was used to achieve project success at NASA’s Langley Research Center through integrating three common OD models. Taken together, this paper will inform change agents operating in a similar capacity at any organization by providing a roadmap for how to meet client requirements and achieve increased project success through creating integrated, novel OD interventions.

Interdisciplinary↗
NASA NTRSDate not supplied

An Overview of Ground-Based Radar and Optical Measurements Utilized By the Nasa Orbital Debris Program Office

For over 30 years, the NASA Orbital Debris Program Office (ODPO) has led the characterization of orbital debris (OD) too small to be tracked by the U.S. Space Surveillance Network (SSN), yet which may pose the greatest threat to human spaceflight and robotic missions. Measurements from specialized sensors, including ground-based radars and telescopes capable of detecting smaller objects, provide the foundation for developing statistical models to describe the current state and future evolution of the OD environment from low Earth orbit (LEO) to geosynchronous Earth orbit (GEO). Since 1990, the ODPO has partnered with the U.S. Department of Defense and the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL) to collect data using the Haystack Ultrawideband Satellite Imaging Radar (HUSIR) – formerly Haystack – to characterize OD in LEO with a sensitivity of approximately 5 mm at 1000 km altitude. In addition, since 1993, the Goldstone Orbital Debris Radar, operated by NASA’s Jet Propulsion Laboratory, has provided data on OD as small as approximately 2-3 mm for altitudes below 1000 km, some of the most sensitive ground-based measurements achievable at these altitudes. Recently, collaborations with the 18 th Space Control Squadron of the U.S. Space Force have also provided the ODPO with special datasets from the Space Fence to extend coverage below the historical SSN limit of 10 cm and to characterize individual breakup events in LEO. For GEO altitudes, the Eugene Stansbery Meter Class Autonomous Telescope (ES-MCAT), a joint NASA-Air Force Research Laboratory project that reached full operational capability in 2021, collects data on debris smaller than 1 m and provides coverage of debris in historically under-sampled high-altitude orbital regimes. This paper summarizes the radar and optical sensors utilized by the ODPO, their unique capabilities, and recent datasets and applications for statistical sampling of the dynamic OD environment.

Alyssa Manis↗
NASA NTRS2023

Additive Manufacturing of Oxide Dispersion Strengthened Multi Principle Element Alloys for Future Aerospace Applications

Oxide Dispersion Strengthened (ODS) materials have long been of interest for their high temperature applications, and additive manufacturing enables their manufacturing viability. The ODS multi-principle element alloy NiCoCr was prepared using powder metallurgy techniques, additively manufactured, and evaluated for its processingmicrostructure-property relationships. The high temperature foundations of nickel-base superalloys and ODS materials were combined with the manufacturing advantages of 3D printing and the chemical simplicity of NiCoCr to inspire this work, which was divided into powder and printed material assessments. The project was achieved through multiple iterative project loops to assess the processing parameters’ impact on the microstructure and mechanical properties of the feedstock powder and printed material. The powder investigations (Chapter 3) focused on understanding the oxide coating that formed on the metal powder following acoustic mixing. Time of Flight Secondary Ion Mass Spectrometry was used to semi-quantitatively assess the amount of yttrium on the surface of the mixed powders, and indicated that a combination of higher mixing condition energy and moderate mixing time resulted in the most oxide coating on the NiCoCr powder. The results were supported by a qualitative assessment of scanning electron images of coated powder particles. Following mixing, the ODS NiCoCr was consolidated by Laser Powder Bed Fusion. The evaluations of the printed material (Chapter 4) frst considered screening experiments including Archimedes’ density, porosity, and grain size and number metrics from electron backscatter diffraction data. After the ideal additive manufacturing parameters were identifed, both the oxide homogeneity and yield strength were discussed for the idealized printed material. Overall, the project suggests that the combined use of qualitative or semi-quantitative powder surface analysis with Archimedes’ density analyses can be a valid high-throughput technique which can lead to process optimization of Laser Powder Bed Fusion additively manufactured ODS material.

Laura G Wilson↗
NASA NTRSDate not supplied

An Overview of Ground-Based Radar and Optical Measurements Utilized By the Nasa Orbital Debris Program Office

For over 30 years, the NASA Orbital Debris Program Office (ODPO) has led the characterization of orbital debris (OD) too small to be tracked by the U.S. Space Surveillance Network (SSN), yet which may pose the greatest threat to human spaceflight and robotic missions. Measurements from specialized sensors, including ground-based radars and telescopes capable of detecting smaller objects, provide the foundation for developing statistical models to describe the current state and future evolution of the OD environment from low Earth orbit (LEO) to geosynchronous Earth orbit (GEO). Since 1990, the ODPO has partnered with the U.S. Department of Defense and the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL) to collect data using the Haystack Ultrawideband Satellite Imaging Radar (HUSIR) – formerly Haystack – to characterize OD in LEO with a sensitivity of approximately 5 mm at 1000 km altitude. In addition, since 1993, the Goldstone Orbital Debris Radar, operated by NASA’s Jet Propulsion Laboratory, has provided data on OD as small as approximately 2-3 mm for altitudes below 1000 km, some of the most sensitive ground-based measurements achievable at these altitudes. Recently, collaborations with the 18 th Space Control Squadron of the U.S. Space Force have also provided the ODPO with special datasets from the Space Fence to extend coverage below the historical SSN limit of 10 cm and to characterize individual breakup events in LEO. For GEO altitudes, the Eugene Stansbery Meter Class Autonomous Telescope (ES-MCAT), a joint NASA-Air Force Research Laboratory project that reached full operational capability in 2021, collects data on debris smaller than 1 m and provides coverage of debris in historically under-sampled high-altitude orbital regimes. This paper summarizes the radar and optical sensors utilized by the ODPO, their unique capabilities, and recent datasets and applications for statistical sampling of the dynamic OD environment.

Alyssa Manis↗
DOE OSTI2016

Effect of Irradiation on Strengthening of a Model Fe-9Cr Oxide Dispersion Strengthened Alloy

The growing energy demand will increasingly call upon advanced nuclear reactors to supply safe and reliable energy worldwide. However, structural and cladding materials in these reactors will be subject to extreme conditions of up to a few hundred displacements per atom (dpa) at temperatures as high as 600 deg. C. Oxide dispersion strengthened (ODS) alloys are leading candidates for these components because their dispersion of Y-Ti-O nanoclusters provides high strength at elevated temperatures and dimensional stability under irradiation. But recent work has suggested that the oxides are unstable under irradiation, which has serious implications on mechanical performance. Thus, the objective of this work is to understand the change in strengthening mechanisms of an Fe-9Cr ODS alloy under irradiation. We use two approaches to assess strengthening of a proton-irradiated and neutron-irradiated Fe-9Cr ODS. First, nanoindentation directly measures changes in yield strength. Second, microstructure measurements are passed through models of two strengthening mechanisms. Results of these two approaches are compared to infer the strengthening mechanisms in the irradiated ODS alloy. A model Fe-9Cr ODS steel was irradiated to 3 dpa at 500 deg. C using either 2.0 MeV protons or a fast neutron spectrum. Both irradiation types induced the formation of dislocation loops and voids. Both proton and neutron irradiation resulted in dissolution of oxide nanoclusters, though neutron irradiation led to much more extensive oxide nano-cluster dissolution. The irradiated microstructure was used to predict irradiation hardening by considering both the precipitation strengthening and solid solution strengthening mechanisms. Due to more extensive oxide nano-cluster dissolution under neutron irradiation, the solid solution strengthening mechanism must be considered in order for the predicted change in yield strength to be comparable to that measured by nanoindentation. (authors)

36 MATERIALS SCIENCE↗
DOE OSTI2019

Microstructural investigation of an extruded austenitic oxide dispersion strengthened steel containing a carbon-containing process control agent

The adhesion of austenitic oxide dispersion strengthened (ODS) steel during mechanical alloying and a decreased powder production yield can be overcome by the addition of a process control agent: stearic acid. Here, the influence of stearic acid and the introduction of carbon in an extruded and annealed austenitic ODS steel was investigated. In particular the impact of carbon on the precipitate formation, the stability of particle and grain sizes during a heat treatment of 2 h at temperatures in a range between 500 and 1100 °C and the resulting grain size were investigated. No direct influence of carbon on the formation of precipitates was detected in the as-extruded condition. The orientation relationship of oxide nano-particles and the austenitic matrix was found to be size dependent. Also, a surprising growth of oxide precipitates was recorded, which starts at annealing temperatures as low as 700 °C. Precipitates in other steels do not show a growth in this temperature regime at all. For that reason, a possible link between the unexpected growth and the formation of carbides was investigated. M 7 C 3 and M 23 C 6 carbides were found in every sample condition and we were able to show that their amount follows a trend suggested by thermodynamic simulations. The grain size of the extruded austenitic ODS steel was examined and a grain refinement was found after a heat treatment of 2 h at 700 °C or higher was performed. That is caused by the inhabitation of further grain growth after nucleation as part of the recrystallization process has happened. The dragging force exerted by precipitates is strong enough to pin grain boundaries. Furthermore, no direct impact of carbon on the oxide precipitate growth was found, an indirect impact of carbon on the growth of ODS precipitates is supposed but requires long-term annealing studies to be verified.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Elucidating structure and dynamics of crystalline α-zirconium phosphates intercalated with water and methanol by multinuclear solid-state MAS NMR: A comprehensive NMR approach

Solid-state NMR experiments on 2 H, 31 P, 13 C, and 1 H nuclei, including 31 P T 1 , 1 H T 1 , and 1 H T 1ρ measurements, as well as on the kinetics of proton-phosphorus cross-polarization have been performed to characterize the crystalline and amorphous α-zirconium phosphates, which were intercalated with D 2 O and/or CD 3 OD. The 13 C{ 1 H} CP MAS NMR experiment performed for compound 1-CD 3 OD (Zr (HPO 4 ) 2 .0.2CD 3 OD) with carbon cross-polarization via protons of phosphate groups has provided a prove that the methanol was intercalated into the interlayer spaces of this compound. The variable-temperature 2 H solid-echo MAS NMR spectra of intercalated compounds demonstrated that the methanol molecules, in contrast to the mobile water, were immobile, keeping, however, free CD 3 rotations around the C 3 -axis. It has been demonstrated that the intercalated species, D 2 O and CD 3 OD, do not affect the high-frequency motions of the phosphate groups. By utilizing local structural models that satisfy the constraints of the experimental data, it has been suggested that the immobile methanol molecules are located in the cavity between two neighboring layers of the zirconium phosphates. Here, the present work illustrates the reliable criteria in a comprehensive NMR approach to structural and dynamic studies of such systems.

1H↗
DOE OSTI2019

Mechanical Alloying and Powder Forging of 18%Cr Oxide Dispersion-Strengthened Steel Produced Using Elemental Powders

Oxide dispersion-strengthened (ODS) ferritic steels are potential materials for cladding tubes in fast breeder fission reactors. These are mostly prepared by mechanical alloying of yttria powder with pre-alloyed powders. Using elemental powders offers flexibility in the choice of alloy compositions. Here we report mechanical alloying of Fe-18Cr-2W-0.2Ti-0.35Y{sub 2}O{sub 3} (compositions in wt.%) ODS steel using elemental powders of Fe, Cr, W and Ti with yttria powder. After 5 h of milling, no significant changes in particle size and crystallite size were observed. Powders milled for 5 and 7 h were consolidated through powder forging route. The optimum milling time for mechanical alloying could be determined only after evaluating the forgings. It is difficult to achieve recrystallization in ODS alloys. The forging process parameters were optimized to achieve a dense alloy with a fine recrystallized microstructure. Factors leading to recrystallization are discussed. It is shown that recrystallization in ODS steels is more likely to occur during forging as compared to extrusion/rolling. The powder forging route offers several advantages over the conventional extrusion or HIP routes.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Stress relaxation behavior of nanocluster-strengthened ferritic alloy at high temperatures

Stress relaxation behavior was investigated for the nanoclusters/dispersoids-strengthened steels including the nanostructured ferritic alloy 14YWT (SM10), oxide-dispersion strengthened (ODS) Eurofer97, and commercial ODS steel PM2000. The stress relaxation tests were carried out at high temperatures ranging from 600 to 1000 degrees C. Overall, the relaxation rates of 14YWT and ODS-Eurofer97 were lower than that of PM2000. To analyze the strain rate sensitivity of the alloys, the load drop-time curves were converted to the stress-strain rate curves. In the log-log plots of these curves, no significant change in slope was observed in the strain rate range of 2 x 10(-5)-1 x 10(-3)s(-1). At 600 degrees C, 14YWT and ODS-Eurofer97 have similar activation values of similar to 50b(3) while PM2000 has similar to 100b(3). Above 700 degrees C, the differences of the activation energy among alloys become more noticeable with increasing temperature. The activation energies of the three alloys were derived and compared. The rate-controlling mechanisms in the stress relaxation of the three nanoclusters/dispersoids-hardened alloys include dislocation glide and climb, and further study is necessary to clarify detailed contributing mechanisms.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Characterisation of a complex thin walled structure fabricated by selective laser melting using a ferritic oxide dispersion strengthened steel

Oxide dispersion strengthened (ODS) alloys exhibit superior mechanical and physical properties due to the presence of nanoscopic Y(Al, Ti) oxide precipitates, but their manufacturing process is complex. The present study is aimed at further investigation of the application of an alternative, Additive Manufacturing (AM) technique, Selective Laser Melting (SLM), to the production of consolidated ODS alloy components. Mechanically alloyed PM2000 (ODS-FeCrAl) powders have been consolidated and a fine dispersion of Y-containing precipitates were observed in an as built thin-walled component, but these particles were typically poly-crystalline and contained a variety of elements including O, Al, Ti, Cr and Fe. Application of post-build heat treatments resulted in the modification of particle structures and compositions; in the annealed condition most precipitates were transformed to single crystal yttrium aluminium oxides. During the annealing treatment, precipitate distributions homogenised and localised variations in number density were diminished. The resulting volume fractions of those precipitates were 25–40% lower than have been reported in conventionally processed PM2000, which was attributed to Y-rich slag-like surface features and inclusions formed during SLM. - Highlights: • A wall structure was grown from ODS steel powder using selective laser melting. • A fine dispersion of nano-precipitates was apparent in as-build material. • Precipitates were multi-phased containing several elements, e.g. O, Ti, Al, Fe, Cr, Y. • Post-build annealing changed those into typically single-crystalline Y–Al–O. • The anneal also reduced and stabilised the volume fraction of precipitates to ~ 0.006.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Characterization of martensite-austenite constituents and micro-hardness in intercritical reheated and coarse-grained heat affected zones of API X70 HSLA steel

Highlights: • The influence of cold wire addition to the tandem submerged arc welding process on the ICRCGHAZ is investigated. • Comprehensive characterization of the microstructure and micro-hardness in the ICRCGHAZ of a HSLA steel is performed. • A lower fraction of finely distributed M-A formed in the ICRCGHAZ of TSAW + cold wire steel, leading to lower micro-hardness. • The aspect ratio and inter-particle spacing of M-A constituents decreased in the ICRCGHAZ through cold wire addition. - Abstract: The thermal cycles that high strength low alloy (HSLA) low carbon steels experience during welding inevitably affect the microstructure and mechanical properties of the weld joints. It is generally agreed that the coarse-grained heat affected zone (CGHAZ) and the intercritical reheated coarse-grained heat affected zone (ICRCGHAZ) in one-pass and multi-pass welding, respectively, have the poorest microstructure and mechanical properties relative to the rest of the steel joint. The martensite-austenite (M-A) constituents formed in the HAZ regions predominantly govern property deterioration in the CGHAZ and the ICRCGHAZ by promoting the initiation and propagation of micro-cracks. However, the characteristics of the M-A constituents, i.e., fraction, size, shape and aspect ratio, are strongly affected by the welding heat input. Accordingly, in this study, the aim was to evaluate the influence of a cold wire addition in conventional tandem submerged arc welding (TSAW + cold-wire) on the microstructure and micro-hardness in the CGHAZ and ICRCGHAZ. Microstructural characterization showed that a lower fraction of finely distributed M-A constituents associated with smaller prior austenite grains (PAGs) formed in the CGHAZ of the steel welded by the TSAW + cold-wire process (CW-OD weld) relative to that welded by the conventional TSAW process (TW-OD weld). Furthermore, the fraction of M-A constituents in the ICRCGHAZ of the CW-OD weld was decreased. A higher fraction of slender shaped M-A constituents in the ICRCGHAZ of the TW-OD weld resulted in an increase in the micro-hardness. The microstructure and micro-hardness changes associated with cold wire addition were attributed to the lower welding heat input and, consequently, the faster cooling rate with a corresponding reduction in the retention time in the austenitic region and ferrite/austenite region in the CGHAZ and ICRCGHAZ regions, respectively.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Effect of processor temperature on film dosimetry

Optical density (OD) of a radiographic film plays an important role in radiation dosimetry, which depends on various parameters, including beam energy, depth, field size, film batch, dose, dose rate, air film interface, postexposure processing time, and temperature of the processor. Most of these parameters have been studied for Kodak XV and extended dose range (EDR) films used in radiation oncology. There is very limited information on processor temperature, which is investigated in this study. Multiple XV and EDR films were exposed in the reference condition (d{sub max.}, 10 Multiplication-Sign 10 cm{sup 2}, 100 cm) to a given dose. An automatic film processor (X-Omat 5000) was used for processing films. The temperature of the processor was adjusted manually with increasing temperature. At each temperature, a set of films was processed to evaluate OD at a given dose. For both films, OD is a linear function of processor temperature in the range of 29.4-40.6 Degree-Sign C (85-105 Degree-Sign F) for various dose ranges. The changes in processor temperature are directly related to the dose by a quadratic function. A simple linear equation is provided for the changes in OD vs. processor temperature, which could be used for correcting dose in radiation dosimetry when film is used.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2022

Optimizing lane reversals in transportation networks to reduce traffic congestion: A global optimization approach

This paper studies how to reduce the overall travel time of commuters in a transportation network by reversing the direction of some lanes in the network using a macroscopic network-wide perspective. Similar to the Network Design Problem, the lane reversal problem has been shown to be NP-hard given the dependence of the users’ route selection on the lane direction decision. Herein, we propose and compare three efficient methods to solve the routing and lane reversal problem jointly. First, we introduce an alternating method that decouples the routing and lane assignment problems. Second, we propose a Frank–Wolfe method that jointly takes gradient steps to adjust both the lane assignment and routing decisions. Third, we propose a convex approximation method that uses a threshold-based approach to convexify the joint routing and lane reversal objective. The convex approximation method is advantageous since it finds a global optimum solution for the approximated problem and it enables the possibility to include linear constraints. Using this method, we extend the main formulation to be able to limit a maximum number of reversed lanes, as well as to incorporate multiple origin–destination (OD) patterns. We test the proposed methods in a case study using the transportation network of Eastern Massachusetts where our results indicate an overall reduction in travel times of 4.7% by selecting the best 15 reversals. Moreover, using a small test network, we investigate the performance of the lane reversal strategies as a function of the OD demand symmetry. As expected, we observe that when the OD demand is very asymmetric (e.g., for a single OD pair, evacuations, large events), the reduction in travel times is larger than the symmetric case, reaching travel time reductions of 60%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2017

Nature and Distribution of Stable Subsurface Oxygen in Copper Electrodes During Electrochemical CO 2 Reduction

Oxide-derived copper (OD-Cu) electrodes exhibit higher activity than pristine copper during the carbon dioxide reduction reaction (CO 2 RR) and higher selectivity toward ethylene. The presence of residual subsurface oxygen in OD-Cu has been proposed to be responsible for such improvements, although its stability under the reductive CO 2 RR conditions remains unclear. This work sheds light on the nature and stability of subsurface oxygen. Our spectroscopic results show that oxygen is primarily concentrated in an amorphous 1–2 nm thick layer within the Cu subsurface, confirming that subsurface oxygen is stable during CO 2 RR for up to 1 h at –1.15 V vs RHE. Besides, it is associated with a high density of defects in the OD-Cu structure. In conclusion, we propose that both low coordination of the amorphous OD-Cu surface and the presence of subsurface oxygen that withdraws charge from the copper sp- and d-bands might selectively enhance the binding energy of CO.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗