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Reversible Single Spin Control of Individual Magnetic Molecule by Hydrogen Atom Adsorption
The reversible control of a single spin of an atom or a molecule is of great interest in Kondo physics and a potential application in spin based electronics. Here we demonstrate that the Kondo resonance of manganese phthalocyanine molecules on a Au(111) substrate have been reversibly switched off and on via a robust route through attachment and detachment of single hydrogen atom to the magnetic core of the molecule. As further revealed by density functional theory calculations, even though the total number of electrons of the Mn ion remains almost the same in the process, gaining one single hydrogen atom leads to redistribution of charges within 3d orbitals with a reduction of the molecular spin state from S 5 3/2 to S 5 1 that directly contributes to the Kondo resonance disappearance. This process is reversed by a local voltage pulse or thermal annealing to desorb the hydrogen atom.
Low frequency electric and magnetic fields
Following preliminary investigations of the low frequency electric and magnetic fields that may exists in the Earth-ionospheric cavity, measurements were taken with state-of-the art spectrum analyzers. As a follow up to this activity, an investigation was initiated to determine sources and values for possible low frequency signal that would appear in the cavity. The lowest cavity resonance is estimated at about 8 Hz, but lower frequencies may be an important component of our electromagnetic environment. The potential field frequencies produced by the electron were investigated by a classical model that included possible cross coupling of the electric and gravitation fields. During this work, an interesting relationship was found that related the high frequency charge field with the extremely low frequency of the gravitation field. The results of numerical calculations were surprisingly accurate and this area of investigation is continuing. The work toward continued development of a standardized monitoring facility is continuing with the potential of installing the prototype at West Virginia State College early in 1990. This installation would be capable of real time monitoring of ELF signals in the Earth-ionoshpere cavity and would provide some directional information. A high gain, low noise, 1/f frequency corrected preamplifier was designed and tested for the ferrite core magnetic sensor. The potential application of a super conducting sensor for the ELF magnetic field detection is under investigation. It is hoped that a fully operational monitoring network could pinpoint the location of ELF signal sources and provide new information on where these signals originate and what causes them, assuming that they are natural in origin.
Gravity, Topography, and Magnetic Field of Mercury from Messenger
On 18 March 2011, the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft was inserted into a 12-hour, near-polar orbit around Mercury, with an initial periapsis altitude of 200 km, initial periapse latitude of 60 deg N, and apoapsis at approximately 15,200 km altitude in the southern hemisphere. This orbit has permitted the mapping of regional gravitational structure in the northern hemisphere, and laser altimetry from the MESSENGER spacecraft has yielded a geodetically controlled elevation model for the same hemisphere. The shape of a planet combined with gravity provides fundamental information regarding its internal structure and geologic and thermal evolution. Elevations in the northern hemisphere exhibit a unimodal distribution with a dynamic range of 9.63 km, less than that of the Moon (19.9 km), but consistent with Mercury's higher surface gravitational acceleration. After one Earth-year in orbit, refined models of gravity and topography have revealed several large positive gravity anomalies that coincide with major impact basins. These candidate mascons have anomalies that exceed 100 mGal and indicate substantial crustal thinning and superisostatic uplift of underlying mantle. An additional uncompensated 1000-km-diameter gravity and topographic high at 68 deg N, 33 deg E lies within Mercury's northern volcanic plains. Mercury's northern hemisphere crust is generally thicker at low latitudes than in the polar region. The low-degree gravity field, combined with planetary spin parameters, yields the moment of inertia C/MR2 = 0.353 +/- 0.017, where M=3.30 x 10(exp 23) kg and R=2440 km are Mercury's mass and radius, and a ratio of the moment of inertia of Mercury's solid outer shell to that of the planet of Cm/C = 0.452 +/- 0.035. One proposed model for Mercury's radial density distribution consistent with these results includes silicate crust and mantle layers overlying a dense solid (possibly Fe-S) layer, a liquid Fe-rich outer core of radius 2030 +/- 37 km, and an assumed solid inner core. Magnetic field measurements indicate a northward offset of Mercury's axial magnetic dipole from the geographic equator by 479 +/-3 km and provide evidence for a regional-scale magnetic field approximately collocated with the northern volcanic plains of possible crustal origin. These results from MESSENGER indicate a complex and asymmetric evolution of internal structure and dynamics in this end-member inner planet.
Collapse and fragmentation of magnetic molecular cloud cores with the Enzo AMR MHD code. II. Prolate and oblate cores
We present the results of a large suite of three-dimensional models of the collapse of magnetic molecular cloud cores using the adaptive mesh refinement code Enzo2.2 in the ideal magnetohydrodynamics approximation. The cloud cores are initially either prolate or oblate, centrally condensed clouds with masses of 1.73 or 2.73 M {sub ☉}, respectively. The radial density profiles are Gaussian, with central densities 20 times higher than boundary densities. A barotropic equation of state is used to represent the transition from low density isothermal phases, to high density optically thick phases. The initial magnetic field strength ranges from 6.3 to 100 μG, corresponding to clouds that are strongly to marginally supercritical, respectively, in terms of the mass to magnetic flux ratio. The magnetic field is initially uniform and aligned with the clouds' rotation axes, with initial ratios of rotational to gravitational energy ranging from 10{sup –4} to 0.1. Two significantly different outcomes for collapse result: (1) formation of single protostars with spiral arms, and (2) fragmentation into multiple protostar systems. The transition between these two outcomes depends primarily on the initial magnetic field strength, with fragmentation occurring for mass to flux ratios greater than about 14 times the critical ratio for prolate clouds. Oblate clouds typically fragment into several times more clumps than prolate clouds. Multiple, rather than binary, system formation is the general rule in either case, suggesting that binary stars are primarily the result of the orbital dissolution of multiple protostar systems.
Micromagnetic model analysis of integrated single-pole-type head with tilted spin-torque oscillator for high-frequency microwave-assisted magnetic recording
The spin-torque oscillator (STO) is the most important component in microwave-assisted magnetic recording. Some requirements for the STO are: large amplitude and stable oscillation, small injected current, and oscillation at a frequency that excites resonance in a recording medium. It is also necessary for the STO oscillation to closely follow the head coil current. In this paper, STOs were integrated into write heads and micromagnetic analyses carried out to obtain a write head structure with stable STO oscillation that could follow a high-frequency head coil current.
Core inductive electric field during sawtooth crashes on DIII-D
Sawtooth crashes on tokamak plasmas exhibit relaxation much faster than resistive time scales via a mechanism not fully understood. Using core magnetic measurements from the Radial Interferometer-Polarimeter (RIP) diagnostic on the DIII-D tokamak, Grad–Shafranov equilibria constrained by internal magnetic measurements that have high time resolution (<1μs) can be computed, allowing analysis of how equilibrium parameters such as safety factor q, current density J, and parallel electric field E ∥ , particularly on-axis, evolve. At the sawtooth crash, on-axis safety factor q 0 is observed to rise by 5% but remain below 1 throughout the cycle, and on-axis current density J 0 is observed to drop by 5%. On-axis parallel electric field E ∥ (0) is found to be balanced by ηJ 0 (resistivity times on-axis current density) except during the 200 µs crash period, where E ∥ (0) reaches 22 V m –1 , exceeding ηJ 0 by a factor of more than 2000. These first measurements in tokamak plasmas verify that generalized Ohm's law is not balanced during the crash by resistive effects alone; this is a finding expected due to the relaxation being much faster than resistive timescales. As a result, measurement of the electric field during the tokamak sawtooth serves to illuminate the physical mechanisms at work.
Validation of the 'full reconnection model' of the sawtooth instability in KSTAR
In this paper, the central safety factor (q 0 ) during sawtooth oscillation has been measured with a great accuracy with the motional Stark effect (MSE) system on KSTAR and the measured value was However, this measurement alone cannot validate the disputed full and partial reconnection models definitively due to non-trivial off-set error (~0.05). Supplemental experiment of the excited m = 2, m = 3 modes that are extremely sensitive to the background q 0 and core magnetic shear definitively validates the 'full reconnection model'. The radial position of the excited modes right after the crash and time evolution into the 1/1 kink mode before the crash in a sawtoothing plasma suggests that in the MHD quiescent period after the crash and before the crash. Finally, additional measurement of the long lived m = 3, m = 5 modes in a non-sawtoothing discharge (presumably ) further validates the 'full reconnection model'.
Design and Optimization of High-frequency Transformer for Isolated Single-Stage Three-Phase AC/DC Converter using Bidirectional Switches
This paper presents the design and optimization of the high-frequency transformer for an isolated single-stage threephase AC/DC converter enabled by the 4H-SiC BiDirectional Field Effect Transistor (BiDFET). Non-dominated Sorting Genetic Algorithm II (NSGA-II) is used to perform a multiobjective optimization to minimize loss, weight, and volume. A 20 kW, 50 kHz hardware prototype based on the selected optimal point is characterized by a power amplifier. The finite element analysis simulation results are also presented to validate the core magnetic flux density and winding electric field strength. The experimental prototype was tested at 800 Vdc/480 Vrms at 10 kW rated power.
Thermal Analysis of Wireless Power Transfer Coils for Dynamic Wireless Electric Vehicle Charging
In this paper, safe operating conditions of a wireless power transfer coil were identified and road infrastructure for a dynamic wireless electric vehicle charging system was studied. Magneto-thermal simulations were used to map the power loss directly into the computed fluid dynamics solver. This method allowed the authors to analyze the heating pattern of the enclosed wireless power transfer coil in the road structure, as well as for the vehicle coil. Thermal heating patterns for three types of rectangular coil structures were analyzed. Heating patterns were analyzed for 200 kW coils and different magnetic field densities in the magnetic core.
Applications of Solid-State Transformers for Electric Power Grid HEMP/GMD Resilience
A high-altitude electromagnetic pulse (HEMP) or geomagnetic disturbance (GMD) can disrupt power grids by inducing low-frequency common-mode (CM) currents. When these currents flow through grounded transformers, they can bias the magnetic core, driving it into saturation and reducing performance or damaging equipment. This work presents a solid-state transformer (SST) to replace vulnerable assets and improve grid resilience. The paper reviews half-cycle saturation in conventional transformers, then describes an SST architecture that neutralizes and redirects CM currents during HEMP/GMD events. A prototype SST is built and validated, demonstrating stable CM-disturbance operation and protection of nearby transformers. Finally, large-scale simulations show how coordinated SST deployment mitigates CM disturbances and strengthens overall grid resilience.
Phasing Magnet for CSX-2 Beamline at NSLS-II
A phasing magnet has been developed at National Synchrotron Light Source II (NSLS-II) for the Coherent Soft X-ray Scattering (CSX) beamline. The phasing magnet will be located at the center of the straight section in between two identical and independent variably polarized APPLE-II devices. Based on Permanent Magnet technology, the phasing magnet has been designed to achieve the required electron beam delay to properly adjust the phase matching of these two consecutive EPUs (Elliptically Polarizing Undulators) and ensure a positive interference between the photon beam emitted in each device. Also this paper will describe the mechanical and magnetic design together with the final field measurements and magnetic tuning results. Also, the spectral performance of the two EPUs and the method used to properly set the field strength of the phasing magnet for any given radiation wavelength and polarization mode will be presented as well.
Novel Electrically Tunable Microwave Solenoid Inductor and Compact Phase Shifter Utilizing Permaloy and PZT Thin Films
A Permalloy (Py) thin film enabled tunable 3-D solenoid inductor is designed and fabricated. The special configuration of magnetic core is discussed and by selectively patterning Py thin film, the proposed tunable inductor can work at frequency up to several GHz range. The inductance of the solenoid inductor can be electrically tuned by dc current and the tunability is above 10%. Utilizing the implemented Py enabled tunable solenoid inductor and Lead Zirconate Titanate (PZT) thin film enabled metal-insulator-metal (MIM) capacitor, a compact fully electrically tunable lumped elements phase shifter is achieved. The tunable phase shifter has both inductive and capacitive tunability and the dual tunability significantly improves the tuning range and design flexibility. Moreover, the dual tunability is able to retain the equivalent characteristic impedance of the device in the process of the phase being tuned. Here, the phase of the device can be tuned by fully electrical methods and when dc current and dc voltage are provided, the length normalized phase tunability is up to 210°/cm
Design and Optimization of a 200-kW Medium-Frequency Transformer for Medium-Voltage SiC PV Inverters
This paper presents a design and optimization methodology for a 200-kW medium-frequency transformer (MFT) based on low-loss magnetic core (FINEMET FT-3TL). The proposed optimal design methodology consists of predesign, preliminary design, and optimal design. In the preliminary design, the parallel-concentric winding structure is selected to increase the current carrying capability and reduce the leakage inductance. Based on the parallel-concentric winding concept, a novel cooing and insulation structure with 3-D printed bobbins are proposed. The optimal designed MFT prototype achieves a power density higher than 19.23 kW/L. The electrical insulation system is tested at 12 kV ac peak voltage. In addition, the partial discharge (PD) test is conducted at 7.5 kV ac peak voltage to ensure the PD-free design. The high-frequency bipolar pulsewidth modulation voltage insulation (PD) test is the first time applied in MFT design and test process. Finally, the transformer is applied in a dual-active-bridge (DAB) converter with 200 kW rated power. The peak efficiency of the DAB converter is 99.53%, and the efficiency at 200 kW is 98.85%. The peak efficiency of MFT is 99.844%, and the efficiency at 200 kW is 99.842%.
Finite element modeling of nanoscale-enabled microinductors for power electronics
Here, this paper focuses on the finite element modeling of toroidal microinductors, employing first-of-its-kind nanocomposite magnetic core material and superparamagnetic iron nanoparticles covalently cross-linked in an epoxy network. Energy loss mechanisms in existing inductor core materials are covered as well as discussions on how this novel core material eliminates them providing a path toward realizing these low form factor devices. Designs for both a 2 μH output and a 500 nH input microinductor are created via the model for a high-performance buck converter. Both modeled inductors have 50 wire turns, less than 1 cm 3 form factors, less than 1 Ω AC resistance, and quality factors, Q’s, of 27 at 1 MHz. In addition, the output microinductor is calculated to have an average output power of 7 W and a power density of 3.9 kW/in 3 by modeling with the 1st generation iron nanocomposite core material.
Tapless Voltage Regulating Transformer. Final Report
Voltage regulation is a common practice in power grid operation. The conventional voltage regulation methods have been facing ever increasing challenges as the penetration of renewable generations deepens in the grid. The intermittent nature of the renewable sources may result in sudden rise or drop of power generation, possibly breaking the generation-load balance. A lack of adequate voltage control not only affects the power quality but is detrimental to the system operation with the potential for large economic losses. Most conventional voltage regulation devices rely on mechanical tap changers to impose the regulation in a step-wise manner. Although sufficient for normal operations, the mechanical tap changers can be easily worn out in the challenging situations created by renewables. In this project, a novel technology called tapless voltage regulating transformer (TAREX) was proposed and investigated. It has the potential to excel at addressing the new voltage regulation challenges and replace the conventional regulating transformers. TAREX is based on the concept of the saturable-core reactor (SCR). The voltage of a TAREX can be smoothly and continuously regulated in a reasonable range by using a low rating power electronics based controller. It uses control of the transformer core magnetization to regulate the voltage on the windings, and thus eliminates the mechanical tap changer. This project is to prove the principle of TAREX, understand the voltage regulation mechanism, and preliminarily understand its impacts on the power systems through modeling, prototyping, and testing.
Surface Oxidation Behavior of FeNi-based Metal Amorphous Nanocomposite (MANC) Alloys for High-Speed Motor Applications
New interest in high performance soft magnetic materials (SMMs) have been fueled by the need to lower losses at higher operating frequencies while maintaining high flux density and tunable permeability in electrical motors, transformer, and generator applications. Conventional SMMs like electrical steels and Fe-based metal amorphous nanocomposite (MANC) alloys are dominated by eddy current losses at high frequencies. Recent breakthrough in high-performance FeNi MANC have shown promise in reducing eddy current losses as compared to electrical steels. Their intrinsic adherent native surface oxide layer provides sufficient electrical insulation to reduce interlaminate eddy current losses. However, notwithstanding advances in MANCs, there exists a gap in literature on investigations of the surface oxide layer responsible for significant reduction of interlaminate eddy current losses in magnetic cores. This work presents a detailed characterization of the surface oxide, oxidation behavior, and relationship between oxide thickness and resistivity of a new FeNi MANC alloy (Fe70Ni30)80Nb4B14Si2.
Rapid-cycling HTS magnet for muon acceleration
A very wide range of operational temperatures of the HTS (YBCO) superconductor makes it suitable for the construction of rapid-cycling magnets required for the muon acceleration. The measured [3] very low power loss of the 0.4 T magnet operating at 300 T/s suggested a realistic possibility of the HTS-based accelerator magnet with much higher magnetic field and ramp rate. The magnet core and the HTS cable designs for the 2 T field in the 30 mm beam gap are presented. The simulation of the HTS cable hysteresis power loss for the 1000 T/s ramp rate is discussed in terms of the operational temperatures and required cryogenic power.