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At least 253 records · Page 14

Reaction dynamics of H + O2 at 1.6 eV collision energy

The hot hydrogen atom reaction, H + O2 yields OH + O, has been studied at a center of mass collision energy of 1.6 eV. H atoms were generated by 266 nm photolysis of HI in a mixture of HI and O2 at 293 K. The OH product was probed by laser induced fluorescence and the nascent OH vibrational, rotational, and fine structure distributions were determined. The OH(v=0)/OH(v=1) vibrational branching ratio was measured to be 1.72 + or - 0.09. The data suggest that the H + O2 reaction at this collision energy proceeds via two competing mechanisms: reaction involving a long-lived complex and direct reaction.

Bronikowski, Michael J.↗

Betavoltaics Of Increased Power

Batteries of newly developed betavoltaic cells proposed as long-lived sources of power of order of watts. High-power betavoltaic cell resembles solar photo voltaic cell, except it includes layer of beta-emitting material. Betavoltaic battery cells are stacked as in chemical battery, and surrounded by material containing beta rays. Intended for use aboard spacecraft, batteries also used in surgically implanted devices requiring high power.

Pool, Frederick S.↗

Probing the tides in interacting galaxy pairs

Detailed spectroscopic and imaging observations of colliding elliptical galaxies revealed unmistakable diagnostic signatures of the tidal interactions. It is possible to compare both the distorted luminosity distributions and the disturbed internal rotation profiles with numerical simulations in order to model the strength of the tidal gravitational field acting within a given pair of galaxies. Using the best-fit numerical model, one can then measure directly the mass of a specific interacting binary system. This technique applies to individual pairs and therefore complements the classical methods of measuring the masses of galaxy pairs in well-defined statistical samples. The 'personalized' modeling of galaxy pairs also permits the derivation of each binary's orbit, spatial orientation, and interaction timescale. Similarly, one can probe the tides in less-detailed observations of disturbed galaxies in order to estimate some of the physical parameters for larger samples of interacting galaxy pairs. These parameters are useful inputs to the more universal problems of (1) the galaxy merger rate, (2) the strength and duration of the driving forces behind tidally stimulated phenomena (e.g., starbursts and maybe quasi steller objects), and (3) the identification of long-lived signatures of interaction/merger events.

Borne, Kirk D.↗

The transition of ground-based space environmental effects testing to the space environment

The goal of the space flight program at the Center for Commercial Development of Space (CCDS)--Materials for Space Structures is to provide environmentally stable structural materials to support the continued humanization and commercialization of the space frontier. Information on environmental stability will be obtained through space exposure, evaluation, documentation, and subsequent return to the supplier of the candidate material for internal investigation. This program provides engineering and scientific service to space systems development firms and also exposes CCDS development candidate materials to space environments representative of in-flight conditions. The maintenance of a technological edge in space for NASA suggests the immediate search for space materials that maintain their structural integrity and remain environmentally stable. The materials being considered for long-lived space structures are complex, high strength/weight ratio composites. In order for these new candidate materials to qualify for use in space structures, they must undergo strenuous testing to determine their reliability and stability when subjected to the space environment. Ultraviolet radiation, atomic oxygen, debris/micrometeoroids, charged particles radiation, and thermal fatigue all influence the design of space structural materials. The investigation of these environmental interactions is the key purpose of this center. Some of the topics discussed with respect to the above information include: the Space Transportation System, mission planning, spaceborne experiments, and space flight payloads.

Zaat, Stephen V.↗

Proposed reference models for nitrous oxide and methane in the middle atmosphere

Data from the Stratospheric and Mesospheric Sounder (SAMS) on the Nimbus 7 satellite, for the period from Jan. 1979 - Dec. 1981, are used to prepare a reference model for the long-lived trace gases, methane and nitrous oxide, in the stratosphere. The model is presented in tabular form on seventeen pressure surfaces from 20 to 0.1 mb, in 10 degree latitude bins from 50S to 70N, and for each month of the year. The means by which the data quality and interannual variability, and some of the more interesting globally and seasonally variable features of the data are discussed briefly.

Taylor, F. W.↗

Spatial distribution of visible lightning on Jupiter

An analysis of Voyager images of Jupiter is used to evaluate the horizontal spatial distribution of visible lightning over most of one hemisphere. Essentially all the detectable activity is confined to very narrow latitude bands at 13.5 N and 49 N. The active regions at 49 N are the brightest, most numerous, and periodic in longitude. Activity at this latitude is long-lived and is most likely associated with moist convective regions deep in Jupiter's atmosphere. The longitudinal periodicity of the lightning storms may represent the effects of a planetary scale atmospheric wave trapped at the depth of the moist convection.

Magalhaes, J. A.↗

Mapping the composition of planetary surfaces by Auger electron spectroscopy

The feasibility of AES as a remote-sensing technique to map the composition of the sunlit surfaces of planetary bodies without atmospheres is studied. Solar X-rays eject photoelectrons from the planetary surface. The resulting ions relax by emission of fluorescence X-rays or Auger electrons, with energies characteristic of the element which is ionized. The spectrum of Auger electrons and photoelectrons is computed for a variety of elements and for representative lunar rock types illuminated by soft-X-ray line and continuum emission typical of solar long-lived coronal active regions. The Auger electron lines for O, Si, Mg, Al, Fe, and Ca in lunar rocks stand well above the continuum background from photoelectrons and backscattered interplanetary electrons, with typical line-to-continuum ratios from about 20 to over 1000.

Lin, R. P.↗

Large-scale solar and heliospheric magnetic fields

The magnetic structure of the extended solar corona varies with the changing photospheric field during the solar cycle. A simple potential model of the corona using solar surface observations from 1976 to the present shows how the large-scale coronal field evolves over more than a solar activity cycle. These predictions match well with large stable structures inferred from measurements of coronal electron density and the IMF, though dynamic changes are poorly modeled. The sun's polar field was about 25 stronger at solar minimum in 1986 than in 1976; the heliospheric current sheet was also flatter. In Cycle 21 the coronal and photospheric large-scale long-lived field patterns rotated every 26.9 days in the northern hemisphere; the southern field rotated every 28 days. Similar periods have been present in the IMF and in the occurrence of solar flares during the last several solar cycles.

Hoeksema, J. Todd↗

Atmospheric degradation mechanisms of hydrogen containing chlorofluorocarbons (HCFC) and fluorocarbons (HFC)

The current knowledge of atmospheric degradation of hydrogen containing chlorofluorocarbons (HCFC 22 (CHClF2), HCFC 123 (CHCl2CF3), HCFC 124 (CHClFCF3), HCFC 141b (CFCl2CH3), HCFC 142b (CF2ClCH3)) and fluorocarbons (HFC 125 (CHF2CF3), HFC 134a (CH2FCF3), HFC 152a (CHF2CH3)) is assessed. Except for the initiation reaction by OH radicals, there are virtually no experimental data available concerning the subsequent oxidative breakdown of these molecules. However, from an analogy to the degradation mechanisms of simple alkanes, some useful guidelines as to the expected intermediates and final products can be derived. A noteable exception from this analogy, however, appears for the oxi-radicals. Here, halogen substitution induces new reaction types (C-Cl and C-C bond ruptures) which are unknown to the unsubstituted analogues and which modify the nature of the expected carbonyl products. Based on an evaluation of these processes using estimated bond strength data, the following simplified rules with regards to the chlorine content of the HCFC's may be deduced: (1) HCFC's containing one chlorine atom such as 22 and 142b seem to release their chlorine content essentially instantaneous with the initial attack on the parent by OH radicals, and for HCFC 124, such release is apparently prevented; (2) HCFC's such as 123 and 141b with two chlorine atoms are expected to release only one of these instantaneously; and the second chlorine atom may be stored in potentially long-lived carbonyl compounds such as CF3CClO or CClFO.

Zellner, Reinhard↗

Numerical simulations of microflare evolution in the solar transition region and corona

Several observers report transient ultraviolet brightenings, often referred to as microflares, in the solar atmosphere. In this paper, the results are presented of a series of one-dimensional numerical simulations examining possible relationships between microflares and the generation of dynamical chromospheric and transition region features. Low-energy and medium-energy microflares eject long-lived cool, dense gas plugs into the corona, with the gas plug traversing the loop apex in the medium energy case. In the case of high-energy microflares, the gas plug is rapidly heated to the temperature of the surrounding corona, and the results resemble the dynamics occurring in standard solar flare thick-target electron beam models.

Sterling, Alphonse C.↗

Galactic oscillations

Long-lived oscillations that act like normal modes are described. The total kinetic energy is found to vary with time by amounts far in excess of the fluctuations expected from the virial theorem, and the variation shows periodic patterns that suggest oscillations. Experimental results indicate that oscillation amplitudes depend on the nature of the model. It is noted that it is difficult to answer questions about likely amplitudes in real galaxies with any confidence at the present time.

Miller, R. H.↗

Radioactive dating of the elements

The extent to which an accurate determination of the age of the Galaxy, and thus a lower bound on the age of the universe, can be obtained from radioactive dating is discussed. Emphasis is given to the use of the long-lived radioactive nuclei Re-187, Th-232, U-238, and U-235. The nature of the production sites of these and other potential Galactic chronometers is examined along with their production ratios. Age determinations from models of nucleocosmochronology are reviewed and compared with age determination from stellar sources and age constraints form cosmological considerations.

Cowan, John J.↗

Solar-cosmic-ray fluxes during the last ten million years

The fluxes of energetic (E is greater than or approximately equal to 10 MeV) solar particles in the vicinity of the earth in the past can be determined from nuclides that they produced in the top centimeter of lunar rocks. Activity-vs-depth profiles of short-lived radioactivities measured in the top centimeter of lunar rocks agree with profiles calculated with directly measured solar-proton fluxes since about 1965 and were used with indirect observations to get solar-proton fluxes back to 1956. Lunar-rock profiles for long-lived radionuclides have been used to infer solar-proton fluxes averaged over several time periods in the past. New results are reported for solar-proton-produced Kr-81 measured in lunar rock 68815. Activities of 76,000-yr Ni-59 can be used to get fluxes of solar alpha particles averaged over the last 100,000 yr. The average solar-proton fluxes in the past are not greatly different from those observed during the last three 11-yr solar cycles. The work that needs to be done to determine more and better fluxes of energetic particles from the sun in the past is discussed.

Reedy, Robert C.↗

Versatile dynamic isotope power systems for the exploration of space

Dynamic, isotope-heated power systems are needed to carry out the exploration of space and are major elements identified by NASA for the Space Exploration Initiative (SEI). The Dynamic Isotope Power System (DIPS) Demonstration Program is aimed at establishing the advanced technology as well as the system designs and hardware for the SEI and other exploratory missions. Several conceptual designs of DIPS systems have been developed to provide compact, reliable, and long-lived power systems.

Johnson, Richard A.↗

The structure of the clouds distributed operating system

A novel system architecture, based on the object model, is the central structuring concept used in the Clouds distributed operating system. This architecture makes Clouds attractive over a wide class of machines and environments. Clouds is a native operating system, designed and implemented at Georgia Tech. and runs on a set of generated purpose computers connected via a local area network. The system architecture of Clouds is composed of a system-wide global set of persistent (long-lived) virtual address spaces, called objects that contain persistent data and code. The object concept is implemented at the operating system level, thus presenting a single level storage view to the user. Lightweight treads carry computational activity through the code stored in the objects. The persistent objects and threads gives rise to a programming environment composed of shared permanent memory, dispensing with the need for hardware-derived concepts such as the file systems and message systems. Though the hardware may be distributed and may have disks and networks, the Clouds provides the applications with a logically centralized system, based on a shared, structured, single level store. The current design of Clouds uses a minimalist philosophy with respect to both the kernel and the operating system. That is, the kernel and the operating system support a bare minimum of functionality. Clouds also adheres to the concept of separation of policy and mechanism. Most low-level operating system services are implemented above the kernel and most high level services are implemented at the user level. From the measured performance of using the kernel mechanisms, we are able to demonstrate that efficient implementations are feasible for the object model on commercially available hardware. Clouds provides a rich environment for conducting research in distributed systems. Some of the topics addressed in this paper include distributed programming environments, consistency of persistent data and fault-tolerance.

Dasgupta, Partha↗

The fragmentation of the Fengyun 1-2 rocket body

On 4 Oct. 1990 a Chinese Long March 4A third stage rocket body, which had been in orbit for one month, experienced a major breakup at an altitude of approximately 900 km. Within four weeks of the event 81 moderately long-lived debris were being tracked by U.S. Space Command. An analysis of the unclassified satellite catalog rules out the possibility of an inadvertent collision between the subject rocket body and any other tracked satellite. The official cause of the breakup remains unknown, but a propellant-induced explosion is considered a leading candidate.

Johnson, Nicholas L.↗

Moist wind relationships

The equations describing the temporal and spatial behavior of the kinematic moisture and heat flux are described. In these nonlinear equations, the contribution by diabatic processes to the large-scale flux is composed of two parts. One part is associated with a Rayleigh damping term while the other arises from temporal and spatial changes in the pressure gradient term. It was found that the influence of diabatic processes on large-scale moisture fluxes depends greatly on the degree of balance between forcing and damping terms in the governing kinematic flux equations. The existence of a near balance requires a reduction in the large-scale horizontal geostrophic wind speed. Based on an examination of the moisture flux equations, it is argued that reductions in the large-scale horizontal wind speed observed within major cumulus cloud systems help conserve large-scale moisture fluxes. The deviation of the wind from geostrophic conditions is easily estimated for a near balanced state. This wind modification induces secondary vertical circulations that contribute to convergence, creating or supporting long-lived mesoscale flows. We believe this process to be a major supporter of the mesoscale circulations observed in severe storms and squall lines. In the tropics the wind modification has an antitriptic relationship. These diagnostic findings suggest possible modifications to the wind field in the application of a cumulus parameterization, and may be important in diabatic initialization of numerical weather prediction models.

Raymond, William H.↗

Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987

Infrared solar absorption spectra recorded at 0.02/ cm resolution from the National Oceanic and Atmospheric Administration (NOAA) Geophysical Monitoring for Climate Change (GMCC) program station at Mauna Loa, Hawaii (latitude 19.5 deg N, longitude 155.6 deg W, elevation 3.40 km), in February 1997 have been analyzed to determine simultaneous total vertical column amounts for 13 atmospheric gases. Average tropospheric concentrations of CO2, N2O, CH4, and CHCIF2 and the daytime diurnal variations or the total columns of NO and NO2 have also been inferred. The retrieved total columns (in molecules /sq cm) of the nondiurnally varying gases are 1.6 +/- 0.2 x 10(exp 15) for HCl, 5.9 +/- 1.2 x 10(exp 15) for HNO3, 2.0 +/- 0.2 x 10(exp 21) for H2O16, 4.4 +/- 0.7 x 10(exp 18) for H2O18, 2.7 +/- 0.1 x 10(exp 17) for HDO, 2.3 +/- 0.2 x 10(exp 19) for CH4, 5.0 +/- 0.5 x 10(exp 21) for CO2, 6.7 +/- 0.8 x 10(exp 18) for O3, 4.3 +/- 0.4 x 10(exp 18) for N2O, 1.0 +/- 0.2 x 10(exp 16) for C2H6, and 9.7 +/- 2.5 x 10(exp 14) for CHClF2. We compare the total column measurements of HCl and HNO3 with previously reported ground-based, aircraft, and satellite measurements. The results for HCl are or particular interest because of the expected temporal increase in the concentration of this gas in the stratosphere. However, systematic differences among stratospheric HCl total column measurements from 1978 to 1980 and the absence of observations of free tropospheric HCl above Mauna Loa make it impossible to obtain a reliable estimate of the trend in the total burden of HCl. The measured HNO3 total column is consistent with aircraft measurements from approx. 12 km altitude. The O3 total column deduced from the IR spectra agrees with correlative Mauna Loa Umkehr measurements within the estimated error limits. The column-averaged D/H ratio of water vapor is (68 +/- 9) x- 10(exp -6), which is 0.44 +/- 0.06 times the reference value of 155.76 x 10(exp -6) for standard mean ocean water (SMOW). This large depletion in the D content of water vapor is similar to published measurements of the upper troposphere and lower stratosphere. Average tropospheric concentrations deduced for CO2, N2O, and CH4 are in good agreement with correlative NOAA GMCC surface data, indicating consistency between the measurement techniques for determining tropospheric volume mixing ratios. Results of the present study indicate that Mauna Loa is a favorable site for infrared monitoring of atmospheric gases. The site is particularly favorable for monitoring the tropospheric volume mixing ratios of long-lived gases, since the high altitude of the tropopause reduces corrections required to account for the decrease in volume mixing ratio in the stratosphere.

Rinsland, C. P.↗