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At least 253 records · Page 14

Dissociative Ionization of Pyridine by Electron Impact

In order to understand the damage of biomolecules by electrons, a process important in radiation damage, we undertake a study of the dissociative ionization (DI) of pyridine (C5H5N) from the low-lying ionization channels. The methodology used is the same as in the benzene study. While no experimental DI data are available, we compare the dissociation products from our calculations with the dissociative photoionization measurements of Tixier et al. using dipole (e, e(+) ion) coincidence spectroscopy. Comparisons with the DI of benzene is also made so as to understand the difference in DI between a heterocyclic and an aromatic molecule.

Dateo, Christopher↗

Threshold Laws for Two-Electron Ejection Processes: A Still Controversial Problem in Atomic Physics

This talk deals with collision processes of the following kind: (a) an ionizing collision of an electron with a neutral atom, (b) a photon incident of a negative ion resulting in two-electron ejection. In both cases the final state is a positive ion and two outgoing electrons, and in principle both processes should be governed by the same form of threshold law. It is generally conceded that this is one of the most difficult basic problems in nonrelativistic quantum mechanics. The standard treatment (due to Wannier) will be briefly reviewed in terms of the derivation of his well- known threshold law for the yield (Q) of positive ions vs. the excess energy (E): Q(sub w) varies as E(exp 1.127...). The derivation is a brilliant analysis based on Newton's equations, leading to the dominance of events in which the two electrons emerge on opposite sides of the residual ion with similar energies. In contrast, I will argue on the basis of quantum mechanical ideas that in the threshold limit the more likely outcome are events in which the electrons emerge with decidedly different energies, leading to a formally different (Coulomb-dipole) threshold law Q(sub CD) varies as E(1 + C sin(alpha ln(E)+mu)]/[ln(E)](exp 2). Additional aspects of that approach will be discussed . Some: experimental results will be presented, and more incisive predictions involving polarized projectiles and targets will be given.

Temkin, Aaron↗

Radio waves and circuits

Diffraction and scattering of electromagnetic waves, radio wave propagation in ionized media, radio antennas, and signal processing in communications systems

CIRCUIT↗

The physics of the neutral upper atmosphere.

Particular attention is given to models of the upper atmosphere that deal with the diurnal variation and the latitudinal density dependence. The upper atmosphere is considered as essentially an ideal gas, or rather a weakly ionized plasma, where physical and chemical processes of considerable complexity take place. The final goal for the theoretical models of the upper atmosphere is to derive the time and space dependence of the physical quantities density, composition, temperature, pressure, and state of motion by theoretical considerations from basic physical assumptions. Questions of the dynamics of the upper atmosphere are discussed together with one- and two-dimensional models of the upper atmosphere, three-dimensional models, the geomagnetic effect, and the semiannual density variation.

Blum, P.↗

Some optical and kinetic properties of the nearby interstellar gas

A model for resonant scattering of sunlight by the nearby interstellar gas is developed which takes into account the modification of a Maxwell-Boltzmann velocity distribution by a central force. While the formalism applies to both hydrogen and helium, the latter is emphasized. Theoretical line profiles and integrated emission rates for helium are compared with those of approximate models and with existing observations. As a result of this analysis, an upward revision of the bulk flow velocity of interstellar helium relative to the solar system, previously deduced from He 584-A observations, is required. Velocities of 15-20 km/s, temperatures of the order of 5000-10,000 K, and densities of the order of 0.008-0.02 per cu cm are sufficient to explain the (helium) observations. However, higher-precision measurements are required in order to place more stringent limits on the gas parameters. Calculations of the flux of interstellar helium atoms impinging on earth's upper atmosphere show that the resulting impact ionization is small compared with terrestrial processes.

Meier, R. R.↗

The critical velocity phenomenon and the origin of the regular satellites

A theory is developed for the formation of the satellite systems which are likely to have been formed in situ, that is, not by capture of the satellite by the central planet. The foundation of the theory is the observation of the similarity between the band structure of such satellites and the band structure of cosmically abundant elements. That means that the values of the quantity log Gamma, where Gamma is the ratio of the mass of the central body to the orbital radius of the secondary body, are grouped into three bands which can be identified with the three bands into which are grouped the values of the ratio of the mass of a central body to the distance at which the kinetic energy of a freely falling cloud of atoms of a given kind equals the ionization energy. A coherent series of processes that could have led to the formation of satellites is outlined. The theory is valid also for planets, since the above-mentioned band structure is noted for the sun-planets system also.

De, B. R.↗

Initial observations of the nightside ionosphere of Venus from Pioneer Venus Orbiter radio occultations

Results of radio occultation measurements of electron density profiles of the nightside ionosphere of Venus at solar zenith angles from 90 to 164 deg, obtained from the Pioneer Venus Orbiter, are reported. Data were derived from closed-loop S- and X-band signals received by the Deep Space Network upon ionospheric entry and exit of the spacecraft. Nightside electron density profiles are found to be rather uniform in the solar zenith angle range of from 95 to 107 deg, with peak electron densities ranging from 23,000 to 40,000/cu cm, while between 110 and 164 deg, profiles exhibit a high degree of variability and peak electron densities vary from 7,600 to 31,800/cu cm. A possible mechanism for the maintenance of the nightside Venus ionosphere during the long Venus night, which is consistent with the observed spatial and temporal variability of deep ionospheric electron density profiles, is proposed to be impact ionization by precipitating particles, although transport processes from the dayside may also be important.

Kliore, A. J.↗

Superthermal electron processes in the upper atmosphere of Uranus: Aurora and electroglow

Strong ultraviolet emissions from the upper atmosphere of Uranus suggest that both auroral and electroglow phenomena are of significant aeronomical consequences in the structure of the upper atmosphere. Combined modeling and data analysis were performed to determine the effect of electroglow and auroral phenomena on the global heat and atomic hydrogen budgets in the Uranus upper atmosphere. The results indicate that the auroral and electroglow heat sources are not adequate to explain the high exospheric temperature observed at Uranus, but that the atomic hydrogen supplied by these processes is more than sufficient to explain the observations. The various superthermal electron distributions modeled have significantly different efficiencies for the various processes such as UV emission, heating, ionization, and atomic hydrogen production, and produce quite different H2 band spectra. However, additional information on the UV spectra and global parameters is needed before modeling can be used to distinguish between the possible mechanisms for electroglow.

Waite, J. H., Jr.↗

Superthermal electron processes in the upper atmosphere of Uranus - Aurora and electroglow

Strong ultraviolet emissions from the upper atmosphere of Uranus suggest that both auroral and electroglow phenomena are of significant aeronomical consequences in the structure of the upper atmosphere. Combined modeling and data analysis were performed to determine the effect of electroglow and auroral phenomena on the global heat and atomic hydrogen budgets in the Uranus upper atmosphere. The results indicate that the auroral and electroglow heat sources are not adequate to explain the high exospheric temperature observed at Uranus, but that the atomic hydrogen supplied by these processes is more than sufficient to explain the observations. The various superthermal electron distributions modeled have significantly different efficiencies for the various processes such as UV emission, heating, ionization, and atomic hydrogen production, and produce quite different H2 band spectra. However, additional information on the UV spectra and global parameters is needed before modeling can be used to distinguish between the possible mechanisms for electroglow.

Waite, J. H., Jr.↗

Shock temperature measurements of planetary ices - NH3, CH4, and 'synthetic Uranus'

Shock temperature measurements have been performed on several materials which have relevance to the modeling of the outer planets. These materials are methane, ammonia and a mixture of water, ammonia, and isopropanol known as synthetic Uranus. Temperatures have been measured in these materials over the pressure range 33-76 GPa for which there also exists measurements of equation of state and electrical conductivity. The temperatures are found to agree well with available calculations, with small discrepancies between data and theory ascribed to energy absorbing processes such as dissociation and molecular ionization.

Radousky, H. B.↗

CLEAR: Boosted Lyα Transmission of the Intergalactic Medium in UV-bright Galaxies

Reionization is an inhomogeneous process, thought to begin in small ionized bubbles of the intergalactic medium (IGM) around overdense regions of galaxies. Recent Lyα studies during the epoch of reionization show evidence that ionized bubbles formed earlier around brighter galaxies, suggesting higher IGM transmission of Lyα from these galaxies. We investigate this problem using IR slitless spectroscopy from the Hubble Space Telescope (HST) Wide-Field Camera 3 (WFC3) G102 grism observations of 148 galaxies selected via photometric redshifts at 6.0 < z < 8.2. These galaxies have spectra extracted from the CANDELS Lyα Emission at Reionization (CLEAR) survey. We combine the CLEAR data for 275 galaxies with the Keck Deep Imaging Multi-Object Spectrograph and MOSFIRE data set from the Texas Spectroscopic Search for Lyα Emission at the End of Reionization Survey. We constrain the Lyα equivalent width (EW) distribution at 6.0 < z < 8.2, which is described by an exponential form, dN / dEW ∝ exp(-EW) W(sub 0), with the characteristic e-folding scale width (W(sub 0)). We confirm a significant drop in the Lyα strength (i.e., W(sub 0)) at z > 6. Furthermore, we compare the redshift evolution of W(sub 0) between galaxies at different UV luminosities. UV-bright (M(sub UV) < −21 [i.e., L(sub UV) > L*]) galaxies show weaker evolution with a decrease of 0.4 ( ± 0.2) dex in W(sub 0) at z > 6, while UV-faint (M(sub UV) > −21 [LUV < L*]) galaxies exhibit a significant drop of 0.7–0.8 (±0.2) dex in W(sub 0) from z < 6 to z > 6. If the change in W(sub 0) is proportional to the change in the IGM transmission for Lyα photons, then this is evidence that the transmission is “boosted” around UV-brighter galaxies, suggesting that reionization proceeds faster in regions around such galaxies.

Reionization↗

CLEAR: Boosted Ly alpha Transmission of the Intergalactic Medium in UV-bright Galaxies

Reionization is an inhomogeneous process, thought to begin in small ionized bubbles of the intergalacticmedium (IGM) around overdense regions of galaxies. Recent Lyman-alpha (Lyα) studies during the epochof reionization show growing evidence that ionized bubbles formed earlier around brighter galaxies, suggest-ing higher IGM transmission of Lyαfrom these galaxies. We investigate this problem using IR slitless spec-troscopy from the Hubble Space Telescope (HST) Wide-Field Camera 3 (WFC3) G102 grism observations of148 galaxies selected via photometric redshifts at6.0< z <8.2. These galaxies have spectra extracted fromthe CANDELS LyαEmission at Reionization (CLEAR) survey. We combine the CLEAR data for 275 galaxieswith the Keck/DEIMOS+MOSFIRE dataset from the Texas Spectroscopic Search for LyαEmission at the Endof Reionization Survey. We then constrain the Lyαequivalent-width (EW) distribution at6.0< z <8.2, whichis described by an exponential form,dN/dEW∝exp(-EW)/W0, with the characteristice-folding scale width(W0). We confirm a significant drop of the Lyαstrength (orW0) atz >6. Furthermore, we compare the redshiftevolution ofW0between galaxies at different UV luminosities. The UV-bright (MUV<−21, orLUV> L∗)galaxies show weaker evolution with a decrease of 0.4 (±0.2) dex inW0atz >6while UV-faint (MUV>−21,orLUV< L∗) galaxies exhibit a significant drop by a factor of 0.7-0.8 (±0.2) dex inW0fromz <6toz >6.Our results add to the accumulating evidence that UV-bright galaxies exhibit boosted Lyαtransmission in theIGM, suggesting that reionization completes sooner in regions proximate to galaxies of higher UV luminosity.

Intae Jung↗

The relative abundances of Sn, Te, Xe, Ba and Ce

Elements with even atomic number (Z) in the interval 50 or = Z or = 58 were resolved in the cosmic radiation using the Heavy Nuclei Experiment on the HEAO-3 satellite. Their relative abundances were compared with the results expected from pure r-process material, pure s-process material, and solar system material, both with and without a modification due to possible first ionization potential effects. Such effects may be the result of the preferential acceleration, and hence enhancement in the cosmic rays, of those elements having low first ionization potentials. Measurements were found to be inconsistent with pure r-process material at the greater than 98% confidence level whether or not the first ionization potential adjustments are made.

Krombel, K. E.↗

Chromosomal changes in cultured human epithelial cells transformed by low- and high-LET radiation

For a better assessment of radiation risk in space, an understanding of the responses of human cells, especially the epithelial cells, to low- and high-LET radiation is essential. In our laboratory, we have successfully developed techniques to study the neoplastic transformation of two human epithelial cell systems by ionizing radiation. These cell systems are human mammary epithelial cells (H184B5) and human epidermal keratinocytes (HEK). Both cell lines are immortal, anchorage dependent for growth, and nontumorigenic in athymic nude mice. Neoplastic transformation was achieved by irradiating cells successively. Our results showed that radiogenic cell transformation is a multistep process and that a single exposure of ionizing radiation can cause only one step of transformation. It requires, therefore, multihits to make human epithelial cells fully tumorigenic. Using a simple karyotyping method, we did chromosome analysis with cells cloned at various stages of transformation. We found no consistent large terminal deletion of chromosomes in radiation-induced transformants. Some changes of total number of chromosomes, however, were observed in the transformed cells. These transformants provide an unique opportunity for further genetic studies at a molecular level.

NASA Discipline Number 04-10↗