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At least 253 records · Page 14

Composition of the earth's upper mantle. II - Volatile trace elements in ultramafic xenoliths

Radiochemical neutron activation analysis was used to determine the nine volatile elements Ag, Bi, Cd, In, Sb, Se, Te, Tl, and Zn in 19 ultramafic rocks, consisting mainly of spinel and garnet lherzolites. A sheared garnet lherzolite, PHN 1611, may approximate undepleted mantle material and tends to have a higher volatile element content than the depleted mantle material represented by spinel lherzolites. Comparisons of continental basalts with PHN 1611 and of oceanic ridge basalts with spinel lherzolites show similar basalt: source material partition factors for eight of the nine volatile elements, Sb being the exception. The strong depletion of Te and Se in the mantle, relative to lithophile elements of similar volatility, suggests that 97% of the earth's S, Se and Te may be in the outer core.

Morgan, J. W.↗

Predictions of mineral assemblages in planetary interiors

It is shown that mineral compatibilities in the model system CaO-MgO-Al2O3-SiO2 can be applied to deduce the mineral assemblages expected in planetary interiors and their variation with depth. In general, the available estimates of bulk composition of the terrestrial planets suggest that the terrestrial planets can be divided into two groups based on their predicted mineral assemblages. The terrestrial, Venusian, and lunar bulk compositions are expected to display the following sequence of mineral assemblages with increasing pressure: plagioclase lherzolite, spinel lherzolite, and garnet lherzolite. The sequences expected in Martian and Mercurian are different: spinel-plagioclase wehrlite, spinel lherzolite, and spinel-garnet wehrlite. These assemblages have a major influence on the compositions of liquids produced by melting of these planetary interiors, on the solidus temperatures, and thus on the nature of planetary differentiation and the types of magmas extruded at planetary surfaces.

Stolper, E.↗

Resonant isolator for maser amplifier

An isolator is described for use in a low noise maser amplifier, which provides low loss across a wide bandwidth and which can be constructed at moderate cost. The isolator includes a train of garnet or ferrite elements extending along the length of a microwave channel parallel to the slow wave structure, with the elements being of staggered height, so that the thin elements which are resonant to the microwaves are separated by much thicker elements. The thick garnet or ferrite elements reduce the magnetic flux passing through the thin elements to permit altering of the shape of the thin elements so as to facilitate their fabrication and to provide better isolation with reduced loss, by increasing the thickness of the thin elements and decreasing their length and width.

Clauss, R. C.↗

Partition coefficients of Hf, Zr, and REE between phenocrysts and groundmasses

Partition coefficients of Hf, Zr, and REE between olivine, orthopyroxene, clinopyroxene, plagioclase, garnet, amphibole, ilmenite, phlogopite, and liquid are presented. Samples consist of megacrysts in kimberlite, phenocrysts in alkaline basalts, tholeiitic basalts and andesitic to dacitic rocks, and synthetic garnet and clinopyroxene in Hawaiian tholeiites. The Hf-Lu and Zr-Lu elemental fractionations are as large as the Lu-Sm or Lu-Nd fractionation. The Hf and Zr partition coefficients between mafic phenocrysts and liquids are smaller than the Lu partition coefficients, but are similar to the Nd or Sm partition coefficients. The Hf and Zr partition coefficients between ilmenite, phlogopite, and liquid are larger than the Lu partition coefficients for these minerals and their corresponding liquids. The Hf-Zr elemental fractionation does not occur except for extreme fractionation involving Zr-minerals and extremely low fO2. These data have an important bearing on chronological and petrogenetic tracer studies involving the Lu-Hf isotopic system.

Fujimaki, H.↗

Advanced detectors and signal processing for bubble memories

The feasibility of combining silicon and magnetic bubble technologies is demonstrated. Results of bubble film annealing indicate that a low temperature silicon on garnet technology is the most likely one to succeed commercially. Annealing ambients are also shown to have a major effect on the magnetic properties of bubble films. Functional MOSFETs were fabricated on bubble films coated with thick (approximately 1 micron) SiO2 layers. The two main problems with these silicon on garnet MOSFETs are low electron mobilities and large gate leakage currents. Results indicate that the laser recrystallized silicon and gate oxide (SiO2) layers are contaminated. The data suggest that part of the contaminating ions originate in the sputtered oxide spacer layer and part originates in the bubble film itself. A diffusion barrier, such as silicon nitride, placed between the bubble film and the silicon layer should eliminate the contamination induced problem.

Kryder, M. H.↗

Phosphoran pyroxene and olivine in silicate inclusions in natural iron-carbon alloy, Disko Island, Greenland

A survey of literature data on the P contents of olivine, pyroxene, and garnet in mantle xenoliths and the bulk P contents of mantle xenoliths shows that available data is ambiguous as to whether mantle P is primarily contained in silicates or in phosphates, even though phosphates are rarely observed in mantle xenoliths. Garnet probably contains more of the mantle's P than olivine or pyroxene. Bulk P contents of mantle xenoliths vary significantly. Estimation of the primitive mantle P content from xenoliths requires interpretation of the partial melting and contamination histories of the xenoliths.

Goodrich, C. A.↗

Petrochemical and petrophysical characterization of the lower crust and the Moho beneath the West African Craton, based on Xenoliths from Kimberlites

Additional evidence to the composition of the lower crust and uppermost mantle was presented in the form of xenolith data. Xenoliths from the 2.7-Ga West African Craton indicate that the Moho beneath this shield is a chemically and physically gradational boundary, with intercalations of garnet granulite and garnet eclogite. Inclusions in diamonds indicate a depleted upper mantle source, and zenolith barometry and thermometry data suggest a high mantle geotherm with a kink near the Moho. Metallic iron in the xenoliths indicates that the uppermost mantle has a significant magnetization, and that the depth to the Curie isotherm, which is usually considered to be at or above the Moho, may be deeper than the Moho.

Haggerty, Stephen E.↗

Metamorphic conditions in the Nilgiri Granulite Terrane and the adjacent Moyar and Bhavani Shear Zones: A reevaluation

Data were presented on pressure and temperature determinations from the Nilgiri Hills. About 70 samples were analyzed by probe and several calibrations of garnet-pyroxene thermometry and barometry applied. Most calibrations gave considerable scatter; however, a new calibration by Bhattacharya, Raith, Lal, and others, accounting for nonideality in both garnet and orthopyroxene, gave consistent results of 754 + or - 52 C and 9.2 + or - 0.7 kbar. On the regional scale, a pressure increase of 6.5 to 7 kbar in the SW to 11 kbar in the NE was related to block tilting. A continuous pressure gradient into the Moyar shear zone suggests that the zone is not a suture juxtaposing unrelated blocks.

Raith, M.↗

Major line operation in vertical Bloch line memory

An experimental and numerical study is conducted of the operation of a major line in a vertical Bloch-line memory that employs a partial garnet-grooving architecture and contains (1) a bubble generator; (2) a bubble-propagation track; (3) a bubble-expander for detection; and (4) a bubble annihilator. The bubble expander is a modification of the propagation track; the meandering conductor and groove width were gradually increased to stretch the bubble into a stripe. The numerical model employed encompasses the garnet-grooving effect. Agreement is obtained between exparimental and simulation results.

Wu, J. C.↗

Primary differentiation in the early Earth: Nd and Sr isotopic evidence from diamondiferous eclogites for both old depleted and old enriched mantle, Yakutia, Siberia

Ancient, stable, continental cratons possess thick, subcontinental-lithospheric mantle 'keels' which favor particularly the emplacement of diamondiferous kimberlites and included peridotites and eclogites. These refractory mantle samples of the roots provide hard constraints on the theories of formation, growth, and evolution of these cratons. Xenoliths containing only primary garnet and clinopyroxene (eclogites), although rare in most kimberlites, can retain the geochemical signatures of their parent protoliths (e.g., subducted oceanic crust, ancient mantle) thus offering the opportunity to address mantle processes which may have taken place at earlier times in the Earth's history. In fact, it has been postulated that some eclogites are residues from the accretion of the early Earth. Nd and Sr isotopic data are presented which may be interpreted as evidence of an early (greater than 4 Ga) mantle differentiation event. The kimberlites of Yakutia are located both marginal and central to the Siberian craton, and a wide variety of xenoliths are present within them. The Siberian mantle samples have received little attention in the western world, largely because suitable suites of Yakutian samples have not been readily available. Importantly, there is evidence that metasomatism of the Siberian lithosphere has been considerably less intense or extensive than for the Kaapvaal craton. Therefore, it should be considerably easier to elicit the igneous/metamorphic histories of Siberian kimberlitic xenoliths. One of the notable features of the Siberian eclogites is the common appearance of diamonds, especially in the Mir and Udachnaya pipes. In all, eight eclogite samples (eight garnet separates and eight clinopyroxene separates) have been analyzed to date on the Udachnaya pipe, seven from our group.

Snyder, Gregory A.↗

Emittance Theory for Thin Film Selective Emitter

Thin films of high temperature garnet materials such as yttrium aluminum garnet (YAG) doped with rare earths are currently being investigated as selective emitters. This paper presents a radiative transfer analysis of the thin film emitter. From this analysis the emitter efficiency and power density are calculated. Results based on measured extinction coefficients for erbium-YAG and holmium-YAG are presented. These results indicated that emitter efficiencies of 50 percent and power densities of several watts/sq cm are attainable at moderate temperatures (less than 1750 K).

Chubb, Donald L.↗

Subduction of hydrated basalt of the oceanic crust: Implications for recycling of water into the upper mantle and continental growth

Subduction zones are presently the dominant sites on Earth for recycling and mass transfer between the crust and mantle; they feed hydrated basaltic oceanic crust into the upper mantle, where dehydration reactions release aqueous fluids and/or hydrous melts. The loci for fluid and/or melt generation will be determined by the intersection of dehydration reaction boundaries of primary hydrous minerals within the subducted lithosphere with slab geotherms. For metabasalt of the oceanic crust, amphibole is the dominant hydrous mineral. The dehydration melting solidus, vapor-absent melting phase relationships; and amphibole-out phase boundary for a number of natural metabasalts have been determined experimentally, and the pressure-temperature conditions of each of these appear to be dependent on bulk composition. Whether or not the dehydration of amphibole is a fluid-generating or partial melting reaction depends on a number of factors specific to a given subduction zone, such as age and thickness of the subducting oceanic lithosphere, the rate of convergence, and the maturity of the subduction zone. In general, subduction of young, hot oceanic lithosphere will result in partial melting of metabasalt of the oceanic crust within the garnet stability field; these melts are characteristically high-Al2O3 trondhjemites, tonalites and dacites. The presence of residual garnet during partial melting imparts a distinctive trace element signature (e.g., high La/Yb, high Sr/Y and Cr/Y combined with low Cr and Y contents relative to demonstrably mantle-derived arc magmas). Water in eclogitized, subducted basalt of the oceanic crust is therefore strongly partitioned into melts generated below about 3.5 GPa in 'hot' subduction zones. Although phase equilibria experiments relevant to 'cold' subduction of hydrated natural basalts are underway in a number of high-pressure laboratories, little is known with respect to the stability of more exotic hydrous minerals (e.g., ellenbergite) and the potential for oceanic crust (including metasediments) to transport water deeper into the mantle.

Rapp, R. P.↗

Thermal Line Shift and Broadening of Ho(3+) in Y3AI5O12 and Lu3AIO12

The interaction between the active ion and the host lattice manifests itself in two distinct ways: the static interaction with the crystal field that causes the splitting of the free ion energy levels and the active interaction through the surrounding phonon system that produces temperature dependent characteristics in the optical spectrum of the ion (e.g. line broadening and line shift). The strength of the splitting depends heavily on the electronic configuration of the atom. The model give by McCumber and Sturge describes the thermal effects on line width and position above 77 K with Raman scattering of Debye model phonons. These processes predict a Lorentzian line shape. However, below 77 K the principal contributions are from crystal inhomogeneities that result in a Gaussian line shape. We have investigated the experimental Stark levels as well as the thermal effects on the line width and the position of trivalent holmium ions in both yttrium aluminum garnet, Y3Al5O12 (YAG) and lutetium aluminum garnet, Lu3Al5O12 (LuAG) crystals. We have compared the Stark levels of the (5)I(6) state, and the thermal line shift and broadening of an isolated transition (Z2 to X13) between the (5)I(8) and (5)I(6) stark levels in these crystals. This transition occurs in the near infrared region at approximately 1117 nm.

Snoke, Elizabeth R.↗

Stress Tuning of Laser Crystals

The topic of stress tunable laser crystals is addressed in this study with the purpose of determining the piezo-optic coefficients of a new laser material. This data was collected using a quadruple pass birefringence technique because of its high degree of sensitivity relative to the other methods examined including fringe shift analysis using a Mach-Zender interferometer. A green He-Ne laser was passed through a light chopper and Glan-Thompson prism before entering a crystal of Erbium doped Yttrium Aluminum Garnet (Er:YAG) (used in order to validate the experimental technique). The Er:YAG crystal is mounted in a press mechanism and the laser is quadruple passed through test specimen before being returned through the prism and the orthogonally polarized portion of the beam measured with a optical sensor. At a later stage, the Er:YAG crystal was replaced with a new crystal in order to determine the piezo-optic coefficients of this uncharacterized material. The applied load was monitored with the use of a 50 lb. load cell placed in line with the press. Light transmission readings were taken using a lock-in amplifier while load cell measurements were taken with a voltmeter from a 5 volt, 0.5 amp power supply. Despite the fact that an effective crystal press damping system was developed, size limitations precluded the use of the complete system. For this reason, data points were taken only once per full turn so as to minimize the effect of non uniform load application on the collected data. Good correlation was found in the transmission data between the experimentally determined Er:YAG and the previously known peizo-optic constants of non-doped crystal with which it was compared. The variation which was found between the two could be accounted for by the aforementioned presence of Erbium in the experimental sample (for which exact empirical data was not known). The same test procedure was then carried out on a Yttrium Gallium Aluminum garnet (YGAG) for the purpose of establishing values of its unknown piezo-optic constant tensor using experimentally collected transmission data. Significant variation between the piezo-optic constants of YAG and YGAG crystals was found however, the excellent data correlation of separate experimental runs carried out on the YGAG sample demonstrates the validity of these results. The data collected during the stressing of the YGAG was of high quality, however the amount of data collected was somewhat limited by a fracture of YGAG specimen which undoubted altered the crystalline lattice structure and hence precluded any further testing.

Carty, Atherton A.↗

Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet, and magnesium oxide.

Zhu, Dongming↗

Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet and magnesium oxide.

Zhu, Dongming↗

Lunar and Planetary Science XXXV: Viewing the Lunar Interior Through Titanium-Colored Glasses

The session"Viewing the Lunar Interior Through Titanium-Colored Glasses" included the following reports:Consequences of High Crystallinity for the Evolution of the Lunar Magma Ocean: Trapped Plagioclase; Low Abundances of Highly Siderophile Elements in the Lunar Mantle: Evidence for Prolonged Late Accretion; Fast Anorthite Dissolution Rates in Lunar Picritic Melts: Petrologic Implications; Searching the Moon for Aluminous Mare Basalts Using Compositional Remote-Sensing Constraints II: Detailed analysis of ROIs; Origin of Lunar High Titanium Ultramafic Glasses: A Hybridized Source?; Ilmenite Solubility in Lunar Basalts as a Function of Temperature and Pressure: Implications for Petrogenesis; Garnet in the Lunar Mantle: Further Evidence from Volcanic Glasses; Preliminary High Pressure Phase Relations of Apollo 15 Green C Glass: Assessment of the Role of Garnet; Oxygen Fugacity of Mare Basalts and the Lunar Mantle. Application of a New Microscale Oxybarometer Based on the Valence State of Vanadium; A Model for the Origin of the Dark Ring at Orientale Basin; Petrology and Geochemistry of LAP 02 205: A New Low-Ti Mare-Basalt Meteorite; Thorium and Samarium in Lunar Pyroclastic Glasses: Insights into the Composition of the Lunar Mantle and Basaltic Magmatism on the Moon; and Eu2+ and REE3+ Diffusion in Enstatite, Diopside, Anorthite, and a Silicate Melt: A Database for Understanding Kinetic Fractionation of REE in the Lunar Mantle and Crust.

Source record↗

Lu-Hf and Sm-Nd Isotopic Studies of Shergottites and Nakhlites: Implications for Martian Mantle Sources

We present a new Lu-Hf and Sm-Nd isotope systematics study of four enriched shergottites (Zagami, Shergotty, NWA856 and Los Angeles), and three nakhlites (Nakhla, MIL03346 and Yamato 000593) in order to further understand processes occurring during the early differentiation of Mars and the crystallization of its magma ocean. Two fractions of the terrestrial petrological analogue of nakhlites, the Archaean Theo's flow (Ontario, Canada) were also measured. The coupling of Nd and Hf isotopes provide direct insights on the mineralogy of the melt sources. In contrast to Sm/Nd, Lu/Hf ratios can be very large in minerals such as garnet. Selective partial melting of garnet bearing mantle sources can therefore lead to characteristic Lu/Hf signatures that can be recognized with Hf-176/Hf-177Hf ratios.

Debaille, V.↗