Aliovalent fluorine doping and anodization-induced amorphization enable bifunctional catalysts for efficient water splitting
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Highly crystalline anatase TiO 2 nanosheets, made by controlled oxidation of TiS 2 nanosheets, expose the {001} and {100} facets, giving rise to enhancement in HER as compared to Degussa P25 TiO 2 nanoparticles. No enhancement in ORR was observed.
Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF 3 , and Br substituents showing quasi-reversible redox events in the 0.59–1.32 V range is reported. A few have been isolated as [HCB 11 Cl 11 ] − salts.
Delivered capacities of non-flammable LHCE vs. flammable LiPF 6 EC:DMC electrolyte at low temperature, high voltage charge, and fast charge.
We investigate switching of photoluminescence from PbS quantum dots crosslinked with photochromic diarylethene molecules with different degree of halogenation.
The development of theranostic agents for radiopharmaceuticals based on therapeutic alpha emitters marks an important clinical need.
CF 3 alteration in FMOF-1 to different X groups yields enhanced porosity and selectivity for specific guests (e.g., CO 2 adsorption was improved for all X variants; for X = COOH, CO 2 /CH 4 = 59.6 & CO 2 /N 2 = 128.7, >40× vs . FMOF-1).
Superhydrophobicity of MeMOFs, methylated analogues of FMOFs (CF 3 → CH 3 ) is predicted by GCMC simulations (high-RH CO 2 or CH 4 adsorption in MeMOFs > FMOFs) validated experimentally (H 2 O contact angle ∼172° for MeMOF@plastic dry-coated substrates).
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