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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Bubble Mass Transport Measurement in the Large-Scale Test Loops at Oak Ridge National Laboratory

Molten salts are complex fluids that incorporate multi-phase behavior depending on the chemistry and the physical properties of the entrained components. These components include the carrier salt, the actinide fuel, and fission, activation, and corrosion products, the concentrations of which depends on the burnup history of the salt. Radionuclide transport from the salt into the cover gas / off-gas system depends on volatility as predicted by thermochemistry, but data from the Molten Salt Reactor Experiment (MSRE) conducted in the late 1960s suggest that bubble formation and transport are also important. Anomalously high fractions of noble metals were found in the off-gas system and were attributed to transportation with parent salt aerosols and their association with rising noble gas bubbles. The prediction of such phenomena requires coupled neutronic, thermal hydraulic, and chemical equilibrium calculations, the framework of which is being developed within the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program supported by the US Department of Energy (DOE) Office of Nuclear Energy (NE). However, separate effects tests and models of experiments using tools such as SAM and Thermochimica can guide model developers through important processes. Conversely, model development guides the choice of experiments and systems to provide data that are relevant for validation. This report describes several experiments that tracked gas transport in molten salts, ranging from small-scale systems to large-scale loops. Gas transportation in a molten salt, LiCl-KCl, has been studied using the shadowgraph technique. Sensors such as residual gas analysis, Raman spectroscopy, and laser-induced breakdown spectroscopy have been tested for off-gas measurements. These data were used to interpret how the gases move through the upstream salt / cover gas and the interface between them. Differential pressure measurements were able to detect individual gas bubbles as they popped at the liquid–gas interface. Salt aerosols were collected on a cascade impactor. Their formation was also observed directly via the shadowgraph method, and most of these aerosols were launched ballistically into the cover gas. Fine mists could also be observed. Convection currents through the salt were visualized and can be used to calculate the thermophysical properties of the salt itself. The apparatuses described in this report and in a previous work (McFarlane et al. 2023) have been commissioned and are available for use in making further measurements of salt/surrogate fission product behavior. Novel approaches using neutron imaging are planned for the study of fluoride salts, which cannot be contained in quartz, so shadowgraph visualization is not available. Bubble transport in convective flow and in a slow-moving salt column are planned. The mobile laser-induced breakdown spectroscopy (LIBS) system is available for several applications, including iodine capture in a molten hydroxide scrubber, H2 transport though molten salts to complement Raman analysis, and online tracking of salt aerosol generation, transport, and deposition. This report summarizes the findings from FY24 and the plans for FY25. The work completes milestone M2AT-24OR0702013 of the DOE-NE Advanced Reactor Technology, Molten Salt Reactor Campaign, DOE-NE-5.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1977

General instability analysis

HOLBOAT computer program provides instability analysis of inhomogeneous, anisotropic, right-circular cylinder or segment under combined loading. Program is based on Kirchhoff-Love hypothesis, general anisotropic constitutive equations, and Flugge's differential equations of equilibrium.

Bianca, C. J.↗
NASA NTRS1992

Swept shock/boundary layer interaction experiments in support of CFD code validation

Research on the topic of shock wave/turbulent boundary-layer interaction was carried out during the past three years at the Penn State Gas Dynamics Laboratory. This report describes the experimental research program which provides basic knowledge and establishes new data on heat transfer in swept shock wave/boundary-layer interactions. An equilibrium turbulent boundary-layer on a flat plate is subjected to impingement by swept planar shock waves generated by a sharp fin. Five different interactions with fin angle ranging from 10 deg to 20 deg at freestream Mach numbers of 3.0 and 4.0 produce a variety of interaction strengths from weak to very strong. A foil heater generates a uniform heat flux over the flat plate surface, and miniature thin-film-resistance sensors mounted on it are used to measure the local surface temperature. The heat convection equation is then solved for the heat transfer distribution within an interaction, yielding a total uncertainty of about +/- 10 percent. These experimental data are compared with the results of numerical Navier-Stokes solutions which employ a k-epsilon turbulence model. Finally, a simplified form of the peak heat transfer correlation for fin interactions is suggested.

Settles, G. S.↗
NASA NTRS1993

On the preferred source location for the convective amplification of ion cyclotron waves

The propagation, growth, and absorption of electromagnetic ion cyclotron waves (EMICs) in the Pc1 range are studied using the HOTRAY ray tracing program for a realistic distribution of thermal plasma (H+, He+, O+), which is assumed to be in diffusive equilibrium inside the plasmasphere and collisionless in the low-density region outside the plasmapause. It is demonstrated that there are two principal source regions for the growth of EMIC waves. The theoretical results are related to the most recent satellite and ground-based observations.

Horne, Richard B.↗
NASA NTRS1994

Heat-transfer measurements and computations of swept-shock-wave boundary-layer interactions

An experimental and computational research program providing new knowledge of the heat transfer in swept-shock-wave/boundary-layer interactions is described. An equilibrium turbulent boundary layer on a flat plate is subjected to impingement by a swept planar shock wave generated by a sharp fin. Five different interactions with fin angles ranging from 10 to 20 deg at freestream Mach numbers of 3 and 4 produce a variety of interaction strengths ranging from weak to very strong. A foil heater generates a uniform heat flux over the flat plate surface, and miniature thin-film-resistance sensors are used to measure the local surface temperature. The heat convection equation is then solved for the heat transfer distribution within an interaction, yielding an uncertainty of about +/- 10%. These data are compared with numerical Navier-Stokes solutions that employ a k-epsilon turbulence model. A simple peak heat transfer correlation for fin interactions is suggested.

Lee, Y.↗
NASA NTRS1991

The Navy/NASA Engine Program (NNEP89): A user's manual

An engine simulation computer code called NNEP89 was written to perform 1-D steady state thermodynamic analysis of turbine engine cycles. By using a very flexible method of input, a set of standard components are connected at execution time to simulate almost any turbine engine configuration that the user could imagine. The code was used to simulate a wide range of engine cycles from turboshafts and turboprops to air turborockets and supersonic cruise variable cycle engines. Off design performance is calculated through the use of component performance maps. A chemical equilibrium model is incorporated to adequately predict chemical dissociation as well as model virtually any fuel. NNEP89 is written in standard FORTRAN77 with clear structured programming and extensive internal documentation. The standard FORTRAN77 programming allows it to be installed onto most mainframe computers and workstations without modification. The NNEP89 code was derived from the Navy/NASA Engine program (NNEP). NNEP89 provides many improvements and enhancements to the original NNEP code and incorporates features which make it easier to use for the novice user. This is a comprehensive user's guide for the NNEP89 code.

Plencner, Robert M.↗
NASA NTRS1988

An integrated approach to the synthesis of geometrically non-linear structures

An integrated approach to the minimum weight design of geometrically nonlinear three-dimensional truss structures with geometric imperfections, subject to inequality constraints on static displacements, stresses, local buckling and cross sectional areas, is investigated. The integrated structural synthesis problem involves design and response quantities as independent variables and equilibrium equations, describing the finite element model, as equality constraints. The nonlinear structural analysis and the optimization are thus merged together into a single process. A computer program developed to compute the constraint values and analytical gradients is coupled with a generalized reduced gradient algorithm to solve the integrated problem. Numerical results for a geometrically nonlinear shallow dome example problem are presented for various types of imperfections. Furthermore, it is found that the algorithm is capable of detecting and guarding against system as well as element elastic instability using equilibrium information only, that is, without imposing system and local buckling inequality constraints.

Smaoui, H.↗
NASA NTRS1996

A Parametric Study of a Plug Nozzle, Using the Liquid Propellant Program (LPP) Code

The Liquid Propellant Program (LPP) computer code is a super-set of the industry standard Two Dimensional Kinetics (TDK) computer code. The TDK code uses a two dimensional method of characteristics solution with fully coupled finite rate kinetics for axially symmetric nozzles. The chemical reactions are modeled with a generalized reaction package that include three dimensional body efficiencies and four reaction rate forms. The code performs optional solutions for frozen or equilibrium flow. TDK evaluates discrete shocks, both attached or induced. The Transonic module models variable mixture ratio profiles from the combustion chamber injector. The Mass Addition Boundary Layer module (MABL) calculates the boundary parameters with the same chemistry options, and includes transpiration or tangential slot injection of gas at the wall. The LPP upgrades include: planar nozzle, scarfed nozzles, plug nozzles, and scramjet nozzle configurations. The code evaluates both upper and lower wall flow simulation, and includes the interaction with the external flow. The MABL module evaluates equilibrium radiation heat transfer for both upper and lower walls. In addition, LPP code models combustion effects due to injector inefficiencies with the Spray Combustion Analysis Program (SCAP) module. The LPP package provides extensive post plotting capabilities for flow visualization. The LPP is sufficiently fast and robust to provide performance predictions for extensive parametric studies and sufficiently accurate to provide flow field and performance solutions for detailed studies.

Dunn, Stuart S.↗
NASA NTRS1983

Postglacial rebound observed by Lageos and the effective viscosity of the lower mantle

Sixty-four observations of the orbital node made by the Lageos satellite over a five year time interval reveal an acceleration of (-8.1 + or 1.8) x 10 to the -8 power arcseconds day/2 due to a source which is not presently modeled in the GEODYN orbit determination computer program. This acceleration cannot be explained by the ocean tide with 18.6 year period, assuming it to be an equilibrium tide. Instead it seems to be due to postglacial rebound, which changes the J(2) coefficient in the spherical harmonic expansion of the earth's gravitational field at the rate of (-8.2 + or - 18) x 10 to the -19th power/s; this in turn accelerates the node. This rate does not agree with the -32 x 10 to the -19th power/s predicted by Wu and Peltier's (1982) L2 model, which has upper and lower mantle effective viscosities of 10 to the 21st and 22nd powers Pa's, respectively. it does agree well with their L1 model, which gives about 10 x 10 to the 19th power/s. Since the effective viscosity is 10 to the 21st power Pa s throughout the entire mantle in the L1 model, the results support the contentions that the effective viscosity is near 10 to the 21st power Pa s everywhere in the mantle, and this relatively low value for the effective viscosity may have permitted several degrees of polar wander due to glaciation during the Quaternary Ice Age.

Rubincam, D. P.↗
NASA NTRS1984

Postglacial rebound observed by Lageos and the effective viscosity of the lower mantle

Sixty-four observations of the orbital node made by the Lageos satellite over a five year time interval reveal an acceleration of (-8.1 + or - 1.8) x 10 to the -8 power arcseconds day/2 due to a source which is not presently modeled in the GEODYN orbit determination computer program. This acceleration cannot be explained by the ocean tide with 18.6 year period, assuming it to be an equilibrium tide. Instead it seems to be due to postglacial rebound, which changes the J(2) coefficient in the spherical harmonic expansion of the earth's gravitational field at the rate of (-8.2 + or - 18) x 10 to the -19th power/s; this in turn accelerates the node. This rate does not agree with the -32 x 10 to the -19th power/s predicted by Wu and Peltier's (1982) L2 model, which has upper and lower mantle effective viscosities of 10 to the 21st and 22nd powers Pa's, respectively. It does agree well with their L1 model, which gives about 10 x 10 to the 19th power/s. Since the effective viscosity is 10 to the 21st power Pa s throughout the entire mantle in the L1 model, the results support the contentions that the efective viscosity is near 10 to the 21st power Pa s everyhere in the mantle, and this relatively low value for the effective viscosity may have permitted several degrees of polar wander due to glaciation during the Quaternary Ice Age. Previously announced in STAR as N84-13705

Rubincam, D. P.↗
NASA NTRS1988

Fluid-thermal-structural study of aerodynamically heated leading edges

A finite element approach for integrated fluid-thermal-structural analysis of aerodynamically heated leading edges is presented. The Navier-Stokes equations for high speed compressible flow, the energy equation, and the quasi-static equilibrium equations for the leading edge are solved using a single finite element approach in one integrated, vectorized computer program called LIFTS. The fluid-thermal-structural coupling is studied for Mach 6.47 flow over a 3-in diam cylinder for which the flow behavior and the aerothermal loads are calibrated by experimental data. Issues of the thermal-structural response are studied for hydrogen-cooled, super thermal conducting leading edges subjected to intense aerodynamic heating.

Deuchamphai, Pramote↗
NASA NTRS1988

Flow-thermal-structural study of aerodynamically heated leading edges

A finite element approach for integrated fluid-thermal-structural analysis of aerodynamically heated leading edges is presented. The Navier-Stokes equations for high speed compressible flow, the energy equation, and the quasi-static equilibrium equations for the leading edge are solved using a single finite element approach in one integrated, vectorized computer program called LIFTS. The fluid-thermal-structural coupling is studied for Mach 6.47 flow over a 3-inch diameter cylinder for which the flow behavior and the aerothermal loads are calibrated by experimental data. Issues of the thermal-structural response are studied for hydrogen cooled, super thermal conducting leading edges subjected to intense aerodynamic heating.

Dechaumphai, Pramote↗
NASA NTRS1999

Frequency-Dependent Viscosity of Xenon Near the Critical Point

We used a novel, overdamped oscillator aboard the Space Shuttle to measure the viscosity eta of xenon near its critical density rho(sub c), and temperature T(sub c). In microgravity, useful data were obtained within 0.1 mK of T(sub c), corresponding to a reduced temperature t = (T -T(sub c))/T(sub c) = 3 x 10(exp -7). The data extend two decades closer to T(sub c) than the best ground measurements, and they directly reveal the expected power-law behavior eta proportional to t(sup -(nu)z(sub eta)). Here nu is the correlation length exponent, and our result for the small viscosity exponent is z(sub eta) = 0.0690 +/- 0.0006. (All uncertainties are one standard uncertainty.) Our value for z(sub eta) depends only weakly on the form of the viscosity crossover function, and it agrees with the value 0.067 +/- 0.002 obtained from a recent two-loop perturbation expansion. The measurements spanned the frequency range 2 Hz less than or equal to f less than or equal to 12 Hz and revealed viscoelasticity when t less than or equal to 10(exp -1), further from T(sub c) than predicted. The viscoelasticity scales as Af(tau), where tau is the fluctuation-decay time. The fitted value of the viscoelastic time-scale parameter A is 2.0 +/- 0.3 times the result of a one-loop perturbation calculation. Near T(sub c), the xenon's calculated time constant for thermal diffusion exceeded days. Nevertheless, the viscosity results were independent of the xenon's temperature history, indicating that the density was kept near rho(sub c), by judicious choices of the temperature vs. time program. Deliberately bad choices led to large density inhomogeneities. At t greater than 10(exp -5), the xenon approached equilibrium much faster than expected, suggesting that convection driven by microgravity and by electric fields slowly stirred the sample.

Berg, Robert F.↗
DOE OSTI2020

SorpPropLib : An Open-Source Database for Sorption Equilibrium Properties

Hundreds of sorption working pair equilibrium measurements have been reported in the literature, and many experimental results have been fitted to equilibrium equations. However, an open database does not exist for the equilibrium equations. Therefore, this work compiled 438 published equilibrium equations of sorption working pairs into an open-source database called SorpPropLib. SorpPropLib is accessible from six programming environments commonly used in sorption cycle simulation (C++, Excel®, Python®, Matlab®, Modelica® and Lab-VIEW™). Plotting capabilities allow fast cycle visualization in each programming environment. Thereby, the open-source database SorpPropLib aims to enable and encourage easy data sharing to advance sorption research.

Engelpracht, Mirko↗
DOE OSTI2022

A parametric approach to identify synergistic domains of process intensification for reactive separation

Process intensification aims to combine multiple tasks within multi-functional units to drastically improve economic, energy or sustainability metrics of a chemical process. Limited work exists to systematically identify the synergistic domains where intensification outperforms its nonintensified counterpart. In this work, we computationally derive the synergistic domains of a reactive separation system. Specifically, we first postulate general models for both intensified and nonintensified systems. We use these models to generate data to train a ReLU-type artifical neural network (ANN). Further, the trained ReLU-NN model is formulated as a multi-parametric mixed-integer linear program (mp-MILP), and the critical regions of this mp-MILP define the synergistic feasible domains of intensification. We have derived these synergistic domains of vapor–liquid equilibrium (VLE)-based reactive separation for several industrial applications. These synergistic domains enable quick screening of properties that favor intensification.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Preparation and Characterization of Materials for Low- to Intermediate-Temperature CO2 Adsorption

Global carbon dioxide emissions are rising and the use of fossil fuels in several sectors are the leading causes. As global population and economies continue to grow significantly, the most practical method of lowering such emissions is to capture CO2. Although other technologies are more developed, adsorption is very promising and has attracted much attention. To ensure this technology’s success, it is essential to have suitable CO2 adsorbent materials. In this work, several new hydrotalcites (HTs) with different initial concentrations of ion precursors were prepared for the first time by the co-precipitation method—it was possible to verify that the ion concentrations influence the characteristics of the materials. The prepared HTs were characterized by thermogravimetric analysis (TG), X-Ray diffraction (XRD), surface area measurements and temperature-programmed desorption of CO2 (TPD-CO2) to relate their CO2 capture capacity to their physicochemical properties; the CO2 adsorption equilibrium isotherms were determined at 35 and 300 °C for the prepared samples, as well as for some commercial materials: magnesium oxide, calcium oxide, aluminium oxide and Zeolite 13X. After determining which materials present the best CO2 adsorption capacity, these were submitted to adsorption-desorption cycles to study their stability. The main objective of the work was to prepare and study different CO2 adsorbents for processes that are carried out at low and intermediate temperatures. From the experimental results, it was possible to conclude that the Zeolite 13X showed the best capacity at 35 °C, 3.38 mmol·g−1 (@ pCO2 = 1 bar), and a prepared calcined HT (c-HT2) was the best at 300 °C, 0.97 mmol·g−1 (@ pCO2 = 1 bar). Moreover, it seems there is an optimum initial concentration of the ions’ solutions for the tested HTs, which depends on the final application—c-HT1 showed a better capacity at 35 °C and c-HT2 at 300 °C. From the adsorption-desorption cycles—performed at 35 and 300 °C with the best materials using a magnetic suspension microbalance at 1 bar of CO2 partial pressure —, a working cyclic capacity of 2.69 mmol∙g−1 was achieved by the Zeolite at 35 °C; in turn, c-HT2 showed a working cyclic capacity of 0.79 mmol∙g−1 at 300 °C.

Figueiredo, Anabela↗
NASA NTRS1992

Dynamics and energetics of the solar corona

The primary objective of this research program is to improve our understanding of the dynamics and energetics of the solar corona both in the quiescent dynamic equilibrium state when coronal structure is dominated by the equatorial streamer belt and in the eruptive state when coronal plasma is ejected into the interplanetary medium. Numerical solutions of the time-dependent magnetohydrodynamic (MHD) equations and comparisons of the computed results with observations form the core of the approach to achieving this objective. Some of the specific topics that have been studied are: (1) quiescent coronal streamers in an atmosphere dominated by a dipole magnetic field at large radii, (2) the formation of coronal mass ejections (CMEs) in quiescent streamers due to the emergence of new magnetic flux and due to photospheric shear motion, (3) MHD shock formation near the leading edge of CMEs, (4) coronal magnetic arcade eruption as a result of applied photospheric shear motion, and (5) the three-dimensional structure of CMEs.

Steinolfson, R. S.↗
NASA NTRS1992

Heat transfer measurements and CFD comparison of swept shock wave/boundary-layer interactions

An experimental research program providing basic knowledge and establishing new data on the heat transfer in swept shock wave/boundary-layer interactions is described. An equilibrium turbulent boundary-layer on a flat plate is subjected to impingement by swept planar shock waves generated by a sharp fin. Five different interactions with fin angles ranging from 10 to 20 deg at freestream Mach numbers of 3.0 and 4.0 produce a variety of interaction strengths from weak to very strong. A foil heater generates a uniform heat flux over the flat plate surface and miniature thin-film-resistance sensors mounted on it are used to measure the local surface temperature. The heat convection equation is then solved for the heat transfer distribution within an interaction, yielding a total uncertainty of about +/- 10 percent. These experimental data are compared with the results of numerical Navier-Stokes solutions which employ a kappa-epsilon turbulence model. Finally, a simplified form of the peak heat transfer correlation for fin interactions is suggested.

Lee, Y.↗