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At least 253 records · Page 14

Reforming of glucose and wood at the critical conditions of water

Reforming of organics in aqueous solutions is being investigated as a potential waste treatment process. Earlier studies showed that glucose in water reacts to form a gaseous mixture of CO, H2, CH4, CO2, C2H6, and C2H4 in the vicinity of the critical conditions of water (374 C, 22 MPa). The earlier work has been extended to determine the effect of variations in temperature and feed concentration on the extent of gasification. The percent gasification decreases with increasing feed concentration, indicating an overall kinetic order less than unity. Surprisingly, the percent gasification decreases with increasing temperature. A number of preliminary experiments were conducted with maple sawdust feed, which was thought to be representative of complex organic wastes from paper and vegetable matter. Once again, no solid products were found under the critical conditions; the percent gasification ranged from 16 to 88 percent, depending on the feed composition and residence time.

Modell, M.↗

Critical phenomena in a low gravity environment

Various types of critical point phenomena are discussed including the gas-liquid phase transition of a fluid, the spontaneous magnetization of a ferromagnet below the Curie temperature, and structural phase transitions of solid materials. The interrelation of thermodynamic properties by scaling laws is considered noting theories for the validity of scaling laws and the principle of universality. Gravity effects are reviewed noting that in earth-based experiments the phenomena are significantly influenced by the earth's gravitational field and that fluid samples that are spatially homogeneous cannot be realized near the gas-liquid critical point.

Sengers, J. V.↗

The critical points of alloys of iron and cobalt during rapid heating

The influence of the rate of heating on the position of the critical points of iron-cobalt alloys was studied. It is shown that when an alloy with 8% Co by weight is heated at the rate of 7000 deg/sec, a shift in the temperature of phase conversion of almost 30 deg occurs. When an alloy with 15% Co by weight is heated at the same rate, the conversion temperature is shifted by approximately 20 deg. For an alloy with 15% Co by weight, for which under ordinary conditions of heating the points of phase conversion and magnetic randomization (the Curie point) coincide, it was possible to show that for high rates of heating, a separation with respect to temperature occurs which clearly confirms the fact of the shift in the critical points of phase conversion.

Gridnev, V. N.↗

The secondary circulation associated with a vertically aligned planetary wave critical line

An analytic model of the secondary circulation associated with a vertically aligned, energy absorbing, planetary wave critical line shows that strong zonal mean vertical motions and heating (or cooling) can develop even though no eddy transport of heat occurs. The type of secondary circulation which develops around a vertically aligned critical line may provide a mechanism for stratosphere-troposphere exchange of air. The model predictions are discussed with reference to the 76/77 sudden warming.

Schoeberl, M. R.↗

Analytical investigation of critical phenomena in MHD power generators

Critical phenomena in the Arnold Engineering Development Center (AEDC) High Performance Demonstration Experiment (HPDE) and the U.S. U-25 Experiment, are analyzed. The performance of a NASA specified 500 MW(th) flow train is analyzed. Critical phenomena analyzed include: Hall voltage overshoots; optimal load schedules; parametric dependence of the electrode voltage drops; boundary layer behavior; near electrode phenomena with finite electrode segmentation; current distribution in the end regions; scale up rules; optimum Mach number distribution; and the effects of alternative cross sectional shapes.

Source record↗

Spacecraft utility and the development of confidence intervals for criticality of anomalies

The concept of spacecraft utility, a measure of its performance in orbit, is discussed and its formulation is described. Performance is defined in terms of the malfunctions that occur and the criticality to the mission of these malfunctions. Different approaches to establishing average or expected values of criticality are discussed and confidence intervals are developed for parameters used in the computation of utility.

Williams, R. E.↗

Coal gasification systems engineering and analysis. Appendix F: Critical technology items/issues

Critical technology items and issues are defined in which there is a need for developmental research in order to assure technical and economic success for the state of the art of coal gasification in the United States. Technology development needs for the main processing units and the supporting units are discussed. While development needs are shown for a large number of systems, the most critical areas are associated with the gasifier itself and those systems which either feed the gasifier or directly receive products form the gasifier.

Source record↗

Defining critical point experiments for a space laboratory

Three representative low-gravity experiments for a fluid near its liquid-vapor critical point are being defined. Two of these experiments require very careful measurements of properties of the fluid in thermodynamic equilibrium, while the third experiment is a series of optical observations of the phenomena which occur as a fluid is changed from one phase to two phases, either by cooling through the critical point, or by adiabatic expansion. There is concern that residual spacecraft motions may complicate the interpretation of the data from the proposed experiments. It is possible that the Spacelab environment will render certain desirable experiments impractical.

Moldover, M. R.↗

Generalized Roche potential for misaligned binary systems - Properties of the critical lobe

The paper considers the Roche potential for binary systems where the stellar rotation axis is not aligned with the orbital revolution axis. It is shown that, as the degree of misalignment varies, internal Lagrangian points and external Lagrangian points may switch their roles. A systematic method to identify the internal Lagrangian point and to calculate the volume of the critical lobe is developed, and numerical results for a wide range of parameters of binary systems with circular orbits are presented. For binary systems with large enough misalignment, discrete changes occur in the topological structure of the equipotential surfaces as the orbital phase varies. The volume of the critical lobe has minima, as a function of orbital phase, at the two instances when the secondary crosses the equatorial plane of the primary. In semidetached systems, mass transfer may be confined to the vicinity of these two instances.

Avni, Y.↗

Time-critical multirate scheduling using contemporary real-time operating system services

Although real-time operating systems provide many of the task control services necessary to process time-critical applications (i.e., applications with fixed, invariant deadlines), it may still be necessary to provide a scheduling algorithm at a level above the operating system in order to coordinate a set of synchronized, time-critical tasks executing at different cyclic rates. The scheduling requirements for such applications and develops scheduling algorithms using services provided by contemporary real-time operating systems.

Eckhardt, D. E., Jr.↗

Frequency encoded auditory display of the critical tracking task

The use of auditory displays for selected cockpit instruments was examined. In auditory, visual, and combined auditory-visual compensatory displays of a vertical axis, critical tracking task were studied. The visual display encoded vertical error as the position of a dot on a 17.78 cm, center marked CRT. The auditory display encoded vertical error as log frequency with a six octave range; the center point at 1 kHz was marked by a 20-dB amplitude notch, one-third octave wide. Asymptotic performance on the critical tracking task was significantly better when using combined displays rather than the visual only mode. At asymptote, the combined display was slightly, but significantly, better than the visual only mode. The maximum controllable bandwidth using the auditory mode was only 60% of the maximum controllable bandwidth using the visual mode. Redundant cueing increased the rate of improvement of tracking performance, and the asymptotic performance level. This enhancement increases with the amount of redundant cueing used. This effect appears most prominent when the bandwidth of the forcing function is substantially less than the upper limit of controllability frequency.

Stevenson, J.↗

A critical review of noise production models for turbulent, gas-fueled burners

The combustion noise literature for the period between 1952 and early 1984 is critically reviewed. Primary emphasis is placed on past theoretical and semi-empirical attempts to predict or explain observed direct combustion noise characteristics of turbulent, gas-fueled burners; works involving liquid-fueled burners are reviewed only when ideas equally applicable to gas-fueled burners are pesented. The historical development of the most important contemporary direct combustion noise theories is traced, and the theories themselves are compared and criticized. While most theories explain combustion noise production by turbulent flames in terms of randomly distributed acoustic monopoles produced by turbulent mixing of products and reactants, none is able to predict the sound pressure in the acoustic farfield of a practical burner because of the lack of a proven model which relates the combustion noise source strenght at a given frequency to the design and operating parameters of the burner. Recommendations are given for establishing a benchmark-quality data base needed to support the development of such a model.

Mahan, J. R.↗

Turbidity very near the critical point of methanol-cyclohexane mixtures

The turbidity of a critical mixture of methanol and cyclohexane has been measured extremely close to the consolute point. The data span the reduced-temperature range between 10 to the -7th and 10 to the -3d, which is two decades closer to Tc than previous measurements. In this temperature range, the turbidity varies approximately as 1nt, as expected from the integrated form for Ornstein-Zernike scattering. A thin cell (200-micron optical path) with a very small volume (0.08 ml) was used to avoid multiple scattering. A carefully controlled temperature history was used to mix the sample and to minimize the effects of critical wetting layers. The data are consistent with a correlation-length amplitude of 3.9 plus or minus 1.0 A, in agreement with the value 3.5 A calculated from two-scale-factor universality and heat-capacity data from the literature.

Kopelman, R. B.↗

Combining destination diversion decisions and critical in-flight event diagnosis in computer aided testing of pilots

Rockwell and Giffin (1982) and Giffin and Rockwell (1983) have discussed the use of computer aided testing (CAT) in the study of pilot response to critical in-flight events. The present investigation represents an extension of these earlier studies. In testing pilot responses to critical in-flight events, use is made of a Plato-touch CRT system operating on a menu based format. In connection with the typical diagnostic problem, the pilot was presented with symptoms within a flight scenario. In one problem, the pilot has four minutes for obtaining the information which is needed to make a diagnosis of the problem. In the reported research, the attempt has been made to combine both diagnosis and diversion scenario into a single computer aided test. Tests with nine subjects were conducted. The obtained results and their significance are discussed.

Rockwell, T. H.↗

Interfacial tension of fluids near critical points and two-scale-factor universality

Measurements of interfacial tension in the critical region of a wide variety of fluids are reviewed. The data are analyzed using theoretical values of the critical exponents to obtain amplitude ratios. Many of the data are consistent within a few percent of sigma(0). Comparison of these amplitude ratios with ratios from a field-theory calculation and from a simulation suggests that the theoretical values are about half the experimental ones. Systematic errors which are the source of this discrepancy are discussed. The data sources and processing procedures of this study are also discussed, pointing out that for liquid-vapor systems the capillary length often has a remarkably simple temperature dependence.

Moldover, M. R.↗

Review of the critical ionization velocity effect in space

Laboratory experiments have shown under a variety of conditions that when a neutral gas passes through a magnetized plasma with a relative velocity perpendicular to the magnetic field that is greater than a critical velocity, anomalously high ionization of the neutrals occurs. The conditions under which the same effect is to be expected in space plasmas is still unclear. The experimental evidence for the occurrence of the critical ionization velocity effect in space is summarized, and various areas in which it has been proposed that the effect should be significant are discussed.

Newell, P. T.↗

Competing atomic processes in Ba and Sr injection critical velocity experiments

The critical ionization velocity effect requires a superthermal electron population to ionize through collisional impact. Such superthermal electrons can however lose energy to competing atomic processes, as well as to ionization, thus limiting the efficiency of the effect. Considering Ba and Sr magnetospheric injection experiments designed to test the CIV theory, it is found that in both cases roughly 60 percent of the superthermal electron energy is lost on exciting line radiation. Moreover, energy loss to background neutral oxygen places a strict limit on the injected cloud densities for which critical velocity effects are possible; a finding which explains the consistently negative results in radial injection experiments.

Newell, P. T.↗

A parametric study of slow shock Rankine-Hugoniot solutions and critical Mach numbers

The relationship between Rankine-Hugoniot solutions and critical Mach numbers is studied. The range of upstream parameters for which the resistivity or thermal conduction provide all the dissipation required by the slow shock Rankine-Hugoniot relations are evaluated. The calculation of the critical Mach number by analyzing the flux of shock catching ions is examined. It is observed that the properties of slow shocks depend on shock normal angle, and the ratio of the sound and Alfven speeds upstream. The Rankine-Hugoniot solutions are applicable to the analysis of spacecraft observations of slow shocks.

Edmiston, J. P.↗