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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Controlled dehumidification to extract clean water from a multicomponent gaseous mixture of organic contaminants

Rapid expansion of the unconventional oil and gas extraction has increased American energy independence, but also led to increased production of large amounts of contaminated water. Wastewater from the oil and gas industry contains a wide range of contaminants. Injecting such contaminated water into disposal wells or discharging it to the environment jeopardizes freshwater resources. Conventional and membrane-based wastewater treatment techniques are often not effective choices to treat highly contaminated wastewater; however, a suitable way to remove contaminants from wastewater is to selectively separate water in a process analogous to humidification-dehumidification (HDH). Only a few studies have investigated the use of HDH for wastewater treatment. In this study, a novel HDH system is introduced for treating highly contaminated water, such as oil and gas flowback and produced water. In this HDH process, a non-condensable gas, such as air, mixes with wastewater vapor to facilitate the separation of contaminants. As a result, clean water condenses from the multicomponent gaseous mixture while air carries organic contaminants out of the dehumidification section. A laboratory apparatus was constructed and experiments were performed to investigate the HDH process for wastewater treatment and to study the effects of flow dynamics including air flow rate on the composition of treated water. Different contaminants including benzene, toluene, 2-propanol and 2-butoxyethanol were tested. Experimental results showed that the system can be successfully applied for removing volatile and/or toxic organic contaminants from wastewater. A representative multicomponent mixture of fracking wastewater was successfully treated using the experimental setup and clean water with quality of 98.3% was obtained. It was revealed that increasing the air-to-vapor mass ratio improves purity of treated water. Quantitative analysis showed that by increasing the air-to-vapor mass ratio from 0.6 to 5.9, the fraction of separated 2-propanol through the air was improved from 43% to more than 96% of the initial amount. ASPEN software was employed to simulate equilibrium conditions. Finally, experimental results were observed to have lower mass fraction of residual contaminant in the treated water compared to equilibrium state.

42 ENGINEERING↗
DOE OSTI2015

Post-closure program streamlining at the Nevada national security site - 15290

More than 200 sites on the Nevada National Security Site (NNSS), Nevada Test and Training Range (NTTR), and Tonopah Test Range (TTR) have been closed in place. At these sites, contamination has been left in place, and protection of human health, safety, and the environment is ensured through the establishment of use restrictions (URs). Post-closure requirements were initially established in the Closure Report (CR) for each site and include a variety of inspection, monitoring, maintenance, and reporting commitments. Post-closure requirements and site controls (fences, monuments, soil covers, and postings) may vary depending on site location, accessibility, land use scenario, and the nature of contaminants left in place. Corrective Action Sites (CASs) on the NNSS, NTTR, and TTR have been identified for closure under the Federal Facility Agreement and Consent Order (FFACO), which was signed in 1996. Over 1,900 CASs have been closed under the framework of the FFACO, and more than 200 of those have URs. Many post-closure requirements have been modified over time. In addition, because the scope of the program has spanned almost 20 years, the post-closure requirements have varied due to changing strategies and expectations. Because of the number of sites closed over the course of the program, post-closure requirements are found in hundreds of closure documents, addendums, errata sheets, Records of Technical Change, inspection reports, permit modifications, and correspondence. Furthermore, resources such as personnel and funding necessary to conduct the post-closure program have diminished, while computer capabilities and configuration control principles have improved since closure activities under the FFACO began. Because of these factors, to effectively manage the post-closure program, ensure that all commitments are being met, and improve the ease of identifying the most current post-closure requirements for each UR, the current requirements for every use-restricted site under the purview of the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office will be consolidated into a single Post-Closure Plan. The Consolidated Post-Closure Plan will also outline a strategy and present possible criteria that may be used for future evaluation of post-closure requirements. Continual assessment of the post-closure program will ensure that the post-closure requirements for URs across the NNSS, NTTR, and TTR are consistently justifiable and sufficient to protect site workers, the public, and the environment while increasing efficiency. Future changes to post-closure requirements and justification for those changes will be recorded in revisions to the Consolidated Post-Closure Plan. This process will provide a comprehensive, consistent, and streamlined method for evaluation of post-closure requirements and implementation of changes. (authors)

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Synthesis and characterization of redox-active ferric nontronite

Heterogeneous redox reactions on clay mineral surfaces control mobility and bioavailability of redox-sensitive nutrients and contaminants. Iron (Fe) residing in clay mineral structures can either catalyze or directly participate in redox reactions; however, chemical controls over its reactivity are not fully understood. In our previous work we demonstrated that converting a minor portion of Fe(III) to Fe(II) (partial reduction) in the octahedral sheet of natural Fe-rich clay mineral nontronite (NAu-1) activates its surface, making it redox-active. In this study we produced and characterized synthetic ferric nontronite (SIP), highlighting structural and chemical similarities and differences between this synthetic nontronite and its natural counterpart NAu-1, and probed whether mineral surface is redox-active by reacting it with arsenic As(III) under oxic and anoxic conditions. We demonstrate that synthetic nontronite SIP undergoes the same activation as natural nontronite NAu-1 following the partial reduction treatment. Similar to NAu-1, SIP oxidized As(III) to As(V) under both oxic (catalytic pathway) and anoxic (direct oxidation) conditions. The similar reactivity trends observed for synthetic nontronite and its natural counterpart make SIP an appropriate analog for laboratory studies. The development of chemically pure analogs for ubiquitous soil minerals will allow for systematic research of the fundamental properties of these minerals.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2016

Validation of picogram- and femtogram-input DNA libraries for microscale metagenomics

High-throughput sequencing libraries are typically limited by the requirement for nanograms to micrograms of input DNA. This bottleneck impedes the microscale analysis of ecosystems and the exploration of low biomass samples. Current methods for amplifying environmental DNA to bypass this bottleneck introduce considerable bias into metagenomic profiles. For this study, we describe and validate a simple modification of the Illumina Nextera XT DNA library preparation kit which allows creation of shotgun libraries from sub-nanogram amounts of input DNA. Community composition was reproducible down to 100 fg of input DNA based on analysis of a mock community comprising 54 phylogenetically diverse Bacteria and Archaea. The main technical issues with the low input libraries were a greater potential for contamination, limited DNA complexity which has a direct effect on assembly and binning, and an associated higher percentage of read duplicates. We recommend a lower limit of 1 pg (~100–1,000 microbial cells) to ensure community composition fidelity, and the inclusion of negative controls to identify reagent-specific contaminants. Applying the approach to marine surface water, pronounced differences were observed between bacterial community profiles of microliter volume samples, which we attribute to biological variation. This result is consistent with expected microscale patchiness in marine communities. We thus envision that our benchmarked, slightly modified low input DNA protocol will be beneficial for microscale and low biomass metagenomics.

100 fg↗
DOE OSTI2018

Evaluation of Potential Dose to Off-site Receptors from On-site Removable Contamination - 18521

Calculations used in making corrective action decisions estimate the maximum potential dose to on-site receptors exposed to contamination from nuclear testing activities at U.S. Department of Energy, Environmental Management Nevada Program Soils Activity release sites. At many of these release sites, removable contamination is present at levels that require controls to be in place under Title 10 Code of Federal Regulations Part 835, 'Occupational Radiation Protection.' When significant levels of removable contamination are present at a release site, it may be necessary to evaluate the potential dose to off-site receptors from removable contamination that has the potential to be transported off the contaminated site. The protocols described herein could be used to evaluate the potential dose to off-site receptors to ensure that corrective action decisions consider both on-site and off-site potential receptors. The calculation of estimated dose to a receptor can be accomplished by establishing a scenario that describes the exposure (e.g., time and pathway) of the individual to the radiological contamination and by using the properties of the contaminants (e.g., dose conversion factors). Radiological contamination transported from the site has the potential to expose off-site receptors under a potentially large number of exposure scenarios that cannot be comprehensively defined. However, a scenario was developed to represent a maximally exposed off-site receptor. Because the estimated dose to the maximally exposed off-site receptor based on maximum post-closure release site activity levels is less than the on-site dose decision level, corrective action decisions at the Nevada National Security Site Soils Activity release sites are also protective of potential off-site receptors when significant levels of removable contamination are present. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Evaluation of Gaseous Substrates for Microbial Immobilization of Contaminant Mixtures in Unsaturated Subsurface Sediments

Extensive vadose zone metals and organic contamination remains at many former industrial and defense manufacturing sites, and effective remedial solutions are needed to slow or prevent its migration to groundwater. In this study, the application of gaseous substrates to stimulate microbial respiratory reduction of comingled radioisotopes and nitrate under unsaturated conditions was examined for possible application at the Hanford Site, a former nuclear production facility in southeastern WA, USA. First, screening studies were performed to qualitatively measure the sediment respiratory response to 14 gaseous or volatile organic substrates at two moisture contents, 4% and 8%. Volatile substrates produced the strongest respiratory response, among them were butyrate, pentane, butyl acetate. Ethane and butane were the most effective gaseous substrates but only at 8% water content. Hanford sediment from two waste sites with distinctive chemistries were wetted to 7% moisture content, packed into columns, and treated with ethane or butane. After 4 weeks, columns were then leached to quantify retardation in the mobility of aqueous contaminant concentrations compared to no gas control columns. Treatment with both gases resulted in >80% removal of Cr from the aqueous phase. However, NO3 concentration and a waste sites exposure history to NO3 had a major effect on U and Tc reduction. Incomplete nitrate reduction outcompeted U and Tc in waste site sediments having limited prior exposure to NO3. Conversely, waste site sediments co-contaminated with NO3 were able to achieve highly reduced conditions resulting in complete denitrification of NO3, and delayed leaching of U and Tc. This implied effective reduction of both contaminants to less mobile species. This study demonstrates that unsaturated vadose sediments at Hanford waste sites have the capacity for a sustained respiratory response to gaseous substrate injection, which could potentially be deployed as part of an overall strategy to reduce the flux of long-lived radionuclides to groundwater at Hanford and other legacy waste sites.

Bagwell, Christopher E.↗
DOE OSTI2019

Optimizing Long-term Monitoring of Radiation Air Dose Rates - 19169

Radiation air dose rates near the Fukushima Daiichi Nuclear Power Plant (NPP) have been steadily decreasing over the past seven years since the accident in March 2011. After seven years, the radiation monitoring program is expected to transition from short-term emergency responses to long-term monitoring. The objectives of long-term monitoring are often different from early emergency responses, since extensive data accumulation has led to an understanding of contaminant distributions and mobility. The main long-term monitoring objectives are (1) to confirm system stability and the continuing reduction of contaminant and hazard levels, (2) to provide assurance for the public, (3) to accumulate the basic datasets for scientific knowledge and future preparation, and (4) to detect changes or anomalies in contaminant mobility (if they occur), or any unexpected processes or events. In this work, we have developed a methodology for optimizing the sampling locations of radiation air dose-rate monitoring. Three steps are taken in order to determine sampling locations in a systematic manner: (1) prioritizing the critical locations, such as schools or regulatory requirement locations, (2) diversifying locations across the key environmental controls that are known to influence contaminant mobility and distributions, and (3) capturing the heterogeneity of radiation air dose rates across the domain. In the second step, we use a Gaussian mixture model to identify the representative locations in multiple environmental variables, such as elevation and land-cover types. In the third step, we use a Gaussian process model to capture and estimate the heterogeneity of air dose rates across the domain. We use the integrated dose-rate map from the Bayesian geostatistical method as the reference map and distribute the sampling in such a way as to capture the heterogeneity of the reference map. Although we assume hypothetical sets of measurement locations to evaluate the performance of the methodology and algorithms, we have demonstrated this approach using real, spatially extensive datasets, including the integrated air-dose-rate map of 2016. Our results have shown that this approach allows us to add sampling locations in a systematic manner. Increasing the number of sampling locations can better capture the heterogeneity of dose rates, although the estimation error does not decrease further after a certain number of samples. We have also found that when there are restrictions such as pre-existing monitoring locations or the ones along roads, the spatial estimation becomes poor even with the same number of monitoring locations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

HOW TO FIND GRAVITATIONALLY LENSED TYPE Ia SUPERNOVAE

Type Ia supernovae (SNe Ia) that are multiply imaged by gravitational lensing can extend the SN Ia Hubble diagram to very high redshifts ( z ≳ 2), probe potential SN Ia evolution, and deliver high-precision constraints on H {sub 0}, w , and Ω{sub m} via time delays. However, only one, iPTF16geu, has been found to date, and many more are needed to achieve these goals. To increase the multiply imaged SN Ia discovery rate, we present a simple algorithm for identifying gravitationally lensed SN Ia candidates in cadenced, wide-field optical imaging surveys. The technique is to look for supernovae that appear to be hosted by elliptical galaxies, but that have absolute magnitudes implied by the apparent hosts’ photometric redshifts that are far brighter than the absolute magnitudes of normal SNe Ia (the brightest type of supernovae found in elliptical galaxies). Importantly, this purely photometric method does not require the ability to resolve the lensed images for discovery. Active galactic nuclei, the primary sources of contamination that affect the method, can be controlled using catalog cross-matches and color cuts. Highly magnified core-collapse SNe will also be discovered as a byproduct of the method. Using a Monte Carlo simulation, we forecast that the Large Synoptic Survey Telescope can discover up to 500 multiply imaged SNe Ia using this technique in a 10 year z -band search, more than an order of magnitude improvement over previous estimates. We also predict that the Zwicky Transient Facility should find up to 10 multiply imaged SNe Ia using this technique in a 3 year R -band search—despite the fact that this survey will not resolve a single system.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Optimizing long-term monitoring of radiation air-dose rates after the Fukushima Daiichi Nuclear Power Plant

Radiation air dose rates near the Fukushima Daiichi Nuclear Power Plant (FDNPP) have been steadily decreasing over the past eight years since the release of radioactive elements in March 2011. Currently, the radiation monitoring program is expected to transition to long-term monitoring after most of the remediation activities are completed. The main long-term monitoring objectives are to (1) confirm the continuing reduction of contaminant and hazard levels, (2) provide assurance for the public, (3) accumulate the basic datasets for scientific knowledge and future preparation, and (4) detect changes or anomalies in contaminant mobility (if they occur), or any unexpected processes or events. In this work, we have developed a methodology for optimizing the monitoring locations of radiation air dose-rate monitoring. Our approach consists of three steps in order to determine monitoring locations in a systematic manner: (1) prioritizing the critical locations, such as schools or regulatory requirement locations, (2) diversifying locations that cover the key environmental controls that are known to influence contaminant mobility and distributions, and (3) capturing the heterogeneity of radiation air-dose rates across the domain. Therefore, for the second step, we use a Gaussian mixture model to identify the representative locations among multiple environmental variables, such as elevation and land-cover types. For the third step, we use a Gaussian process model to capture and estimate the heterogeneity of air-dose rates across the domain. Employing an integrated dose-rate map derived from Bayesian geostatistical methods as a reference map, we distribute the monitoring locations in such a way as to capture the heterogeneity of the reference map. Our results have shown that this approach allows us to select monitoring locations in a systematic manner such that the heterogeneity of air dose rates is captured by the minimal number of monitoring locations.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2022

Solubility controls on plutonium and americium release in subsurface environments exposed to acidic processing wastes

To identify the role of waste composition and sediment interactions in controlling Pu and Am mobility in contaminated sediments at Hanford, a legacy nuclear site, Pu and Am concentrations in solutions equilibrated with contaminated sediments from beneath the 216-Z-9 (Z-9) Trench were compared to the solubilities of PuO 2 materials, synthesized by methods representative of the disposed wastes, in the absence of sediments. Furthermore, this work shows that the solubilities of PuO 2 materials synthesized by different methods, and with varying particle sizes, agree with PuO 2 (am,hyd), although dissolution kinetics differed between materials. According to saturation index (SI) calculations, PuO 2 (am,hyd) is likely also controlling Pu release from sediments under conditions where phosphate concentrations are low. However, both Pu-phosphate and Am-phosphate phases, identified in SI calculations and by high resolution transmission electron microscopy, play roles in controlling release in low pH, high phosphate, shallow sediments just below the Z-9 Trench. The elevated phosphate is likely due to decomposition of tributyl phosphate from waste solutions over time. Sediments from deeper in the subsurface beneath the Z-9 Trench are less acidic and contain less phosphate, with Pu solubility likely controlled by PuO 2 (am,hyd) that precipitated following neutralization of the acidic waste stream. Controls on Am concentrations in deeper sediments are more complex and potentially involve sediment adsorption and/or release from Pu (1-x) Am x O 2 following Am in-growth. The concentrations of both Pu and Am were elevated in the colloidal fraction associated with shallow sediments, but not in PuO 2 experiments, suggesting the presence of Pu/Am pseudocolloids (e.g., Pu/Am associated with mineral colloids). However, Pu and Am association with the colloidal size fraction was not observed in deeper sediments, suggesting transport of Pu and Am to these depths beneath the Z-9 Trench was not due to colloidal transport.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2015

Quo vadis? Microbial profiling revealed strong effects of cleanroom maintenance and routes of contamination in indoor environments

Space agencies maintain highly controlled cleanrooms to ensure the demands of planetary protection. To study potential effects of microbiome control, we analyzed microbial communities in two particulate-controlled cleanrooms (ISO 5 and ISO 8) and two vicinal uncontrolled areas (office, changing room) by cultivation and 16S rRNA gene amplicon analysis (cloning, pyrotagsequencing, and PhyloChip G3 analysis). Maintenance procedures affected the microbiome on total abundance and microbial community structure concerning richness, diversity and relative abundance of certain taxa. Cleanroom areas were found to be mainly predominated by potentially human-associated bacteria; archaeal signatures were detected in every area. Results indicate that microorganisms were mainly spread from the changing room (68%) into the cleanrooms, potentially carried along with human activity. The numbers of colony forming units were reduced by up to ~400 fold from the uncontrolled areas towards the ISO 5 cleanroom, accompanied with a reduction of the living portion of microorganisms from 45% (changing area) to 1% of total 16S rRNA gene signatures as revealed via propidium monoazide treatment of the samples. Our results demonstrate the strong effects of cleanroom maintenance on microbial communities in indoor environments and can be used to improve the design and operation of biologically controlled cleanrooms.

42 ENGINEERING↗
DOE OSTI2013

In Situ Decommissioning (ISD) Concepts and Approaches for Excess Nuclear Facilities Decommissioning End State - 13367

The United States Department of Energy (DOE) currently has numerous radiologically contaminated excess nuclear facilities waiting decommissioning throughout the Complex. The traditional decommissioning end state is complete removal. This commonly involves demolishing the facility, often segregating various components and building materials and disposing of the highly contaminated, massive structures containing tons of highly contaminated equipment and piping in a (controlled and approved) landfill, at times hundreds of miles from the facility location. Traditional demolition is costly, and results in significant risks to workers, as well as risks and costs associated with transporting the materials to a disposal site. In situ decommissioning (ISD or entombment) is a viable alternative to demolition, offering comparable and potentially more protective protection of human health and the environment, but at a significantly reduced cost and worker risk. The Savannah River Site (SRS) has completed the initial ISD deployment for radiologically contaminated facilities. Two reactor (P and R Reactors) facilities were decommissioned in 2011 using the ISD approach through the American Recovery and Reinvestment Act. The SRS ISD approach resolved programmatic, regulatory and technical/engineering issues associated with avoiding the potential hazards and cost associated with generating and disposing of an estimated 124,300 metric tons (153,000 m{sup 3}) of contaminated debris per reactor. The DOE Environmental Management Office of Deactivation and Decommissioning and Facility Engineering, through the Savannah River National Laboratory, is currently investigating potential monitoring techniques and strategies to assess ISD effectiveness. As part of SRS's strategic planning, the site is seeking to leverage in situ decommissioning concepts, approaches and facilities to conduct research, design end states, and assist in regulatory interactions in broad national and international government and private industry decommissioning applications. SRS offers critical services based upon the SRS experience in decommissioning and reactor entombment technology (e.g., grout formulations for varying conditions, structural and material sciences). The SRS ISD approach follows a systems engineering framework to achieve a regulatory acceptable end state based on established protocols, attains the final end state with minimal long stewardship requirements, protects industrial workers, and protects groundwater and the environment. The ISD systems engineering framework addresses key areas of the remedial process planning, technology development and deployment, and assessment to attain the ultimate goal of natural resource stewardship and protecting the public. The development and deployment of the SRS ISD approach has established a path for ISD of other large nuclear facilities in the United States and around the globe as an acceptable remedial alternative for decommissioning nuclear facilities. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Frisker Response to Soil Concentrations (Bq/g) Compared to NaI(Tl) - 19338

The Chalk River Laboratories (CRL) began nuclear operations in 1947. Portions of the site land areas have become radiologically contaminated through the 1952 National Reactor Experimental (NRX) accident and/or waste management activities over the past 70 years of site operations. The Environmental Remediation Projects Group (ERP) characterizes, and performs risk assessment, and remedial actions, as required over these contaminated land areas. ERP work activities are subject to controls established by CRL's Radiation Protection (RP) Group such that RP establishes the radiological controls and monitoring requirements for ERP field work activities. The different methods of monitoring soil contamination between ERP and the RP program present some challenges in the interpretation and comparison of the two sets of results and the soil disposition. ERP utilizes NaI(Tl) scintillation detectors and MARSSIM land scanning techniques to measure soil concentrations between sample locations and in excavated materials. Whereas, RP utilizes surface contamination monitoring equipment in the form of a 15.5 cm{sup 2} open area pancake Geiger-Mueller (GM) tube detector to measure soil contamination levels reported in counts per minute (cpm). This paper presents a method to evaluate the theoretical best responses that could be obtained from surface contamination monitoring instrumentation for a known concentration (1 Bq/g) of various radionuclides. A static efficiency of cpm/Bq{sup -1} g{sup -1} is obtained from these calculations. These contamination monitoring sensitivities are then used in a MARSSIM scanning sensitivity equation and compared to the scanning sensitivity of an NaI(Tl) scintillation detector. The results demonstrate that the sensitivity of the frisker probes to particle radiations (betas for pancake) tend to fall in a range of only a few cpm/Bq{sup -1} g{sup -1}. Rather, the primary static response of the pancake probe to soil contamination is from gamma radiation where a value of 36 cpm/Bq{sup -1} g{sup -1} for Cs-137 was obtained at 2.54 cm distance without the application of scanning statistics. In comparison, a 7.6 cm x 7.6 cm NaI(Tl) detector has a Cs-137 static response factor of 10,000 cpm/Bq{sup -1} g{sup -1} at 15 cm distance without applying scanning statistics. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

The LUX-ZEPLIN (LZ) radioactivity and cleanliness control programs

LUX-ZEPLIN (LZ) is a second-generation direct dark matter experiment with spin-independent WIMP-nucleon scattering sensitivity above 1.4×10 –48 cm 2 for a WIMP mass of 40GeV/c 2 and a 1000 days exposure. LZ achieves this sensitivity through a combination of a large 5.6 t fiducial volume, active inner and outer veto systems, and radio-pure construction using materials with inherently low radioactivity content. The LZ collaboration performed an extensive radioassay campaign over a period of six years to inform material selection for construction and provide an input to the experimental background model against which any possible signal excess may be evaluated. The campaign and its results are described in this paper. We present assays of dust and radon daughters depositing on the surface of components as well as cleanliness controls necessary to maintain background expectations through detector construction and assembly. Finally, examples from the campaign to highlight fixed contaminant radioassays for the LZ photomultiplier tubes, quality control and quality assurance procedures through fabrication, radon emanation measurements of major sub-systems, and bespoke detector systems to assay scintillator are presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Erratum to: The LUX-ZEPLIN (LZ) radioactivity and cleanliness control programs

LUX-ZEPLIN (LZ) is a second-generation direct dark matter experiment with spin-independent WIMP-nucleon scattering sensitivity above 1.4 × 10 -48 cm 2 for a WIMP mass of 40 GeV/c 2 and a 1000 d exposure. LZ achieves this sensitivity through a combination of a large 5.6 t fiducial volume, active inner and outer veto systems, and radio-pure construction using materials with inherently low radioactivity content. The LZ collaboration performed an extensive radioassay campaign over a period of six years to inform material selection for construction and provide an input to the experimental background model against which any possible signal excess may be evaluated. The campaign and its results are described in this paper. We present assays of dust and radon daughters depositing on the surface of components as well as cleanliness controls necessary to maintain background expectations through detector construction and assembly. Finally, examples from the campaign to highlight fixed contaminant radioassays for the LZ photomultiplier tubes, quality control and quality assurance procedures through fabrication, radon emanation measurements of major sub-systems, and be spoke detector systems to assay scintillator are presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Effect of Iron Contamination and Polysilicon Gettering on the Performance of Polysilicon‐Based Passivating Contact Solar Cells

Over the past decade, silicon solar cells with carrier-selective passivating contacts based on polysilicon capping an ultra-thin silicon oxide (commonly known as TOPCon or POLO) have demonstrated promising efficiency potentials and are regarded as an evolutionary upgrade to the PERC (passivated emitter and rear contact) cells in manufacturing. The polysilicon-based passivating contacts also exhibit excellent gettering effects that relax the wafer and cleanroom requirements to some extent. Here, in this work, we experimentally explore the impact of bulk iron contamination and polysilicon gettering on the passivation quality of the polysilicon/oxide structure and the resulting solar cells performance. Results show that both n- and p-type polysilicon/oxide passivating contacts are not affected by iron gettering, demonstrating robust and stable passivation quality. However, for a very high bulk iron contamination (1 × 10 13 cm −3 ), the accumulated iron in the p-type lightly boron-doped emitter in crystalline silicon would degrade the emitter saturation current density. This can cause a reduction in both open-circuit voltage and short-circuit current. Meanwhile, this very high iron content (1 × 10 13 cm −3 ) can further degrade the fill factor and temperature coefficient of the cells. On the other hand, for an initial iron content of 2 × 10 12 cm −3 , which should be well above the iron level in the current industrial Czochralski silicon wafers, the resulting cells demonstrate similar performance as the control group with no intentional iron contamination. This work brings attention to both the benefits of polysilicon gettering effects as well as the potential degradation due to the accumulation of metal impurities in the p-type emitter region.

14 SOLAR ENERGY↗
DOE OSTI2019

Sources and Assessment of Mercury and Other Heavy Metal Contamination in Soils Surrounding the Wuda Underground Coal Fire Area, Inner Mongolia, China

Concentrations of mercury and other heavy metals were measured in soils surrounding the Wuda Coalfield, Inner Mongolia where underground coal fires are regarded as an important contamination source. Soil samples at the downwind direction were nearly all enriched mercury in surface layers, with their concentrations ~ 10 times higher than those from upwind soils. Mercury concentrations generally increased along soil profiles upward, indicative of increasing atmospheric mercury deposition in recent decades. We suggest that underground coal fire emissions were the potential mercury contamination source and the key factor controlling mercury enrichment in soils. Other heavy metals showed no clear spatial and vertical trends, suggesting that underground coal fire emissions may not the main factor for their enrichment in soils. Antimony showed the highest enrichment followed by tin, while chromium, mercury and cadmium only exhibited slight enrichment. Risk evaluation indicated that heavy metals in the studied soils pose no ecological threats.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

The Relative Importance of Saturated Silica Sand Interfacial and Pore Fluid Geochemistry on the Spectral Induced Polarization Response

Adsorption at the solid-pore fluid interface is a key mechanism controlling the mobility of nutrients and contaminants in subsurface soils and sediments. The spectral induced polarization (SIP) method has been shown to be sensitive to the quantity and type of adsorbed ions. Extending previous results, we investigated the relevance of pH, solution conductivity, and ion type on the SIP response of saturated silica sand. We also performed adsorption experiments to evaluate whether adsorption plays a relevant role on the effect of saturating solution conductivity and pH. Given their environmental relevance and different electrochemical characteristics, we focused on exploring the influence of Cu 2+ and Na + adsorption on the SIP signature. The adsorption results confirm the expected and modeled pH influence on the adsorption of both Cu 2+ and Na + . The measured quadrature conductivity spectra indicate that pH and solution conductivity control the electrical double layer electrochemical state and its capacitive behavior. On the contrary, no appreciable SIP signal changes are associated with ion substitution. The adsorption experiments highlight low values of site occupancy for Na and Cu, which suggests that the effects of pH and fluid conductivity are unrelated to their control on the ion adsorption. We interpret the solution conductivity as a proxy for ionic strength. The relative importance of pH and solution conductivity over ion type helps to further constrain the interpretation of SIP results in field geochemical and biogeochemical characterization and monitoring.

58 GEOSCIENCES↗